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1. 发明授权

US07736866B2 Enzyme-based time temperature indicator 失效
标题翻译：基于酶的时间温度指标
公开(公告)号：US07736866B2
公开(公告)日：2010-06-15
申请号：US11659645
申请日：2005-08-03
申请人： Hans Reichert , Peter Simmendinger , Thomas Bolle
发明人： Hans Reichert , Peter Simmendinger , Thomas Bolle
IPC分类号： C12Q1/34
CPC分类号： C12Q1/25 , G01K3/04 , G01N31/229
摘要： A time temperature indicator for indicating temperature change over time is provided, comprising an immobilized enzyme and a substrate of the enzyme, wherein the reaction of the substrate catalyzed by the enzyme produces a reaction product in a time and temperature dependent manner and wherein the formation of the reaction product can be detected by monitoring a physical characteristic of the substrate and/or the product which is linked to its concentration. Also provided is a method of time temperature indication comprising the step of an enzyme-catalyzed reaction, a method of printing the enzyme-based time temperature indicator on a packaging material or a label, a printing ink or printing ink concentrate comprising components of the enzyme-based time temperature indicator and a packaging material or a label comprising the enzyme-based time temperature indicator.
摘要翻译：提供了用于指示随时间的温度变化的时间温度指示器，其包括固定化酶和酶的底物，其中由酶催化的底物的反应以时间和温度依赖的方式产生反应产物，并且其中形成可以通过监测与其浓度相关的底物和/或产物的物理特性来检测反应产物。还提供了一种时间温度指示的方法，其包括酶催化反应的步骤，在包装材料或标签上印刷基于酶的时间温度指示剂的方法，包含酶的组分的印刷油墨或印刷油墨浓缩物的时间温度指示剂和包含材料或包含基于酶的时间温度指示剂的标签。

2. 发明申请

US20090226948A1 Enzyme-based time temperature indicator 失效
标题翻译：基于酶的时间温度指标
公开(公告)号：US20090226948A1
公开(公告)日：2009-09-10
申请号：US11659645
申请日：2005-08-03
申请人： Hans Reichert , Peter Simmendinger , Thomas Bolle
发明人： Hans Reichert , Peter Simmendinger , Thomas Bolle
IPC分类号： C12Q1/44 , C12Q1/00 , C12Q1/34 , C09D11/02 , C07D487/04 , C07D498/04 , C07H17/02 , C07D403/04
CPC分类号： C12Q1/25 , G01K3/04 , G01N31/229
摘要： The present invention relates to a time temperature indicator for indicating temperature change over time, comprising an immobilized enzyme and a substrate of the enzyme, wherein the reaction of the substrate catalyzed by the enzyme produces a reaction product in a time and temperature dependent manner and wherein the formation of the reaction product can be detected by monitoring a physical characteristic of the substrate and/or the product which is linked to its concentration. The invention further relates to a method of time temperature indication comprising the step of an enzyme-catalyzed reaction, a method of printing the enzyme-based time temperature indicator on a packaging material or a label, a printing ink or printing ink concentrate comprising components of the enzyme-based time temperature indicator and a packaging material or a label comprising the enzyme-based time temperature indicator.
摘要翻译：本发明涉及用于指示随着时间的温度变化的时间温度指示器，其包括固定化酶和酶底物，其中由酶催化的底物的反应以时间和温度依赖的方式产生反应产物，其中通过监测与其浓度相关的底物和/或产物的物理特性，可以检测反应产物的形成。本发明还涉及一种时间温度指示方法，其包括酶催化反应步骤，在包装材料或标签上印刷基于酶的时间温度指示剂的方法，印刷油墨或印刷油墨浓缩物，其包含基于酶的时间温度指示剂和包含基于酶的时间温度指示剂的包装材料或标签。

3. 发明申请

US20130208327A1 SECURITY ELEMENT 有权
标题翻译：安全元素
公开(公告)号：US20130208327A1
公开(公告)日：2013-08-15
申请号：US13823348
申请日：2011-09-27
申请人： Thomas Bolle , Hans Reichert , Michelle Richert , Igor Zhurminsky , Marc Schnieper
发明人： Thomas Bolle , Hans Reichert , Michelle Richert , Igor Zhurminsky , Marc Schnieper
IPC分类号： G03H1/00
CPC分类号： G03H1/0011 , B41M3/144 , B42D25/29 , B42D25/328 , B42D25/373 , B42D25/387 , B42D2033/04 , G03H1/0244 , G03H2222/15 , G03H2240/54
摘要： The present invention is in the field of security documents, more particularly in the field of security elements aimed to protect security documents against copying (illegal reproduction) and counterfeiting. It discloses a security element having a security feature which changes its visual appearance after irradiation with light, especially with UV light and at rotation and/or tilting. Security documents comprising said security element, as well as a method for producing said security element, are also disclosed.
摘要翻译：本发明在安全性文件领域，更具体地涉及旨在保护安全文件免受复制（非法复制）和伪造的安全性要素领域。它公开了一种具有安全特征的安全元件，该安全特征在用光照射之后特别是用UV光并且在旋转和/或倾斜下改变其视觉外观。还公开了包括所述安全元件的安全文件，以及用于生成所述安全元件的方法。

