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1. 发明授权

US09334207B2 Integrated process to coproduce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane 有权
标题翻译：共同生产反式-1-氯-3,3,3-三氟丙烯，反式-1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷的综合方法
公开(公告)号：US09334207B2
公开(公告)日：2016-05-10
申请号：US13219831
申请日：2011-08-29
申请人： Konstantin A. Pokrovski , Daniel C. Merkel , Haiyou Wang , Hsueh Sung Tung , Ian Shankland
发明人： Konstantin A. Pokrovski , Daniel C. Merkel , Haiyou Wang , Hsueh Sung Tung , Ian Shankland
IPC分类号： C07C17/00 , C07C17/25 , C01B7/07 , C07C17/087 , C07C17/20 , C07C17/383 , C07C21/18
CPC分类号： C07C17/25 , C01B7/0706 , C01B7/0712 , C07C17/087 , C07C17/206 , C07C17/383 , C07C21/18 , Y02P20/125 , Y02P20/582 , C07C19/08
摘要： Disclosed is an integrated manufacturing process to co-produce (E)1-chloro-3,3,3-trifluoropropene, (E)1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoro-propane starting from a single chlorinated hydrocarbon feed stock, 240fa. The process includes a combined liquid or vapor phase reaction/purification operation which directly produces (E)1-chloro-3,3,3-trifluoropropene (1233zd(E)) from 240fa. In the second liquid phase fluorination reactor 1233zd(E) is contacted with HF in the presence of catalyst to produce 1,1,1,3,3-pentafluoropropane (245fa) with high conversion and selectivity. A third reactor is used for dehydrofluorination of 245fa to produce (E)1,3,3,3-tetrafluoropropene (1234ze(E)) by contacting in the liquid phase with a caustic solution or in the vapor phase using a dehydrofluorination catalyst. This operation may be followed by one or more purification processes to recover the 1234ze(E) product.
摘要翻译：公开了共同生产（E）1-氯-3,3,3-三氟丙烯，（E）1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷从单一氯化烃原料240fa开始。该方法包括从240fa直接产生（E）1-氯-3,3,3-三氟丙烯（1233zd（E））的组合的液相或汽相反应/纯化操作。在第二液相氟化反应器1233zd（E）中，在催化剂存在下与HF接触，得到具有高转化率和选择性的1,1,1,3,3-五氟丙烷（245fa）。第三反应器用于245fa的脱氟化氢以通过使用脱氟化氢催化剂在液相中与苛性碱溶液接触或以蒸气相接触来制备（E）1,3,3,3-四氟丙烯（1234ze（E））。该操作之后可以进行一个或多个纯化过程以恢复1234ze（E）产物。

2. 发明授权

US08648221B2 Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane 有权
标题翻译：共同生产反式-1-氯-3,3,3-三氟丙烯，反式-1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷的综合方法
公开(公告)号：US08648221B2
公开(公告)日：2014-02-11
申请号：US13315341
申请日：2011-12-09
申请人： Daniel C. Merkel , Haiyou Wang , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
发明人： Daniel C. Merkel , Haiyou Wang , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
IPC分类号： C07C17/23
CPC分类号： C07C17/25 , C07C17/087 , C07C17/206 , Y02P20/125 , Y02P20/582 , C07C21/18 , C07C19/10 , C07C19/08
摘要： Disclosed is an integrated process to co-produce trans-1-chloro-3,3,3-trifluoro-propene (1233zd(E)), trans-1,3,3,3-tetrafluoropropene (1234ze(E)), and 1,1,1,3,3-pentafluoropropane (245fa). Overall the co-production is a three-step process. The chemistry involves the steps of: (1) the reaction of 240fa with anhydrous HF in excess in a liquid-phase catalyzed reactor in such a way as to co-produce primarily 1233zd(E) and 244fa (plus byproduct HCl); (2) the 244fa stream can then be used to directly produce any of the three desired products; (3a) the 244fa stream can be dehydrochlorinated to produce the desired second product 1234ze(E); and/or (3b) the 244fa stream can be dehydrofluorinated to produce 1233zd(E) if more of that product is desired; and/or (3c) the 244fa stream can be further fluorinated to form 245fa.
摘要翻译：公开了共同生产反式-1-氯-3,3,3-三氟丙烯（1233zd（E）），反式-1,3,3,3-四氟丙烯（1234ze（E））和 1,1,1,3,3-五氟丙烷（245fa）。总的来说，联合制作是一个三步骤的过程。该化学方法包括以下步骤：（1）在液相催化的反应器中240fa与无水HF的过量反应，以共同主要生成1233zd（E）和244fa（加副产物HCl）; （2）然后可以使用244fa流直接生产三种所需产物中的任何一种; （3a）244fa流可以脱氯化氢以产生所需的第二产物1234ze（E）; 和/或（3b）如果需要更多的该产物，则244fa流可以被脱氟化氢以产生1233zd（E）和/或（3c）244fa流可以进一步氟化以形成245fa。

