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1. 发明申请

US20090286999A1 CATALYST SYSTEM FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES 审中-公开
标题翻译：用于制备羧酸和/或羧酸类的催化剂体系
公开(公告)号：US20090286999A1
公开(公告)日：2009-11-19
申请号：US12296885
申请日：2007-04-05
申请人： Hagen Wilmer , Cornelia Dobner , Frank Rosowski , Jürgen Zühlke , Sebastian Storck , Hans-Martin Allmann , Thomas Lautensack
发明人： Hagen Wilmer , Cornelia Dobner , Frank Rosowski , Jürgen Zühlke , Sebastian Storck , Hans-Martin Allmann , Thomas Lautensack
IPC分类号： C07D307/89 , B01J8/04 , C07C51/21
CPC分类号： B01J23/002 , B01J23/22 , B01J27/198 , B01J35/0006 , B01J35/1004 , B01J2523/00 , C07C51/265 , C07C51/313 , C07D307/89 , C07C63/16 , B01J2523/15 , B01J2523/47 , B01J2523/51 , B01J2523/55 , B01J2523/56 , B01J2523/53
摘要： The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides which has at least three catalyst layers arranged one on top of the other in the reaction tube, with the proviso that the most inactive catalyst layer is preceded in the upstream direction by a more active catalyst layer. The invention further relates to a process for gas phase oxidation in which a gaseous stream which comprises one hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers, the least active catalyst layer being upstream of a more active catalyst layer.
摘要翻译：本发明涉及一种用于制备羧酸和/或羧酸酐的催化剂体系，其具有在反应管中一个在另一个上排列的至少三个催化剂层，条件是最不活泼的催化剂层在上游方向通过更活泼的催化剂层。本发明还涉及一种用于气相氧化的方法，其中包含一种烃和分子氧的气流通过多个催化剂层，最少活性催化剂层位于较活泼的催化剂层的上游。

2. 发明授权

US08263789B2 Catalyst system and method for gas phase oxidation using an upstream layer 有权
标题翻译：使用上游层的催化剂体系和气相氧化方法
公开(公告)号：US08263789B2
公开(公告)日：2012-09-11
申请号：US12520648
申请日：2007-12-12
申请人： Hagen Wilmer , Jürgen Zühlke , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Dobner
发明人： Hagen Wilmer , Jürgen Zühlke , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Dobner
IPC分类号： C07D307/89
CPC分类号： B01J8/067 , B01J8/0496 , B01J23/002 , B01J35/0006 , B01J35/026 , B01J2208/024 , B01J2208/025 , C07C51/265 , C07C51/313 , C07C63/16
摘要： The present invention relates to a process for gas-phase oxidation, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed through two or more catalyst zones. Furthermore, the present invention relates to a catalyst system for gas-phase reaction using a preliminary zone.
摘要翻译：本发明涉及一种气相氧化方法，其中包含芳烃和分子氧的气流通过两个或多个催化剂区。此外，本发明涉及使用预备区域进行气相反应的催化剂体系。

3. 发明授权

US09067187B2 Catalyst system and method for gas phase oxidation using an upstream layer 有权
标题翻译：使用上游层的催化剂体系和气相氧化方法
公开(公告)号：US09067187B2
公开(公告)日：2015-06-30
申请号：US13586963
申请日：2012-08-16
申请人： Hagen Wilmer , Jürgen Zühlke , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Dobner
发明人： Hagen Wilmer , Jürgen Zühlke , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Dobner
IPC分类号： B01J8/06 , B01J8/04 , B01J23/00 , B01J35/00 , B01J35/02 , C07C51/265 , C07C51/31
CPC分类号： B01J8/067 , B01J8/0496 , B01J23/002 , B01J35/0006 , B01J35/026 , B01J2208/024 , B01J2208/025 , C07C51/265 , C07C51/313 , C07C63/16
摘要： The present invention relates to a process for gas-phase oxidation, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed through two or more catalyst zones. Furthermore, the present invention relates to a catalyst system for gas-phase reaction using a preliminary zone.
摘要翻译：本发明涉及一种气相氧化方法，其中包含芳烃和分子氧的气流通过两个或多个催化剂区。此外，本发明涉及使用预备区域进行气相反应的催化剂体系。

