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1. 发明授权

US4307040A Process for producing phosphonomaleic acid esters 失效
标题翻译：制备膦酰基酸酯的方法
公开(公告)号：US4307040A
公开(公告)日：1981-12-22
申请号：US140891
申请日：1980-04-16
申请人： Hans-Dieter Block , Friedrich Schwochow , Reinhard Schliebs
发明人： Hans-Dieter Block , Friedrich Schwochow , Reinhard Schliebs
IPC分类号： C07F9/32 , C07F9/40 , C08K5/5317 , C08K5/5333
CPC分类号： C08K5/5333 , C07F9/3217 , C07F9/4015 , C08K5/5317
摘要： Novel phosphonomaleic acid esters of the formula ##STR1## in which R.sup.1 is an optionally substituted alkyl radical containing from 1 to 6 carbon atoms and, where n=0, may also be an optionally substituted aryl radical,R.sup.2, R.sup.3 and R.sup.4 each independently is an optionally substituted alkyl radical containing from 1 to 16 carbon atoms,R.sup.5 is hydrogen, an alkyl or aryl radical containing from 1 to 7 carbon atoms, andn=0 or 1,are produced by reacting a base with a 1-halogen-1-phosphonosuccinic acid ester of the formula ##STR2## in which Hal is chlorine or bromine. The esters are useful as intermediates in the synthesis of sequestrants, corrosion inhibitors, stabilizers, flameproofing agents, pharmaceuticals and pesticides.
摘要翻译：新颖的式“IMAGE”的膦酰基酸酯，其中R 1是含有1至6个碳原子的任选取代的烷基，并且其中n = 0也可以是任选取代的芳基，R 2，R 3和R 4各自独立地是含有1至16个碳原子的任选取代的烷基，R 5是氢，含有1至7个碳原子的烷基或芳基，n = 0或1，通过使碱与1-卤素-1 其中Hal是氯或溴的式“IMAGE”的膦酰基琥珀酸酯。酯可用作螯合剂，腐蚀抑制剂，稳定剂，防火剂，药物和杀虫剂合成中的中间体。

2. 发明授权

US4080377A Production of cyclic five-membered ring unsaturated phosphine dichlorides 失效
标题翻译：环状五元环不饱和二氯化磷的制备
公开(公告)号：US4080377A
公开(公告)日：1978-03-21
申请号：US766418
申请日：1977-02-07
申请人： Hans-Dieter Block , Reinhard Schliebs
发明人： Hans-Dieter Block , Reinhard Schliebs
IPC分类号： C07F9/6568 , C07F9/34 , C07F9/53
CPC分类号： C07F9/65686 , C07F9/65685
摘要： In the production of isomeric five-membered ring cyclic unsaturated phosphine dichlorides by reacting an organophosphorus dichloride with a diene, the improvement which comprises carrying out the reaction in a carboxylic acid chloride. The product, without isolation, can be directly used in reaction with the carboxylic acid anhydride corresponding to the acid chloride to produce the phosphine oxide, the reaction producing additional acid chloride from the anhydride.
摘要翻译：通过使二氯化有机磷与二烯反应制备异构五元环环状不饱和二氯化膦，其改进包括在羧酸氯化物中进行反应。不分离的产物可以直接用于与酰氯反应生成氧化膦的羧酸酐反应，该反应从酸酐产生另外的酰氯。

