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1. 发明授权

US5786419A Powder coating composition and its use for the preparation of matte coatings 失效
标题翻译：粉末涂料组合物及其用于制备无光泽涂料的用途
公开(公告)号：US5786419A
公开(公告)日：1998-07-28
申请号：US649044
申请日：1996-05-16
申请人： Hans-Ulrich Meier-Westhues , Wolfgang Schultz , Hans Josef Laas , Walter Schafer , Hans-Peter Klee
发明人： Hans-Ulrich Meier-Westhues , Wolfgang Schultz , Hans Josef Laas , Walter Schafer , Hans-Peter Klee
IPC分类号： C09D5/03 , C08G18/10 , C08G18/38 , C08G18/66 , C08G18/79 , C09D5/00 , C09D5/28 , C09D5/46 , C09D175/00 , C09D175/04 , C09D175/06 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/798 , C08G18/10 , C08G18/3825 , C08G18/6633 , C08G2150/20 , Y10T428/31551
摘要： The present invention relates to a powder coating composition for the production of matte coatings, containing A) a hydroxyl group-containing component, B) an addition polymerization compound which is based on aliphatic and/or cycloaliphatic diisocyanates and contains uretdione groups, C) a component which contains carboxyl and/or carboxylic acid anhydride groups and is selected from C1) aliphatic and/or cycloaliphatic dicarboxylic acids containing 4 to 20 carbon atoms, C2) monomeric and/or polymeric anhydrides of the acids C1) which may optionally be modified and C3) aliphatic hydroxycarboxylic acids containing 4 to 18 carbon atoms, and D) a component which contains groups which are reactive with carboxyl and/or carboxylic acid anhydride groups, provided that components A), B), C) and D) are present in amounts such that 0.6 to 1.4 isocyanate groups of component B) are present for each hydroxyl group of component A), 0.3 to 1.5 groups of component D) which are reactive with carboxyl and/or carboxylic acid anhydride groups are present for each carboxyl equivalent of component C) and the amount of components C) and D) is 10 to 40% by weight of the total amount of components A), B), C) and D). The present invention also relates to the use of this powder coating composition for coating heat-resistant substrates.
摘要翻译：本发明涉及一种用于生产无光泽涂层的粉末涂料组合物，其含有A）含羟基的组分，B）基于脂族和/或脂环族二异氰酸酯并含有脲二酮基团的加成聚合化合物，C）含有羧基和/或羧酸酐基团的组分，并且选自C1）含有4至20个碳原子的脂族和/或脂环族二羧酸，C2）可任选地被修饰的酸C1）的单体和/或聚合酸酐， C3）含有4至18个碳原子的脂族羟基羧酸，以及D）含有与羧基和/或羧酸酐基团反应的基团的组分，条件是组分A），B），C）和D）存在于数量使得组分B）的每个羟基存在0.6至1.4个异氰酸酯基团组分A），0.3至1.5组与羧基反应的组分D）对于组分C）的每个羧基当量存在d /或羧酸酐基团，并且组分C）和D）的量为组分A），B），C）和D的总量的10至40重量％）。本发明还涉及这种粉末涂料组合物用于涂覆耐热基材的用途。

