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1. 发明授权

US4730041A Preparation of .epsilon.-caprolactams 失效
标题翻译： ε-己内酰胺的制备
公开(公告)号：US4730041A
公开(公告)日：1988-03-08
申请号：US7789
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
发明人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
IPC分类号： B01J23/74 , B01J23/78 , B01J25/00 , C07B61/00 , C07D201/08
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared by a process in which(a) a 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as a solvent and in the presence of a hydrogenation catalyst under superatmospheric pressure in the liquid phase at from 40.degree. to 130.degree. C.,(b) excess ammonia and hydrogen are separated off from the reaction mixture and(c) the reaction mixture thus obtained is heated to 150.degree.-250.degree. C. and .epsilon.-caprolactam is obtained.
摘要翻译：己内酰胺通过以下方法制备：其中（a）5-烷基戊酸酯与过量的氨和氢在烷醇作为溶剂的存在下和氢化催化剂的存在下在超大气压下在40℃的液相中反应至130℃，（b）从反应混合物中分离出过量的氨和氢，（c）将所得反应混合物加热至150-250℃，得到ε-己内酰胺。

2. 发明授权

US4766237A Preparation of 6-aminocaproates 失效
标题翻译： 6-氨基己酸酯的制备
公开(公告)号：US4766237A
公开(公告)日：1988-08-23
申请号：US7578
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
发明人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
IPC分类号： C07B61/00 , B01J21/16 , B01J23/00 , B01J23/74 , B01J23/755 , B01J25/02 , C07C67/00 , C07C227/00 , C07C227/04 , C07C227/08 , C07C229/08 , C07C67/30
CPC分类号： C07C227/08
摘要： In an improved process for the preparation of 6-aminocaproates by reacting a 5-formylvalerate with ammonia and hydrogen using an alkanol as a solvent in the presence of a hydrogenation catalyst at elevated temperatures and under superatmospheric pressure, the improvement comprises carrying out the reaction at from 40.degree. to 95.degree. C.
摘要翻译：在氢化催化剂存在下，在升高的温度和超大气压下，通过使用烷醇作为溶剂使5-甲酰基戊酸与氨和氢反应制备6-氨基己酸酯的改进方法，其改进包括在从40℃到95℃

3. 发明授权

US4745228A Preparation of cyclic ketones 失效
标题翻译：环酮的制备
公开(公告)号：US4745228A
公开(公告)日：1988-05-17
申请号：US65959
申请日：1987-06-24
申请人： Martin Decker , Rolf Fischer , Wolfgang Franzischka , Rudolf Kummer , Heinz-Walter Schneider , Uwe Vagt
发明人： Martin Decker , Rolf Fischer , Wolfgang Franzischka , Rudolf Kummer , Heinz-Walter Schneider , Uwe Vagt
IPC分类号： C07C45/48 , C07C45/00 , C07C45/51
CPC分类号： C07C45/48
摘要： Cyclic ketones of the formula ##STR1## where n is an integer from 4 to 6, are prepared by converting an aliphatic dicarboxylate of the formulaR.sup.1 OCC--(CH.sub.2).sub.n --COOR.sup.2 IIwhere n has the above meaning, R.sup.1 and R.sup.2 are each alkyl, cycloalkyl, aralkyl or aryl and R.sup.2 may furthermore be hydrogen, at from 150.degree. to 450.degree. C. over a solid oxide catalyst.
摘要翻译：通过将式R 1 OCC-（CH 2）n -COOR 2 II的脂肪族二羧酸酯转化为其中n具有上述含义，R1和R2各自为烷基，其中n为4-6的整数，其中n为4至6的整数的式，环烷基，芳烷基或芳基，R2可以为氢，在固体氧化物催化剂上为150-450℃。