4. 发明授权

US09310766B2 Security element 有权
标题翻译：安全元素
公开(公告)号：US09310766B2
公开(公告)日：2016-04-12
申请号：US13823348
申请日：2011-09-27
申请人： Thomas Bolle , Hans Reichert , Michelle Richert , Igor Zhurminsky , Marc Schnieper
发明人： Thomas Bolle , Hans Reichert , Michelle Richert , Igor Zhurminsky , Marc Schnieper
IPC分类号： G03H1/00 , G02B5/18 , B41M3/14 , G03H1/02 , B42D25/29 , B42D25/328 , B42D25/387
CPC分类号： G03H1/0011 , B41M3/144 , B42D25/29 , B42D25/328 , B42D25/373 , B42D25/387 , B42D2033/04 , G03H1/0244 , G03H2222/15 , G03H2240/54
摘要： The present invention is in the field of security documents, more particularly in the field of security elements aimed to protect security documents against copying (illegal reproduction) and counterfeiting. It discloses a security element having a security feature which changes its visual appearance after irradiation with light, especially with UV light and at rotation and/or tilting. Security documents comprising said security element, as well as a method for producing said security element, are also disclosed.
摘要翻译：本发明在安全性文件领域，更具体地涉及旨在保护安全文件免受复制（非法复制）和伪造的安全性要素领域。它公开了一种具有安全特征的安全元件，该安全特征在用光照射之后特别是用UV光并且在旋转和/或倾斜下改变其视觉外观。还公开了包括所述安全元件的安全文件，以及用于生成所述安全元件的方法。

5. 发明申请

US20070060667A1 Process for preparing pigment concentrates for use in radiation-curable coatings 审中-公开
标题翻译：用于制备用于可辐射固化涂料的颜料浓缩物的方法
公开(公告)号：US20070060667A1
公开(公告)日：2007-03-15
申请号：US10557227
申请日：2004-05-24
申请人： Tunja Jung , Thomas Healy , Andre Fuchs , Thomas Bolle
发明人： Tunja Jung , Thomas Healy , Andre Fuchs , Thomas Bolle
IPC分类号： C08K5/00 , C09D11/00
CPC分类号： C09D11/101 , B41M7/0045 , B41M7/0081 , C08F290/061 , C09B67/006
摘要： A process for preparing pigment concentrates is provided which comprises dispersing a dry pigment in a radiation polymerizable (curable) ethylenically-unsaturated compound. The concentrates to which optionally photoinitiators are added can be used for preparing radiation, preferably ultraviolet radiation, curable printing inks, paints or other coating compositions which in turn are applied in printing processes or in the painting or coating of substrates. The performance enhancement of the cured pigmented inks/paints/coatings include e.g. good tinctorial strength and gloss, as well as surface hardness, good adhesion to substrate and chemical and corrosion resistance.
摘要翻译：提供了一种制备颜料浓缩物的方法，其包括将干颜料分散在可辐射聚合的（可固化的）烯属不饱和化合物中。添加任选的光引发剂的浓缩物可以用于制备辐射，优选紫外线辐射，可固化的印刷油墨，油漆或其它涂料组合物，这些涂料组合物又被应用于印刷方法或涂料或涂料中。固化的着色油墨/油漆/涂料的性能提高包括例如。良好的着色强度和光泽度，以及表面硬度，对基材的良好粘合性以及耐化学腐蚀性。

