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1. 发明授权

US4728443A Textile softening detergent composition 失效
标题翻译：纺织软化洗涤剂组合物
公开(公告)号：US4728443A
公开(公告)日：1988-03-01
申请号：US725376
申请日：1985-04-22
申请人： Hans-Peter Rieck , Jurgen Grosse , Werner Gohla
发明人： Hans-Peter Rieck , Jurgen Grosse , Werner Gohla
IPC分类号： C11D3/12 , D06M11/00
CPC分类号： C11D3/1273 , C11D3/124
摘要： A textile softening detergent composition contains from 5 to 70 wgt % surfactant, from 0.5 to 50 wgt % builder, from 1 to 20 wgt % crystalline laminated silicic acid and/or a corresponding alkali metal silicate and standard detergent aids. It is characterized in that the crystalline laminated silicic acid or its alkali metal salt of the general formulaM.sub.2 Si.sub.x O.sub.2x+1 .multidot.y H.sub.2 Oin which x stands for a number larger than 7.0, M stands for sodium, potassium or hydrogen, and y stands for a number of from 0 to 25, shows one or more reflexes unassignable to quartz, tridymite and cristobalite in the X-ray diffraction diagram in the range of the d-values of 3.0-4.0.multidot.10.sup.-8 cm. Process for rinsing textiles using the crystalline laminated silic acid or its alkali metal salts as a textile softening agent.
摘要翻译：织物软化洗涤剂组合物含有5-70重量％表面活性剂，0.5-50重量％助洗剂，1-20重量％结晶层状硅酸和/或相应的碱金属硅酸盐和标准洗涤助剂。其特征在于结晶层状硅酸或其通式为M2SixO2x + 1xyH2O的碱金属盐，其中x表示大于7.0的数，M表示钠，钾或氢，y表示数从0到25，在d值为3.0-4.0x10-8 cm的范围内，在X射线衍射图中显示了对石英，鳞石英和方英石不可分的一种或多种反射。使用结晶层状硅酸或其碱金属盐作为织物软化剂漂洗纺织品的方法。

2. 发明授权

US4950310A Process for the preparation of crystalline sheet sodium silicates 失效
标题翻译：制备结晶片状硅酸钠的方法
公开(公告)号：US4950310A
公开(公告)日：1990-08-21
申请号：US281805
申请日：1988-12-08
申请人： Hans-Peter Rieck , Martin Schott , Willy Ott , Werner Gohla
发明人： Hans-Peter Rieck , Martin Schott , Willy Ott , Werner Gohla
IPC分类号： C01B33/32 , C01B33/38 , C11D3/08 , C11D3/12 , C11D11/02
CPC分类号： C01B33/38 , C11D11/02 , C11D3/1273
摘要： X-ray crystalline sodium silicates having a sheet structure and an SiO.sub.2 :Na.sub.2 O molar ratio of 1.9 to 3.5 are prepared by dissolving an X-ray crystalline sodium silicate having a sheet structure and an SiO.sub.2 /Na.sub.2 O molar ratio of 1.9:1 to 3.5:1 in water and evaporating the solution at temperatures of 20.degree. to 445.degree. C.For the preparation of detergents or cleaners, a mixture of surfactants and builders, which may also contain fillers, bleaching agents, bleach activators and enzymes, is made into a paste with water, mixed with an X-ray crystalline sheet sodium silicate having an SiO.sub.2 /Na.sub.2 O molar ratio of 1.9:1 to 3.5:1, mixed thoroughly and then spray-dried.
摘要翻译：通过将具有片状结构和SiO 2 / Na 2 O摩尔比为1.9:1的X射线结晶硅酸钠溶解为3.5:1制备具有片状结构和SiO 2 :Na 2 O摩尔比为1.9至3.5的X射线结晶硅酸钠。 1在水中并在20℃至445℃的温度下蒸发溶液。为了制备洗涤剂或清洁剂，还可以含有填料，漂白剂，漂白活化剂和酶的表面活性剂和助洗剂的混合物制成用水糊化，与SiO 2 / Na 2 O摩尔比为1.9:1〜3.5:1的X射线结晶片硅酸钠混合，充分混合，然后喷雾干燥。