4. 发明授权

US5189182A Preparation of 5-methylbutyrolactone 失效
标题翻译： 5-甲基丁酰胺的制备
公开(公告)号：US5189182A
公开(公告)日：1993-02-23
申请号：US236199
申请日：1988-08-25
申请人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： C07D315/00
CPC分类号： C07D315/00
摘要： 5-Methylbutyrolactone is prepared by a process in which a pentenoic ester of the formula IX--CO.sub.2 R (I),where X is CH.sub.2 .dbd.CH--CH.sub.2 --CH.sub.2 --, CH.sub.3 --CH.dbd.CH--CH.sub.2 -- or CH.sub.3 --CH.sub.2 --CH.dbd.CH-- and R is alkyl, cycloalkyl, aralkyl or aryl, or a mixture of these esters is reacted with water at from 50.degree. to 350.degree. C. in the presence or absence of a diluenta) over a zeolite and/or phosphate catalyst orb) in the presence of from 0.01 to 0.25 mole of a sulfonic acid, a Lewis acid and/or a non-oxidizing mineral acid per mole of pentenoic ester or over from 0.1 to 40% by weight, based on the pentenoic ester, of a strongly acidic ion exchanger as a catalyst in a first stage, or the pentenoic ester of the formula I, where X and R have the stated meanings, is hydrolyzed in a first stage with the aid of a strongly acidic ion exchanger as a catalyst to give the pentenoic acid of the formula I, where R is hydrogen, and the resulting pentenoic acid is subjected to cyclization in a second stage in the presence of from 0.005 to 0.1 mole of a sulfonic acid, a Lewis acid or a non-oxidizing mineral acid per mole of pentenoic acid or over from 0.1 to 20% by weight, based on the pentenoic acid, of a strongly acidic ion exchanger at from 50.degree. to 350.degree. C.
摘要翻译：通过以下方法制备5-甲基丁内酯，其中式I X-CO 2 R（I）的戊烯酸酯，其中X为CH 2 = CH-CH 2 -CH 2 - ，CH 3 -CH = CH-CH 2 - 或CH 3 -CH 2 -CH = CH-和R是烷基，环烷基，芳烷基或芳基，或这些酯的混合物与水在50-350℃下在存在或不存在稀释剂a）的情况下与沸石和/或磷酸盐催化剂或b）在0.01至0.25摩尔磺酸，路易斯酸和/或非氧化性无机酸/摩尔烯酸酯存在下或基于戊烯酸酯为0.1至40重量％的作为第一阶段的催化剂的强酸性离子交换剂或其中X和R具有所述含义的式I的戊烯酸在第一阶段中借助于强酸性离子交换剂作为催化剂得到式I的戊烯酸，其中R是氢，所得戊烯酸在第二阶段中在0.005t的存在下进行环化 o 0.1摩尔磺酸，路易斯酸或非氧化性无机酸/摩尔烯酸，或超过0.1-20重量％，基于戊烯酸，强酸性离子交换剂为50〜 350℃

5. 发明授权

US5003102A Preparation of 5-formylvaleric esters 失效
标题翻译： 5-甲酰戊酸酯的制备
公开(公告)号：US5003102A
公开(公告)日：1991-03-26
申请号：US206751
申请日：1988-06-15
申请人： Werner Bertleff , Rolf Fischer , Rudolf Kummer , Franz Merger , Heinz-Walter Schneider
发明人： Werner Bertleff , Rolf Fischer , Rudolf Kummer , Franz Merger , Heinz-Walter Schneider
IPC分类号： C07B61/00 , C07C67/313 , C07C69/66 , C07C69/67
CPC分类号： C07C67/347
摘要： 5-Formylvaleric esters are prepared by a process which comprises the following steps:(a) Hydroformylation of a pentenoic ester by reaction with carbon monoxide and hydrogen at elevated temperatures and under superatmospheric pressure in the presence of a carbonyl complex of a metal of group 8 of the Periodic Table with formation of a mixture of 5-, 4- and 3-formylvaleric esters,(b) Isolation of the 5-formylvaleric ester from the resulting mixture of 5-, 4- and 3-formylvaleric esters, a mixture essentially consisting of 4- and 3-formylvaleric esters remaining,(c) Cleavage of the mixture essentially consisting of 4- and 3-formylvaleric esters at from 50.degree. to 400.degree. C. in the presence of a catalyst to give pentenoic esters and(d) Recycling of the pentenoic esters to stage (a).
摘要翻译： 5-甲酰戊酸酯通过包括以下步骤的方法制备：（a）在升高的温度和超大气压下，在第8组的金属的羰基络合物存在下，通过与一氧化碳和氢气反应来进行戊烯基酯的加氢甲酰化的化合物，形成5-，4-和3-甲酰基戊酸酯的混合物，（b）从得到的5-，4-和3-甲酰基戊酸酯混合物中分离5-甲酰基戊酸酯，基本上由4-和3-甲酰基戊酸酯组成，（c）在催化剂存在下，在50-400℃下将基本上由4-和3-甲酰基戊酸酯组成的混合物切割，得到戊烯酸酯和（d ）将戊烯酸酯循环回到（a）阶段。

