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    • 1. 发明授权
    • Resinous polymer sheet materials having selective, surface decorative
effects and methods of making the same
    • US4248922A
    • 1981-02-03
    • US62432
    • 1979-07-30
    • Harry A. ShortwayAlan A. GrahamCharles H. Miller
    • Harry A. ShortwayAlan A. GrahamCharles H. Miller
    • B32B5/20D06N7/00B32B31/22B32B31/26
    • B32B5/20D06N7/0002D06N7/0013D06N2209/0838D06N2211/12D06N2211/14D06N2211/263Y10S264/82Y10T156/1039Y10T156/1041Y10T428/24504Y10T428/24612Y10T428/24868Y10T428/249992Y10T428/31935
    • Resinous polymer sheet materials having selective, surface decorative effects comprising:(1) a base layer or substrate, such as a fibrous backing sheet material and/or a blown or unblown resinous polymer composition having either an embossed or a relatively smooth surface;(2) a pattern or design printed or otherwise deposited on and adhered to the base layer or substrate, certain portions of the printed pattern or design having certain colors, and other portions of the printed pattern or design having other colors; and(3) a wear layer having an embossed or a relatively smooth surface and containing reactive polymerizable monomers and having certain surface portions provided with a certain texture or effect, such as a flat, dead or dull mat finish, and other surface portions provided with another texture or effect, such as a sleek, glossy or lustrous finish, the interior portions of the wear layer lying under the flat, dead or dull mat finish having a relatively high melt viscosity and containing relatively high concentrations of polymerized and/or cross-linked reactive polymerizable monomers, and the interior portions of the wear layer lying under the sleek, glossy or lustrous finish having either (a) a relatively low melt viscosity and containing substantially no significant or substantial concentrations of polymerized and/or cross-linked reactive polymerizable monomers, or (b) a relatively high melt viscosity and containing relatively high concentrations of polymerized and/or cross-linked reactive polymerizable monomers.(i) the certain colors of the printed pattern or design, and (ii) the flat, dead or dull mat finish areas, and (iii) the interior portions of the wear layer having a relatively high melt viscosity and containing the relatively high concentrations of the polymerized and/or cross-linked reactive polymerizable monomers all being in substantially perfect registry, and(i) the other colors of the printed pattern or design, and (ii) the sleek, glossy or lustrous finish areas, and (iii) the interior portions of the wear layer having a relatively low melt viscosity and containing relatively low or no concentrations of polymerized and/or cross-linked reactive polymerizable monomers also all being in substantially perfect registry.
    • 2. 发明授权
    • Resinous polymer sheet materials having selective, surface decorative
effects and methods of making the same
    • US4217385A
    • 1980-08-12
    • US5632
    • 1979-01-22
    • Harry A. ShortwayAlan A. GrahamCharles H. Miller
    • Harry A. ShortwayAlan A. GrahamCharles H. Miller
    • B32B5/20B44C1/20B44C1/24D06N3/06D06N3/08D06N7/00B32B31/22B32B31/26
    • D06N7/0013B32B5/20B44C1/205B44C1/24D06N3/06D06N3/08D06N7/001Y10S264/82Y10T156/1039Y10T156/1041Y10T428/24504Y10T428/24612Y10T428/24868Y10T428/249992Y10T428/31935
    • Resinous polymer sheet materials having selective, surface decorative effects comprising:(1) a base layer or substrate, such as a fibrous backing sheet material and/or a blown or unblown resinous polymer composition having either an embossed or a relatively smooth surface;(2) a pattern or design printed or otherwise deposited on and adhered to the base layer or substrate, certain portions of the printed pattern or design having certain colors, and other portions of the printed pattern or design having other colors; and(3) a wear layer having an embossed or a relatively smooth surface and containing reactive polymerizable monomers and having certain surface portions provided with a certain texture or effect, such as a flat, dead or dull mat finish, and other surface portions provided with another texture or effect, such as a sleek, glossy or lustrous finish, the interior portions of the wear layer lying under the flat, dead or dull mat finish having a relatively high melt viscosity and containing relatively high concentrations of polymerized and/or cross-linked reactive polymerizable monomers, and the interior portions of the wear layer lying under the sleek, glossy or lustrous finish having either (a) a relatively low melt viscosity and containing substantially no significant or substantial concentrations of polymerized and/or cross-linked reactive polymerizable monomers, or (b) a relatively high melt viscosity and containing relatively high concentrations of polymerized and/or cross-linked reactive polymerizable monomers,(i) the certain colors of the printed pattern or design, and (ii) the flat, dead or dull mat finish areas, and (iii) the interior portions of the wear layer having a relatively high melt viscosity and containing the relatively high concentrations of the polymerized and/or cross-linked reactive polymerizable monomers all being in substantially perfect registry, and(i) the other colors of the printed pattern or design, and (ii) the sleek, glossy or lustrous finish areas, and (iii) the interior portions of the wear layer having a relatively low melt viscosity and containing relatively low or no concentrations of polymerized and/or cross-linked reactive polymerizable monomers also all being in substantially perfect registry.