3. 发明授权

US4749758A Process for the preparation of copolymers of vinylphosphonic acid and (meth) acrylic acid in aqueous solution 失效
标题翻译：乙烯基膦酸和（甲基）丙烯酸在水溶液中的共聚物的制备方法
公开(公告)号：US4749758A
公开(公告)日：1988-06-07
申请号：US858568
申请日：1986-04-24
申请人： Walter Dursch , Jurgen Grosse , Werner Gohla , Friedrich Engelhardt , Ulrich Riegel
发明人： Walter Dursch , Jurgen Grosse , Werner Gohla , Friedrich Engelhardt , Ulrich Riegel
IPC分类号： C08F2/00 , C08F4/32 , C08F30/00 , C08F30/02 , C08F220/06 , C08F230/02 , C11D3/37
CPC分类号： C08F230/02 , C11D3/3784
摘要： Process for the preparation of polymers of vinylphosphonic acid in water with the aid of catalysts which form free radicals, which comprises heating vinylphosphonic acid and (meth)acrylic acid to temperatures of 40.degree. to 120.degree. C. in water in the presence of 1 to 5.5% by weight of aliphatic peroxy esters and/or diacyl peroxides which dissociate by half in one hour at temperatures below 122.degree. C., the total amount of vinylphosphonic acid being taken together with up to 30% by weight, based on the total amount of monomer, of (meth)acrylic acid and the remainder of the (meth)acrylic acid being added in the course of the reaction.The copolymers are suitable for use in detergent and cleaning agents.
摘要翻译：借助于形成自由基的催化剂制备乙烯基膦酸在水中的聚合物的方法，该催化剂包括将乙烯基膦酸和（甲基）丙烯酸在40℃至120℃的温度下在1〜 5.5％（重量）脂肪族过氧酯和/或二酰基过氧化物，其在低于122℃的温度下在1小时内解离了一半，乙烯基膦酸的总量基于总量达到30重量％的单体，（甲基）丙烯酸，其余的（甲基）丙烯酸是在反应过程中加入的。该共聚物适用于洗涤剂和清洁剂。

4. 发明授权

US4265776A Detergent and cleaning compositions 失效
标题翻译：洗涤剂和清洁剂组合物
公开(公告)号：US4265776A
公开(公告)日：1981-05-05
申请号：US130156
申请日：1980-03-13
申请人： Werner Gohla , Klaus Hestermann , Joachim Kandler , Horst-Dieter Wasel-Nielen , Klaus Sommer , Hans-Adolf Rohlfs , Karl Merkenich
发明人： Werner Gohla , Klaus Hestermann , Joachim Kandler , Horst-Dieter Wasel-Nielen , Klaus Sommer , Hans-Adolf Rohlfs , Karl Merkenich
IPC分类号： C07F9/38 , C07F9/40 , C11D3/36 , C11D3/30 , C11D7/56 , C11D9/42
CPC分类号： C11D3/365
摘要： The invention provides cleaning and detergent compositions which contain about 0.2 to 5 weight % of at least one compound of the general formula (I) ##STR1## in which R stands for a hydrogen atom or a methyl group and R.sub.1 stands for a hydrogen atom or an alkali metal or NH.sub.4 -ion.
摘要翻译：本发明提供了包含约0.2至5重量％的至少一种通式（I）的化合物的清洁和洗涤剂组合物，其中R代表氢原子或甲基，R1代表氢原子或碱金属或NH4-离子。

5. 发明授权

US5078895A Washing agent with storage-stabilized bleach system 失效
标题翻译：洗涤剂与储存稳定的漂白系统
公开(公告)号：US5078895A
公开(公告)日：1992-01-07
申请号：US627884
申请日：1990-12-13
申请人： Franz-Josef Dany , Werner Gohla , Gunther Schimmel , Hans P. Rieck , Ingrid Czeslik
发明人： Franz-Josef Dany , Werner Gohla , Gunther Schimmel , Hans P. Rieck , Ingrid Czeslik
IPC分类号： C11D3/395 , C11D3/08 , C11D3/12 , C11D3/39 , D06L1/12 , D06L3/02
CPC分类号： C11D3/1273 , C11D3/3917
摘要： The invention relates to a washing agent with a storage-stabilized bleach system and 2 to 20% by weight of detergents and conventional washing auxiliaries, including fillers, the washing agent containing 10 to 50% by weight of a crystalline layered silicate as a builder as well as 1 to 5% by weight of tetraacetylethylenediamine (TAED) and a bleach, the quantity of bleach being such that 0.5 to 4% by weight of washing-active oxygen (AVOX) is present in the washing agent.
摘要翻译：本发明涉及具有储存稳定的漂白系统和2至20重量％的洗涤剂和常规洗涤助剂（包括填料）的洗涤剂，洗涤剂含有10至50重量％的作为助洗剂的结晶层状硅酸盐，以及1-5重量％的四乙酰乙二胺（TAED）和漂白剂，洗涤剂中存在漂白剂的量为0.5-4重量％的洗涤活性氧（AVOX）。

