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1. 发明授权

US07687202B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US07687202B2
公开(公告)日：2010-03-30
申请号：US11315189
申请日：2005-12-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M4/58 , H01M2/16 , H01M6/04 , H10M4/62
CPC分类号： H01M4/131 , H01M2/1653 , H01M4/505 , H01M4/525 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode active material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The estimated heat generation rate is determined by obtaining a relation between absolute temperature T and heat generation rate V of the positive electrode material mixture using an accelerating rate calorimeter; plotting a relation between the inverse of absolute temperature T and the logarithm of heat generation rate V according to the Arrhenius law; obtaining a straight line fitted to the plotted points in a heat generation temperature range of T
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极活性物质混合物在200℃下的估计发热率不大于50W / kg。通过使用加速率量热计获得正极材料混合物的绝对温度T和发热量V之间的关系来确定估计发热速率; 根据Arrhenius定律绘制绝对温度T的倒数与发热量V的对数之间的关系; 在T <200℃的发热温度范围内获得拟合到绘图点的直线; 并将直线外推至200℃的温度。

2. 发明申请

US20060286445A1 Non-aqueous electrolyte secondary battery 有权
公开(公告)号：US20060286445A1
公开(公告)日：2006-12-21
申请号：US11473334
申请日：2006-06-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M10/50 , H01M4/58 , H01M4/40
CPC分类号： H01M4/131 , H01M2/1653 , H01M2/1673 , H01M4/133 , H01M4/525 , H01M4/58 , H01M10/0431 , H01M10/0525 , H01M10/0587 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The positive electrode and the negative electrode are wound together with the separator and the heat-resistant insulating layer interposed therebetween.

3. 发明授权

US08951674B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08951674B2
公开(公告)日：2015-02-10
申请号：US11473327
申请日：2006-06-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M4/13 , H01M4/50
CPC分类号： H01M4/131 , H01M2/1653 , H01M4/505 , H01M4/525 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The positive electrode and the negative electrode are wound together with the separator and the heat-resistant insulating layer interposed therebetween.
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极材料混合物在200℃下的估计发热速率不大于50W / kg。将正极和负极与隔板缠绕在一起，并且将耐热绝缘层插入其间。

4. 发明授权

US08187748B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08187748B2
公开(公告)日：2012-05-29
申请号：US11473334
申请日：2006-06-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M4/13
CPC分类号： H01M4/131 , H01M2/1653 , H01M2/1673 , H01M4/133 , H01M4/525 , H01M4/58 , H01M10/0431 , H01M10/0525 , H01M10/0587 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The positive electrode and the negative electrode are wound together with the separator and the heat-resistant insulating layer interposed therebetween.
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极材料混合物在200℃下的估计发热速率不大于50W / kg。将正极和负极与隔板缠绕在一起，并且将耐热绝缘层插入其间。

5. 发明申请

US20060286444A1 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US20060286444A1
公开(公告)日：2006-12-21
申请号：US11473327
申请日：2006-06-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M10/50 , H01M2/16 , H01M4/58 , H01M4/48 , H01M4/50 , H01M4/52
CPC分类号： H01M4/131 , H01M2/1653 , H01M4/505 , H01M4/525 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode material mixture has an estimated heat generation rate at 200° C of not greater than 50 W/kg. The positive electrode and the negative electrode are wound together with the separator and the heat-resistant insulating layer interposed therebetween.
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极材料混合物在200℃下的估计发热速率不大于50W / kg。将正极和负极与隔板缠绕在一起，并且将耐热绝缘层插入其间。

6. 发明申请

US20060141341A1 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US20060141341A1
公开(公告)日：2006-06-29
申请号：US11315189
申请日：2005-12-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M10/50 , H01M4/48 , H01M4/52 , H01M4/50
CPC分类号： H01M4/131 , H01M2/1653 , H01M4/505 , H01M4/525 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode active material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The estimated heat generation rate is determined by obtaining a relation between absolute temperature T and heat generation rate V of the positive electrode material mixture using an accelerating rate calorimeter; plotting a relation between the inverse of absolute temperature T and the logarithm of heat generation rate V according to the Arrhenius law; obtaining a straight line fitted to the plotted points in a heat generation temperature range of T
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极活性物质混合物在200℃下的估计发热率不大于50W / kg。通过使用加速率量热计获得正极材料混合物的绝对温度T和发热量V之间的关系来确定估计发热速率; 根据Arrhenius定律绘制绝对温度T的倒数与发热量V的对数之间的关系; 在T <200℃的发热温度范围内获得拟合到绘图点的直线; 并将直线外推至200℃的温度。

