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    • 1. 发明授权
    • Photoelectrosynthetically active heterostructures
    • 光电合成活性异质结构
    • US09593053B1
    • 2017-03-14
    • US13676901
    • 2012-11-14
    • HYPERSOLAR, INC.
    • Eric McFarlandTim YoungNirala SinghSyed Mubeen Jawahar Hussaini
    • H01L31/18C07C1/04C25B1/00H01G9/20
    • H01L31/186C07C1/0495C23C14/24C23C14/5873C23C16/45525C25B1/003C25D7/126H01G9/20H01L31/0236H01L31/0336H01L31/108Y02P20/134
    • A two-step process, consisting of a photoelectrosynthetic process combined with a thermochemical process, is configured to produce a reduction product (e.g., methane gas, methanol, or carbon monoxide) from carbon dioxide and liquid waste streams. In a first step, photoelectrosynthetically active heterostructures (PAHs) and sunlight are used to drive oxidation/reduction reactions in which one primary product is hydrogen gas. In the second step, hydrogen generated in the first step is thermally catalytically reacted with carbon dioxide to form a reduction product from carbon dioxide (e.g., CO, formaldehyde, methane, or methanol). Synthesis gas (CO and H2) can be further reacted to form alkanes. The methods and systems may employ PAHs known in the art or improved PAHs having lower costs, improved stability, solar energy conversion efficiency, and/or other desired attributes as disclosed herein.
    • 由光电合成工艺与热化学工艺结合组成的两步​​法被配置为从二氧化碳和液体废物流中产生还原产物(例如,甲烷气,甲醇或一氧化碳)。 在第一步中,使用光电合成活性异质结构(PAH)和阳光来驱动其中一个初级产物是氢气的氧化/还原反应。 在第二步骤中,在第一步骤中产生的氢气与二氧化碳热催化反应以形成来自二氧化碳(例如CO,甲醛,甲烷或甲醇)的还原产物。 合成气(CO和H 2)可进一步反应形成烷烃。 方法和系统可以使用本领域已知的多环芳烃或具有较低成本,改进的稳定性,太阳能转化效率和/或如本文所公开的其它期望的属性的改进的PAH。