3. 发明授权

US4102949A Production of 3,4-dihydroxy phospholane oxides 失效
标题翻译： 3,4-二羟基磷酰氧化物的生产
公开(公告)号：US4102949A
公开(公告)日：1978-07-25
申请号：US758527
申请日：1977-01-11
申请人： Reinhard Schliebs , Hans-Dieter Block
发明人： Reinhard Schliebs , Hans-Dieter Block
IPC分类号： C07F9/36 , C07F9/6568 , C07F9/32 , C07F9/53
CPC分类号： C07F9/36 , C07F9/65681 , C07F9/65685
摘要： A process for the preparation of a 3,4-dihydroxy phsopholane oxide of the formula ##STR1## in which R.sup.1 represents an alkyl, alkoxy, alkenyl, alkenyloxy, alkinyl or alkinyloxy with up to 18 carbon atoms and substitution products thereof; aryl and aryloxy having up to 14 carbon atoms and substitution products thereof; cycloalkyl and cycloalkoxy having up to 6 ring carbon atoms and substitution products thereof; dialkylamino having up to 6 carbon atoms per alkyl radical and substitution products thereof; and N-hetero-radicals, andR.sup.2, r.sup.3 and R.sup.4 independently of one another represent a C.sub.1 -C.sub.4 -alkyl radical or hydrogen,Comprising reacting a phospholene oxide of the formula ##STR2## with hydrogen peroxide in the presence of a catalytic amount of an osmium compound at a temperature in the range of about 20.degree. to 150.degree. C, especially about 35.degree. to 100.degree. C.
摘要翻译：制备式“IMAGE”的3,4-二羟基环己烷氧化物的方法，其中R 1表示具有至多18个碳原子的烷基，烷氧基，烯基，烯氧基，炔基或烷氧基及其取代产物; 具有至多14个碳原子的芳基和芳氧基及其取代产物; 环烷基和具有至多6个环碳原子的环烷氧基及其取代产物; 每个烷基具有至多6个碳原子的二烷基氨基及其取代产物; 和N-杂原子，R 2，R 3和R 4彼此独立地表示C 1 -C 4 - 烷基或氢，在过氧化氢的存在下，在催化量的锇化合物在约20至150℃，特别是约35至100℃的温度范围内。

4. 发明授权

US4052484A Substituted cyclic phosphine oxides 失效
标题翻译：取代的环磷酰氧化物
公开(公告)号：US4052484A
公开(公告)日：1977-10-04
申请号：US648710
申请日：1976-01-13
申请人： Reinhard Schliebs , Hans-Dieter Block
发明人： Reinhard Schliebs , Hans-Dieter Block
IPC分类号： C07F9/53 , C07F9/6568 , C07F9/32 , C07F9/48
CPC分类号： C07F9/65685
摘要： A cyclic phosphine oxide of the formula ##STR1## in which R.sup.1 is an alkyl or an aryl radical having up to 14 carbon atoms,R.sup.2, r.sup.3 and R.sup.4 each independently is a C.sub.1 -C.sub.4 -alkyl radical, hydrogen, chlorine or bromine,X and Y each independently is oxygen or sulfur,a, b, and c each independently is 0 or 1, andR.sup.5 is a C.sub.1 -C.sub.12 -alkyl radical and, where a = 0, also an aryl radical and, where a = 1, an equivalent of a cation,R.sup.6 is a C.sub.1 -C.sub.12 -alkyl radical and, where b = 0, also an aryl radical and, where b = 1, an equivalent of a cation,Is produced by reacting an unsaturated 5-membered cyclic phosphine oxide of the formula ##STR2## with a compound containing a phosphorus-hydrogen bond and of the formula ##STR3## in which R.sup.7 is a C.sub.1 -C.sub.12 -alkyl radical or, where a = 0, also an aryl radical, andR.sup.8 is a C.sub.1 -C.sub.12 -alkyl radical or, where b = 0, also an aryl radical,In the presence of free radicals at a temperature of about 50.degree. C to about 300.degree. C, and the reaction product is optionally hydrolyzed and converted into a salt.

5. 发明授权

US06905576B1 Method and system for producing silane 失效
标题翻译：生产硅烷的方法和系统
公开(公告)号：US06905576B1
公开(公告)日：2005-06-14
申请号：US09868792
申请日：1999-12-14
申请人： Hans-Dieter Block , Hans-Joachim Leimkühler , Dirk Müller , Johannes-Peter Schäfer , Georg Ronge
发明人： Hans-Dieter Block , Hans-Joachim Leimkühler , Dirk Müller , Johannes-Peter Schäfer , Georg Ronge
IPC分类号： C01B33/04 , C01B33/107 , B01D3/34 , B01D5/00 , B01V8/02
CPC分类号： C01B33/043 , Y10S203/06
摘要： This invention relates to a continuous process for the preparation of silane by catalytic disproportionation of trichlorosilane in a reactive/distillative reaction zone having a catalyst bed of catalytically active solid.
摘要翻译：本发明涉及通过在具有催化活性固体催化剂床的反应/蒸馏反应区中催化歧化三氯硅烷来制备硅烷的连续方法。

