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1. 发明申请

WO2010046192A3 AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF 审中-公开
公开(公告)号：WO2010046192A3
公开(公告)日：2010-04-29
申请号：PCT/EP2009/062300
申请日：2009-09-23
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , PETERMANN, Ralf , SUPPIGER, Christian , LAUK, Urs
发明人： PETERMANN, Ralf , SUPPIGER, Christian , LAUK, Urs
IPC分类号： C09B29/00
摘要： The present invention relates to dyes of formula (I) wherein R 1 and R 2 are each independently of the other hydrogen, vinyl, allyl or C 1 -C 6 alkyl which is unsubstituted or substituted by cyano, carboxy, hydroxy, C 1 -C 6 alkoxy or C 6 -C 24 aryl, R 3 is hydrogen, C 1 -C 6 alkyl or C 6 -C 24 aryl, R 4 is hydrogen, C 1 -C 6 alkyl or C 6 -C 24 aryl, 2-Cyano-C 1 -C 6 alkyl, 2-Alkoxy-C 1 -C 6 alkyl, 2-Oxo-C 1 -C 6 alkyl, n is 0, 1 or 2, and D denotes a radical of formula (2), (3), (4), (5), (6) or (7) wherein R 5 is hydrogen, nitro, cyano or halogen, R 6 and R 7 are each independently of the other hydrogen, nitro, cyano or halogen, R 8 and R 9 are each independently of the other hydrogen, nitro, cyano or halogen, R 10 and R 11 are each independently of the other nitro, cyano, trifluoromethyl, carboxy, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 1 -C 6 acylamino or halogen, R 12 and R 13 are each independently of the other hydrogen, nitro, cyano, trifluoromethyl, carboxy, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 alkylsulfonylamino, C 1 -C 6 acylamino or halogen, R 14 represents nitro, cyano or halogen and R 15 is C 1 -C 6 alkyl, and R 16 is nitro, cyano, trifluoromethyl, carboxy, C 1 -C 6 alkylsulfonyl, C 1 -C 6 alkylsulfonylamino, C 1 -C 6 acylamino or halogen, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fibre materials, more especially textile materials.

2. 发明申请

WO2011072966A1 DISPERSE AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF 审中-公开
标题翻译：分散AZO染色剂，其制备方法及其用途
公开(公告)号：WO2011072966A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/067436
申请日：2010-11-15
申请人： HUNSTSMAN ADVANCED MATERIALS (SWITZERLAND) GmbH , PETERMANN, Ralf , LAUK, Urs , MURER, Kevin , SUPPIGER, Christian
发明人： PETERMANN, Ralf , LAUK, Urs , MURER, Kevin , SUPPIGER, Christian
IPC分类号： C09B29/00 , C09B29/08 , C09B29/36 , D06P1/16
CPC分类号： C09B29/081 , C09B29/0081 , C09B29/0813 , C09B29/0815 , C09B29/0817 , C09B29/0826 , C09B29/0844 , C09B29/3634 , C09B29/3639 , C09B29/3691
摘要： The present invention relates to dyes of formula (1), wherein either A is -CO- and Q is -SO 2 - or A is -SO 2 - and Q is -CO-, R 1 denotes C 1 -C 6 alkyl, benzyl, allyl, -C n H 2n -COOR Or -C n H 2n -CN, wherein n is a number from 1 to 3 and R represents hydrogen or C 1 -C 6 alkyl; X is nitro, cyano or halogen; Y is hydrogen, nitro, cyano or halogen, and K is the radical of a coupling component of the benzene, naphthalene, pyrazolone; 6-hydroxypyridone-(2) or acetoacetic acid arylamide series, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fibre materials, more especially textile materials.
摘要翻译：本发明涉及式（1）的染料，其中A是-CO-，Q是-SO 2 - 或A是-SO 2 - ，Q是-CO-，R 1表示C 1 -C 6烷基，苄基，烯丙基，-C n H 2n -COOR或-C n H 2n-CN，其中n为1至3的数，R为氢或C 1 -C 6烷基; X为硝基，氰基或卤素; Y是氢，硝基，氰基或卤素，K是苯，萘，吡唑啉酮的偶联组分; 6-羟基吡啶酮 - （2）或乙酰乙酸芳酰胺系列，以及其制备方法及其在半合成和特别合成的疏水性纤维材料，特别是纺织材料的染色或印花中的应用。

