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1. 发明授权

US6111140A Ru--Pd halogen-free catalyzers and method for producing cycloaliphatic amines 失效
标题翻译： Ru-Pd无卤催化剂及其制备方法
公开(公告)号：US6111140A
公开(公告)日：2000-08-29
申请号：US269929
申请日：1999-04-05
申请人： Hans-Josef Buysch , Gerhard Darsow , Otto Immel , Reinhard Langer
发明人： Hans-Josef Buysch , Gerhard Darsow , Otto Immel , Reinhard Langer
IPC分类号： B01J23/58 , B01J23/63 , B01J23/656 , C07B61/00 , C07C209/72 , C07C211/16 , C07C211/35 , C07C207/00
CPC分类号： C07C209/72 , B01J23/58 , B01J23/63 , B01J23/6565
摘要： Catalysts containing ruthenium and palladium for the hydrogenation of aromatic amines to cycloaliphatic amines. Methods for making and using the catalysts.
摘要翻译： PCT No.PCT / EP97 / 05315 Sec。 371日期1999年4月5日 102（e）日期1999年4月5日PCT 1997年9月29日PCT公布。第WO98 / 15351号公报日期1998年4月16日含有钌和钯用于芳族胺氢化成脂环族胺的催化剂。制备和使用催化剂的方法。

2. 发明授权

US5196592A Process for the preparation of diphenylamines 失效
标题翻译：制备二苯胺的方法
公开(公告)号：US5196592A
公开(公告)日：1993-03-23
申请号：US805441
申请日：1991-12-11
申请人： Otto Immel , Helmut Waldmann , Reinhard Langer , Gerhard Darsow , Hans-Josef Buysch
发明人： Otto Immel , Helmut Waldmann , Reinhard Langer , Gerhard Darsow , Hans-Josef Buysch
IPC分类号： B01J27/055 , B01J23/46 , B01J23/58 , C07B61/00 , C07C209/52 , C07C209/68 , C07C211/54 , C07C211/55 , C07C213/02 , C07C215/76 , C07C217/84 , C07C217/90 , C07D521/00
CPC分类号： C07C209/68
摘要： Diphenylamine, which can be substituted by lower alkyl and/or lower alkoxy, is obtained from the corresponding N-cyclohexylidene-aniline by catalytic dehydrogenation, a rhodium-containing catalyst being employed.
摘要翻译：可以由低级烷基和/或低级烷氧基取代的二苯胺通过催化脱氢从相应的N-亚环己基苯胺获得，使用含铑催化剂。

3. 发明授权

US5371294A Process for the preparation of a mixture of cyclohexylamine and dicyclohexylamine 失效
标题翻译：制备环己胺和二环己胺的混合物的方法
公开(公告)号：US5371294A
公开(公告)日：1994-12-06
申请号：US955957
申请日：1992-10-02
申请人： Otto Immel , Hans-Josef Buysch , Gerhard Darsow
发明人： Otto Immel , Hans-Josef Buysch , Gerhard Darsow
IPC分类号： B01J23/648 , C07B61/00 , C07C209/16 , C07C209/72 , C07C211/35 , C07C209/18
CPC分类号： C07C209/72 , C07C209/16
摘要： Cyclohexylamine and dicyclohexylamine can be prepared as a mixture with one another by reaction of phenol with aniline, ammonia or a mixture of aniline and ammonia in the presence of hydrogen over a catalyst, the reaction being carried out according to the invention over a palladium catalyst which has a support of niobic acid or tantalic acid or a mixture of niobic acid and tantalic acid or a support containing such acids. The reaction is carried out at 100.degree.-220.degree. C. under an H.sub.2 partial pressure of 0.5-500 bar.
摘要翻译：环己胺和二环己基胺可以通过在氢气存在下在催化剂上与苯胺，氨或苯胺和氨的混合物的反应彼此混合来制备，该反应根据本发明通过钯催化剂进行具有铌酸或钽酸或铌酸和钽酸的混合物或含有这些酸的载体的载体。反应在100-220℃，0.5-500巴的H 2分压下进行。

4. 发明授权

US5344987A Process for preparing diphenylamines 失效
标题翻译：二苯胺制备方法
公开(公告)号：US5344987A
公开(公告)日：1994-09-06
申请号：US092735
申请日：1993-07-16
申请人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
发明人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
IPC分类号： B01J27/053 , C07B61/00 , C07C209/24 , C07C209/26 , C07C209/60 , C07C211/55 , C07C213/02 , C07C217/92 , C07C209/72
CPC分类号： C07C209/26
摘要： Optionally substituted diphenylamines can be obtained by reacting optionally substituted anilines with optionally substituted cyclohexanones over a supported catalyst at 200.degree.-450.degree. C. and 0.1-20 bar, the supported catalyst containing one or more metals having a dehydrogenating action selected from the group Ru, Pd, Os, Ir, Pt, Fe, Co, Ni, Re, Mn, Cu, Ag, Cr and Ce.
摘要翻译：任选取代的二苯胺可以通过使任选取代的苯胺与任选取代的环己酮在200-450℃和0.1-20巴的负载催化剂上反应，所述载体催化剂含有一种或多种具有脱氢作用的金属选自Ru ，Pd，Os，Ir，Pt，Fe，Co，Ni，Re，Mn，Cu，Ag，Cr和Ce。

