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    • 6. 发明申请
    • PYRIDAZINE DERIVATIVES
    • 吡啶衍生物
    • US20100144674A1
    • 2010-06-10
    • US12447028
    • 2007-10-23
    • Stephan TrahClemens LamberthSebastian Wendeborn
    • Stephan TrahClemens LamberthSebastian Wendeborn
    • A01N57/00C07D237/02A01N43/58A01N43/54A01N43/84A01P3/00A01P15/00
    • C07D237/14A01N43/58C07D237/08C07D237/12C07D307/60C07D307/79C07D401/04C07D401/12C07D403/04C07D405/04C07D405/12C07D407/04C07D409/04C07D409/12C07D413/04C07D417/04
    • The present invention relates to novel pyridazine derivatives of formula (I) as active ingredients which have microbiocidal activity, in particular fungicidal activity: wherein R1 is hydrogen, C1-C6alkyl, C1-C8haloalkyl or C3-C6cycloalkyl; R2 is cycloalkyl, cycloalkylalkyl, halocycloalkyl, cycloalkoxy, halocycloalkoxy, cycloalkylalkoxy, halocycloalkylalkoxy, alkoxyalkyl, cycloalkoxyalkoxyalkyl, haloalkoxyalkyl, trialkylsilyl, alkylthioalkyl, haloalkylthioalkyl, cycloalkylthio, halocycloalkylthio, cycloalkylalkylthio, halocycloalkylalkylthio, alkylsulfinylalkyl, alkylsulfonylalkyl, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, C2-C6alkenyl, C2-C6alkynyl, optionally substituted arylsulfonyl, optionally substituted aryloxy, optionally optionally substituted heteroaryloxy, optionally substituted arylthio, optionally substituted heteroarylthio; or R2 together with an adjacent carbon atom forms an optionally substituted fused ring; R3 is an optionally substituted aryl; R4 is hydrogen, halogen, C1-C6alkyl, C1-C6haloalkyl, C1-C8alkoxy, C1-C6haloalkoxy, hydroxy or cyano; and n is a whole number from 1 to 4; or an agrochemically usable salt form thereof.
    • 本发明涉及具有杀微生物活性,特别是杀真菌活性的活性成分的式(I)的新哒嗪衍生物,其中R1是氢,C1-C6烷基,C1-C8卤代烷基或C3-C6环烷基; R 2是环烷基,环烷基烷基,卤代环烷基,环烷氧基,卤代环烷氧基,环烷基烷氧基,卤代环烷基烷氧基,烷氧基烷基,环烷氧基烷氧基烷基,卤代烷氧基烷基,三烷基甲硅烷基,烷硫基烷基,卤代烷硫基烷基,环烷硫基,卤代环烷硫基,环烷基烷硫基,卤代环烷基烷硫基,烷基亚磺酰基烷基,烷基磺酰基烷基,烷基亚磺酰基,卤代烷基亚磺酰基,烷基磺酰基,卤代烷基磺酰基, C 6链烯基,C 2 -C 6炔基,任选取代的芳基磺酰基,任选取代的芳氧基,任选任选取代的杂芳氧基,任选取代的芳硫基,任选取代的杂芳硫基; 或R 2与相邻的碳原子一起形成任选取代的稠环; R3是任选取代的芳基; R4是氢,卤素,C1-C6烷基,C1-C6卤代烷基,C1-C8烷氧基,C1-C6卤代烷氧基,羟基或氰基; n为1〜4的整数; 或其农业化学上可用的盐形式。
    • 7. 发明申请
    • PESTICIDALLY ACTIVE KETONE AND OXIME DERIVATIVES
    • 杀虫活性酮和氧化衍生物
    • US20090298898A1
    • 2009-12-03
    • US12533302
    • 2009-07-31
    • Werner ZambachRoger Graham HallPeter RenoldStephan Trah
    • Werner ZambachRoger Graham HallPeter RenoldStephan Trah
    • A01N43/80C07C233/02C07C249/02C07D261/06A01N37/18A01N33/02A01P7/00
    • C07D333/58A01N33/24A01N35/10A01N37/52A01N41/06A01N43/10A01N43/40A01N43/78A01N43/80C07C49/753C07C49/755C07C49/84C07C235/84C07C251/44C07C251/48C07C251/54C07C251/58C07C311/04C07C311/05C07C311/09C07C323/47C07D213/50C07D213/53C07D213/61C07D213/64C07D261/08C07D277/24C07D277/28C07D307/52C07D307/81C07D333/22
    • Compounds of formula wherein A0, A1 and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, O, S, SO or SO2; M is O or NOR6, X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8cycloalkyl, C3-C8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.
    • 下式化合物其中A0,A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥,其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如O,S,SO或SO 2; M为O或NOR6,X1和X2各自独立地为氟,氯或溴; R1,R2和R3是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷基羰基,C2-C6链烯基,C2-C6卤代烯基或C2-C6炔基; Q是例如O,S,SO或SO 2; W是例如O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; T是例如键O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; D是CH或N; R4是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基,C3-C8环烷基或-N(R7)2; R 7是H,C 1 -C 6烷基,C 1 -C 3卤代烷基,C 1 -C 6烷基羰基,C 1 -C 3卤代烷基羰基,C 1 -C 6烷氧基羰基,C 3 -C 8环烷基,C 3 -C 8环烷基羰基或甲酰基; k为0,1,2,3或4; m为1或2; q为0,1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 已经从这些化合物和农业化学上可接受的盐中选择活性成分,以及这些组合物的制备方法及其用途,用这些组合物处理的繁殖材料以及控制害虫的方法。