3. 发明申请

WO2012084417A1 DISPERSE AZO DYES 审中-公开
标题翻译：分歧AZO DYES
公开(公告)号：WO2012084417A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/071170
申请日：2011-11-28
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , NOWACK, Patric , LAUK, Urs , TZIKAS, Athanassios
发明人： NOWACK, Patric , LAUK, Urs , TZIKAS, Athanassios
IPC分类号： C09B29/01 , C09B29/42 , D06P3/54
CPC分类号： C09B29/3639 , D06P1/18 , D06P3/54
摘要： The present invention relates to disperse azo dyes based on diazo components having at least one fluorine-containing substituent and an 2,6-diaminosubstituted pyridine coupling component, to a process for the preparation of such dyes and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.
摘要翻译：本发明涉及将基于具有至少一个含氟取代基和2,6-二氨基取代的吡啶偶联组分的重氮组分分散在偶氮染料的制备方法中，并将其用于染色或印刷特别是合成疏水纤维材料，尤其是纺织材料。

4. 发明申请

WO2009013122A2 AZO DYES 审中-公开
标题翻译： AZO染料
公开(公告)号：WO2009013122A2
公开(公告)日：2009-01-29
申请号：PCT/EP2008/058828
申请日：2008-07-08
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GmbH , DREIER, Romeo , ARQUINT, Alfons , LAUK, Urs , NOWACK, Patric
发明人： DREIER, Romeo , ARQUINT, Alfons , LAUK, Urs , NOWACK, Patric
IPC分类号： C09B29/085 , C09B67/22 , D06P1/18 , D06P3/54 , C07D209/48 , C07D275/06
CPC分类号： C09B29/083 , C07D409/12 , C07D417/12 , C09B29/0811 , C09B29/0813 , C09B29/0821 , C09B67/0041 , C09B67/0046 , C09B67/0051 , D06P1/18 , D06P3/26 , D06P3/54 , D06P3/8204 , Y10S8/92 , Y10T428/24802
摘要： The present invention relates to disperse azo dyes based on a phthalimido-substituted aniline coupling component and an aromatic-carbocyclic or an aromatic-heterocyclic diazo component, to a process for the preparation of such dyes and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.
摘要翻译：本发明涉及基于邻苯二甲酰亚胺基取代的苯胺偶联组分和芳族碳环或芳族杂环重氮组分的分散偶氮染料，涉及制备这样的染料及其用于染色或印刷半合成纤维，尤其是合成疏水纤维材料，更特别是纺织材料。

5. 发明申请

WO2006120148A3 DYE MIXTURES 审中-公开
公开(公告)号：WO2006120148A3
公开(公告)日：2006-11-16
申请号：PCT/EP2006/062018
申请日：2006-05-03
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , CLÉMENT, Antoine , ARQUINT, Alfons , LAUK, Urs
发明人： CLÉMENT, Antoine , ARQUINT, Alfons , LAUK, Urs
IPC分类号： C09B67/22 , D06P3/54
摘要： The present invention relates to dye mixtures comprising (A) from 20 to 80% by weight of one or more compounds of formula (1) wherein R 1 is C 1 -C 12 alkyl, or C 1 -C 12 alkyl interrupted by one or more oxygen atoms or -COO-groups and R 2 , R 3 , R 4 and R 5 , each independently of the others, is hydrogen, C 1 -C 12 alkyl, chlorine, bromine, hydroxy or amino and (B) from 20 to 80% by weight of at least one further yellow disperse dye the sum of components (A) + (B) being 100% by weight, and to the use of those dye mixtures in the dyeing or printing of semi-synthetic or synthetic hydrophobic fibre materials.