6. 发明授权

US4537987A Preparation of pure monoesters of adipic acid 失效
标题翻译：己二酸纯单酯的制备
公开(公告)号：US4537987A
公开(公告)日：1985-08-27
申请号：US629766
申请日：1984-07-11
申请人： Heinz-Walter Schneider , Wolfgang Richter , Walter Disteldorf , Rudolf Kummer
发明人： Heinz-Walter Schneider , Wolfgang Richter , Walter Disteldorf , Rudolf Kummer
IPC分类号： B01J31/00 , B01J31/20 , B01J31/24 , C07B61/00 , C07C67/313 , C07C67/38 , C07C67/39 , C07C69/44 , C07C69/67
CPC分类号： C07C67/39
摘要： Pure monoesters of adipic acid are prepared by a process in which(a) a pentenoate is reacted with carbon monoxide and hydrogen at from 90.degree. to 140.degree. C. and under from 5 to 300 bar in the presence of a carbonyl complex of cobalt or of rhodium, and a 5-formylvalerate is separated off, and(b) the 5-formylvalerate thus obtained is oxidized with molecular oxygen, or with a gas containing this, at from 20.degree. to 100.degree. C. under from 1 to 10 bar.
摘要翻译：己二酸的纯单酯通过以下方法制备，其中（a）戊烯酸酯与一氧化碳和氢气在90至140℃和5至300巴下在钴或羰基络合物存在下反应的铑，并分离出5-甲酰基戊酸酯，（b）将所得的5-甲酰基戊酸酯用分子氧或含有该气体的气体在20至100℃下在1至10巴。

7. 发明授权

US5817592A Process for the preparation of a hydrogenation catalyst 失效
标题翻译：制备氢化催化剂的方法
公开(公告)号：US5817592A
公开(公告)日：1998-10-06
申请号：US590455
申请日：1996-01-23
申请人： Daniel Heineke , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Heinz-Walter Schneider , Alfred Thome
IPC分类号： B01J23/42 , B01J23/96 , B01J37/16 , B01J38/64 , C01B21/14 , B01J21/18 , B01J23/16 , B01J27/185
CPC分类号： B01J23/42 , B01J37/16 , C01B21/1418
摘要： A process for the preparation of a hydrogenation catalyst by reduction of platinum in an oxidation stage of not less than 2 in an aqueous medium in the presence of a carboniferous support, optionally following partial poisoning with a sulfur, arsenic, tellurium, or antimony-containing compound, using a reducing agent, in which the reducing agent used is an ammonium or phosphonium salt of the general formula I �XR.sup.4 !.sub.n Y I in which X stands for N or P, R stands for hydrogen, C.sub.1 --C.sub.18 alkyl, C.sub.5 --C.sub.10 cycloalkyl, phenyl radical, and also a C.sub.1 --C.sub.4 alkyl radical substituted by phenyl, the phenyl radicals being mono-to tri-substituted by C.sub.1 --C.sub.6 alkyl, halogen, nitro or amino, if desired, provided that the radicals R may be the same or different but cannot simultaneously denote hydrogen, if X is P, n is an integer of 1 to 3, and Y is an organic anion which can reduce platinum in an oxidation stage other than zero to platinum in the oxidation stage of zero.
摘要翻译：一种通过在含水载体的存在下在水性介质中在不少于2的氧化阶段还原铂的氢化催化剂的方法，任选地在用硫，砷，碲或含锑的部分中毒后化合物，使用还原剂，其中所用的还原剂是通式I [XR4] nYinin的铵盐或鏻盐，其中X代表N或P，R代表氢，C1-C18烷基，C5-C10环烷基苯基，以及被苯基取代的C1-C4烷基，如果需要，苯基由C1-C6烷基，卤素，硝基或氨基单取代至三取代，条件是基团R可以相同或不同，但不能同时表示氢，如果X为P，n为1至3的整数，Y为有机阴离子，在氧化阶段为零的情况下，铂可以在除氧以外的氧化阶段中还原为铂。