2. 发明授权

US5492955A Powder coating compositions and their use for coating heat resistant substrates 失效
标题翻译：粉末涂料组合物及其用于涂覆耐热基材的用途
公开(公告)号：US5492955A
公开(公告)日：1996-02-20
申请号：US333091
申请日：1994-10-31
申请人： Christian Wamprecht , Hans-Josef Laas , Manfred Bock , Hans-Ulrich Meier-Westhues , Wolfgang Schultz , Lothar Kahl
发明人： Christian Wamprecht , Hans-Josef Laas , Manfred Bock , Hans-Ulrich Meier-Westhues , Wolfgang Schultz , Lothar Kahl
IPC分类号： B05D7/24 , B05D7/14 , C08G18/42 , C08G18/58 , C08G18/62 , C08G18/79 , C08G18/80 , C08G59/42 , C09D5/03 , C09D5/46 , C09D133/06 , C09D163/00 , C09D175/00 , C09D175/04 , C08F8/00
CPC分类号： C08G18/8064 , C08G18/4277 , C08G18/6237 , C08G18/798 , C08G18/8012 , C08G59/4207 , C09D133/068 , C08G2150/20
摘要： A powder coating composition which is curable at 120.degree. to 150.degree. C. and contains A) one or more copolymers prepared from olefinically unsaturated monomers and containing epoxy groups and optionally hydroxyl groups, B) one or more curing agents containing carboxylic acid or carboxylic acid anhydride groups, and C) one or more polyaddition compounds which contain uretdione groups, have a melting point or range of 40.degree. C. to 120.degree. C. and are prepared from (cyclo)aliphatic diisocyanates; and its use for coating of heat-resistant substrates, especially automotive substrates.
摘要翻译：一种粉末涂料组合物，其可在120-150℃下固化并含有A）一种或多种由烯属不饱和单体制备并含有环氧基和任选的羟基的共聚物，B）含有羧酸或羧酸的一种或多种固化剂酸酐基团，和C）含有脲二酮基团的一种或多种加聚化合物，其熔点或范围为40℃至120℃，并由（环）脂族二异氰酸酯制备; 以及其用于涂覆耐热基材，特别是汽车基材的用途。

3. 发明授权

US5464921A Polyisocyanate mixtures, a process for their production and their use for the production of polyurethanes 失效
标题翻译：多异氰酸酯混合物，其生产方法及其用于生产聚氨酯的方法
公开(公告)号：US5464921A
公开(公告)日：1995-11-07
申请号：US156202
申请日：1993-11-22
申请人： Hans-Josef Laas , Reinhard Halpaap , Christian Wamprecht , Hans-Ulrich Meier-Westhues , Wolfgang Schultz , Lothar Kahl
发明人： Hans-Josef Laas , Reinhard Halpaap , Christian Wamprecht , Hans-Ulrich Meier-Westhues , Wolfgang Schultz , Lothar Kahl
IPC分类号： C07C265/14 , C07C265/04 , C07C265/10 , C07C271/10 , C07C271/24 , C07D251/34 , C08G18/10 , C08G18/73 , C08G18/75 , C08G18/76 , C09D5/03 , C09D5/46 , C09D175/00 , C09D175/04 , C08G18/32
CPC分类号： C07C265/10 , C07C265/04 , C07C271/10 , C07C271/24 , C07D251/34
摘要： The present invention relates to polyisocyanate mixtures which are solid below 40.degree. C. and liquid above 125.degree. C. and which havea) an average isocyanate functionality of at least 2.1,b) a content of free isocyanate groups bonded to tertiary (cyclo)aliphatic carbon atoms (calculated as NCO; molecular weight=42) of 5 to 22 wt. %,c) a urethane group content calculated as --NH--CO--O--; molecular weight=59) of 2 to 30 wt. %,d) an isocyanurate group content (calculated as C.sub.3 N.sub.3 O.sub.3 ; molecular weight=126) of 0 to 30 wt. % ande) a carboxylic acid ester group content (calculated as --CO--O--; molecular weight=44) of 0 to 25 wt. % and/orf) a carbonate group content (calculated as --O--CO--O--; molecular weight=60) of from 0 to 34 wt. %with the proviso that the total amount of ester groups e) and carbonate groups f) is at least 2 wt. %.The present invention also relates to a process for the production of these polyisocyanate mixtures and to their use for the production of polyurethanes, in particular as the crosslinking component in heat-curable two-component polyurethane powder coatings for coating heat-resistant substrates.
摘要翻译：本发明涉及固体低于40℃和高于125℃的液体的多异氰酸酯混合物，其具有a）平均异氰酸酯官能度至少为2.1，b）结合到叔（环）的游离异氰酸酯基团的含量，脂肪族碳原子（以NCO计算;分子量= 42）为5〜22重量份。％，c）以-NH-CO-O-计算的氨基甲酸酯基含量; 分子量= 59）为2〜30wt。％，d）异氰脲酸酯基含量（以C3N3O3计算;分子量= 126）为0〜30wt。％和e）羧酸酯基含量（以-CO-O-计算;分子量= 44）为0〜25重量％。％和/或f）0至34重量％的碳酸酯基含量（以-O-CO-O-计算;分子量= 60）％，条件是酯基e）和碳酸酯基团f）的总量为至少2重量％。％。本发明还涉及生产这些多异氰酸酯混合物的方法及其用于生产聚氨酯的方法，特别是作为用于涂覆耐热基材的可热固化双组分聚氨酯粉末涂料中的交联组分。

