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1. 发明授权

US4777319A Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons 失效
标题翻译：烷烃氧化脱氢为不饱和烃
公开(公告)号：US4777319A
公开(公告)日：1988-10-11
申请号：US69284
申请日：1987-07-01
申请人： Harold H. Kung , Mohamed A. Chaar
发明人： Harold H. Kung , Mohamed A. Chaar
IPC分类号： C07C5/48 , C07C5/09 , C07C5/327
CPC分类号： C07C5/48
摘要： Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M.sub.3 (VO.sub.4).sub.2 and MV.sub.2 O.sub.6, M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.
摘要翻译：在氧化条件下，在金属钒酸盐催化剂上进行烷烃到不饱和烃的氧化脱氢。钒酸盐催化剂由式M3（VO4）2和MV2O6表示，M表示Mg，Zn，Ca，Pb或Cd。反应在氧的存在下进行，但是含氧化合物副产物的形成被抑制。

2. 发明授权

US08551650B2 Graphene materials having randomly distributed two-dimensional structural defects 有权
标题翻译：石墨烯材料随机分布二维结构缺陷
公开(公告)号：US08551650B2
公开(公告)日：2013-10-08
申请号：US13106210
申请日：2011-05-12
申请人： Harold H. Kung , Xin Zhao , Cary M. Hayner , Mayfair C. Kung
发明人： Harold H. Kung , Xin Zhao , Cary M. Hayner , Mayfair C. Kung
IPC分类号： H01M6/04 , H01M10/00 , H01M6/00 , H01M4/02 , H01M4/13 , H01M4/58
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/192 , C01B32/23 , H01B1/04 , H01M4/134 , H01M4/386 , H01M4/625 , H01M10/052 , Y02P70/54
摘要： Graphene-based storage materials for high-power battery applications are provided. The storage materials are composed of vertical stacks of graphene sheets and have reduced resistance for Li ion transport. This reduced resistance is achieved by incorporating a random distribution of structural defects into the stacked graphene sheets, whereby the structural defects facilitate the diffusion of Li ions into the interior of the storage materials.
摘要翻译：提供了大容量电池应用的石墨烯储存材料。存储材料由石墨烯片的垂直堆叠组成，并且具有降低的Li离子传输阻力。这种降低的电阻是通过将堆积的石墨烯片中的结构缺陷的随机分布结合而实现的，由此结构缺陷便于Li离子扩散到储存材料的内部。

3. 发明授权

US08778538B2 Electrode material comprising graphene-composite materials in a graphite network 有权
标题翻译：在石墨网络中包含石墨烯复合材料的电极材料
公开(公告)号：US08778538B2
公开(公告)日：2014-07-15
申请号：US12940241
申请日：2010-11-05
申请人： Harold H. Kung , Jung K. Lee
发明人： Harold H. Kung , Jung K. Lee
IPC分类号： H01M4/583 , H01M4/02 , H01M4/04 , H01M10/0525 , H01B1/04
CPC分类号： H01M4/364 , H01B1/18 , H01M4/134 , H01M4/1395 , H01M4/625 , Y10T29/49108 , Y10T29/49115
摘要： A durable electrode material suitable for use in Li ion batteries is provided. The material is comprised of a continuous network of graphite regions integrated with, and in good electrical contact with a composite comprising graphene sheets and an electrically active material, such as silicon, wherein the electrically active material is dispersed between, and supported by, the graphene sheets.
摘要翻译：提供适用于锂离子电池的耐用电极材料。该材料包括与包含石墨烯片和电活性材料（例如硅）的复合材料集成并且与电极良好电接触的石墨区域的连续网络，其中电活性材料分散在石墨烯之间并由石墨烯支撑床单。

