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    • 1. 发明授权
    • Polymerizable halogenated vinyl ethers
    • 可聚合的卤代乙烯基醚
    • US06743943B2
    • 2004-06-01
    • US09854244
    • 2001-05-11
    • Russell F. AndersonDavid E. BradleyDavid NalewajekHaridasan K. NairMariola J. ProszowskiEugene V. SitzmanEllen L. Swan
    • Russell F. AndersonDavid E. BradleyDavid NalewajekHaridasan K. NairMariola J. ProszowskiEugene V. SitzmanEllen L. Swan
    • C07C6934
    • C07C43/17C07C43/172C07C43/176C07C69/63C07C309/73C07C2601/14C08F8/18C08F16/26C09D11/101C09D129/10C09J4/00C09J129/10G02B6/1221G02B6/13G11B7/2531G11B7/2532G11B7/2533G11B7/2542G11B7/2545G11B7/256G11B7/2572C08F216/125
    • Vinyl ether compounds having the formula: R—O—X—O—CH═CH2 wherein R is a radical selected from R1—CnHm—, R1—CnHm—C(═O)—, R1—CnHm—CH[—O—X—O—CH═CH2—], R1—CnHm—CH[—O—X—O—CH═CH2—]C(═O)—, R1—CnHm—CH[—C(═O)—O—X—O—CH═CH2—], R1—CnHm—CH[—C(═O)—O—X—O—CH═CH2—]C(═O)—, R1—[CFCl—CF2—]pCH2— and HCFCl—CF2—, wherein R1 is hydrogen, an unsubstituted or substituted fluorinated aliphatic radical, an unsubstituted or substituted fluorinated cyclic aliphatic radical, an unsubstituted or substituted fluorinated aromatic radical, an unsubstituted or substituted fluorinated araliphatic radical, or an unsubstituted or substituted fluorinated heterocyclic radical; n is an integer between 1 and 6, inclusive; n≦m≦2n; p is an integer between 1 and 20, inclusive and X is an unsubstituted or substituted aliphatic radical, an unsubstituted or substituted cyclic aliphatic radical, an unsubstituted or substituted aromatic radical, an unsubstituted or substituted araliphatic radical, or an unsubstituted or substituted heterocyclic radical; provided that when R1 of R1—CnHm— is an otherwise unsubstituted fluorinated aliphatic group, X is not ethylene or propylene. Curable compositions containing the vinyl ether compounds are also disclosed, as well as polymers polymerized from the vinyl ether compounds.
    • 具有下式的乙烯基醚化合物:其中R是选自R1-CnHm-,R1-CnHm-C(= O) - ,R1-CnHm-CH [-OXO-CH = CH2-],R1-CnHm-CH [-OXO-CH = CH2-] C(= O) - ,R1-CnHm-CH [-C(= O)-OXO-CH = CH2-],R1-CnHm-CH [-C(= O) OXO-CH = CH 2 - ] C(= O) - ,R 1 - [CFCl-CF 2 - ] pCH 2 - 和HCFCl-CF 2 - ,其中R 1是氢,未取代或取代的氟化脂族基,未取代或取代的氟代环状脂族 基团,未取代或取代的氟化芳族基团,未取代或取代的氟化芳脂族基团,或未取代或取代的氟化杂环基团; n是1和6之间的整数,包括1和6; n <= m <= 2n; p是1至20的整数,包括1和20,X是未取代或取代的脂族基团,未取代或取代的环状脂族基团,未取代或取代的芳族基团,未取代或取代的芳脂族基团,或未取代或取代的杂环基团; 条件是当R1-CnHm-的R1是另外未被取代的氟代脂族基团时,X不是乙烯或丙烯。 还公开了含有乙烯基醚化合物的可固化组合物,以及由乙烯基醚化合物聚合的聚合物。
    • 2. 发明授权
    • Polymerizable halogenated vinyl ethers
    • 可聚合的卤代乙烯基醚
    • US06291704B1
    • 2001-09-18
    • US09271650
    • 1999-03-18
    • Russell F. AndersonDavid E. BradleyDavid NalewajekHaridasan K. NairMariola J. ProszowskiEugene V. SitzmanEllen L. Swan
    • Russell F. AndersonDavid E. BradleyDavid NalewajekHaridasan K. NairMariola J. ProszowskiEugene V. SitzmanEllen L. Swan
    • C07C6963
    • C07C43/17C07C43/172C07C43/176C07C69/63C07C309/73C07C2601/14C08F8/18C08F16/26C09D11/101C09D129/10C09J4/00C09J129/10G02B6/1221G02B6/13G11B7/2531G11B7/2532G11B7/2533G11B7/2542G11B7/2545G11B7/256G11B7/2572C08F216/125