4. 发明授权

US5621064A Uretdione powder coating cross-linking agents having a low melt viscosity 失效
标题翻译：具有低熔体粘度的Uretdione粉末涂料交联剂
公开(公告)号：US5621064A
公开(公告)日：1997-04-15
申请号：US556549
申请日：1995-11-29
申请人： Hans-Josef Laas , Reinhard Halpaap , Hans-Ulrich Meier-Westhues , Wolfgang Schultz
发明人： Hans-Josef Laas , Reinhard Halpaap , Hans-Ulrich Meier-Westhues , Wolfgang Schultz
IPC分类号： C08G18/32 , C08G18/42 , C08G18/44 , C08G18/65 , C08G18/66 , C08G18/78 , C08G18/79 , C08G18/80 , C09D5/03 , C09D5/46 , C08G18/10
CPC分类号： C08G18/798 , C08G18/8012 , C08G18/8064 , C08G18/808 , C08G2150/20
摘要： The present invention relates to polyaddition compounds that are solid below 40.degree. C. and liquid above 125.degree. C. and contain, based on the weight of the polyaddition compounds,a) 0 to 2% by weight of free isocyanate groups (calculated as NCO; molecular weight=42),b) 3 to 16% by weight of uretdione groups (calculated as C.sub.2 N.sub.2 O.sub.2 ; molecular weight=84),c) 10 to 22% by weight of urethane groups (calculated as --NH--CO--O--; molecular weight=59).d) 0 to 20% by weight of carboxylic add ester groups (calculated as CO--O--; molecular weight=44) ande) of 0 to 25% by weight of carbonate groups (calculated as --O--CO--O--; molecular weight=60),provided that the total content of carboxylic add ester groups and carbonate groups is at least 1% by weight.The present invention also relates to a process for the preparation of these polyaddition compounds and to their use as a starting component for the manufacture of polyurethane plastics, especially as the cross-linking component in thermally cross-linkable two-component polyurethane powder coatings for heat-resistant substrates.
摘要翻译：本发明涉及固体低于40℃，液体高于125℃并含有基于加聚化合物的重量的加成化合物，a）0至2重量％的游离异氰酸酯基团（以NCO计算 ;分子量= 42），b）3至16重量％的脲二酮基团（以C 2 N 2 O 2计算;分子量= 84），c）10至22重量％的氨基甲酸酯基团（以-NH-CO-O- ;分子量= 59）。 d）0至20重量％的羧酸酯基（以CO-O-计算;分子量= 44）和e）0至25重量％的碳酸酯基团（以-O-CO-O-计算）分子量= 60），条件是羧酸酯基和碳酸酯基的总含量为至少1重量％。本发明还涉及一种制备这些加聚化合物的方法及其用作制备聚氨酯塑料的起始组分的用途，特别是作为用于热交联的双组分聚氨酯粉末涂料中的交联组分耐性基材。