4. 发明申请

US20130039821A1 CATALYST SYSTEM AND METHOD FOR GAS PHASE OXIDATION USING AN UPSTREAM LAYER 审中-公开
标题翻译：催化剂系统和使用上层层气相氧化的方法
公开(公告)号：US20130039821A1
公开(公告)日：2013-02-14
申请号：US13586963
申请日：2012-08-16
申请人： Hagen Wilmer , Jürgen Zühlke , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Dobner
发明人： Hagen Wilmer , Jürgen Zühlke , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Dobner
IPC分类号： B01J8/04
CPC分类号： B01J8/067 , B01J8/0496 , B01J23/002 , B01J35/0006 , B01J35/026 , B01J2208/024 , B01J2208/025 , C07C51/265 , C07C51/313 , C07C63/16
摘要： The present invention relates to a process for gas-phase oxidation, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed through two or more catalyst zones. Furthermore, the present invention relates to a catalyst system for gas-phase reaction using a preliminary zone.
摘要翻译：本发明涉及一种气相氧化方法，其中包含芳烃和分子氧的气流通过两个或多个催化剂区。此外，本发明涉及使用预备区域进行气相反应的催化剂体系。

5. 发明申请

US20100029955A1 CATALYST SYSTEM AND METHOD FOR GAS PHASE OXIDATION USING AN UPSTREAM LAYER 有权
标题翻译：催化剂系统和使用上层层气相氧化的方法
公开(公告)号：US20100029955A1
公开(公告)日：2010-02-04
申请号：US12520648
申请日：2007-12-12
申请人： Hagen Wilmer , Jürgen Zühlke , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Dobner
发明人： Hagen Wilmer , Jürgen Zühlke , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Dobner
IPC分类号： C07D307/89 , C07C51/21 , C07D305/00 , B01J8/04
CPC分类号： B01J8/067 , B01J8/0496 , B01J23/002 , B01J35/0006 , B01J35/026 , B01J2208/024 , B01J2208/025 , C07C51/265 , C07C51/313 , C07C63/16
摘要： The present invention relates to a process for gas-phase oxidation, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed through two or more catalyst zones. Furthermore, the present invention relates to a catalyst system for gas-phase reaction using a preliminary zone.
摘要翻译：本发明涉及一种气相氧化方法，其中包含芳烃和分子氧的气流通过两个或多个催化剂区。此外，本发明涉及使用预备区域进行气相反应的催化剂体系。

6. 发明申请

US20090163726A1 CATALYST SYSTEM FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES 审中-公开
标题翻译：用于制备羧酸和/或羧酸类的催化剂体系
公开(公告)号：US20090163726A1
公开(公告)日：2009-06-25
申请号：US12301420
申请日：2007-05-14
申请人： Hagen Wilmer , Cornelia Dobner , Frank Rosowski , Sebastian Storck , Jürgen Zühlke
发明人： Hagen Wilmer , Cornelia Dobner , Frank Rosowski , Sebastian Storck , Jürgen Zühlke
IPC分类号： C07D307/77 , B01J23/04 , B01J27/198
CPC分类号： B01J23/002 , B01J23/22 , B01J27/198 , B01J35/0006 , B01J2523/00 , C07C51/265 , C07C63/16 , B01J2523/15 , B01J2523/47 , B01J2523/53 , B01J2523/55 , B01J2523/51
摘要： The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides which has at least four catalyst layers arranged one on top of another in the reaction tube, the ratio of the bed lengths of the more selective catalyst layers to the bed lengths of the more active catalyst layers being between 1.4 and 2. The present invention further relates to a process for gas phase oxidation in which a gaseous stream which comprises a hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers, the ratio of the bed lengths of the more selective catalyst layers to the bed lengths of the more active catalyst layers being between 1.4 and 2.
摘要翻译：本发明涉及一种用于制备羧酸和/或羧酸酐的催化剂体系，其具有在反应管中一个在另一个上排列的至少四个催化剂层，更多选择性催化剂层的床长与床的比例更活泼的催化剂层的长度在1.4和2之间。本发明还涉及一种用于气相氧化的方法，其中包含烃和分子氧的气流通过多个催化剂层，更多选择性催化剂层的床长比更活泼的催化剂层的床长在1.4和2之间。

