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    • 2. 发明授权
    • Process for the production of electroluminescence element,
electroluminescence element
    • 电致发光元件,电致发光元件的制造方法
    • US5853552A
    • 1998-12-29
    • US300552
    • 1994-09-07
    • Hajime IshiharaYutaka HattoriMasayuki KatayamaNobuei ItoTadashi Hattori
    • Hajime IshiharaYutaka HattoriMasayuki KatayamaNobuei ItoTadashi Hattori
    • C09K11/61C09K11/77C23C14/00C23C14/06H05B33/10H05B33/14H05B33/18C23C14/34
    • C23C14/0057C09K11/612C09K11/7745C09K11/776C23C14/0629H05B33/10H05B33/14H05B33/18
    • A process for producing an electroluminescence element provided with a luminescent layer sandwiched between two electrodes on an insulating substrate, the luminescent layer being composed of a host material with a luminescent center element added. The process comprises a step of forming the aforesaid luminescent layer as a film onto the insulating substrate by either sputtering or evaporation, by use of a source material composed of a compound of an element of Group II and an element of Group VI, to which a halide of a rare earth element is added as the luminescent center element. The atmosphere at the time of the film formation contains either a halogen gas or halide gas. The aforesaid luminescent layer is formed as a film onto the insulating substrate by either sputtering or evaporation, by use of a source material composed of the aforesaid compound of an element of Group II and an element of Group VI, to which a fluoride or fluorine compound of the luminescent center element and a halide other than fluoride of the element of Group II are added. The film formation atmosphere may be pretreated with a chlorine-containing gas prior to a film formation step of forming the luminescent layer as a film onto the insulating substrate by a sputtering method by use of a source material composed of the host material with the luminescent center element. An electro-luminescence element is further disclosed, wherein the X-ray diffraction spectrum thereof has only a single peak at an X-ray diffraction angle from the luminescent layer, ranging from 25.degree. to 30.degree. according to a thin film X-ray diffraction measuring method using Cu-Kd radiation, and no other peaks of the X-ray diffraction spectrum exist at an X-ray diffraction angle of approximately 27.degree..
    • 一种制造电致发光元件的方法,所述电致发光元件在绝缘基板上具有夹在两个电极之间的发光层,所述发光层由添加有发光中心元件的主体材料构成。 该方法包括通过溅射或蒸发,通过使用由II族元素和VI族元素的化合物组成的源材料,通过溅射或蒸发将上述发光层作为膜形成在绝缘基板上的步骤,其中 加入稀土元素的卤化物作为发光中心元件。 成膜时的气氛中含有卤素气体或卤化物气体。 上述发光层通过溅射或蒸镀通过使用由上述化合物II族元素和VI族元素组成的源材料形成为绝缘基板,氟化物或氟化合物 的发光中心元素和除了II族元素的氟化物之外的卤化物。 成膜气氛可以在通过使用由主体材料与发光中心构成的源材料通过溅射法将形成发光层作为膜的成膜步骤之前用含氯气体预处理 元件。 进一步公开了一种电致发光元件,其中,根据薄膜X射线衍射,其X射线衍射光谱在距发光层的X射线衍射角仅为单峰,为25〜30° 使用Cu-Kd辐射的测量方法,并且在大约27°的X射线衍射角处不存在X射线衍射光谱的其它峰。
    • 3. 发明授权
    • Dry etching method and manufacturing method of manufacturing EL element
using same
    • 干蚀刻方法和使用其制造EL元件的制造方法
    • US5888410A
    • 1999-03-30
    • US825579
    • 1997-03-31
    • Hajime IshiharaKazuhiro InoguchiYutaka HattoriNobuei ItoTadashi Hattori
    • Hajime IshiharaKazuhiro InoguchiYutaka HattoriNobuei ItoTadashi Hattori
    • C23F4/00H01L21/302H01L21/3065H01L21/461H01L21/465H05B33/10H05B33/12H05B33/14B44C1/22
    • H05B33/10H01L21/465
    • A dry etching method performing dry etching of a material containing zinc forms and patterns a resist on the material to be etched, and etches the material using an etching gas which is a mixed gas of methane gas and an inert gas. A dry etching method that dry etches a material containing zinc etches the material using an etching gas that consists only of methane gas, an inert gas, and hydrogen gas alone. Another dry etching method that dry etches a material containing zinc introduces an etching gas that contains methane gas, an inert gas, and hydrogen gas into a dry etching device, in which the flow rate of the hydrogen gas is set such that it is equal to or greater than the value at which the amount of dissociated hydrogen becomes saturated, and etches the material using the etching gas. An EL element manufacturing method forms a first luminescent material containing zinc in its composition on a first insulated layer, forms a first resist that has a first pattern on the first luminescent material, dry etches the first luminescent material through the first resist, thereby forming the first luminescent layer; forms a second luminescent material having zinc in its composition on the first luminescent layer, forms a second resist on the second luminescent material, and dry etches the second luminescent material through the second resist.