    • 3. 发明授权
    • Resinous polymer sheet materials having surface decorative effects and
methods of making the same
    • US4214028A
    • 1980-07-22
    • US5277
    • 1979-01-22
    • Harry A. ShortwayAlan A. GrahamCharles H. Miller
    • Harry A. ShortwayAlan A. GrahamCharles H. Miller
    • B32B5/20B44C1/20D06N7/00B32B31/22B32B31/26
    • D06N7/0007B32B5/20B44C1/20B44C1/205Y10S264/82Y10T156/1039Y10T156/1041Y10T428/24504Y10T428/24612Y10T428/24868Y10T428/249991Y10T428/31935
    • Resinous polymer sheet materials having selective, surface decorative effects comprising:(1) a base layer or substrate, such as a fibrous backing sheet material and/or a blown or unblown resinous polymer composition having either an embossed or a relatively smooth surface;(2) a pattern or design printed or otherwise deposited on and adhered to the base layer or substrate, certain portions of the printed pattern or design having certain colors, and other portions of the printed pattern or design having other colors; and(3) a wear layer having an embossed or a relatively smooth surface and containing reactive polymerizable monomers and having certain surface portions provided with a certain texture or effect, such as a flat, dead or dull mat finish, and other surface portions provided with another texture or effect, such as a sleek, glossy or lustrous finish, the interior portions of the wear layer lying under the flat, dead or dull mat finish having a relatively high melt viscosity and containing relatively high concentrations of polymerized and/or cross-linked reactive polymerizable monomers, and the interior portions of the wear layer lying under the sleek, glossy or lustrous finish having either (a) a relatively low melt viscosity and containing substantially no significant or substantial concentrations of polymerized and/or cross-linked reactive polymerizable monomers, or (b) a relatively high melt viscosity and containing relatively high concentrations of polymerized and/or cross-linked reactive polymerizable monomers,(i) the certain colors of the printed pattern or design, and (ii) the flat, dead or dull mat finish areas, and (iii) the interior portions of the wear layer having a relatively high melt viscosity and containing the relatively high concentrations of the polymerized and/or cross-linked reactive polymerizable monomers all being in substantially perfect registry, and(i) the other colors of the printed pattern or design, and (ii) the sleek, glossy or lustrous finish areas, and (iii) the interior portions of the wear layer having a relatively low melt viscosity and containing relatively low or no concentrations of polymerized and/or cross-linked reactive polymerizable monomers also all being in substantially perfect registry.
    • 5. 发明授权
    • Solar heat energy collecting systems and methods of making the same
    • 太阳能热能收集系统及其制作方法
    • US4375808A
    • 1983-03-08
    • US182739
    • 1980-08-29
    • Alan A. GrahamLaurence F. HaemerCharles H. Miller
    • Alan A. GrahamLaurence F. HaemerCharles H. Miller
    • B29C44/00F24S10/50F24J3/02
    • B29C67/20F24J2/204F24J2/4641Y02E10/44
    • A method of making a solar heat energy collecting system which comprises: forming a potentially foamable, resinous base layer containing a blowing agent; applying a printing composition to the surface of the potentially foamable, resinous base layer in the form of at least one continuous path extending from one edge point to another edge point of the potentially foamable, resinous base layer, the printing composition comprising a blowing inhibitor and a release agent; applying a top surface layer to the surface of the printed potentially foamable, resinous base layer which adheres thereto except in those areas containing the blowing inhibitor and release agent; heating the potentially foamable, resinous base layer to decompose or to activate the blowing agent in those portions of the potentially foamable, resinous base layer not lying under the blowing inhibitor and release agent, whereby such portions are blown and expand to extend and stretch upwardly so as to form upright walls of foamed, relatively lower density resinous material extending substantially vertically from the main portion of the resinous base layer, while those other portions of the potentially foamable, resinous base layer lying under the blowing inhibitor and release agent remain relatively unaffected; and supplying a fluid medium to those printed areas of the potentially foamable, resinous base layer lying over the blowing inhibitor and release agent, whereby the top surface layer is moved upwardly to form at least one continuous open channel extending from one edge point of the resinous base layer to another edge point of the resinous base layer and capable of conducting a heat transfer fluid medium therethrough. The inventive concept also relates to the solar heat energy collecting systems resulting from such methods.