3. 发明授权

US08436217B2 Integrated process to co-produce 1,1,1,3,3-pentafluoropropane, trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene 有权
标题翻译：共同生产1,1,1,3,3-五氟丙烷，反式-1-氯-3,3,3-三氟丙烯和反式-1,3,3,3-四氟丙烯的综合方法
公开(公告)号：US08436217B2
公开(公告)日：2013-05-07
申请号：US13093007
申请日：2011-04-25
申请人： Haiyou Wang , Daniel C. Merkel , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
发明人： Haiyou Wang , Daniel C. Merkel , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
IPC分类号： C07C17/25 , C07C19/08 , C07C21/18 , C07C23/00 , C07C25/00 , C07C17/00
CPC分类号： C07C17/206 , C07B2200/09 , C07C17/087 , C07C17/25 , C07C17/383 , Y02P20/125 , C07C19/10 , C07C19/08 , C07C21/18
摘要： Disclosed is a fully integrated process for making 1,1,1,3,3-pentafluoropropane (HFC-245fa), trans-1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)), and trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)). The chemistry involves (a) the reaction of 1,1,1,3,3-pentachloropropane (HCC-240fa), or a derivative thereof selected from 1,1,3,3-tetrachloropropene and 1,3,3,3-tetrachloropropene, with anhydrous HF in excess in the presence of a catalyst in a liquid-phase reactor in such a way as to co-produce HCFO-1233zd, HFO-1234ze, HCFC-244fa (3-chloro-1,1,1,3-tetrafluoropropane), and HFC-245fa in a first reactor; (b) the reaction of HCFO-1233zd and HFO-1234ze with HCl in excess in the presence of a catalyst in a second reactor to convert these two olefins into HCFC-243fa and HCFC-244fa, respectively; (c) the reaction of HCFC-243fa and HCFC-244fa over a dehydrochlorination catalyst or in a caustic solution in a third reactor to form HCFO-1233zd and HFO-1234ze; and (d) the reaction of HCFO-1233zd(Z) and HFO-1234ze(Z) in the presence of a catalyst in a fourth reactor to form trans-1233zd and trans-1234ze, respectively.
摘要翻译：公开了制备1,1,1,3,3-五氟丙烷（HFC-245fa），反式-1-氯-3,3,3-三氟丙烯（HCFO-1233zd（E））的完全一体化方法， 1,3,3,3-四氟丙烯（HFO-1234ze（E））。该化学方法包括（a）1,1,1,3,3-五氯丙烷（HCC-240fa）或其衍生物选自1,1,3,3-四氯丙烯和1,3,3,3-四氯丙烯的反应，四氯丙烯，在催化剂存在下，在液相反应器中以无水HF过剩，以共同生产HCFO-1233zd，HFO-1234ze，HCFC-244fa（3-氯-1,1,1， 3-四氟丙烷）和HFC-245fa在第一反应器中; （b）HCFO-1233zd和HFO-1234ze与HCl在过渡催化剂存在下在第二反应器中的反应，分别将这两种烯烃转化为HCFC-243fa和HCFC-244fa; （c）HCFC-243fa和HCFC-244fa在脱氯化氢催化剂或第三反应器中的苛性碱溶液中的反应，形成HCFO-1233zd和HFO-1234ze; 和（d）HCFO-1233zd（Z）和HFO-1234ze（Z）在催化剂存在下在第四反应器中的反应分别形成反式-1233zd和反式1234ze。