    • 对含有锌的材料进行干蚀刻的干式蚀刻方法形成并在待蚀刻材料上形成抗蚀剂,并使用作为甲烷气体和惰性气体的混合气体的蚀刻气体蚀刻材料。 使用仅由甲烷气体,惰性气体和氢气单独构成的蚀刻气体来干燥蚀刻含锌材料的干蚀刻方法蚀刻材料。 对含有锌的材料进行干蚀刻的另一种干蚀刻方法将含有甲烷气体,惰性气体和氢气的蚀刻气体引入到干法蚀刻装置中,其中氢气的流量设定为等于 或大于解离氢的量饱和的值,并且使用蚀刻气体蚀刻该材料。 EL元件制造方法在第一绝缘层上形成含有锌的第一发光材料,在第一发光材料上形成具有第一图案的第一抗蚀剂,通过第一抗蚀剂干燥蚀刻第一发光材料,从而形成 第一发光层; 在第一发光层上形成具有锌组成的第二发光材料,在第二发光材料上形成第二抗蚀剂,并通过第二抗蚀剂干蚀刻第二发光材料。
    • 5. 发明授权
    • Multi-color electroluminescent display panel
    • 多色电致发光显示面板
    • US6137222A
    • 2000-10-24
    • US98958
    • 1998-06-17
    • Hajime IshiharaTomoya UchidaYutaka HattoriKazuhiro Inoguchi
    • Hajime IshiharaTomoya UchidaYutaka HattoriKazuhiro Inoguchi
    • H05B33/08C09K11/57C09K11/77G09F9/30H05B33/12H05B33/14H05B33/22H05B33/26
    • H05B33/12C09K11/574C09K11/7745H05B33/14H05B33/26
    • An electroluminescent display panel which is able to selectively display different colors by changing a voltage level imposed thereon is made in a simple structure. A first luminescent layer (4) emitting green light, for example, and a second luminescent layer (5) emitting orange light, for example, are directly laminated on each other without interposing an intermediate electrode therebetween. The second luminescent layer covers only a part of the first luminescent layer to form a single layer portion and a double layer portion. The single layer portion emits green light at a low voltage level, while the double layer portion emits lemon light having a higher luminance at a high voltage level. The display may be made in a form of a matrix or a certain pattern. The display panel may be used as an instrument panel for an automobile. The green light display is used at night time, while the lemon light display with a high luminance is used at day time to cope with sun light.
    • 通过改变施加在其上的电压电平能够选择性地显示不同颜色的电致发光显示面板以简单的结构进行。 例如,发射绿光的第一发光层(4)和例如发射橙色光的第二发光层(5)彼此直接层叠,而不在其间插入中间电极。 第二发光层仅覆盖第一发光层的一部分,以形成单层部分和双层部分。 单层部分以低电压水平发射绿光,而双层部分在高电压水平下发出具有较高亮度的柠檬光。 显示器可以以矩阵或某种图案的形式制成。 显示面板可以用作汽车的仪表板。 绿灯显示屏在夜间使用,而白天采用高亮度的柠檬灯显示屏可以应付日光。
    • 8. 发明授权
    • Method and apparatus for separating isomers of chiral substance
    • 用于分离手性物质异构体的方法和装置
    • US08084266B2
    • 2011-12-27
    • US12735002
    • 2008-12-12
    • Hajime IshiharaTakuya IidaHiroki Eguchi
    • Hajime IshiharaTakuya IidaHiroki Eguchi
    • C07D487/22C07D487/00
    • C07D519/00B01D57/00C07B57/00C09B47/00C09B67/0096C09B69/108C09B69/109
    • In order to realize a method and an apparatus, each of which requires no contact treatment and no chemical reaction, for separating isomers of a chiral substance by irradiating a chiral substance with light such as circularly polarized light, so as to separate isomers in accordance with a difference in acceleration between the isomers, separation of isomers of a chiral substance in accordance with at least one embodiment of the present invention includes: (i) a circularly polarized light irradiating apparatus for irradiating, with circularly polarized light, a chiral substance which is a mixture of different isomers and is released from a molecular beam generating apparatus in a vacuum chamber; and (ii) isomer inlets for separating the different isomers of the chiral substance in accordance with a difference in acceleration between the different isomers.
    • 为了实现不需要接触处理和无化学反应的方法和装置,通过用诸如圆偏振光的光照射手性物质来分离手性物质的异构体,以便根据 根据本发明的至少一个实施方案,异构体之间的加速差异,手性物质的异构体的分离包括:(i)用圆偏振光照射手性物质的圆偏振光照射装置, 不同异构体的混合物,并在真空室中从分子束发生装置中释放; 和(ii)用于根据不同异构体之间的加速差的差异分离手性物质的不同异构体的异构体入口。