    • 一种制造太阳能热能收集系统的方法,包括:形成含有发泡剂的潜在可发泡的树脂基层; 将印刷组合物施加到潜在可发泡的树脂基层的表面,其形式为从潜在可发泡的树脂基层的一个边缘点延伸到另一个边缘点的至少一个连续路径,印刷组合物包含吹塑抑制剂和 脱模剂; 将上表面层施加到印刷的潜在可发泡的树脂基层的表面,所述表面层附着在其上,除了在含有防发泡剂和脱模剂的那些区域之外; 加热潜在可发泡的树脂基层以分解或活化在不在吹泡抑制剂和脱模剂下面的可发泡的树脂基层的那些部分中的发泡剂,由此这些部分被吹胀并膨胀以向上延伸和向上拉伸 为了形成从树脂基层的主要部分基本上垂直延伸的泡沫的相对较低密度的树脂材料的直立壁,而位于吹塑抑制剂和脱模剂下方的潜在可发泡的树脂基层的其它部分保持相对不受影响; 并将流体介质供应到位于所述防发泡剂和脱模剂上方的可发泡的树脂基层的印刷区域,由此顶表面层向上移动以形成从树脂的一个边缘点延伸的至少一个连续的开放通道 基层到树脂基层的另一边缘点,并且能够传导通过其的传热流体介质。 本发明的概念还涉及由这些方法产生的太阳能热能收集系统。
    • 6. 发明授权
    • Solar heat energy collecting systems and methods of making the same
    • 太阳能热能收集系统及其制作方法
    • US4294786A
    • 1981-10-13
    • US26274
    • 1979-04-02
    • Alan A. GrahamLaurence F. HaemerCharles H. Miller
    • Alan A. GrahamLaurence F. HaemerCharles H. Miller
    • B29C44/00F24S10/50B29D27/00
    • B29C67/20F24J2/204F24J2/4641Y02E10/44Y10S264/82
    • A method of making a solar heat energy collecting system which comprises: forming a potentially foamable, resinous base layer containing a blowing agent; applying a printing composition to the surface of the potentially foamable, resinous base layer in the form of at least one continuous path extending from one edge point to another edge point of the potentially foamable, resinous base layer, the printing composition comprising a blowing inhibitor and a release agent; applying a top surface layer to the surface of the printed potentially foamable, resinous base layer which adheres thereto except in those areas containing the blowing inhibitor and release agent; heating the potentially foamable, resinous base layer to decompose or to activate the blowing agent in those portions of the potentially foamable, resinous base layer not lying under the blowing inhibitor and release agent, whereby such portions are blown and expand to extend and stretch upwardly so as to form upright walls of foamed, relatively lower density resinous material extending substantially vertically from the main portion of the resinous base layer, while those other portions of the potentially foamable, resinous base layer lying under the blowing inhibitor and release agent remain relatively unaffected; and supplying a fluid medium to those printed areas of the potentially foamable, resinous base layer lying over the blowing inhibitor and release agent, whereby the top surface layer is moved upwardly to form at least one continuous open channel extending from one edge point of the resinous base layer to another edge point of the resinous base layer and capable of conducting a heat transfer fluid medium therethrough. The inventive concept also relates to the solar heat energy collecting systems resulting from such methods.