6. 发明授权

US5608099A Process for the recovery of tributyl phosphate from spent hydraulic oils 失效
标题翻译：从废液压油中回收磷酸三丁酯的方法
公开(公告)号：US5608099A
公开(公告)日：1997-03-04
申请号：US548795
申请日：1995-11-01
申请人： Hans-G unter Fr ohlen , Hans-Dieter Block , Wolfgang Ohlendorf , Hans-Heinrich Moretto , Peter Schmidt
发明人： Hans-G unter Fr ohlen , Hans-Dieter Block , Wolfgang Ohlendorf , Hans-Heinrich Moretto , Peter Schmidt
IPC分类号： C07F9/02 , C07F9/11
CPC分类号： C07F9/025 , C07F9/11
摘要： A process for the recovery by distillation of tributyl phosphate (TBPO) from spent hydraulic oils, which are employed particularly in aircraft used for civilian air traffic.
摘要翻译：通过蒸馏磷酸三丁酯（TBPO）从废液化油中回收的方法，特别是用于民用航空的飞机。

7. 发明授权

US5424474A Fluorinated carboxylic acid esters of phosphono- and phosphinocarboxylic acids containing hydroxyl and/or mercapto groups, a method for their preparation, and their use 失效
标题翻译：含有羟基和/或巯基的膦酰基和膦酰基羧酸的氟化羧酸酯，其制备方法及其用途
公开(公告)号：US5424474A
公开(公告)日：1995-06-13
申请号：US172274
申请日：1993-12-23
申请人： Klaus Pohmer , Rainer Weber , Hans-Dieter Block , Hans-Heinrich Moretto
发明人： Klaus Pohmer , Rainer Weber , Hans-Dieter Block , Hans-Heinrich Moretto
IPC分类号： B05D7/26 , C07F9/30 , C07F9/38 , C09K3/18 , C14C9/00 , D06M13/29
CPC分类号： D06M13/29 , C07F9/301 , C07F9/3808 , Y02E60/36
摘要： The present invention relates to fluorinated carboxylic acid esters of phosphono- and phosphinocarboxylic acids containing hydroxyl and/or mercapto groups, their use as waterproofing and/or oil-repellency agents, and a method for their preparation.
摘要翻译：本发明涉及含有羟基和/或巯基的膦酰基和膦酰基羧酸的氟化羧酸酯，它们作为防水和/或拒油剂的用途及其制备方法。

8. 发明授权

US4344855A Process for the production of polyisocyanates which contain carbodiimide groups and which are stable in storage 失效
标题翻译：用于生产含有碳二亚胺基团并且在储存中稳定的多异氰酸酯的方法
公开(公告)号：US4344855A
公开(公告)日：1982-08-17
申请号：US741432
申请日：1976-11-12
申请人： Walter Schafer , Kuno Wagner , Hans-Dieter Block
发明人： Walter Schafer , Kuno Wagner , Hans-Dieter Block
IPC分类号： C08G18/00 , B01J31/00 , C07C67/00 , C07C241/00 , C07C265/12 , C07C265/14 , C07C267/00 , C07D229/00 , C07F9/6568 , C08G18/02 , C08G18/72 , C08G18/78 , C08G18/79 , C09K3/00
CPC分类号： C07C263/18 , C07C267/00 , C07F9/65685 , C08G18/3271 , C08G18/4829 , C08G18/485 , C08G18/6688 , C08G18/725 , C08G18/73 , C08G18/755 , C08G18/7621 , C08G18/78 , C08G18/797 , C08G2101/00 , Y10S521/901
摘要： The instant invention relates to a process for producing stable equilibrium mixtures of carbodiimides, uretone imines and organic isocyanates and storage-stable solutions of carbodiimides and uretone imines in polyisocyanates which are free from carbodiimide groups. Either the carbodiimide, or the uretone imine, or both, may contain isocyanate groups. The invention relates to the process for the preparation of these products by so-called heterogeneous catalysis and the use of these products for the production of polyurethane resins.
摘要翻译：本发明涉及一种制备碳二亚胺，脲酮亚胺和有机异氰酸酯和碳二亚胺和脲酮亚胺在不含碳二亚胺基团的多异氰酸酯中的稳定平衡混合物的方法。碳二亚胺或者脲酮亚胺或两者都可能含有异氰酸酯基团。本发明涉及通过所谓的多相催化制备这些产物的方法以及这些产品用于生产聚氨酯树脂的用途。