7. 发明申请

US20050026036A1 Battery 审中-公开
标题翻译：电池
公开(公告)号：US20050026036A1
公开(公告)日：2005-02-03
申请号：US10895085
申请日：2004-07-21
申请人： Hirokazu Kimiya , Shinji Kasamatsu , Hajime Nishino , Kazuhiro Okamura , Mikinari Shimada
发明人： Hirokazu Kimiya , Shinji Kasamatsu , Hajime Nishino , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M2/02 , H01M2/14 , H01M2/16 , H01M2/18 , H01M2/22 , H01M4/64 , H01M6/00 , H01M10/04 , H01M10/052 , H01M10/42
CPC分类号： H01M2/1686 , H01M2/0207 , H01M2/1653 , H01M10/052 , H01M10/4235 , Y10T29/49114
摘要： A battery has an electrode with a mixture layer including electroactive material formed on a current collector whose exposed part is welded to a lead, and also a separator that shrinks with heat. In the battery, a heat shrinkage-preventing layer is provided on a portion of the separator that faces the lead. As a result, even if a minor short-circuit occurs and a large amount of current is flown to a minor short-circuit region, the heat shrinkage-preventing layer prevents expansion of a short-circuit area resulting from heat shrinkage of the separator. Thus, a conspicuous decrease in battery properties is prevented.
摘要翻译：电池具有具有混合层的电极，包括形成在集电体上的电活性材料，其暴露部分焊接到引线上，以及还具有热收缩的隔板。在电池中，隔板的面向引线的部分设置有防热层。结果，即使发生小的短路并且大量的电流流向短路区域，因此防热层防止由隔板的热收缩引起的短路区域的膨胀。因此，防止了电池特性的显着降低。

8. 发明授权

US06605386B1 Non-aqueous electrolyte secondary battery comprising composite particles 有权
标题翻译：包含复合颗粒的非水电解质二次电池
公开(公告)号：US06605386B1
公开(公告)日：2003-08-12
申请号：US09601224
申请日：2000-09-18
申请人： Shinji Kasamatsu , Hiroshi Yoshizawa , Kazuhiro Okamura , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
发明人： Shinji Kasamatsu , Hiroshi Yoshizawa , Kazuhiro Okamura , Hizuru Koshina , Harunari Shimamura , Yoshiaki Nitta
IPC分类号： H01M462
CPC分类号： H01M4/38 , H01M4/04 , H01M4/13 , H01M4/364 , H01M4/366 , H01M4/386 , H01M4/387 , H01M4/485 , H01M4/58 , H01M4/5835 , H01M6/10 , H01M10/0525 , H01M10/446 , H01M2010/4292
摘要： A non-aqueous electrolyte secondary battery comprises a positive electrode and a negative electrode capable of intercalating and de-intercalating lithium, a non-aqueous electrolyte and separators or solid electrolytes. The negative electrode contains, as a main component, composite particles constructed in such a manner that at least part of the surface of nuclear particles comprising at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound composed of the element included in the nuclear particles and another predetermined element which is not an element included in the nuclear particles. To improve the ability of the battery, the composite particles mentioned above can include at least one trace element selected from iron, lead and bismuth. The porosity of a mixture layer at the negative electrode is 10% or more and 50% or less. The amount of the non-aqueous electrolyte, the thickness of the separators or the like is restricted in a specific value. The foregoing construction suppresses occurrence of an internal short circuit between the positive electrode and the negative electrode caused by expansion of the negative electrode materials, thereby achieving a high capacity battery with a superior charge/discharge cycle properties, which is suitable for a high-speed charging.
摘要翻译：非水电解质二次电池包括能够插入和脱嵌锂的正极和负极，非水电解质和隔膜或固体电解质。作为主要成分的负极以作为构成要素的锡，硅，锌中的至少一种的核粒子的至少一部分表面的固体溶液或由包含在核粒子中的元素构成的金属间化合物和不包含在核粒子中的元素的另一规定元素。为了提高电池的能力，上述复合颗粒可以包括至少一种选自铁，铅和铋的痕量元素。负极上的混合层的孔隙率为10％以上且50％以下。非水电解质的量，分离器的厚度等被限制在特定值。上述结构抑制了由负极材料的膨胀引起的正极和负极之间的内部短路的发生，从而实现了具有优良的充放电循环特性的高容量电池，适用于高速充电。