4. 发明申请

US20120059200A1 Integrated Process to Coproduce Trans-1-Chloro-3,3,3-Trifluoropropene, Trans-1,3,3,3-Tetrafluoropropene, and 1,1,1,3,3-Pentafluoropropane 有权
标题翻译：共同生产反式-1-氯-3,3,3-三氟丙烯，反式1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷的综合方法
公开(公告)号：US20120059200A1
公开(公告)日：2012-03-08
申请号：US13219831
申请日：2011-08-29
申请人： Konstantin A. Pokrovski , Daniel C. Merkel , Haiyou Wang , Hsueh Sung Tung , Ian Shankland
发明人： Konstantin A. Pokrovski , Daniel C. Merkel , Haiyou Wang , Hsueh Sung Tung , Ian Shankland
IPC分类号： C07C21/18 , C07C19/08
CPC分类号： C07C17/25 , C01B7/0706 , C01B7/0712 , C07C17/087 , C07C17/206 , C07C17/383 , C07C21/18 , Y02P20/125 , Y02P20/582 , C07C19/08
摘要： Disclosed is an integrated manufacturing process to co-produce (E)1-chloro-3,3,3-trifluoropropene, (E)1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoro-propane starting from a single chlorinated hydrocarbon feed stock, 240fa. The process includes a combined liquid or vapor phase reaction/purification operation which directly produces (E)1-chloro-3,3,3-trifluoropropene (1233zd(E)) from 240fa. In the second liquid phase fluorination reactor 1233zd(E) is contacted with HF in the presence of catalyst to produce 1,1,1,3,3-pentafluoropropane (245fa) with high conversion and selectivity. A third reactor is used for dehydrofluorination of 245fa to produce (E)1,3,3,3-tetrafluoropropene (1234ze(E)) by contacting in the liquid phase with a caustic solution or in the vapor phase using a dehydrofluorination catalyst. This operation may be followed by one or more purification processes to recover the 1234ze(E) product.
摘要翻译：公开了共同生产（E）1-氯-3,3,3-三氟丙烯，（E）1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷从单一氯化烃原料240fa开始。该方法包括从240fa直接产生（E）1-氯-3,3,3-三氟丙烯（1233zd（E））的组合的液相或汽相反应/纯化操作。在第二液相氟化反应器1233zd（E）中，在催化剂存在下与HF接触，得到具有高转化率和选择性的1,1,1,3,3-五氟丙烷（245fa）。第三反应器用于245fa的脱氟化氢以通过使用脱氟化氢催化剂在液相中与苛性碱溶液接触或以蒸气相接触来制备（E）1,3,3,3-四氟丙烯（1234ze（E））。该操作之后可以进行一个或多个纯化过程以恢复1234ze（E）产物。