5. 发明授权

US5596066A Dimeric diol-modified powder coating cross-linking agents containing uretdione groups 失效
标题翻译：二元二醇改性粉末涂料含有脲二酮基团的交联剂
公开(公告)号：US5596066A
公开(公告)日：1997-01-21
申请号：US582715
申请日：1996-01-04
申请人： Hans-Josef Laas , Reinhard Halpaap , Hans-Ulrich Meier-Westhues , Wolfgang Schultz
发明人： Hans-Josef Laas , Reinhard Halpaap , Hans-Ulrich Meier-Westhues , Wolfgang Schultz
IPC分类号： C08G18/10 , C08G18/32 , C08G18/79 , C08G18/80 , C09D5/03 , C09D5/46 , C09D175/00 , C09D175/04
CPC分类号： C08G18/8064 , C08G18/798 , C08G18/8012 , C08G2150/20
摘要： Polyisocyanate polyaddition products which are solid below 40.degree. C. and liquid above 125.degree. C., contain uretdione and urethane groups and have a content of at least 1 wt. % of urethane groups obtained from the reaction of dimeric diols with isocyanate groups; a method of producing the these products by the reaction of polyisocyanates containing uretdione groups with dimeric diols; and the use of these polyaddition compounds as the starting component in the manufacture of polyurethane plastics, particularly as the cross-linking component in thermally cross-linkable two-component polyurethane powder coating compositions.
摘要翻译：固体低于40℃的多异氰酸酯加成产物和高于125℃的液体含有脲二酮和氨基甲酸酯基并且含量至少为1重量％。由二聚二醇与异氰酸酯基反应获得的氨基甲酸酯基团的％; 通过含有脲二酮基团的多异氰酸酯与二聚二醇的反应制备这些产物的方法; 以及这些加聚化合物作为起始组分在制备聚氨酯塑料中的用途，特别是作为可热交联的双组分聚氨酯粉末涂料组合物中的交联组分。

6. 发明授权

US5508337A Powder coating compositions, a process for their preparation, and their use for the coating of heat resistant substrates 失效
标题翻译：粉末涂料组合物，其制备方法及其用于涂覆耐热基材的用途
公开(公告)号：US5508337A
公开(公告)日：1996-04-16
申请号：US238563
申请日：1994-05-05
申请人： Christian Wamprecht , Reinhard Halpaap , Hans-Ulrich Meier-Westhues , Wolfgang Schultz
发明人： Christian Wamprecht , Reinhard Halpaap , Hans-Ulrich Meier-Westhues , Wolfgang Schultz
IPC分类号： C08G18/40 , C08G18/78 , C08G18/79 , C08G18/80 , C09D5/46 , C08J3/00 , C08F8/30 , C08K3/20 , C08L75/00
CPC分类号： C08G18/7831 , C08G18/4063 , C08G18/792 , C08G18/8077 , C08G2150/20 , Y10T428/31551
摘要： The present invention relates to a powder coating composition having a glass transition temperature of 20.degree. to 80.degree. C. and containing(A) 56 to 86.9% by weight of a polyacrylate polyol component having a hydroxyl number of 30 to 155 and a glass transition temperature of 30.degree. to 120.degree. C.,(B) 0.1 to 9% by weight of a polyester polyol component having a hydroxyl number of 40 to 180 and a glass transition temperature of -40.degree. to 80.degree. C.,(C) 13 to 35% by weight of a polyisocyanate component having a glass transition temperature of -40.degree. to 60.degree. C. and containing at least one ketoxime-blocked polyisocyanate selected from (i) polyisocyanate derivatives prepared from 1,6-diisocyanatohexane and containing biuret, isocyanurate, uretdione, and/or urethane groups, (ii) polyisocyanate derivatives prepared from mixtures of 1,6-diisocyanatohexane and 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane and containing isocyanurate groups and optionally uretdione groups and (iii) polyisocyanate derivatives prepared from 4,4'-diisocyanato-dicyclohexylmethane and containing urethane groups, and(D) at least one catalyst for the reaction between blocked isocyanate groups and hydroxyl groups,wherein i) the percentages of components (A), (B), and (C) are based on the total weight of these components and ii) components (A), (B), and (C) are present in amounts sufficient to provide an equivalent ratio of blocked isocyanate groups to hydroxyl groups of 0.5:1 to 1.5:1.The present invention is also relates to a process for the preparation of this powder coating composition and to heat-resistant substrates, particularly automotive body parts, coated with this powder coating composition.
摘要翻译：本发明涉及玻璃化转变温度为20〜80℃，含有（A）56〜86.9重量％的羟基数为30〜155的聚丙烯酸酯多元醇成分和玻璃化转变温度的粉末涂料组合物温度为30〜120℃，（B）0.1〜9重量％的羟值为40〜180，玻璃化转变温度为-40〜80℃的聚酯多元醇成分，（C） 13至35重量％的玻璃化转变温度为-40至60℃的多异氰酸酯组分，并含有至少一种酮肟封闭的多异氰酸酯，其选自（i）由1,6-二异氰酸根合己烷制备并含有缩二脲，异氰脲酸酯，脲二酮和/或氨基甲酸酯基团，（ii）由1,6-二异氰酸根合己烷和1-异氰酸根合-3,3,5-三甲基-5-异氰酸甲酯基环己烷的混合物制备并含有异氰脲酸酯基团和任选的脲二酮基团的多异氰酸酯衍生物，（iii ）由4,4'-二异氰酸根合二环己基甲烷制备并含有氨基甲酸酯基团的多异氰酸酯衍生物，和（D）至少一种用于封端异氰酸酯基和羟基之间反应的催化剂，其中i）组分（A），（B ）和（C）基于这些组分的总重量，和ii）组分（A），（B）和（C）以足以提供封端异氰酸酯基与羟基的当量比为0.5的量存在：1〜1.5：1。本发明还涉及这种粉末涂料组合物的制备方法以及涂覆有该粉末涂料组合物的耐热基材，特别是汽车车身部件。