8. 发明授权

US5639706A Hydrogenation catalyst based on a platinum metal partially poisoned with finely divided sulfur 失效
标题翻译：基于铂金属的氢化催化剂部分中和细分硫
公开(公告)号：US5639706A
公开(公告)日：1997-06-17
申请号：US511736
申请日：1995-08-07
申请人： Franz-Josef Weiss , Hugo Fuchs , Gerald Neubauer , Heinz-Walter Schneider
发明人： Franz-Josef Weiss , Hugo Fuchs , Gerald Neubauer , Heinz-Walter Schneider
IPC分类号： B01J23/40 , B01J23/42 , B01J27/02 , B01J37/18 , B01J37/20 , C01B21/14
CPC分类号： B01J23/40 , B01J23/42 , B01J27/02 , B01J37/18 , B01J37/20 , C01B21/1418
摘要： A hydrogenation catalyst, obtainable by carrying out essentially the following steps:(a) treatment of a platinum metal salt with finely divided sulfur followed by(b) reduction of the platinum metal salt to metallic platinum metal.
摘要翻译：一种氢化催化剂，可通过基本上进行以下步骤得到：（a）用细碎的硫处理铂金属盐，然后（b）将铂金属盐还原为金属铂金属。

9. 发明授权

US4550195A Manufacture of pent-3-enoic acid and its alkyl esters 失效
标题翻译：戊-3-烯酸及其烷基酯的制备
公开(公告)号：US4550195A
公开(公告)日：1985-10-29
申请号：US295088
申请日：1981-08-21
申请人： Rolf Platz , Rudolf Kummer , Heinz-Walter Schneider , Kurt Schwirten
发明人： Rolf Platz , Rudolf Kummer , Heinz-Walter Schneider , Kurt Schwirten
IPC分类号： C07C69/533 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/14 , C07C57/03 , C07C67/00 , C07C67/38
CPC分类号： C07C51/14
摘要： A process for the manufacture of pent-3-enoic acid and its alkyl esters, of the general formulaCH.sub.3 --CH.dbd.CH--CH.sub.2 --CO--ORwhere R is hydrogen or alkyl of 1 to 4 carbon atoms, comprising carbonylating butadiene with carbon monoxide and a compound ROH at from 300 to 1,000 bars CO pressure and from 100.degree. to 160.degree. C. in the presence of cobalt catalysts and nitrogen bases, wherein C.sub.4 cuts are used as starting materials and a tertiary amine having a pK.sub.A of from 3 to 11 is used as the nitrogen base. The pent-3-enoic acid or alkyl esters produced may be used for the manufacture of adipic acid or its alkyl esters, which compounds are starting materials for the manufacture of nylons.
摘要翻译：制备通式为CH 3 -CH = CH-CH 2 -CO-OR的戊-3-烯酸及其烷基酯的方法，其中R是氢或1至4个碳原子的烷基，其包括将碳酸丁二烯与碳在钴催化剂和氮碱的存在下，在300至1,000巴CO压力和100至160℃下进行一氧化碳和化合物ROH，其中使用C4馏分作为起始原料，并使用pKA为3的叔胺至11为氮基。所制备的戊-3-烯酸或烷基酯可用于制造己二酸或其烷基酯，该化合物是用于制造尼龙的起始原料。