    • Vinyl ether compounds having the formula: R—O—X—O—CH═CH2 wherein R is a radical selected from R1—CnHm—, R1—CnHm—C(═O)—, R1—CnHm—CH[—O—X—O—CH═CH2—], R1—CnHm—CH[—O—X—O—CH═CH2—]C(═O)—, R1—CnHm—CH[—C(═O)—O—X—O—CH═CH2—], R1—CnHm—CH[—C(═O)—O—X—0—CH═CH2—]C(═O)—, R1—[CFCl—CF2—]pCH2— and HCFCl—CF2—, wherein R1 is hydrogen, an unsubstituted or substituted fluorinated aliphatic radical, an unsubstituted or substituted fluorinated cyclic aliphatic radical, an unsubstituted or substituted fluorinated aromatic radical, an unsubstituted or substituted fluorinated araliphatic radical, or an unsubstituted or substituted fluorinated heterocyclic radical; n is an integer between 1 and 6, inclusive; n≦m≦2n; p is an integer between 1 and 20, inclusive and X is an unsubstituted or substituted aliphatic radical, an unsubstituted or substituted cyclic aliphatic radical, an unsubstituted or substituted aromatic radical, an unsubstituted or substituted araliphatic radical, or an unsubstituted or substituted heterocyclic radical; provided that when R1 of R1—CnHm— is an otherwise unsubstituted fluorinated aliphatic group, X is not ethylene or propylene. Curable compositions containing the vinyl ether compounds are also disclosed, as well as polymers polymerized from the vinyl ether compounds.
    • 具有下式的乙烯基醚化合物:其中R是选自R1-CnHm-,R1-CnHm-C(= O) - ,R1-CnHm-CH [-OXO-CH = CH2-],R1-CnHm-CH [-OXO-CH = CH2-] C(= O) - ,R1-CnHm-CH [-C(= O)-OXO-CH = CH2-],R1-CnHm-CH [-C(= O) OX-0-CH = CH 2 - ] C(= O) - ,R 1 - [CFCl-CF 2 - ] pCH 2 - 和HCFCl-CF 2 - ,其中R 1是氢,未取代或取代的氟化脂族基团,未取代或取代的氟化 未取代或取代的氟化芳族基团,未取代或取代的氟化芳脂族基团,或未取代或取代的氟化杂环基团; n是1和6之间的整数,包括1和6; n <= m <= 2n; p是1至20的整数,包括1和20,X是未取代或取代的脂族基团,未取代或取代的环状脂族基团,未取代或取代的芳族基团,未取代或取代的芳脂族基团,或未取代或取代的杂环基团; 条件是当R1-CnHm-的R1是另外未被取代的氟代脂族基团时,X不是乙烯或丙烯。 还公开了含有乙烯基醚化合物的固化组合物以及由乙烯基醚化合物聚合的聚合物。
    • 3. 发明授权
    • Radiation curable fluorinated vinyl ethers derived from hexafluoropropene
    • 衍生自六氟丙烯的可辐射固化氟化乙烯基醚
    • US06579667B2
    • 2003-06-17
    • US10264380
    • 2002-10-04
    • Haridasan K. NairDavid NalewajekDavid E. Bradley
    • Haridasan K. NairDavid NalewajekDavid E. Bradley
    • G03F7028
    • C07C43/17C07C43/172C07C43/176C07C2601/14C08F16/26C09D11/101G02B6/1221G02B6/13
    • Processes for producing optical devices by the steps of: (a) applying a layer of a photocurable composition onto a substrate; (b) imagewise exposing the photocurable composition to actinic radiation to form exposed and non-exposed areas on the substrate; and (c) removing the imagewise non-exposed areas while leaving the imagewise exposed areas on the substrate; wherein the photocurable composition includes: a curable component having at least one compound of the formula: R—O—X—O—CH═CH2  wherein R is R1—CFH—CF2— or R1—CF═CF—, in which R1 is selected from unsubstituted and substituted aliphatic radicals, unsubstituted and substituted cyclic aliphatic radicals, unsubstituted and substituted aromatic radicals, unsubstituted and substituted araliphatic radicals and unsubstituted and substituted heterocyclic radicals; and X is selected from unsubstituted and substituted aliphatic radicals, unsubstituted and substituted cyclic aliphatic radicals, unsubstituted and substituted aromatic radicals, unsubstituted and substituted araliphatic radicals and unsubstituted and substituted heterocyclic radicals; and a photoinitiator compound so that the composition is photocurable.