9. 发明授权

US4331614A Aromatic polyphosphonates and a process for their production 失效
标题翻译：芳香族聚膦酸酯及其生产工艺
公开(公告)号：US4331614A
公开(公告)日：1982-05-25
申请号：US160646
申请日：1980-06-18
申请人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag , Klaus Reinking , Harry Rohr , Hans-Dieter Block
发明人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag , Klaus Reinking , Harry Rohr , Hans-Dieter Block
IPC分类号： C08G79/00 , C08G79/02 , C08G79/04 , C07F9/40
CPC分类号： C08G79/04
摘要： Thermoplastic, branched aromatic polyphosphonates with average molecular weights (number average M.sub.n) of from 11,000 to more than 200,000, obtainable by transesterifying (a) from 97 to 100 moles of at least one diaryl phosphonate, and (b) from 0 to 3 moles of at least one triaryl phosphate--the sum of the moled of (a) and (b) being 100--with (c) from 90 to 99 moles of at least one aromatic dihydroxy compound, and (d) from 0 to 3 moles of at least one aromatic trihydroxy or tetrahydroxy compound--with the proviso that at least one of the components (b) and (d) is present in a quantity of at least 0.001 mole and that, where (b) and (d) are used, the maximum limit on the moles is 3.0.
摘要翻译：平均分子量（数均Mn）为11,000至大于200,000的热塑性支链芳族聚膦酸酯，可通过（a）97-100摩尔的至少一种二芳基膦酸酯和（b）0-3摩尔的至少一种磷酸三芳基酯，（a）和（b）的衍生物的总和为100-（c）90-99摩尔的至少一种芳族二羟基化合物，和（d）0-3摩尔的至少一种芳族三羟基或四羟基化合物 - 条件是组分（b）和（d）中的至少一种以至少0.001摩尔的量存在，并且使用（b）和（d）时，摩尔数的最大限度为3.0。

10. 发明授权

US4257987A Lower alkyl di propargyl phosphates 失效
标题翻译：低级烷基二炔丙基磷酸酯
公开(公告)号：US4257987A
公开(公告)日：1981-03-24
申请号：US76053
申请日：1979-09-17
申请人： Gunter Arend , Wolfgang Behrenz , Hans-Dieter Block
发明人： Gunter Arend , Wolfgang Behrenz , Hans-Dieter Block
IPC分类号： A01N57/00 , A01N57/02 , A01N57/10 , A01N57/12 , A01N57/22 , C07F9/113 , C07F9/12 , C07F9/173 , C07F9/18 , C07F9/32 , C07F9/40 , A01N57/14 , A01N57/16
CPC分类号： C07F9/4078 , A01N57/02 , A01N57/12 , C07F9/113 , C07F9/3217 , C07F9/4006 , C07F9/4015
摘要： Synergistic arthropodicidal compositions containing (1) a phosphorus-containing compound of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 each independently is an optionally substituted alkyl, alkenyl or aryl radical, at least one of R.sup.1, R.sup.2 and R.sup.3 being an optionally substituted alkenyl radical unsaturated in the 2-position,X is oxygen or sulphur, andY and Z each independently is oxygen, sulphur or a direct bond; and if both Y and Z are oxygen or sulphur or a direct bond, then any of R.sup.1, R.sup.2 and R.sup.3 can denote propargyl in addition to the radicals indicated above,and (2) at least one (A) carbamate, (B) carboxylic acid ester, (C) phosphoric acid ester other than (1), (D) halogenocycloalkane or (E) halogenoalkane.
摘要翻译：含有（1）式（IMAGE）的含磷化合物的协同节肢动物杀伤组合物，其中R 1，R 2和R 3各自独立地是任选取代的烷基，烯基或芳基，R 1，R 2和R 3中的至少一个是任选的 2-取代的烯基不饱和，X是氧或硫，Y和Z各自独立地是氧，硫或直接键; 并且如果Y和Z都是氧或硫或直接键，则除了上述基团之外，R 1，R 2和R 3中的任一个可以表示炔丙基，和（2）至少一个（A）氨基甲酸酯，（B）羧酸酸酯，（C）除（1），（D）卤代环烷烃或（E）卤代烷烃以外的磷酸酯。

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