6. 发明申请

WO2021144304A1 DISPERSE AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF 审中-公开
公开(公告)号：WO2021144304A1
公开(公告)日：2021-07-22
申请号：PCT/EP2021/050578
申请日：2021-01-13
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： PETERMANN, Ralf , LAUK, Urs , MURER, Kevin , PFISTER, Simon , PESEK, Yvonne
IPC分类号： C09B56/12 , C09B29/01 , C09B29/52 , C09B67/38 , D06P1/18 , D06P1/20 , D06P3/54 , C09B29/0003 , C09B29/0022 , C09B29/3665 , C09B67/008 , D06P5/30
摘要： The present invention relates to azo dyes of formula (1), wherein D is a radical of formula (2) or (3), R1 and R2 independently denote hydrogen; C6–C10aryl which is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C1–C6alkyl, or C1–C6alkoxy; C1–C12alkyl which may be interrupted one or more times by -O-, -S-, -NR4-, -CO-, -COO- or –OOC-, and is unsubstituted or substituted by cyano, carboxy, hydroxy, C6–C10aryl, or C6–C10aryloxy, which C6–C10aryl or C6–C10aryloxy is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C1–C6alkyl, or C1–C6alkoxy; R3 and R4 are each independently of the other hydrogen, halogen, nitro, cyano, trifluoromethyl, carboxy, C1-C6alkyl, C1-C6alkoxy, C1-C6alkylcarbonyl, C6–C10arylcarbonyl, C1-C6alkoxycarbonyl, C1-C6alkylsulfonyl, C1-C6alkylsulfonylamino or C1-C4alkanoylamino; and R5 is halogen, nitro, cyano, trifluoromethyl, carboxy, C1-C6alkyl, C1-C6alkoxy, C1- C6alkylcarbonyl, C6–C10arylcarbonyl, C1-C6alkoxycarbonyl, C1-C6alkylsulfonyl, C1-C6alkylsulfonylamino or C1-C4alkanoylamino; and R6, R7, R8 and R9 independently of each other are hydrogen, hydroxy, halogen, cyano, nitro or C1-C4alkanoylamino, and the radicals X independently denote N or C-H, with the proviso that at least one radical X denotes C-H, which are distinguished by their good lightfastness properties.

7. 发明申请

WO2019001832A1 DISPERSE AZO DYES 审中-公开
公开(公告)号：WO2019001832A1
公开(公告)日：2019-01-03
申请号：PCT/EP2018/062523
申请日：2018-05-15
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： LAUK, Urs , NOWACK, Patric , DREIER, Romeo
IPC分类号： C09B29/01 , C09B29/08 , C09B67/22 , D06P3/48 , D06P3/52 , D06P1/18
摘要： The present invention relates to disperse azo dyes of formula (1), wherein R 1 is bromo, nitro, cyano, methyl, methoxy or trifluoromethyl; R 2 is hydrogen, chloro, bromo or trifluoromethyl; R 3 is hydrogen, chloro, bromo, methoxy,trifluoromethyl,nitro or cyano; and R 4 is methyl, ethyl, n-propyl, 2-methoxyethyl, methoxycarbonylmethyl or 2-methoxycarbonylethyl; with the proviso that R 1 is cyano in case R 2 denotes chloro or bromo, to a process for the preparation of such dyes and to their use in the dyeing or printing of semi-synthetic and,especially, synthetic hydrophobic fibre materials, more especially textile materials.

8. 发明申请

WO2013182391A1 ANTHRAQUINONE AZO DYES 审中-公开
公开(公告)号：WO2013182391A1
公开(公告)日：2013-12-12
申请号：PCT/EP2013/059990
申请日：2013-05-15
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： PETERMANN, Ralf , LAUK, Urs , MURER, Kevin , PESEK, Yvonne
IPC分类号： C09B29/00 , C09B29/36 , C09B67/22 , C09B67/00 , D06P1/18 , D06P1/20 , C09B56/12 , C09B29/01
CPC分类号： C09B56/12 , C09B29/0022 , C09B67/0046
摘要： The present invention relates to azo dyes of the formula (1), wherein R 1 is hydrogen or hydroxy, R 2 is hydrogen or hydroxy, at least one of the radicals R 1 and R 2 being hydroxy, R 3 is hydrogen, cyano, nitro or halogen, R 4 is hydrogen, cyano, nitro or halogen, D represents a radical of the formula (2) or (3), wherein R 5 denotes C 1 -C 12 alkyl, C 1 -C 12 hydroxyalkyl, C 1 -C 12 alkoxyalkyl, C 2 -C 12 alkenyl, C 6 -C 30 aryl or C 7 -C 36 aralkyl and R 6 and R 7 , each independently of the other, is hydrogen, C 1 -C 12 alkyl, C 1 -C 12 hydroxyalkyl, C 1 C 12 alkoxyalkyl, C 6 -C 30 aryl or C 7 -C 36 aralkyl, with the proviso that the compound of formula (1) is excluded, wherein R 1 is hydrogen, R 2 is hydroxy, R 3 and R 4 is hydrogen and D is the radical of formula (2) wherein R 5 is ethyl, and to the use of those dye mixtures in the dyeing or printing of semi-synthetic or synthetic hydrophobic fibre materials.
摘要翻译：本发明涉及式（1）的偶氮染料，其中R 1是氢或羟基，R 2是氢或羟基，R 1和R 2中的至少一个是羟基，R 3是氢，氰基，硝基或卤素，R 4 D表示式（2）或（3）的基团，其中R 5表示C 1 -C 12烷基，C 1 -C 12羟烷基，C 1 -C 12烷氧基烷基，C 2 -C 12烯基，C 6 -C 30芳基或C 7 -C 36芳烷基和R 6和R 7各自独立地是氢，C 1 -C 12烷基，C 1 -C 12羟烷基，C 1 -C 12烷氧基烷基，C 6 -C 30芳基或C 7 -C 36芳烷基，条件是排除式（1）的化合物，其中R 1是氢，R2是羟基，R3和R4是氢，D是式（2）的基团，其中R5是乙基，以及在半合成或合成疏水纤维材料的染色或印刷中使用这些染料混合物。