    • 通过以下步骤制造光学器件的方法:(a)将光可固化组合物层施加到基底上;(b)将光固化组合物成像曝光于光化辐射,以在基底上形成暴露和未曝光的区域; 并且(c)在将成像曝光区域留在基片上的同时去除成像非曝光区域;其中所述可光固化组合物包括:具有至少一种下式化合物的可固化组分:其中R为R 1 -CFH-CF 2 - 或R 1 -CF = CF-,其中R1选自未取代和取代的脂族基团,未取代和取代的环状脂族基团,未取代和取代的芳族基团,未取代和取代的芳脂族基团和未取代和取代的杂环基团; X选自未取代和取代的脂族基团,未取代和取代的环状脂族基团,未取代和取代的芳族基团,未取代和取代的芳脂族基团和未取代和取代的杂环基团; 和光引发剂化合物,使得组合物是光固化的。
    • 5. 发明授权
    • Radiation curable fluorinated vinyl ethers derived from hexafluoropene
    • 衍生自六氟丙烯的可辐射固化氟化乙烯基醚
    • US06466730B2
    • 2002-10-15
    • US09919015
    • 2001-07-31
    • Haridasan K. NairDavid NalewajekDavid E. Bradley
    • Haridasan K. NairDavid NalewajekDavid E. Bradley
    • G02B600
    • C07C43/17C07C43/172C07C43/176C07C2601/14C08F16/26C09D11/101G02B6/1221G02B6/13
    • Vinyl ether compounds having the formula: R—O—X—O—CH═CH2 wherein R is a radical having the formula: R1—CFH—CF2— or R1—CF═CF2—, wherein R1 is an unsubstituted or substituted aliphatic radical, an unsubstituted or substituted cyclic aliphatic radical, an unsubstituted or substituted aromatic radical, an unsubstituted or substituted araliphatic radical, or an unsubstituted or substituted heterocyclic radical, and X is an unsubstituted or substituted aliphatic radical, an un-substituted or substituted cyclic aliphatic radical, an unsubstituted or substituted aromatic radical, an unsubstituted or substituted araliphatic radical, or an unsubstituted or substituted heterocyclic radical. Curable compositions containing the vinyl ether compounds and methods in which substrate coating layers of the vinyl ether compositions are cured, particularly on optical devices, are also disclosed, as well as polymers polymerized from the vinyl ether compounds.