5. 发明申请

US20120271070A1 INTEGRATED PROCESS TO CO-PRODUCE 1,1,1,3,3-PENTAFLUOROPROPANE, TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE and TRANS-1,3,3,3-TETRAFLUOROPROPENE 有权
标题翻译：合成方法共同生产1,1,1,3,3-三氟硼酸，反式-1-氯代-3,3,3-三氟丙烯和TRANS-1,3,3,3-四氯丙烯
公开(公告)号：US20120271070A1
公开(公告)日：2012-10-25
申请号：US13093007
申请日：2011-04-25
申请人： Haiyou Wang , Daniel C. Merkel , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
发明人： Haiyou Wang , Daniel C. Merkel , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
IPC分类号： C07C17/38 , C07C17/25
CPC分类号： C07C17/206 , C07B2200/09 , C07C17/087 , C07C17/25 , C07C17/383 , Y02P20/125 , C07C19/10 , C07C19/08 , C07C21/18
摘要： Disclosed is a fully integrated process for making 1,1,1,3,3-pentafluoropropane (HFC-245fa), trans-1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)), and trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)). The chemistry involves (a) the reaction of 1,1,1,3,3-pentachloropropane (HCC-240fa), or a derivative thereof selected from 1,1,3,3-tetrachloropropene and 1,3,3,3-tetrachloropropene, with anhydrous HF in excess in the presence of a catalyst in a liquid-phase reactor in such a way as to co-produce HCFO-1233zd, HFO-1234ze, HCFC-244fa (3-chloro-1,1,1,3-tetrafluoropropane), and HFC-245fa in a first reactor; (b) the reaction of HCFO-1233zd and HFO-1234ze with HCl in excess in the presence of a catalyst in a second reactor to convert these two olefins into HCFC-243fa and HCFC-244fa, respectively; (c) the reaction of HCFC-243fa and HCFC-244fa over a dehydrochlorination catalyst or in a caustic solution in a third reactor to form HCFO-1233zd and HFO-1234ze; and (d) the reaction of HCFO-1233zd(Z) and HFO-1234ze(Z) in the presence of a catalyst in a fourth reactor to form trans-1233zd and trans-1234ze, respectively.
摘要翻译：公开了制备1,1,1,3,3-五氟丙烷（HFC-245fa），反式-1-氯-3,3,3-三氟丙烯（HCFO-1233zd（E））的完全一体化方法， 1,3,3,3-四氟丙烯（HFO-1234ze（E））。该化学方法包括（a）1,1,1,3,3-五氯丙烷（HCC-240fa）或其衍生物选自1,1,3,3-四氯丙烯和1,3,3,3-四氯丙烯的反应，四氯丙烯，在催化剂存在下，在液相反应器中以无水HF过剩，以共同生产HCFO-1233zd，HFO-1234ze，HCFC-244fa（3-氯-1,1,1， 3-四氟丙烷）和HFC-245fa在第一反应器中; （b）HCFO-1233zd和HFO-1234ze与HCl在过渡催化剂存在下在第二反应器中的反应，分别将这两种烯烃转化为HCFC-243fa和HCFC-244fa; （c）HCFC-243fa和HCFC-244fa在脱氯化氢催化剂或第三反应器中的苛性碱溶液中的反应，形成HCFO-1233zd和HFO-1234ze; 和（d）HCFO-1233zd（Z）和HFO-1234ze（Z）在催化剂存在下在第四反应器中的反应分别形成反式-1233zd和反式1234ze。

6. 发明申请

US20120184786A1 Integrated Process to Co-Produce Trans-1-Chloro-3,3,3-Trifluoropropene, Trans-1,3,3,3-Tetrafluoropropene, and 1,1,1,3,3-Pentafluoropropane 有权
标题翻译：共同生产反式-1-氯-3,3,3-三氟丙烯，反式-1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷的综合方法
公开(公告)号：US20120184786A1
公开(公告)日：2012-07-19
申请号：US13315341
申请日：2011-12-09
申请人： Daniel C. Merkel , Haiyou Wang , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
发明人： Daniel C. Merkel , Haiyou Wang , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
IPC分类号： C07C17/23
CPC分类号： C07C17/25 , C07C17/087 , C07C17/206 , Y02P20/125 , Y02P20/582 , C07C21/18 , C07C19/10 , C07C19/08
摘要： Disclosed is an integrated process to co-produce trans-1-chloro-3,3,3-trifluoro-propene (1233zd(E)), trans-1,3,3,3-tetrafluoropropene (1234ze(E)), and 1,1,1,3,3-pentafluoropropane (245fa). Overall the co-production is a three-step process. The chemistry involves the steps of: (1) the reaction of 240fa with anhydrous HF in excess in a liquid-phase catalyzed reactor in such a way as to co-produce primarily 1233zd(E) and 244fa (plus byproduct HCl); (2) the 244fa stream can then be used to directly produce any of the three desired products; (3a) the 244fa stream can be dehydrochlorinated to produce the desired second product 1234ze(E); and/or (3b) the 244fa stream can be dehydrofluorinated to produce 1233zd(E) if more of that product is desired; and/or (3c) the 244fa stream can be further fluorinated to form 245fa.
摘要翻译：公开了共同生产反式-1-氯-3,3,3-三氟丙烯（1233zd（E）），反式-1,3,3,3-四氟丙烯（1234ze（E））和 1,1,1,3,3-五氟丙烷（245fa）。总的来说，联合制作是一个三步骤的过程。该化学方法包括以下步骤：（1）在液相催化的反应器中240fa与无水HF的过量反应，以共同主要生成1233zd（E）和244fa（加副产物HCl）; （2）然后可以使用244fa流直接生产三种所需产物中的任何一种; （3a）244fa流可以脱氯化氢以产生所需的第二产物1234ze（E）; 和/或（3b）如果需要更多的该产物，则244fa流可以被脱氟化氢以产生1233zd（E）和/或（3c）244fa流可以进一步氟化以形成245fa。