7. 发明申请

US20090318712A1 CATALYST SYSTEM AND METHOD FOR PRODUCING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ACID ANHYDRIDES 审中-公开
标题翻译：用于生产羧酸和/或羧酸类抗坏血酸的催化剂体系和方法
公开(公告)号：US20090318712A1
公开(公告)日：2009-12-24
申请号：US12305698
申请日：2007-06-06
申请人： Hagen Wilmer , Cornelia Dobner , Tina Einfeld , Sebastian Storck , Jürgen Zühlke , Frank Rosowski
发明人： Hagen Wilmer , Cornelia Dobner , Tina Einfeld , Sebastian Storck , Jürgen Zühlke , Frank Rosowski
IPC分类号： C07D307/60 , B01J23/22 , B01J27/198 , B01J8/02 , C07C51/00
CPC分类号： B01J23/002 , B01J23/22 , B01J27/198 , B01J35/0006 , B01J2523/00 , C07C51/265 , C07C51/313 , C07D307/89 , C07C63/16 , B01J2523/15 , B01J2523/47 , B01J2523/53 , B01J2523/55 , B01J2523/51
摘要： Catalyst systems for preparing carboxylic acids and/or anhydrides, the catalyst system comprising a reaction zone and a layered catalyst, the reaction zone comprises a gas inlet region and a gas outlet region, the layered catalyst comprises an active composition and one or more middle layers, one or more first layers disposed on a side of the one or more middle layers toward the gas inlet region, and one or more second layers on a side of the one or more middle layers toward the gas outlet region, wherein the active composition content of one or more of the middle catalyst layers, based on total mass of the layered catalyst, is lower than the active composition content of the one or more first catalyst layers and is lower than one or more second catalyst layers; and processes for gas phase oxidation employing a layered catalyst of the present invention.
摘要翻译：用于制备羧酸和/或酸酐的催化剂体系，所述催化剂体系包含反应区和层状催化剂，所述反应区包括气体入口区和气体出口区，所述层状催化剂包含活性组合物和一个或多个中间层，一个或多个第一层，设置在所述一个或多个中间层的朝向所述气体入口区域的一侧上，以及一个或多个第二层，所述一个或多个中间层朝向所述气体出口区域的一个或多个第二层，其中所述活性组合物含量一个或多个中间催化剂层，基于层状催化剂的总质量低于一个或多个第一催化剂层的活性组合物含量，并且低于一个或多个第二催化剂层; 以及使用本发明的层状催化剂进行气相氧化的方法。

8. 发明申请

US20110028740A1 METHOD FOR STARTING A GAS PHASE OXIDATION REACTOR THAT CONTAINS A CATALYTICALLY ACTIVE SILVER-VANADIUM OXIDE BRONZE 审中-公开
标题翻译：启动含有催化活性银 - 氧化钒的气相氧化反应器的方法
公开(公告)号：US20110028740A1
公开(公告)日：2011-02-03
申请号：US12936648
申请日：2009-04-07
申请人： Cornelia Dobner , Ulf Dietrich , Thomas Mackewitz , Sebastian Storck , Hagen Wilmer , Frank Rosowski , Andreas Tenten
发明人： Cornelia Dobner , Ulf Dietrich , Thomas Mackewitz , Sebastian Storck , Hagen Wilmer , Frank Rosowski , Andreas Tenten
IPC分类号： C07D307/89 , C07D307/36 , C07C51/347 , C07C63/00 , C07C63/04
CPC分类号： C07C51/265 , C07C63/16
摘要： What is described is a method for starting a gas phase oxidation reactor that contains a bed of a first catalyst whose active material comprises a catalytically active silver-vanadium oxide bronze, and at least one bed of a second catalyst whose catalytically active material comprises vanadium pentoxide and titanium dioxide, and whose temperature is controllable by means of a heat transfer medium. In the operating state, a gas stream which comprises a loading cop of a hydrocarbon and molecular oxygen is passed through the reactor over the bed of the first and second catalyst at a temperature Top of the heat transfer medium. For the startup, a) a gas stream is passed through the reactor with a starting loading c0 which is less than cop, and at a starting temperature T0 of the heat transfer medium which is less than Top, and b) the temperature of the heat transfer medium is brought to Top and the loading of the gas stream to cop. The process combines a short startup time without exceedance of emissions or quality requirements, long catalyst lifetime, high yield and low formation of by-products.
摘要翻译：描述的是一种起始气相氧化反应器的方法，该反应器含有一种第一催化剂床，其活性物质包含催化活性的银 - 钒氧化物青铜，以及至少一个第二催化剂床，其催化活性物质包含五氧化二钒和二氧化钛，其温度可通过传热介质控制。在操作状态下，在传热介质的温度Top下，将包含烃和分子氧的负载管的气流在第一和第二催化剂的床上通过反应器。对于启动，a）气流通过反应器，起动负载c0小于保护时间，并且传热介质的起始温度T0小于Top，b）热量的温度转移介质被带到顶部并将气流装载到管路中。该过程结合了启动时间短，而不会超过排放或质量要求，长催化剂寿命，高产率和低副产物形成。