10. 发明授权

US4310686A Preparation of butanedicarboxylic esters 失效
标题翻译：丁烷二羧酸酯的制备
公开(公告)号：US4310686A
公开(公告)日：1982-01-12
申请号：US153572
申请日：1980-05-27
申请人： Rudolf Kummer , Heinz-Walter Schneider , Volker Taglieber , Franz-Josef Weiss
发明人： Rudolf Kummer , Heinz-Walter Schneider , Volker Taglieber , Franz-Josef Weiss
IPC分类号： C07C67/08 , B01J31/00 , B01J31/20 , C07B61/00 , C07C67/38 , C07C67/58 , C07C69/34 , C07C69/44
CPC分类号： C07C69/34 , C07C67/38
摘要： A process for the preparation of butanedicarboxylic acid esters, wherein(a) an aqueous cobalt salt solution is treated with excess carbon monoxide and hydrogen in the presence of active charcoal laden with cobalt carbonyl,(b) the resulting aqueous solution of cobalt carbonyl hydride is extracted with butadiene or a butadiene containing hydrocarbon mixture and the aqueous phase is separated off,(c) the butadiene, or butadiene/hydrocarbon mixture, containing cobalt carbonyl hydride, cobalt carbonyl and butenyl-cobalt tricarbonyl, is reacted with carbon monoxide and excess C.sub.1 -C.sub.4 -alkanol in the presence of a tertiary nitrogen base,(d) the resulting reaction mixture is freed from the tertiary nitrogen base contained therein, down to a content of from 0.1 to 0.3 mole per mole of pentenoic acid ester, and from excess hydrocarbons, and the pentenoic acid ester remaining in the reaction mixture is reacted with carbon monoxide and excess C.sub.1 -C.sub.4 -alkanol in the presence of the cobalt carbonyl and tertiary nitrogen base contained in the reaction mixture,(e) the reaction mixture is treated with an oxidizing agent in the presence of the aqueous acid solution which has been separated off in stage (b), and the mixture is separated into an organic phase, from which butanedicarboxylic acid esters are isolated by distillation, and an aqueous phase, and(f) the aqueous phase is extracted with water-immiscible solvents, the phases are separated, and the resulting aqueous phase is freed from alkanols and tertiary nitrogen base and is recycled to stage (a).
摘要翻译：制备丁烷二羧酸酯的方法，其中（a）钴水溶液在过量的一氧化碳和氢气的存在下，在负载有羰基钴的活性炭存在下处理，（b）得到的氢化羰基碳水溶液为用丁二烯或含丁二烯的烃混合物萃取并分离出水相，（c）含有羰基氢化钴，羰基钴和三丁基钴的三羰基化合物的丁二烯或丁二烯/烃混合物与一氧化碳和过量的C1 -C 4 - 链烷醇，（d）将所得反应混合物与其中所含的叔氮碱脱除，至每摩尔戊烯酸酯为0.1至0.3摩尔，过量碳氢化合物和残留在反应混合物中的戊烯酸酯在羰基钴a存在下与一氧化碳和过量的C 1 -C 4烷醇反应（e）反应混合物在步骤（b）中分离的酸性水溶液存在下用氧化剂处理，并将混合物分离成有机相通过蒸馏分离丁二羧酸酯和水相，（f）水相用不与水混溶的溶剂萃取，分离相，所得水相脱离链烷醇和叔氮碱，被回收到舞台（a）。

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