    • 一种制造太阳能热能收集系统的方法,包括:形成含有发泡剂的潜在可发泡的树脂基层; 将印刷组合物施加到潜在可发泡的树脂基层的表面,其形式为从潜在可发泡的树脂基层的一个边缘点延伸到另一个边缘点的至少一个连续路径,印刷组合物包含吹塑抑制剂和 脱模剂; 将上表面层施加到印刷的潜在可发泡的树脂基层的表面,所述表面层附着在其上,除了在含有防发泡剂和脱模剂的那些区域之外; 加热潜在可发泡的树脂基层以分解或活化在不在吹泡抑制剂和脱模剂下面的可发泡的树脂基层的那些部分中的发泡剂,由此这些部分被吹胀并膨胀以向上延伸和向上拉伸 为了形成从树脂基层的主要部分基本上垂直延伸的泡沫的相对较低密度的树脂材料的直立壁,而位于吹塑抑制剂和脱模剂下方的潜在可发泡的树脂基层的其它部分保持相对不受影响; 并将流体介质供应到位于所述防发泡剂和脱模剂上方的可发泡的树脂基层的印刷区域,由此顶表面层向上移动以形成从树脂的一个边缘点延伸的至少一个连续的开放通道 基层到树脂基层的另一边缘点,并且能够传导通过其的传热流体介质。 本发明的概念还涉及由这些方法产生的太阳能热能收集系统。
    • 7. 发明授权
    • Methods of obtaining deep through penetration of colorants into
polyvinyl chloride compositions, and the resulting products
    • 获得深色穿透着色剂到聚氯乙烯组合物中的方法,以及得到的产品
    • US4232076A
    • 1980-11-04
    • US960402
    • 1978-11-13
    • John R. StetsonAlan A. GrahamRudolf Frisch
    • John R. StetsonAlan A. GrahamRudolf Frisch
    • D06N7/00B32B3/12B32B5/16
    • D06N7/0028D06N7/0007Y10S428/913Y10S428/914Y10T428/24496Y10T428/24893Y10T428/24901
    • Methods of obtaining deep through penetration of colorants into firmed printable gelled plastisol or sintered dry-blend polyvinyl chloride compositions which comprise: applying a transfer paper or other substrate coated with a sublimable disperse dye to the surface of a firmed printable gelled plastisol or sintered dry-blend polyvinyl chloride composition, wherein the polyvinyl chloride resin is in particulate form having an average particle size of from about 0.5 micron to about 420 microns and contains specified percentages of plasticizer and stabilizer; applying heat thereto in the range of from about 300.degree. F. to about 430.degree. F. for a period of time of from about 6 seconds to about 20 seconds, whereby the sublimable disperse dye sublimes and, while in the sublimed vapor phase, penetrates deeply into the firmed printable gelled plastisol or sintered dry-blend polyvinyl chloride composition; removing the transfer paper or other substrate, leaving the disperse dye in the firmed printable gelled plastisol or sintered dry-blend polyvinyl chloride composition; applying a resinous polymer composition to the surface of the dyed firmed printable gelled plastisol or sintered dry-blend polyvinyl chloride composition as a wear layer; and applying heat to the dyed firmed printable gelled plastisol or sintered dry-blend polyvinyl chloride composition in the range of from about 310.degree. F. to about 470.degree. F. to fuse the polyvinyl chloride resin.
    • 通过将着色剂深入渗透到可印刷胶凝增塑溶胶或烧结干混聚氯乙烯组合物中的方法,其包括:将涂覆有可升华分散染料的转印纸或其他基材施加到可证实的可印刷胶凝增塑溶胶的表面或烧结干 - 共混聚氯乙烯组合物,其中聚氯乙烯树脂是平均粒度为约0.5微米至约420微米的颗粒形式,并含有特定百分比的增塑剂和稳定剂; 在约300°F至约430°F的范围内施加热量约6秒至约20秒的时间,由此升华的分散染料升华,并且在升华的气相中,渗透 深入到可印刷胶凝增塑溶胶或烧结干混聚氯乙烯组合物中; 去除转印纸或其他基材,将分散染料留在可印刷的可印刷胶凝增塑溶胶或烧结干混聚氯乙烯组合物中; 将树脂聚合物组合物施加到染色的可印刷胶凝增塑溶胶或烧结干混聚氯乙烯组合物的表面作为耐磨层; 并将热量加热到约310°F至约470°F范围内的染色的可印刷胶凝增塑溶胶或烧结干混聚氯乙烯组合物以熔融聚氯乙烯树脂。