6. 发明授权

US5096609A Detergent containing sodium disilicate having a water content of 0.3 to 6% by weight 失效
标题翻译：含有0.3〜6％重量含水量的洗涤剂
公开(公告)号：US5096609A
公开(公告)日：1992-03-17
申请号：US649451
申请日：1991-02-01
申请人： Franz-Josef Dany , Werner Gohla , Gerhard Kalteyer , Joachim Kandler , Hans Kramer
发明人： Franz-Josef Dany , Werner Gohla , Gerhard Kalteyer , Joachim Kandler , Hans Kramer
IPC分类号： C11D3/12 , C11D3/08
CPC分类号： C11D3/08
摘要： A detergent containing 5 to 50% by weight of at least one surfactant, 0.5 to 60% by weight of a matrix substance and also standard laundry aids, contains as matrix substance an amorphous, low-water sodium disilicate having a water content of 0.3 to 6% by weight which has preferably been produced by partial dehydration of commercially available powdered amorphous sodium disilicate having a water content of 15 to 23% by weight.
摘要翻译：含有5〜50重量％的至少一种表面活性剂，0.5〜60重量％的基质物质和标准洗衣助剂的洗涤剂含有作为基质物质的无定形低水二硅酸钠，其含水量为0.3〜 6重量％，优选通过部分脱水得到水含量为15〜23重量％的市售粉末状无定形二硅酸钠。

7. 发明授权

US5082504A Process for the preparation of a mixture of sucrose oxidation products and the use thereof 失效
标题翻译：制备硫化氧化产物及其用途的方法
公开(公告)号：US5082504A
公开(公告)日：1992-01-21
申请号：US462489
申请日：1990-01-10
申请人： Ernst I. Leupold , Karl-Heinz Schonwalder , Wolfram Fritsche-Lang , Merten Schlingmann , Adolf Linkies , Werner Gohla , Franz-Josef Dany
发明人： Ernst I. Leupold , Karl-Heinz Schonwalder , Wolfram Fritsche-Lang , Merten Schlingmann , Adolf Linkies , Werner Gohla , Franz-Josef Dany
IPC分类号： A23L1/30 , B01J23/40 , C07B61/00 , C07H7/033 , C11D1/04 , C11D1/08 , C11D3/22
CPC分类号： C11D3/221 , A23L33/10 , C07H7/033 , A23V2002/00
摘要： A process for the preparation of a mixture of sucrose oxidation products which contains a salt of sucrosetricarboxylic acid and which is obtained by reaction of sucrose with oxygen in an aqueous medium in the presence of a platinum metal/active carbon catalyst at elevated temperatures and neutralization of the reaction product to convert into the salt form, which comprises the reaction being carried out discontinuously, the starting materials being heated stepwise over the course of several hours from room temperature up to 60.degree. to 95.degree. C. and then the reaction product being isolated where appropriate.The oxidation products obtained in this way have, in particular, improved washing properties.
摘要翻译：制备蔗糖氧化产物的混合物的方法，所述蔗糖氧化产物含有蔗糖三羧酸的盐，其通过在铂金属/活性炭催化剂的存在下在水性介质中在高温下与蔗糖与氧反应获得并中和反应产物转化为盐形式，其中包括反应不连续地进行，起始物料在几个小时内从室温逐步加热至60℃至95℃，然后将反应产物分离在适当情况下。以这种方式获得的氧化产物尤其具有改进的洗涤性能。

8. 发明授权

US4308158A Detergent and cleaning compositions containing polymeric phosphate builders 失效
标题翻译：含有聚合磷酸盐助洗剂的洗涤剂和清洁组合物
公开(公告)号：US4308158A
公开(公告)日：1981-12-29
申请号：US36403
申请日：1979-05-07
申请人： Werner Gohla , Klaus Hestermann , Joachim Kandler , Horst-Dieter Wasel-Nielen , Karl Merkenich
发明人： Werner Gohla , Klaus Hestermann , Joachim Kandler , Horst-Dieter Wasel-Nielen , Karl Merkenich
IPC分类号： C11D3/06 , C11D3/065 , C11D7/16
CPC分类号： C11D3/06
摘要： The invention provides cleaning and detergent compositions containing about:5 to 30 weight % of a surfactant and10 to 30 weight % of a builder mixture consisting of alkali metal orthophosphate, alkali metal pyrophosphate, alkali metal tripolyphosphate and alkali metal melt phosphate, wherein the ratio by weight of the sum of orthophosphate, pyrophosphate and tripolyphosphate to melt phosphate is about 30:1 to 1:30, the ratio by weight of orthophosphate to pyrophosphate is about 10:1 to 1:10, and the ratio by weight of orthophosphate to tripolyphosphate is about 20:1 to 1:20, the balance being detergent auxiliaries and addends.
摘要翻译：本发明提供了含有约5至30重量％的表面活性剂和10至30重量％的由碱金属正磷酸盐，碱金属焦磷酸盐，碱金属三聚磷酸盐和碱金属熔融磷酸盐组成的助洗剂混合物的清洁和洗涤剂组合物，重量的正磷酸盐，焦磷酸盐和三聚磷酸盐之间的熔融磷酸盐的总量为约30:1至1:30，正磷酸盐与焦磷酸盐的重量比为约10:1至1:10，并且正磷酸盐与重量比三聚磷酸盐约为20:1至1:20，其余为洗涤剂助剂和附加物。

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