7. 发明授权

US5510444A Powder coating compositions and their use for coating heat-resistant substrates 失效
标题翻译：粉末涂料组合物及其用于涂覆耐热基材的用途
公开(公告)号：US5510444A
公开(公告)日：1996-04-23
申请号：US390393
申请日：1995-02-16
申请人： Reinhard Halpaap , Hans-Ulrich Meier-Westhues , Christian Wamprecht , Manfred Bock , Wolfgang Schultz , Lothar Kahl
发明人： Reinhard Halpaap , Hans-Ulrich Meier-Westhues , Christian Wamprecht , Manfred Bock , Wolfgang Schultz , Lothar Kahl
IPC分类号： C09D5/03 , C08G18/38 , C08G18/40 , C08G18/42 , C08G18/62 , C08G18/64 , C08G18/79 , C08G18/80 , C09D5/46 , C09D175/00 , C09D175/04
CPC分类号： C08G18/6415 , C08G18/3831 , C08G18/40 , C08G18/42 , C08G18/6229 , C08G18/6258 , C08G18/792 , C08G18/8009 , C08G2150/20 , Y10T428/31547
摘要： A powder coating composition for the production of non-yellowing, flexible coatings which contains a mixture of a polyisocyanate component which contains one or more lacquer polyisocyanates having free (unblocked) isocyanate groups bound to primary and/or secondary carbon atoms and a polyol component containing one or more polyhydroxyl compounds selected from polyhydroxy polyurethanes, polyhydroxy polyacrylates and polyhydroxy polyesters, wherein at least 50% of the hydroxyl groups are bound to secondary or tertiary carbon atoms; and its use for coating heat-resistant substrates, in particular as clear coating compositions for automobiles.
摘要翻译：一种用于生产非黄变柔性涂层的粉末涂料组合物，其含有多异氰酸酯组分的混合物，所述多异氰酸酯组分含有一个或多个具有与伯和/或次碳原子结合的游离（未封端）异氰酸酯基团的多元醇多异氰酸酯和含有一种或多种选自多羟基聚氨酯，多羟基聚丙烯酸酯和多羟基聚酯的多羟基化合物，其中至少50％的羟基与仲或叔碳原子结合; 以及其用于涂覆耐热基材，特别是作为汽车的透明涂料组合物的用途。