6. 发明申请

US20060160915A1 Photocurable compositions 审中-公开
标题翻译：可光固化组合物
公开(公告)号：US20060160915A1
公开(公告)日：2006-07-20
申请号：US10544509
申请日：2004-02-09
申请人： Andre Fuchs , Rinaldo Husler , Thomas Bolle
发明人： Andre Fuchs , Rinaldo Husler , Thomas Bolle
IPC分类号： C08F2/50
CPC分类号： C08F2/50 , C08K5/07 , G03F7/031
摘要： Benzophenone derivatives of formula I R1, R2 and R3 are each independently of the others hydrogen or C1-C4alkyl, cyclopentyl or cyclohexyl; R4, R5 and R6 are each independently of the others hydrogen, C1-C4alkyl, cyclopentyl or cyclohexyl; R7 and R8 are each independently of the other hydrogen, C1-C4alkyl, cyclopentyl or cyclohexyl; with the provisos that (i) at least one radical R1, R2, R3, R4, R5, R6, R7, R8 is other than hydrogen; (ii) when all radicals R4, R5 , R6, R7 and R8 are hydrogen and only one radical R1, R2, R3 is C1-C4alkyl, that radical must be in the meta-position of the phenyl ring; and (iii) when all radicals R1, R2, R3, R7 and R8 are hydrogen and two of the radicals R4, R5 and R6 are hydrogen and the remaining radical R4, R5 or R6 is C1-C4alkyl, that alkyl radical is not bonded in the para-position on the phenyl ring; are found to be especially suitable in photocurable compositions in respect of solubility, reactivity and a low level of yellowing.
摘要翻译：式IR 1 R 2，R 2和R 3的二苯甲酮衍生物各自独立地为氢或C 1〜 -C 4烷基，环戊基或环己基; R 4，R 5和R 6各自独立地为氢，C 1 -C 3 烷基，环戊基或环己基; R 7和R 8分别独立地为氢，C 1 -C 4烷基，环戊基或环己基条件是（i）至少一个基团R 1，R 2，R 3，R 4， R 5，R 6，R 7，R 8不同于氢; R 5，R 7，R 7，（ii）当所有基团R 4，R 5，R 6，R 7和R 7， 8是氢，只有一个基团R 1，R 2，R 3是C 1 H 2， -C 4 - 烷基，该基团必须在苯环的间位; 和（iii）当所有基团R 1，R 2，R 3，R 7和R SUB > 8 是氢，基团R 4，R 5和R 6中的两个是氢，剩余的基团R' R 4，R 5或R 6是C 1 -C 4烷基，该C 1 -C 4烷基，烷基在苯环的对位不结合; 在溶解性，反应性和黄化程度方面都被认为特别适用于光固化组合物。

7. 发明申请

US20050075465A1 2-Hydroxyphenyl-s-triazine crosslinkers for polymer networks 有权
标题翻译：用于聚合物网络的2-羟基苯基-s-三嗪交联剂
公开(公告)号：US20050075465A1
公开(公告)日：2005-04-07
申请号：US10497297
申请日：2002-11-21
申请人： Thomas Bolle , Andreas Valet , David Leppard , Stephen Andrews , Ramanathan Ravichandran , Markus Grob , Dirk Simon
发明人： Thomas Bolle , Andreas Valet , David Leppard , Stephen Andrews , Ramanathan Ravichandran , Markus Grob , Dirk Simon
IPC分类号： C07D251/24 , C08F8/30 , C08F291/00 , C08K5/3492 , C08L101/00 , C07D201/00 , C08F20/00 , C09K3/00
CPC分类号： C08F8/30 , C07D251/24 , C08F291/00 , C08K5/3492 , C08F222/1006
摘要： Compounds of the general formula I′ in which R1 is H, C1-C12alkyl; C5-C12cycloalkyl; C2-C18alkyl which is interrupted by one or more O; SR4; OR5; or is a group of formula II or III R2, R21 and R3 independently of one another, are H or —Y-T as defined in claim 1, where T is a reactive group selected from OH, acryl- and methacryloxy and arylcarbonate groups, and further symbols are as defined in claim 1, are effective as crosslinking agents for polymeric networks, especially as in flexographic printing plates, coatings, and plastic containers or films. Further provided is a method of protecting the content of a clear or lightly colored plastic container or film against the deleterious effects of ultraviolet radiation, which method comprises permanently and covalently bonding one or more UV absorbing moieties of a durable s-triazine UV absorber via condensation to a suitable polymer component.
摘要翻译：通式I'的化合物，其中R 1是H，C 1 -C 12烷基; C5-C12环烷基; 被一个或多个O中断的C 2 -C 18烷基; SR4; OR5; 或者是式II或III中的R 2，R 21和R 3彼此独立的基团是如权利要求1所定义的H或-YT，其中T是选自OH，丙烯酰基和甲基丙烯酰氧基和芳基碳酸酯基的反应性基团，符号如权利要求1中所定义，可用作聚合物网络的交联剂，特别是在柔性版印刷版，涂料和塑料容器或薄膜中。进一步提供了一种保护透明或浅色塑料容器或薄膜的含量以抵抗紫外线辐射的有害影响的方法，该方法包括通过冷凝物永久地和共价键合耐久的三嗪UV吸收剂的一个或多个UV吸收部分到合适的聚合物组分。