9. 发明授权

US08288038B2 Separator and non-aqueous electrolyte secondary battery 有权
标题翻译：分离器和非水电解质二次电池
公开(公告)号：US08288038B2
公开(公告)日：2012-10-16
申请号：US12067910
申请日：2007-05-17
申请人： Shinji Kasamatsu , Kazuhiro Okamura
发明人： Shinji Kasamatsu , Kazuhiro Okamura
IPC分类号： H01M4/00 , H01M2/16
CPC分类号： H01M2/1653 , H01M2/1686 , H01M10/05
摘要： In a non-aqueous electrolyte secondary battery, a separator in which its dynamic hardness DH obtained when the load to an indenter reaches 12 kgf/cm2 is 1000 or more is used. This separator includes at least one porous layer X including a polyolefin, and at least one porous layer Y including a heat resistant resin. The porosity of the porous layer X is 35% or more and 65% or less. In a pore size distribution of the porous layer X measured with a mercury porosimeter, a ratio of pores having a pore size of 0.02 μm or more and 0.2 μm or less is 40 vol % or more relative to a total pore volume. The thermal deformation temperature of the heat resistant resin is 160° C. or more.
摘要翻译：在非水电解质二次电池中，使用当压头的负荷达到12kgf / cm2时获得的动态硬度DH为1000以上的隔膜。该隔板包括至少一个包括聚烯烃的多孔层X和至少一个包含耐热树脂的多孔层Y. 多孔层X的孔隙率为35％以上且65％以下。在用水银孔隙度计测定的多孔层X的孔径分布中，孔径为0.02μm以上且0.2μm以下的孔的比率相对于总孔体积为40体积％以上。耐热树脂的热变形温度为160℃以上。

10. 发明申请

US20100151325A1 SEPARATOR AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 有权
标题翻译：分离器和非水电解质二次电池
公开(公告)号：US20100151325A1
公开(公告)日：2010-06-17
申请号：US12067910
申请日：2007-05-17
申请人： Shinji Kasamatsu , Kazuhiro Okamura
发明人： Shinji Kasamatsu , Kazuhiro Okamura
IPC分类号： H01M4/00 , H01M2/16
CPC分类号： H01M2/1653 , H01M2/1686 , H01M10/05
摘要： In a non-aqueous electrolyte secondary battery, a separator in which its dynamic hardness DH obtained when the load to an indenter reaches 12 kgf/cm2 is 1000 or more is used. This separator includes at least one porous layer X including a polyolefin, and at least one porous layer Y including a heat resistant resin. The porosity of the porous layer X is 35% or more and 65% or less. In a pore size distribution of the porous layer X measured with a mercury porosimeter, a ratio of pores having a pore size of 0.02 μm or more and 0.2 μm or less is 40 vol % or more relative to a total pore volume. The thermal deformation temperature of the heat resistant resin is 160° C. or more.
摘要翻译：在非水电解质二次电池中，使用当压头的负荷达到12kgf / cm2时获得的动态硬度DH为1000以上的隔膜。该隔板包括至少一个包括聚烯烃的多孔层X和至少一个包含耐热树脂的多孔层Y. 多孔层X的孔隙率为35％以上且65％以下。在用水银孔隙度计测定的多孔层X的孔径分布中，孔径为0.02μm以上且0.2μm以下的孔的比率相对于总孔体积为40体积％以上。耐热树脂的热变形温度为160℃以上。

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