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1. 发明授权

US4757106A Aqueous organopolysiloxane emulsions 失效
标题翻译：水性有机聚硅氧烷乳液
公开(公告)号：US4757106A
公开(公告)日：1988-07-12
申请号：US19988
申请日：1987-02-27
申请人： Hans Mayer , Hermann Wilhelm , Bernward Deubzer
发明人： Hans Mayer , Hermann Wilhelm , Bernward Deubzer
IPC分类号： C08L83/04 , C04B24/42 , C04B26/32 , C08J3/03 , C08L83/08 , C09D5/02 , C09D183/04 , D04H1/4209 , D04H1/64 , C08K5/24
CPC分类号： D04H1/4209 , C04B24/42 , C04B26/32 , C04B41/4961 , C08J3/03 , D04H1/64 , C08J2383/04
摘要： Aqueous emulsions of (A) an organopolysiloxane comprising aliphatic radicals that are bonded to silicon via oxygen which have a molecular weight of at least 620 g/mol, and (B) an emulsifier containing a salt of a water-soluble organic or inorganic acid and a polysiloxane which contains siloxane units having monovalent SiC-bonded radicals with basic nitrogen, in which the basic nitrogen is present in an amount of at least 0.5 percent by weight based on the weight of the polysiloxane, and not more than 5 percent by weight of a water-soluble solvent or octanols, based on the weight of the emulsifier (B).These emulsions may be used to impart hydrophobic properties to mineral substances by applying the emulsions to the mineral substances after they have been molded. These emulsions may also be used to impart hydrophobic properties to inorganic binding agents or they may be used as binding agents for inorganic fibrous materials or as binding agents in aqueous paints.
摘要翻译：（A）包含分子量至少为620g / mol通过氧结合到硅上的脂族基团的有机聚硅氧烷的水乳液，和（B）含有水溶性有机酸或无机酸盐的乳化剂和含有具有碱性氮的一价SiC键合基团的硅氧烷单元的聚硅氧烷，其中碱性氮以基于聚硅氧烷的重量计至少0.5重量％的量存在，并且不超过5重量％基于乳化剂（B）的重量的水溶性溶剂或辛醇。这些乳液可以用于通过在成型后将矿物质施加到矿物质上来赋予矿物质疏水性。这些乳液也可以用于赋予无机粘合剂疏水性，或者它们可以用作无机纤维材料的粘合剂或作为水性涂料中的结合剂。

2. 发明授权

US4661551A Transparent aqueous organopolysiloxane compositions 失效
标题翻译：透明的有机聚硅氧烷组合物
公开(公告)号：US4661551A
公开(公告)日：1987-04-28
申请号：US787841
申请日：1985-10-16
申请人： Hans Mayer , Bernward Deubzer , Petra Iretzberger , Rudolf Muhlhofer , Hermann Wilhelm
发明人： Hans Mayer , Bernward Deubzer , Petra Iretzberger , Rudolf Muhlhofer , Hermann Wilhelm
IPC分类号： C08G77/00 , C04B24/42 , C04B41/49 , C04B41/64 , C08G77/12 , C08G77/26 , C08G77/28 , C08G77/38 , C08K5/544 , C08L83/00 , C08L83/04 , C08L83/08 , C09D7/12 , C09K3/18 , D21H19/10 , D21H19/32 , C08K5/05
CPC分类号： C04B41/009 , C04B24/42 , C04B41/4905 , C04B41/4961 , C04B41/64 , C08G77/12 , C08G77/26 , C08K5/544 , C08L83/08
摘要： Transparent aqueous organopolysiloxane compositions comprising (A) a salt of a water-soluble organic or inorganic acid and a polysiloxane, which contains in addition to the other siloxane units siloxane units containing SiC-bonded monovalent radicals having basic nitrogen atoms in an amount of at least 0.5 percent by weight, based on the weight of the polysiloxane; and (B) an organic silicon compound having basic nitrogen atoms in an amount of from 0 to 0.5 percent by weight, based on the weight of the organic silicon compound; and when constituent (B) does not contain at least one organic silicon compound having a molecular weight greater than 600 g/mol in an amount of at least 0.1 part per part by weight of contituent (A), then an organic solvent (C) is present in an amount up to about 5 percent by weight based on the weight of constituent (A), in which the organic solvent is soluble in water up to about 1 part by weight per 100 parts by weight of water at 20.degree. C. and 1020 hPa (abs.) and is free of halogen atoms.The organopolysiloxanes may contain Si-bonded hydrogen as well as at least one SiC-bonded radical having a basic nitrogen atom in one and the same molecule.
摘要翻译：透明含水有机基聚硅氧烷组合物，其包含（A）水溶性有机酸或无机酸的盐和聚硅氧烷，其除了含有其它硅氧烷单元的硅氧烷单元外，所述硅氧烷单元含有至少具有碱性氮原子的具有至少 0.5重量％，基于聚硅氧烷的重量; 和（B）基于有机硅化合物的重量，碱性氮原子的量为0至0.5重量％的有机硅化合物; 当组分（B）不含有至少一种分子量大于600g / mol的至少一种有机硅化合物，其量为每份重量的（A）成分为至少0.1份时，则有机溶剂（C）基于组分（A）的重量，其含量高达约5重量％，其中有机溶剂在水中可溶于高达约1重量份/ 100重量份的20℃的水。和1020hPa（绝对），并且不含卤素原子。有机聚硅氧烷可以含有与Si键合的氢，以及至少一个在一个和相同分子中具有碱性氮原子的与SiC键合的基团。