5. 发明授权

US5300706A Process for the preparation of d,1-menthol 失效
标题翻译：制备d，1-薄荷醇的方法
公开(公告)号：US5300706A
公开(公告)日：1994-04-05
申请号：US28850
申请日：1993-03-10
申请人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
发明人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
IPC分类号： B01J23/656 , B01J27/055 , C07B61/00 , C07C29/20 , C07C35/12 , C07C29/00 , C07C29/17
CPC分类号： C07C35/12
摘要： A process for the preparation of d,l-menthol by catalytic hydrogenation of aromatic or partly hydrogenated cyclic compounds which have the carbon skeleton of menthol having at least one double bond and are substituted by oxygen in the 3-position relative to the methyl group, with simultaneous rearrangement of optically active or inactive stereoisomers of menthol at elevated temperature and under pressure is described. The hydrogenation, which is to be carried out continuously, is carried out on a fixed bed catalyst which comprises, as active constituents, palladium, ruthenium or rhodium or a mixture of these elements, and comprises alkali metal hydroxides and/or alkali metal sulphates as promoters; the support for this catalyst is doped with a rare earth metal and manganese.
摘要翻译：一种通过芳香族或部分氢化的环状化合物的催化氢化制备d，l-薄荷醇的方法，其具有至少一个双键的薄荷醇的碳骨架并相对于甲基在3-位上被氧取代，描述了在升高的温度和压力下同时重新配置薄荷醇的光学活性或无活性立体异构体。要连续进行的氢化在固定床催化剂上进行，固定床催化剂包含作为活性组分的钯，钌或铑或这些元素的混合物，并且包括碱金属氢氧化物和/或碱金属硫酸盐作为发起人; 该催化剂的载体掺杂有稀土金属和锰。

6. 发明授权

US5338885A Process for the preparation of diphenylamines 失效
标题翻译：二苯胺制备方法
公开(公告)号：US5338885A
公开(公告)日：1994-08-16
申请号：US950613
申请日：1992-09-24
申请人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
发明人： Otto Immel , Gerhard Darsow , Hans-Josef Buysch
IPC分类号： B01J23/46 , C07B43/04 , C07B61/00 , C07C209/24 , C07C209/28 , C07C211/55 , C07C213/02 , C07C217/92 , C07C209/26
CPC分类号： C07C209/28
摘要： Substituted or unsubstituted diphenylamnines can be obtained by reaction of substituted or unsubstituted anilines with substituted or unsubstituted cyclohexanones over a supported catalyst containing rhodium or a combination of rhodium with another platinum metal at 200.degree.-450.degree. C. and 0.1-20 bar.
摘要翻译：取代或未取代的二苯胺可以通过取代或未取代的苯胺与取代或未取代的环己酮在含有铑的负载型催化剂或铑与另一种铂金属的组合在200-450℃和0.1-20巴下反应而获得。

7. 发明授权

US5583251A Process for the production of isocyanates and for the production of light-colored foams therefrom 失效
标题翻译：用于生产异氰酸酯和从其生产浅色泡沫的方法
公开(公告)号：US5583251A
公开(公告)日：1996-12-10
申请号：US414543
申请日：1995-03-31
申请人： Hans-Josef Buysch , Manfred Gallus , Herbert Gebauer , Otto Immel , Christine Mendoza-Frohn , Reinhard Langer
发明人： Hans-Josef Buysch , Manfred Gallus , Herbert Gebauer , Otto Immel , Christine Mendoza-Frohn , Reinhard Langer
IPC分类号： B01J23/44 , B01J23/46 , B01J23/50 , B01J23/52 , C07B61/00 , C07C263/10 , C07C263/20 , C07C265/12 , C08G18/76
CPC分类号： C07C263/20 , C07C263/10
摘要： Isocyanates or isocyanate mixtures which contain no appreciable amounts of color causing materials are produced by phosgenating the amine corresponding to the desired isocyanate and treating the isocyanate-containing phosgenation mixture with hydrogen in the presence of a supported catalyst. The supported catalyst is in a form such that its shortest dimension is from about 0.3 to about 3.0 mm. This catalyst has a BET surface of from about 0.5 to about 150 m.sup.2 /g. No alkali material can be present in the catalyst. These isocyanates are particularly useful for the production of light-colored foams.
摘要翻译：通过使对应于所需异氰酸酯的胺光气化并在负载催化剂存在下用氢气处理含异氰酸酯的光气化混合物来产生不含有明显量的着色材料的异氰酸酯或异氰酸酯混合物。负载催化剂的形式是使其最短尺寸为约0.3至约3.0mm。该催化剂具有约0.5至约150m 2 / g的BET表面积。催化剂中不能存在碱性物质。这些异氰酸酯特别可用于生产浅色泡沫。