7. 发明申请

US20120172636A1 HIGH PURITY E-1-CHLORO-3,3,3-TRIFLUOROPROPENE AND METHODS OF MAKING THE SAME 有权
标题翻译：高纯度E-1-氯代-3,3,3-三氟苯酚及其制备方法
公开(公告)号：US20120172636A1
公开(公告)日：2012-07-05
申请号：US12984024
申请日：2011-01-04
申请人： Konstantin A. Pokrovski , Rajiv Ratna Singh , Ian Shankland , Hsueh Sung Tung
发明人： Konstantin A. Pokrovski , Rajiv Ratna Singh , Ian Shankland , Hsueh Sung Tung
IPC分类号： C07C21/18 , C07C17/25 , C07C17/20
CPC分类号： C07C17/361 , C07B2200/09 , C07C17/206 , C07C17/25 , C07C19/10 , C07C21/18
摘要： The present invention discloses high purity E-1-chloro-3,3,3-trifluoropropene (1233zd(E)) and methods to produce the same. More specifically, the present invention discloses the methods of making 1233zd(E) essentially free of toxic impurities (e.g. 2-chloro-3,3,3-trifluoropropene (1233xf), chlorotetrafluoro-propene (1224), and 3,3,3-trifluoropropyne). The present invention further provides methods for making high purity 1233zd(E) with concentration of 1233xf and 1224 at or below 200 parts per million (ppm) and 3,3,3-trifluoropropyne impurities at or below 20 ppm. Formation of 1233xf impurity can be avoided if pure 1,1,1,3,3-pentachloropropane is used as a starting material. It was also found that formation of 1233xf is avoided if a liquid phase manufacturing process is used.
摘要翻译：本发明公开了高纯度E-1-氯-3,3,3-三氟丙烯（1233zd（E））及其制备方法。更具体地说，本发明公开了制备基本上不含有毒杂质的1233zd（E）的方法（例如2-氯-3,3,3-三氟丙烯（1233xf），氯四氟丙烯（1224）和3,3,3 三氟丙炔）。本发明还提供了制备浓度为1233xf和1224等于或低于200ppm（ppm）的高纯度1233zd（E）和等于或低于20ppm的3,3,3-三氟丙炔杂质的方法。如果使用纯1,1,1,3,3-五氯丙烷作为原料，则可以避免形成1233xf杂质。还发现如果使用液相制造方法，则避免形成1233xf。

8. 发明授权

US09156752B2 High purity E-1-chloro-3,3,3-trifluoropropene and methods of making the same 有权
标题翻译：高纯度E-1-氯-3,3,3-三氟丙烯及其制备方法
公开(公告)号：US09156752B2
公开(公告)日：2015-10-13
申请号：US12984024
申请日：2011-01-04
申请人： Konstantin A. Pokrovski , Rajiv Ratna Singh , Ian Shankland , Hsueh Sung Tung
发明人： Konstantin A. Pokrovski , Rajiv Ratna Singh , Ian Shankland , Hsueh Sung Tung
IPC分类号： C07C21/18 , C07C17/20 , C07C17/25
CPC分类号： C07C17/361 , C07B2200/09 , C07C17/206 , C07C17/25 , C07C19/10 , C07C21/18
摘要： The present invention discloses high purity E-1-chloro-3,3,3-trifluoropropene (1233zd(E)) and methods to produce the same. More specifically, the present invention discloses the methods of making 1233zd(E) essentially free of toxic impurities (e.g. 2-chloro-3,3,3-trifluoropropene (1233xf), chlorotetrafluoro-propene (1224), and 3,3,3-trifluoropropyne). The present invention further provides methods for making high purity 1233zd(E) with concentration of 1233xf and 1224 at or below 200 parts per million (ppm) and 3,3,3-trifluoropropyne impurities at or below 20 ppm. Formation of 1233xf impurity can be avoided if pure 1,1,1,3,3-pentachloropropane is used as a starting material. It was also found that formation of 1233xf is avoided if a liquid phase manufacturing process is used.
摘要翻译：本发明公开了高纯度E-1-氯-3,3,3-三氟丙烯（1233zd（E））及其制备方法。更具体地说，本发明公开了制备基本上不含有毒杂质的1233zd（E）的方法（例如2-氯-3,3,3-三氟丙烯（1233xf），氯四氟丙烯（1224）和3,3,3 三氟丙炔）。本发明还提供了制备浓度为1233xf和1224等于或低于200ppm（ppm）的高纯度1233zd（E）和等于或低于20ppm的3,3,3-三氟丙炔杂质的方法。如果使用纯1,1,1,3,3-五氯丙烷作为原料，则可以避免形成1233xf杂质。还发现如果使用液相制造方法，则避免形成1233xf。