4. 发明授权

US08481766B2 Methods of producing epoxides from alkenes using a two-component catalyst system 有权
标题翻译：使用双组分催化剂体系从烯烃生产环氧化物的方法
公开(公告)号：US08481766B2
公开(公告)日：2013-07-09
申请号：US12943138
申请日：2010-11-10
申请人： Mayfair C. Kung , Harold H. Kung , Jian Jiang
发明人： Mayfair C. Kung , Harold H. Kung , Jian Jiang
IPC分类号： C07D301/06
CPC分类号： C07D301/06
摘要： Methods for the epoxidation of alkenes are provided. The methods include the steps of exposing the alkene to a two-component catalyst system in an aqueous solution in the presence of carbon monoxide and molecular oxygen under conditions in which the alkene is epoxidized. The two-component catalyst system comprises a first catalyst that generates peroxides or peroxy intermediates during oxidation of CO with molecular oxygen and a second catalyst that catalyzes the epoxidation of the alkene using the peroxides or peroxy intermediates. A catalyst system composed of particles of suspended gold and titanium silicalite is one example of a suitable two-component catalyst system.
摘要翻译：提供烯烃环氧化方法。所述方法包括在烯烃被环氧化的条件下，在一氧化碳和分子氧的存在下，在水溶液中将烯烃暴露于双组分催化剂体系的步骤。双组分催化剂体系包括在分子氧氧化CO期间产生过氧化物或过氧化物中间体的第一催化剂和使用过氧化物或过氧化物中间体催化烯烃的环氧化的第二催化剂。由悬浮金和钛硅沸石的颗粒组成的催化剂体系是合适的双组分催化剂体系的一个实例。

5. 发明申请

US20110111303A1 ELECTRODE MATERIAL COMPRISING GRAPHENE COMPOSITE MATERIALS IN A GRAPHITE NETWORK FORMED FROM RECONSTITUTED GRAPHENE SHEETS 有权
标题翻译：在由重新绘制的石墨片形成的石墨网络中包含石墨复合材料的电极材料
公开(公告)号：US20110111303A1
公开(公告)日：2011-05-12
申请号：US12940241
申请日：2010-11-05
申请人： Harold H. Kung , Jung K. Lee
发明人： Harold H. Kung , Jung K. Lee
IPC分类号： H01M4/58 , H01M4/62 , H01M4/583
CPC分类号： H01M4/364 , H01B1/18 , H01M4/134 , H01M4/1395 , H01M4/625 , Y10T29/49108 , Y10T29/49115
摘要： A durable electrode material suitable for use in Li ion batteries is provided. The material is comprised of a continuous network of graphite regions integrated with, and in good electrical contact with a composite comprising graphene sheets and an electrically active material, such as silicon, wherein the electrically active material is dispersed between, and supported by, the graphene sheets.
摘要翻译：提供适用于锂离子电池的耐用电极材料。该材料包括与包含石墨烯片和电活性材料（例如硅）的复合材料集成并且与电极良好电接触的石墨区域的连续网络，其中电活性材料分散在石墨烯之间并由石墨烯支撑床单。

6. 发明授权

US09403150B2 Metal catalyst composition 有权
标题翻译：金属催化剂组成
公开(公告)号：US09403150B2
公开(公告)日：2016-08-02
申请号：US14119475
申请日：2012-05-24
申请人： Junling Lu , Peter Stair , Baosong Fu , Harold H. Kung , Mayfair C Kung
发明人： Junling Lu , Peter Stair , Baosong Fu , Harold H. Kung , Mayfair C Kung
IPC分类号： B01J12/00 , B01J37/08 , B01J37/14 , B01J35/10 , B01J23/44 , B01J21/04 , B01J23/38 , B01J35/00 , B01J37/02 , C23C16/30 , C23C16/455 , C07C5/333 , C07C5/42 , B01J37/12 , B01J37/18 , C07C5/48
CPC分类号： B01J23/44 , B01J21/04 , B01J23/38 , B01J35/002 , B01J35/006 , B01J35/0073 , B01J35/1019 , B01J35/1057 , B01J35/1061 , B01J37/0209 , B01J37/0228 , B01J37/0244 , B01J37/08 , B01J37/12 , B01J37/14 , B01J37/18 , C07C5/3335 , C07C5/3337 , C07C5/42 , C07C5/48 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/18 , C07C2523/02 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/755 , C23C16/30 , C23C16/45531 , C23C16/45555 , Y02P20/52 , C07C11/04 , C07C11/02
摘要： Embodiments include metal catalyst compositions and methods of forming metal catalyst compositions. A metal catalyst composition can be formed by (a) contacting a supported metal catalyst surface with a ligand-containing alumina precursor for a predetermined contact time to form an intermediate layer having a plurality of aluminum moieties that chemically bond to the supported metal catalyst surface, optionally, contacting the intermediate layer of aluminum moieties with an inert gas for a predetermined intermediate stripping time to remove unreacted ligand-containing alumina precursors, (b) reacting the aluminum moieties with an oxidation reagent for a predetermined reaction time to convert at least a portion of the ligands to hydroxyl groups thereby forming a layer of the alumina over-coat on the supported metal catalyst surface or a previously formed layer of the alumina over-coat, (c) contacting the layer of the alumina over-coat formed in step (b) with an inert gas for a predetermined stripping time to remove unreacted oxidation reagents, replicating the sequential steps (a-c) to form an additional layer of the alumina over-coat, and (d) activating the alumina over-coat, after forming a final layer of the alumina over-coat, to form a plurality of pores therein.
摘要翻译：实施方案包括金属催化剂组合物和形成金属催化剂组合物的方法。金属催化剂组合物可以通过以下方法形成：（a）使支撑的金属催化剂表面与含配体的氧化铝前体接触预定的接触时间，以形成具有化学键合到负载的金属催化剂表面的多个铝部分的中间层，任选地，将铝部分的中间层与惰性气体接触以达到预定的中间剥离时间以除去未反应的含配体的氧化铝前体，（b）使铝部分与氧化试剂反应达预定的反应时间，以将至少一部分的配体，从而在负载的金属催化剂表面上形成氧化铝过涂层或预先形成的氧化铝覆盖层，（c）使步骤（a）中形成的氧化铝覆盖层 b）用惰性气体预定的剥离时间以除去未反应的氧化剂，复制顺序步骤（ac）t o形成另外的氧化铝覆盖层，和（d）在形成最终的氧化铝覆盖层之后，激活氧化铝覆盖层，以在其中形成多个孔。