3. 发明授权

US4552910A Aqueous compositions containing an organosilicon compound 失效
标题翻译：含有有机硅化合物的水性组合物
公开(公告)号：US4552910A
公开(公告)日：1985-11-12
申请号：US616796
申请日：1984-06-04
申请人： Bernward Deubzer , Hermann Wilhelm
发明人： Bernward Deubzer , Hermann Wilhelm
IPC分类号： B01F17/54 , C08G77/42 , C08G77/442 , C09D183/10 , B01F17/48 , B01F17/52 , C09D5/02
CPC分类号： C08G77/42 , C08G77/442 , C09D183/10
摘要： An aqueous organosilicon composition is prepared by mixing water with an organopolysiloxane having at least one ##STR1## group and having aliphatic radicals which are bonded to silicon via oxygen, a polyvinyl alcohol and/or a water-soluble cellulose ether containing hydroxyl groups in the presence of sufficient acid to provide a composition having an acid pH. The resultant composition may be neutralized and used as additives in aqueous paint compositions.
摘要翻译：含水有机硅组合物通过将水与具有至少一个基团的有机聚硅氧烷混合并且具有通过氧键结合到硅上的脂族基团，聚乙烯醇和/或含有羟基的水溶性纤维素醚在存在下制备足够的酸以提供具有酸性pH的组合物。所得组合物可以被中和并用作水性涂料组合物中的添加剂。

4. 发明授权

US4692474A Method for preparing plastic foams 失效
标题翻译：制备塑料泡沫的方法
公开(公告)号：US4692474A
公开(公告)日：1987-09-08
申请号：US874329
申请日：1986-06-16
申请人： Hans Mayer , Rudolf Muhlhofer , Bernward Deubzer , Walter Mayerhofer
发明人： Hans Mayer , Rudolf Muhlhofer , Bernward Deubzer , Walter Mayerhofer
IPC分类号： C08G77/00 , C08G77/26 , C08G77/28 , C08J9/02 , C08L83/05
CPC分类号： C08J9/02 , C08J2383/04
摘要： Plastic foams are prepared by reacting a compound containing Si-bonded hydrogen and at least one SiC-bonded radical having a basic nitrogen atom in the same molecule with a hydroxyl-containing compound.
摘要翻译：通过使含有Si键合氢的化合物与在同一分子中具有碱性氮原子的至少一个与SiC键合的基团与含羟基化合物反应来制备塑料泡沫。

5. 发明授权

US5627296A Phosphorus-containing organosilicon compounds 失效
标题翻译：含磷有机硅化合物
公开(公告)号：US5627296A
公开(公告)日：1997-05-06
申请号：US559269
申请日：1995-11-15
申请人： Jochen Dauth , Hans Mayer , Bernward Deubzer , Petra Gratzl
发明人： Jochen Dauth , Hans Mayer , Bernward Deubzer , Petra Gratzl
IPC分类号： C07F9/30 , C07F9/38 , C07F9/48 , C07F19/00 , C08G77/395 , C08G77/48 , C07F7/08
CPC分类号： C08G77/395 , C07F9/301 , C07F9/3821 , C07F9/4816 , C08G77/48
摘要： The present invention provides novel phosphorus-containing organosilicon compounds which can be prepared in a simple manner using readily obtainable starting materials, which are hydrophilic to water-soluble and whose hydrophilicity or water-solubility can be specifically controlled by modification of the phosphorus-containing organosilicon compounds.
摘要翻译：本发明提供新颖的含磷有机硅化合物，其可以使用容易获得的起始原料以简单的方式制备，其亲水性为水溶性，并且其亲水性或水溶性可以通过改性含磷有机硅化合物。