8. 发明授权

US06187387B1 Stabilization of wood substrates 有权
标题翻译：木质基材的稳定化
公开(公告)号：US06187387B1
公开(公告)日：2001-02-13
申请号：US09267472
申请日：1999-03-11
申请人： Thomas Bolle , Jean-Pierre Wolf , Raymond Seltzer
发明人： Thomas Bolle , Jean-Pierre Wolf , Raymond Seltzer
IPC分类号： B05D708
CPC分类号： C09D15/00 , B27K3/153 , B27K3/343 , B27K5/02 , B27K2240/90 , C08L67/08 , C08L97/02
摘要： The invention relates to a method of protecting wood against light-induced degradation by treatment with a stain or impregnation which penetrates the surface of the wood comprising a) at least one organic solvent; b) a hindered amine compound of formula I or II where G1 and G2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene, Z1 and Z2 are each methyl, or Z1 and Z2 together form a linking moiety which may additionally be substituted by an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or urethane group, E is oxyl or hydroxyl, X is an inorganic or organic anion, and where the total charge of cations h is equal to the total charge of anions j.
摘要翻译：本发明涉及一种通过用渗透木材表面的污渍或浸渍处理以防止光诱导的降解的方法，该方法包括：a）至少一种有机溶剂; b）式I或II的受阻胺化合物，其中G 1和G 2是独立地为1至4个碳原子的烷基或一起为五亚甲基，Z 1和Z 2各自为甲基，或者Z 1和Z 2一起形成可另外被酯，醚，羟基，氧代，羟腈，酰胺，氨基，羧基或氨基甲酸酯基，E是氧基或羟基，X是无机或有机阴离子，并且其中阳离子的总电荷h等于阴离子j的总电荷。

9. 发明授权

US07214742B2 2-hydroxyphenyl-s-triazine crosslinkers for polymer networks 有权
标题翻译：用于聚合物网络的2-羟基苯基-s-三嗪交联剂
公开(公告)号：US07214742B2
公开(公告)日：2007-05-08
申请号：US10497297
申请日：2002-11-21
申请人： Thomas Bolle , Andreas Valet , David George Leppard , Stephen Mark Andrews , Ramanathan Ravichandran , Markus Grob , Dirk Simon
发明人： Thomas Bolle , Andreas Valet , David George Leppard , Stephen Mark Andrews , Ramanathan Ravichandran , Markus Grob , Dirk Simon
IPC分类号： C08K5/3492 , C07D251/24
CPC分类号： C08F8/30 , C07D251/24 , C08F291/00 , C08K5/3492 , C08F222/1006
摘要： Compounds of the general formula I′ in which R1 is H, C1–C12alkyl; C5–C12cycloalkyl; C2–C18alkyl which is interrupted by one or more O; SR4; OR5; or is a group of formula II or III R2, R21 and R3 independently of one another, are H or —Y—T as defined in claim 1, where T is a reactive group selected from OH, acryl- and methacryloxy and arylcarbonate groups, and further symbols are as defined in claim 1, are effective as crosslinking agents for polymeric networks, especially as in flexographic printing plates, coatings, and plastic containers or films. Further provided is a method of protecting the content of a clear or lightly colored plastic container or film against the deleterious effects of ultraviolet radiation, which method comprises permanently and covalently bonding one or more UV absorbing moieties of a durable s-triazine UV absorber via condensation to a suitable polymer component.
摘要翻译：其中R 1是H，C 1 -C 12烷基的通式I'的化合物; C 5 -C 12环烷基; 被一个或多个O中断的C 2 -C 18烷基; SR 4; 或5