7. 发明申请

US20120288750A1 GRAPHENE MATERIALS HAVING RANDOMLY DISTRIBUTED TWO-DIMENSIONAL STRUCTURAL DEFECTS 有权
标题翻译：具有随机分布式二维结构缺陷的石墨材料
公开(公告)号：US20120288750A1
公开(公告)日：2012-11-15
申请号：US13106210
申请日：2011-05-12
申请人： Harold H. Kung , Xin Zhao , Cary M. Hayner , Mayfair C. Kung
发明人： Harold H. Kung , Xin Zhao , Cary M. Hayner , Mayfair C. Kung
IPC分类号： H01M4/583 , H01M10/02 , C01B31/02 , H01B1/04 , B82Y40/00
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/192 , C01B32/23 , H01B1/04 , H01M4/134 , H01M4/386 , H01M4/625 , H01M10/052 , Y02P70/54
摘要： Graphene-based storage materials for high-power battery applications are provided. The storage materials are composed of vertical stacks of graphene sheets and have reduced resistance for Li ion transport. This reduced resistance is achieved by incorporating a random distribution of structural defects into the stacked graphene sheets, whereby the structural defects facilitate the diffusion of Li ions into the interior of the storage materials.
摘要翻译：提供了大容量电池应用的石墨烯储存材料。存储材料由石墨烯片的垂直堆叠组成，并且具有降低的Li离子传输阻力。这种降低的电阻是通过将堆积的石墨烯片中的结构缺陷的随机分布结合而实现的，由此结构缺陷便于Li离子扩散到储存材料的内部。

8. 发明申请

US20110112315A1 METHODS OF PRODUCING EPOXIDES FROM ALKENES USING A TWO-COMPONENT CATALYST SYSTEM 有权
标题翻译：使用双组分催化剂体系从碱性生产环氧化物的方法
公开(公告)号：US20110112315A1
公开(公告)日：2011-05-12
申请号：US12943138
申请日：2010-11-10
申请人： Mayfair C. Kung , Harold H. Kung , Jian Jiang
发明人： Mayfair C. Kung , Harold H. Kung , Jian Jiang
IPC分类号： C07D301/06
CPC分类号： C07D301/06
摘要： Methods for the epoxidation of alkenes are provided. The methods include the steps of exposing the alkene to a two-component catalyst system in an aqueous solution in the presence of carbon monoxide and molecular oxygen under conditions in which the alkene is epoxidized. The two-component catalyst system comprises a first catalyst that generates peroxides or peroxy intermediates during oxidation of CO with molecular oxygen and a second catalyst that catalyzes the epoxidation of the alkene using the peroxides or peroxy intermediates. A catalyst system composed of particles of suspended gold and titanium silicalite is one example of a suitable two-component catalyst system.
摘要翻译：提供烯烃环氧化方法。所述方法包括在烯烃被环氧化的条件下，在一氧化碳和分子氧的存在下，在水溶液中将烯烃暴露于双组分催化剂体系的步骤。双组分催化剂体系包括在分子氧氧化CO期间产生过氧化物或过氧化物中间体的第一催化剂和使用过氧化物或过氧化物中间体催化烯烃的环氧化的第二催化剂。由悬浮金和钛硅沸石的颗粒组成的催化剂体系是合适的双组分催化剂体系的一个实例。

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