9. 发明申请

US20080227992A1 Catalyst and Methods for Producing Maleic Anhydride 审中-公开
标题翻译：用于生产马来酸酐的催化剂和方法
公开(公告)号：US20080227992A1
公开(公告)日：2008-09-18
申请号：US11997023
申请日：2006-07-21
申请人： Cornelia Dobner , Mark Duda , Andreas Raichle , Hagen Wilmer , Frank Rosowski , Markus Holzle
发明人： Cornelia Dobner , Mark Duda , Andreas Raichle , Hagen Wilmer , Frank Rosowski , Markus Holzle
IPC分类号： C07D307/60 , B01J27/198 , B01J27/16
CPC分类号： B01J37/0009 , B01J23/002 , B01J23/8472 , B01J27/198 , B01J35/002 , B01J37/031 , B01J37/04 , B01J37/16 , B01J2523/00 , C07C51/215 , C07C57/145 , B01J2523/51 , B01J2523/55 , B01J2523/842
摘要： Catalysts comprising a catalytically active composition, the catalytically active composition comprising vanadium, phosphorus, iron and oxygen, wherein the catalytically active composition has an iron:vanadium atomic ratio of 0.005 to
摘要翻译：包含催化活性组合物的催化剂，包含钒，磷，铁和氧的催化活性组合物，其中催化活性组合物的铁：钒原子比为0.005至0.05，并且其中催化活性组合物中的铁衍生自铁原料，包含磷酸铁（III）; 并描述了制备这种催化剂的方法及其用途来制备马来酸酐。

10. 发明申请

US20050222436A1 Catalyst-precursor for the production of maleic acid anhydride and method for the production thereof 有权
标题翻译：用于生产马来酸酐的催化剂前体及其制备方法
公开(公告)号：US20050222436A1
公开(公告)日：2005-10-06
申请号：US10507610
申请日：2003-03-12
申请人： Jens Weiguny , Sebastian Storck , Mark Duda , Cornelia Dobner
发明人： Jens Weiguny , Sebastian Storck , Mark Duda , Cornelia Dobner
IPC分类号： C07D307/60 , B01J27/198 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/03 , B01J37/08 , C07B61/00 , C07C51/215 , C07C51/25 , C07D307/34
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , B01J35/002 , B01J35/1014 , B01J37/0018 , B01J37/031 , B01J2523/00 , C07C51/215 , C07C57/145 , B01J2523/51 , B01J2523/55
摘要： A process for preparing a vanadium, phosphorus, and oxygen catalyst precursor for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of a hydrocarbon having at least four carbon atoms, which comprises (a) reacting vanadium pentoxide with from 102 to 110% strength phosphoric acid in the presence of a primary or secondary, noncyclic or cyclic, unbranched or branched, saturated alcohol having from 3 to 6 carbon atoms in a temperature range from 80 to 160° C.; (b) isolating the precipitate formed; (c) setting an organic carbon content of ≦1.1% by weight in the isolated precipitate by heat treatment in a temperature range from 250 to 350° C., the heat-treated product, following the addition of 3.0% by weight of graphite, giving a powder X-ray diffraction diagram which in the 2θ region features a ratio of the height of the peak of any pyrophosphate phase present at 28.5° to the height of the peak due to the graphite at 26.6° of ≦0.1; and (d) shaping the heat-treated product obtained from step (c) into particles having an averaged diameter of at least 2 mm; a catalyst precursor obtainable from this process; a process for preparing a catalyst from the catalyst precursor; a catalyst obtainable from that process; and also a process for preparing maleic anhydride over that catalyst.
摘要翻译：一种制备用于通过异构催化气相氧化具有至少四个碳原子的烃来制备马来酸酐的钒，磷和氧催化剂前体的方法，其包括（a）使五氧化二钒与102-110％强度的磷酸在80至160℃的温度范围内在具有3至6个碳原子的伯或仲，非环或环状，无支链或支链的饱和醇存在下进行酸反应。（b）分离形成的沉淀物; （c）通过在250-350℃的温度范围内通过热处理将分离的沉淀物中的有机碳含量<= 1.1重量％设定为热处理产物，添加3.0重量％的石墨，给出粉末X射线衍射图，其在2θ区域的特征是存在于28.5°的任何焦磷酸盐相的峰的高度与由于石灰在26.6°<= 0.1处的峰的高度之比; 和（d）将由步骤（c）获得的热处理产物成型为具有至少2mm的平均直径的颗粒; 从该方法获得的催化剂前体; 从催化剂前体制备催化剂的方法; 可从该方法获得的催化剂; 以及在该催化剂上制备马来酸酐的方法。

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