10. 发明授权

US6140326A Morpholinones as light stabilizers 有权
标题翻译：吗啉酮作为光稳定剂
公开(公告)号：US6140326A
公开(公告)日：2000-10-31
申请号：US152985
申请日：1998-09-14
申请人： Dario Lazzari , Thomas Bolle , Mirko Rossi , Hugh Stephen Laver
发明人： Dario Lazzari , Thomas Bolle , Mirko Rossi , Hugh Stephen Laver
IPC分类号： C07C229/12 , C07D265/32 , C07D403/12 , C07D413/10 , C07D413/12 , C07D413/14 , C08K5/357 , C08L101/00 , C09K15/30 , A61K31/535 , C07D265/00 , C07D265/30
CPC分类号： C07C229/12 , C07D265/32 , C08K5/357
摘要： The invention relates to new compounds containing 1-8 active groups of the type 3,3,6,6-polysubstituted 2-morpholinone and having the formula F(A'--Z).sub.m --X (F),wherein m is a number from 1 to 8;X is an organic anchor group of valency m and in case that m is not 1, X may also be a direct bond, SO.sub.2, P or PO;A' is a monovalent group of the formula E ##STR1## containing one linking group; Z is a direct bond, --O--, --S--, --SO--, --SO.sub.2 -- or --NR'.sub.14 --; provided that Z is --O--, --S--, --SO--, --SO.sub.2 -- or --NR'.sub.14 -- if m is 1 and the linking group in formula E is G.sub.3 or G.sub.5 ;G.sub.1 is hydrogen; C.sub.1 -C.sub.18 alkyl; C.sub.2 -C.sub.18 alkyl substituted by OH and/or phenyl; oxyl; OH; C.sub.2 -C.sub.12 cyanoalkyl; C.sub.2 -C.sub.12 cyanoalkoxy; C.sub.1 -C.sub.18 alkoxy; C.sub.5 -C.sub.12 cycloalkoxy; C.sub.3 -C.sub.8 alkenyl; C.sub.3 -C.sub.8 alkynyl; C.sub.3 -C.sub.8 alkenyloxy; C.sub.7 -C.sub.12 phenylalkyl; C.sub.7 -C.sub.12 phenylalkyl substituted by hydroxy, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy; C.sub.7 -C.sub.15 phenylalkoxy; C.sub.7 -C.sub.15 phenylalkoxy, which is substituted by C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy; or G.sub.1 is C.sub.1 -C.sub.8 alkanoyl; C.sub.3 -C.sub.5 alkenoyl; C.sub.1 -C.sub.18 alkanoyloxy; C.sub.3 -C.sub.8 epoxyalkyl; or G.sub.1 is the linking group --R.sub.10 --;G.sub.2 and G.sub.4 are, independently of one another, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkenyl, C.sub.5 -C.sub.12 cycloalkyl, or an oligocyclic hydrocarbon residue of 6-12 carbon atoms;G.sub.3 is as defined for G.sub.2 or is C.sub.1 -C.sub.8 hydroxyalkyl; or G.sub.2 and G.sub.3 together are (CH.sub.2).sub.e, where e is a number from 4 to 11; or G.sub.5 is the linking group --R.sub.5 --;G.sub.5 is as defined for G.sub.4 or is C.sub.1 -C.sub.8 hydroxyalkyl; or G.sub.4 and G.sub.5 together are (CH.sub.2).sub.e, where e is number from 4 to 11; or G.sub.5 is the linking group --R.sub.5 --; G.sub.6 is as defined for G.sub.4 or is hydrogen;or G.sub.6 is the linking group, which is a direct bond or --R.sub.5 --;and other residues are as defined in claim 1. The new compounds are effective as stabilizers for organic material, especially coatings, against harmful effects of light, oxygen and/or heat.
摘要翻译：本发明涉及含有1,3,6,6-三取代的2-吗啉酮类的1-8个活性基团并具有式F（A'-Z）mX（F）的新化合物，其中m是1 到8 X是化合价m的有机锚定基团，在m不为1的情况下，X也可以是直接键合，SO 2，P或PO; A'是含有一个连接基团的式E的单价基团; Z是直接键，-O - ， - S - ， - SO - ， - SO2-或-NR'14-; 条件是Z为-O - ， - S - ， - SO - ， - SO 2 - 或-NR'14-，如果m为1且式E中的连接基团为G3或G5; G1是氢; C 1 -C 18烷基; 由OH和/或苯基取代的C 2 -C 18烷基; 氧基哦; C 2 -C 12氰基烷基; C2-C12氰基烷氧基; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C3-C8链烯氧基; C7-C12苯基烷基; 被羟基，C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 7 -C 12苯基烷基; C7-C15苯基烷氧基; 被C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 7 -C 15苯基烷氧基; 或G1是C1-C8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; C3-C8环氧烷基; 或G1是连接基团-R10-; G2和G4彼此独立地为C 1 -C 18烷基，C 5 -C 12环烯基，C 5 -C 12环烷基或6-12个碳原子的低聚烃残基; G3如对于G2所定义或为C1-C8羟烷基; 或G2和G3一起为（CH 2）e，其中e为4至11的数; 或G5为连接基团-R5-; G5如G4所定义或是C 1 -C 8羟烷基; 或G4和G5一起为（CH 2）e，其中e为4至11; 或G5为连接基团-R5-; G6如G4所定义或为氢; 或G6是连接基团，其是直接键或-R 5 - ; 和其它残基如权利要求1中所定义。新化合物作为有机材料的稳定剂，特别是涂料，有效地防止光，氧和/或热的有害影响。

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