6. 发明授权

US5039724A Process for preparing aqueous emulsions of high-molecular-weight organopolysiloxanes 失效
标题翻译：制备高分子量有机聚硅氧烷的水性乳液的方法
公开(公告)号：US5039724A
公开(公告)日：1991-08-13
申请号：US425094
申请日：1989-10-23
申请人： Ulrich Demlehner , Bernward Deubzer , Hans Mayer , Erich Pilzweger
发明人： Ulrich Demlehner , Bernward Deubzer , Hans Mayer , Erich Pilzweger
IPC分类号： C08J3/07 , C08J3/03 , C08K5/5419 , C08L83/04 , C09D183/04
CPC分类号： C08J3/03 , C08J2383/04
摘要： A process for preparing aqueous emulsions from high-molecular-weight organopolysiloxanes which are solid at room temperature, in the absence of organic solvents, which comprises dissolving the high-molecular-weight organopolysiloxane which is solid at room temperature in a low-molecular-weight organo(poly)siloxane which is liquid at room temperature, and emulsifying this solution with water in the presence of an emulsifier and other additives, if desired.
摘要翻译：在不存在有机溶剂的情况下，室温下为固体的高分子量有机聚硅氧烷制备水性乳液的方法，其包括在室温下将固体的高分子量有机聚硅氧烷溶于低分子量有机（聚）硅氧烷，其在室温下为液体，并且如果需要，在乳化剂和其它添加剂的存在下，用水乳化该溶液。

7. 发明授权

US06182759B2 Process for treating water-containing natural gas wells and natural gas storage wells 失效
标题翻译：含水天然气井和天然气储存井的处理工艺
公开(公告)号：US06182759B2
公开(公告)日：2001-02-06
申请号：US09169543
申请日：1998-10-09
申请人： Willibald Burger , Hans Mayer , Robert Schröck , Holger Wöltje , Bernward Deubzer , Hans Lautenschlager
发明人： Willibald Burger , Hans Mayer , Robert Schröck , Holger Wöltje , Bernward Deubzer , Hans Lautenschlager
IPC分类号： E21B4325
CPC分类号： C09K8/885 , C09K8/5086
摘要： The gas flow in water-containing natural gas wells and natural gas storage wells is improved if a homogeneous phase comprising a water-repellent, solvolysis-resistant active compound is injected into the water-bearing rock.
摘要翻译：如果将包含拒水溶剂分解的活性化合物的均相注入含水岩石，则含水天然气井和天然气储存井中的气体流量得到改善。

8. 发明授权

US06251313B1 Process for the preparation of microencapsulated products having organopolysiloxane walls 失效
标题翻译：制备具有有机聚硅氧烷壁的微囊化产品的方法
公开(公告)号：US06251313B1
公开(公告)日：2001-06-26
申请号：US09261401
申请日：1999-03-03
申请人： Bernward Deubzer , Jochen Dauth
发明人： Bernward Deubzer , Jochen Dauth
IPC分类号： B01J1302
CPC分类号： B01J13/18 , B01J13/04 , Y10T428/257 , Y10T428/2982
摘要： In the preparation of microcapsules having shell walls of organopolysiloxane and a core material, the shell walls are produced in situ by hydrolysis and polycondensation of organosilanes and/or their condensates having not more than 4 silicon atoms.
摘要翻译：在制备具有有机聚硅氧烷和核心材料的壳壁的微胶囊时，壳壁通过有机硅烷和/或其具有不超过4个硅原子的缩合物的水解和缩聚而原位制备。