9. 发明授权

US08766020B2 Process for producing 2,3,3,3-tetrafluoropropene 有权
标题翻译：制备2,3,3,3-四氟丙烯的方法
公开(公告)号：US08766020B2
公开(公告)日：2014-07-01
申请号：US12510740
申请日：2009-07-28
申请人： Haiyou Wang , Hsueh Sung Tung , Rajiv R. Singh , Ian Shankland
发明人： Haiyou Wang , Hsueh Sung Tung , Rajiv R. Singh , Ian Shankland
IPC分类号： C07C17/25 , C07C19/08 , C07C21/18 , C07C21/00 , C07C17/00
CPC分类号： C07C19/08 , C07C17/04 , C07C17/25 , C07C17/383 , C07C17/395 , C07C21/18 , C07C19/10
摘要： The present invention discloses a manufacturing process to produce high purity 1234yf from 245eb, which preferably includes the removal of impurities present in 245eb raw material, the dehydrofluorination of 245eb, and the removal of impurities present in final crude product. The disclosed manufacturing process allows the production of a 1234yf product with lower the levels of 1225ye and/or trifluoropropene, preferably in amounts of less than about 500, and 50 ppm, respectively.
摘要翻译：本发明公开了一种从245eb生产高纯度1234yf的制造方法，其优选包括去除245eb原料中存在的杂质，245eb的脱氟化氢和去除最终粗产物中存在的杂质。所公开的制造方法允许生产具有较低1225ye和/或三氟丙烯含量的1234yf产品，优选分别小于约500ppm和50ppm。

10. 发明授权

US08618040B2 Solvent compositions containing chlorofluoroolefins or fluoroolefins 有权
标题翻译：含有氯氟烯烃或氟烯烃的溶剂组合物
公开(公告)号：US08618040B2
公开(公告)日：2013-12-31
申请号：US13177848
申请日：2011-07-07
申请人： Robert C. Johnson , Hsueh Sung Tung , Rajiv Ratna Singh , Ian Shankland
发明人： Robert C. Johnson , Hsueh Sung Tung , Rajiv Ratna Singh , Ian Shankland
IPC分类号： C09K5/04
CPC分类号： C09K5/044 , A62D1/06 , B01F17/0035 , C08J9/144 , C09K3/00 , C09K5/045 , C09K21/08 , C09K2205/102 , C09K2205/104 , C09K2205/12 , C09K2205/122 , C09K2205/126 , C10M101/02 , C10M171/008 , C10M2203/003 , C10N2220/302 , C10N2240/30 , C11D3/43 , C11D7/30 , C11D7/5018 , C11D11/0047 , C23G5/02809 , C23G5/02825 , F25B1/00 , F25B31/002 , G03F7/426 , H05K3/26 , Y02C20/30
摘要： Compositions and methods based on the use of fluoroalkene containing from 3 to 4 carbon atoms and at least one carbon-carbon double bond, such as HFO-1214, HFO-HFO-1233, or HFO-1354, having properties highly beneficial in foaming and blowing agent applications, articles and methods.
摘要翻译：基于使用含有3至4个碳原子的氟代烯烃和至少一个碳 - 碳双键的组合物和方法，例如HFO-1214，HFO-HFO-1233或HFO-1354，具有在发泡和发泡剂应用，物品和方法。

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