    • 具有下式的乙烯基醚化合物:其中R是具有下式的基团:R1-CFH-CF2-或R1-CF = CF2-,其中R1是未取代或取代的脂族基团,未取代或取代的环状脂族基团,未取代的 或取代的芳族基团,未取代或取代的芳脂族基团,或未取代或取代的杂环基,X是未取代或取代的脂族基团,未取代或取代的环状脂族基团,未取代或取代的芳族基团,未取代或取代的芳族基团, 取代的芳脂族基团,或未取代或取代的杂环基团。 还公开了包含乙烯基醚化合物的可固化组合物和其中乙烯基醚组合物的基底涂层被固化的方法,特别是在光学器件上,以及由乙烯基醚化合物聚合的聚合物。
    • 6. 发明授权
    • Radiation curable fluorinated vinyl ethers derived from hexafluoropropene
    • 衍生自六氟丙烯的可辐射固化氟化乙烯基醚
    • US06308001B1
    • 2001-10-23
    • US09218201
    • 1998-12-22
    • Haridasan K. NairDavid NalewajekDavid E. Bradley
    • Haridasan K. NairDavid NalewajekDavid E. Bradley
    • G02B600
    • C07C43/17C07C43/172C07C43/176C07C2601/14C08F16/26C09D11/101G02B6/1221G02B6/13
    • Vinyl ether compounds having the formula: R—O—X—O—CH═CH2 wherein R is a radical having the formula: R1—CFH—CF2— or R1—CF═CF—, wherein R1 is an unsubstituted or substituted aliphatic radical, unsubstituted or substituted cyclic aliphatic radical, an unsubstituted or substituted aromatic radical, an unsubstituted or substituted araliphatic radical, or an unsubstituted or substituted heterocyclic radical, and X is an unsubstituted or substituted aliphatic radical, an unsubstituted or substituted cyclic aliphatic radical, unsubstituted or substituted aromatic radical, unsubstituted or substituted araliphatic radical or an unsubstituted or substituted heterocyclic radical. Curable compositions containing the vinyl ether compounds and methods in which the substrate coating layers of the vinyl ether compositions are cured, particularly on optical devices, are also disclosed, as well as polymers polymerized from the vinyl ether compounds.
    • 具有下式的乙烯基醚化合物:其中R是具有下式的基团:R1-CFH-CF2-或R1-CF = CF-,其中R1是未取代或取代的脂族基团,未取代或取代的环状脂肪族基团,未取代或未取代的 取代的芳族基团,未取代或取代的芳脂族基团,或未取代或取代的杂环基团,X是未取代或取代的脂族基团,未取代或取代的环状脂族基团,未取代或取代的芳族基团,未取代或取代的芳脂族基团或 未取代或取代的杂环基。 还公开了含有乙烯基醚化合物的可固化组合物和其中乙烯基醚组合物的基底涂层被固化的方法,特别是在光学器件上,以及由乙烯基醚化合物聚合的聚合物。
    • 7. 发明授权
    • Process for producing fluoroolefins
    • 制备氟烯烃的方法
    • US06548719B1
    • 2003-04-15
    • US09962974
    • 2001-09-25
    • Haridasan K. NairMichael Van Der PuyDavid NalewajekTimothy R. DemminAndrew J. PossDavid E. BradleyIan R. Shankland
    • Haridasan K. NairMichael Van Der PuyDavid NalewajekTimothy R. DemminAndrew J. PossDavid E. BradleyIan R. Shankland
    • C07C1725
    • C07C17/04C07C17/25C07C19/14C07C21/18
    • A process for producing a fluoroolefin of the formula: CF3CY═CXnHp wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); n and p are integers independently equal to 0, 1 or 2, provided that (n+p)=2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF3C(R1aR2b)C(R3cR4d), wherein R1, R2, R3, and R4 are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R1, R2, R3, and R4 is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently=0, 1 or 2 and (a+b)=2; and c and d are independently=0, 1, 2 or 3 and (c+d)=3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and 15-crown-5; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olef in is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.
    • 制备下式的氟代烯烃的方法:CF 3 CY = CXnHp其中Y是氢原子或卤素原子(即氟,氯,溴或碘); X是氢原子或卤素原子(即氟,氯,溴或碘); n和p是独立地等于0,1或2的整数,条件是(n + p)= 2; 包括在相转移催化剂存在下使下式化合物:其中R 1,R 2,R 3和R 4独立地为氢原子或选自以下的卤素:式中:CF 3 C(R 1a R 2b)C(R 3 c R 4d) 氟,氯,溴和碘,条件是R 1,R 2,R 3和R 4中的至少一个是卤素,并且在相邻碳原子上具有至少一个氢和一个卤素; a和b独立地为0,1或2,(a + b)= 2; 且c和d独立地为0,1,2或3和(c + d)= 3; 和至少一种碱金属氢氧化物。 碱金属氢氧化物可以是例如氢氧化钾或氢氧化钠,相转移催化剂可以是例如至少一种:冠醚如18-冠-6和15-冠-5; 或鎓盐如季鏻盐和季铵盐。 烯烃可用作例如生产其它工业化学品的中间体,以及用作生产低聚物和聚合物的单体。