9. 发明授权

US06194534B1 Organopolysiloxanes with dye residues 有权
标题翻译：有染料残留的有机聚硅氧烷
公开(公告)号：US06194534B1
公开(公告)日：2001-02-27
申请号：US09380977
申请日：1999-09-20
申请人： Frank Baumann , Gunter Mahr , Bernward Deubzer
发明人： Frank Baumann , Gunter Mahr , Bernward Deubzer
IPC分类号： C08G7726
CPC分类号： C08G77/382 , C07F7/0838 , C09B69/10
摘要： The invention relates to organopolysiloxanes with dye residues comprising units of the general formula R1a(RO)bAcR2dSiO(4−a−b−c−d)/2 (I) wherein R can be identical or different and is hydrogen atom or monovalent, substituted or unsubstituted hydrocarbon radical, R1 can be identical or different and is hydrogen atom or monovalent, SC-bonded hydrocarbon radical, R2 can be identical or different and is substituted, monovalent, Si—C bonded hydrocarbon radical, A can be identical or different and is a radical of a water-soluble organic dye containing at least one of sulfonic acid groups, sulfonate groups, or metal complexes thereof, a is 0, 1, 2, or 3, b is 0, 1, 2 or 3, d is 0, 1, 2, or 3 and c is 0, 1 or 2 with the proviso that the sum of a, b, c and d is less than or equal to 3, the organopolysiloxanes have at least one radical, and, in the units of the formula (I) where c is other than 0, d is 0.
摘要翻译：本发明涉及具有一般化学式R的单元的染料残基的有机聚硅氧烷可以相同或不同，并且是氢原子或一价，取代或未取代的烃基，R 1可以相同或不同，并且是氢原子或一价SC-键合烃基团可以相同或不同，并且是取代的一价Si-C键合的烃基，A可以相同或不同，并且是含有磺酸基，磺酸酯基，磺酸基等的至少一种的水溶性有机染料的基团，或其金属络合物，a为0,1,2或3，b为0,1,2或3，d为0,1,2或3，c为0,1或2，条件是总和的a，b，c和d小于或等于3，有机聚硅氧烷具有至少一个基团，并且以式（I）为单位，其中c不为0，d为0。

10. 发明授权

US5869726A Process for preparing organosilicon compounds containing (meth)acryloxy groups 失效
标题翻译：制备含有（甲基）丙烯酰氧基的有机硅化合物的方法
公开(公告)号：US5869726A
公开(公告)日：1999-02-09
申请号：US931723
申请日：1997-09-16
申请人： Jochen Dauth , Bernward Deubzer , Petra Gratzl , Josef Wolferseder
发明人： Jochen Dauth , Bernward Deubzer , Petra Gratzl , Josef Wolferseder
IPC分类号： C08G77/12 , C08G77/20 , C08G77/38 , C09D183/06 , C09D183/07 , C07F7/08
CPC分类号： C09D183/06 , C08G77/38
摘要： A novel process for preparing organosilicon compounds containing (meth)acxyloxy groups is described, in which alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) of the formula ##STR1## where R.sup.2 is a hydrogen atom or a methyl radical,R.sup.3 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical andR.sub.4 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical, andz is an integer from 1 to 12,are reacted with organosilicon compounds (2) comprising units of the formula ##STR2## where R is an identical or different monovalent, optionally halogenated hydrocarbon radical having from 1 to 18 carbon atoms per radical, ande is 0 or 1, on average from 0.01 to 1.0,f is 0, 1, 2 or 3, on average from 0.0 to 3.0, andhaving at least one Si-bonded hydrogen atom per molecule in the presence of catalysts (3) which promote the addition Si-bonded hydrogen onto aliphatic multiple bonds and also in the presence of polymerization inhibitors (4), where alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) are used in amounts of from 1.01 to 1.5 mole per gram atom of Si-bonded hydrogen in organosilicon compound (2).
摘要翻译：描述了制备含有（甲基）丙氧基的有机硅化合物的新方法，其中式（II）的烷氧基化烷基-2-炔基1,4-二（甲基）丙烯酸酯（1）其中R2是氢原子或甲基，R3是每个基团具有1至6个碳原子的直链或支链亚烷基，R4是每个基团具有1至6个碳原子的直链或支链亚烷基，z是1至 12与包含式（III）的单元的有机硅化合物（2）反应，其中R是相对或不同的每个基团具有1至18个碳原子的单价，任选卤代烃基，e是0或1 平均为0.01〜1.0，f为0,1,2或3，平均为0.0〜3.0，在催化剂（3）的存在下，每分子具有至少一个Si键合的氢原子，促进Si的添加键合的氢键到脂族多重键上，并且在聚合抑制剂的存在下（4），其中烷氧基化的烷基-2-炔1,4-二（甲基）丙烯酸酯（1）的用量为有机硅化合物（2）中每克原子的Si键合氢的1.01至1.5摩尔。

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