8. 发明授权

US5625097A Process for preparing diphenylamines and catalysts usable for this purpose 失效
标题翻译：制备可用于此目的的二苯胺和催化剂的方法
公开(公告)号：US5625097A
公开(公告)日：1997-04-29
申请号：US524556
申请日：1995-09-07
申请人： Hans-Josef Buysch , Christine Mendoza-Frohn , J urgen Scharschmidt , Ulrich Notheis , Rudolf J. Klee , Gerhard Darsow
发明人： Hans-Josef Buysch , Christine Mendoza-Frohn , J urgen Scharschmidt , Ulrich Notheis , Rudolf J. Klee , Gerhard Darsow
IPC分类号： B01J23/40 , B01J23/46 , B01J23/54 , B01J23/58 , B01J23/656 , B01J27/02 , B01J27/053 , B01J27/055 , B01J27/25 , C07B61/00 , C07C209/24 , C07C209/28 , C07C211/55 , C07C209/22
CPC分类号： C07C209/28 , B01J23/464 , B01J23/6562 , B01J27/055
摘要： The preparation of optionally substituted diphenylamine by reaction of optionally substituted aniline with optionally substituted cyclohexanone using a supported Rh catalyst containing rhodium or a combination of rhodium with another platinum metal from the group of palladium, platinum, ruthenium or iridium and which can additionally contain chromium, manganese, alkali metal and a sulphur compound is described. The catalyst of the invention is prepared from halide-free starting materials. The Rh catalyst is distinguished by a low dependence of the initial selectivity, the selectivity in the run-in state and the running-in time on the conditions of the reductive pretreatment and requires only short running-in times to the optimum state.
摘要翻译：通过任选取代的苯胺与任选取代的环己酮的反应制备任选取代的二苯胺，使用含有铑的负载Rh催化剂或铑与钯，铂，钌或铱的另一种铂金属的组合，并可另外含有铬，描述了锰，碱金属和硫化合物。本发明的催化剂由无卤素起始原料制备。 Rh催化剂的特征在于初始选择性的低依赖性，导入状态下的选择性和还原预处理条件下的进入时间，并且仅需要短时间进入最佳状态。

9. 发明授权

US5763717A Process for preparing hydroxybiphenyl 失效
标题翻译：制备羟基联苯的方法
公开(公告)号：US5763717A
公开(公告)日：1998-06-09
申请号：US524554
申请日：1995-09-07
申请人： Hans-Josef Buysch , Christine Mendoza-Frohn , Jurgen Scharschmidt , Ulrich Notheis , Rudolf Jurgen Klee , Gerhard Darsow
发明人： Hans-Josef Buysch , Christine Mendoza-Frohn , Jurgen Scharschmidt , Ulrich Notheis , Rudolf Jurgen Klee , Gerhard Darsow
IPC分类号： C07C37/06 , C07C37/07 , B01J23/24 , B01J23/26 , B01J27/25
CPC分类号： C07C37/07 , C07C37/06
摘要： A description is given of the preparation of hydroxybiphenyl by dehydrogenation of completely or partially hydrogenated precursors using a supported Rh catalyst which additionally contains chromium, manganese and alkali metal and can contain a sulphur compound. The Rh catalyst which can be used according to the invention is prepared from halide-free starting materials. The Rh catalyst is distinguished by a low dependence of the initial selectivity, with the selectivity in the run-in state and the running-in time on the conditions of the reductive pretreatment and requires only short running-in times to reach the optimum state.
摘要翻译：描述了使用另外含有铬，锰和碱金属并且可以含有硫化合物的负载的Rh催化剂，通过完全或部分氢化的前体脱氢来制备羟基联苯。根据本发明可以使用的Rh催化剂由无卤素起始材料制备。 Rh催化剂的特征在于初始选择性的低依赖性，在导入状态下的选择性和还原预处理条件下的进入时间，并且仅需要短的进入时间才能达到最佳状态。

10. 发明授权

US5302774A Process for the production of bisphenols 失效
标题翻译：双酚生产工艺
公开(公告)号：US5302774A
公开(公告)日：1994-04-12
申请号：US103584
申请日：1993-08-09
申请人： Klaus Berg , Hans-Josef Buysch , Alfred Eitel , Gerhard Fennhoff , Otto Immel , Ralf Pakull , Bernhard Wehrle , Claus Wulff
发明人： Klaus Berg , Hans-Josef Buysch , Alfred Eitel , Gerhard Fennhoff , Otto Immel , Ralf Pakull , Bernhard Wehrle , Claus Wulff
IPC分类号： C07B61/00 , C07C37/20 , C07C39/16
CPC分类号： C07C37/20
摘要： The invention relates to a process for the production of bisphenols from acetone and phenols in the presence of sulfonic acid ion exchanger resins modified with alkyl-SH groups, in which 0.6 to 5% by weight H.sub.2 O is added to the mixture of phenol and acetone before the reaction.
摘要翻译：本发明涉及一种在烷基-SH基团改性的磺酸离子交换树脂存在下由丙酮和酚生产双酚的方法，其中在苯酚和丙酮的混合物中加入0.6-5重量％的H 2 O. 反应。

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