8. 发明申请

US20110319982A1 IMPLANT AND METHOD FOR MANUFACTURING SAME 审中-公开
标题翻译：植入物及其制造方法
公开(公告)号：US20110319982A1
公开(公告)日：2011-12-29
申请号：US13164127
申请日：2011-06-20
申请人： Ullrich Bayer , Wolfgang Schultz , Nils Venohr , Johannes Riedmueller , Martina Schroeder
发明人： Ullrich Bayer , Wolfgang Schultz , Nils Venohr , Johannes Riedmueller , Martina Schroeder
IPC分类号： A61F2/82 , B32B38/10 , B32B37/02
CPC分类号： A61L31/022 , A61L31/088 , A61L31/148 , A61L31/18 , Y10T156/10 , Y10T156/1052 , Y10T156/1062
摘要： The present invention relates to an implant, in particular an intraluminal endoprothesis, comprising a body containing a metallic material, and comprising at least one functional element that is fastened to the body and has a material composition in at least a portion of its volume that differs from the material of the body, the material composition preferably including radio-opaque and/or x-ray opaque material. To effectively prevent accelerated degradation due to the formation of a local cell of the material of the body and the functional element, the at least one functional element includes a first layer at least in the region of its surface where it is bonded to the body, the first layer primarily containing at least one metal oxide. Furthermore, the manufacture of an implant of this type is described.
摘要翻译：本发明涉及一种植入物，特别是腔内内方法，其包括含有金属材料的主体，并且包括至少一个功能元件，所述至少一个功能元件被紧固到所述主体并且具有不同的体积的至少一部分的材料组成材料组合物优选地包括不透射线和/或X射线不透明材料。为了有效地防止由于主体和功能元件的材料的局部电池的形成而引起的加速退化，至少一个功能元件至少在其表面的与其结合的主体的区域中包括第一层，第一层主要含有至少一种金属氧化物。此外，描述了这种类型的植入物的制造。

9. 发明授权

US5065524A Device for measuring the internal diameter of tubes 失效
标题翻译：用于测量管内径的装置
公开(公告)号：US5065524A
公开(公告)日：1991-11-19
申请号：US551761
申请日：1990-07-11
申请人： Andreas Langowski , Wolfgang Schultz , Gerhard Walter
发明人： Andreas Langowski , Wolfgang Schultz , Gerhard Walter
IPC分类号： G01B5/12
CPC分类号： G01B5/12
摘要： The device for measuring the internal diameter of tubes 2 consisting of two interconnected measuring units 3 and 4 that are connected to one another. The first measuring unit 3 is formed by a measuring head 9 in conjunction with a displacement transducer 7, which is axially displaceable within a tube 2. The axial displacement of the measuring head 9 is determined by a length measuring device consisting of a friction wheel 25 associated with a rotation transducer. To achieve this, the friction wheel is in functional connection with a flexible tube 24 which is rigidly connected to the measuring head 9. Thus, this measuring device makes it possible to determine internal diameters at two positions located at axially spaced locations from one another in a tube 2.
摘要翻译：用于测量由彼此连接的两个相互连接的测量单元3和4组成的管2的内径的装置。第一测量单元3由测量头9结合位移传感器7形成，位移传感器7可在管2内轴向移动。测量头9的轴向位移由长度测量装置确定，该测量装置由摩擦轮25 与旋转传感器相关联。为了实现这一点，摩擦轮与刚性地连接到测量头9的柔性管24功能连接。因此，该测量装置使得可以确定位于彼此轴向间隔开的位置处的两个位置处的内径管2。

10. 发明授权

US10272183B2 Implant and method for manufacturing same 有权
公开(公告)号：US10272183B2
公开(公告)日：2019-04-30
申请号：US13164127
申请日：2011-06-20
申请人： Ullrich Bayer , Wolfgang Schultz , Nils Venohr , Johannes Riedmueller , Martina Schroeder
发明人： Ullrich Bayer , Wolfgang Schultz , Nils Venohr , Johannes Riedmueller , Martina Schroeder
IPC分类号： A61F2/82 , A61L31/02 , A61L31/08 , A61L31/14 , A61L31/18
摘要： The present invention relates to an implant, in particular an intraluminal endoprothesis, comprising a body containing a metallic material, and comprising at least one functional element that is fastened to the body and has a material composition in at least a portion of its volume that differs from the material of the body, the material composition preferably including radio-opaque and/or x-ray opaque material. To effectively prevent accelerated degradation due to the formation of a local cell of the material of the body and the functional element, the at least one functional element includes a first layer at least in the region of its surface where it is bonded to the body, the first layer primarily containing at least one metal oxide. Furthermore, the manufacture of an implant of this type is described.

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