9. 发明申请

WO2014016072A1 DISPERSE AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF 审中-公开
标题翻译：分散AZO染色剂，其制备方法及其用途
公开(公告)号：WO2014016072A1
公开(公告)日：2014-01-30
申请号：PCT/EP2013/063346
申请日：2013-06-26
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： LAUK, Urs , NOWACK, Patric , PETERMANN, Ralf , DREIER, Romeo
IPC分类号： D06P1/18 , D06P3/54 , C09B29/00 , C09B29/08 , C09B43/42 , C09B67/00 , C09B29/01 , C09B29/036 , C09B29/033
CPC分类号： C09B29/0033 , C09B29/0003 , C09B29/0007 , C09B29/0048 , C09B29/0085 , C09B29/0805 , C09B29/0809 , C09B29/095 , C09B29/3639 , C09B29/3691 , C09B43/42 , C09B67/0046 , C09B67/0051 , D06P3/52 , D10B2331/04
摘要： The present invention relates to azo dyes of formula (1), wherein R 1 denotes C 1 -C 12 alkyl which is unsubstituted or substituted by one or more C 1 -C 12 alkoxy groups, hydroxyl groups, amino groups, cyano groups or halogen atoms and which may be interrupted one or more times by the radical -O-, -S-, -NR 4 -, -COO- or –OOC-; R 4 is hydrogen or C 1 -C 12 alkyl; either R 2 is cyano and R 3 is halogen or R 2 is halogen and R 3 is cyano; and Ar represents a carbocyclic or heterocyclic aromatic radical, to the process for the preparation thereof, to mixtures containing said dyes and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fibre materials, more especially textile materials.
摘要翻译：本发明涉及式（1）的偶氮染料，其中R1表示未被取代或被一个或多个C 1 -C 12烷氧基，羟基，氨基，氰基或卤素原子取代的C1-C12烷基，并且可以被一个或更多次的基团-O - ， - S - ， - NR 4 - ， - COO-或-OOC-; R4是氢或C1-C12烷基; R2是氰基，R3是卤素或R2是卤素，R3是氰基; 并且Ar表示碳环或杂环芳族基团，其制备方法，含有所述染料的混合物及其在染色或印刷半合成和特别合成的疏水纤维材料，尤其是纺织材料中的用途。

10. 发明公开

EP2337820A2 AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF 有权
标题翻译：偶氮染料，其生产和使用
公开(公告)号：EP2337820A2
公开(公告)日：2011-06-29
申请号：EP09783311.5
申请日：2009-09-23
申请人： Huntsman Advanced Materials (Switzerland) GmbH
发明人： PETERMANN, Ralf , SUPPIGER, Christian , LAUK, Urs
IPC分类号： C09B29/00
CPC分类号： C09B29/0003 , C09B29/0033 , C09B29/0059 , C09B29/0081 , C09B29/0085 , C09B29/081 , C09B29/0811 , C09B29/0833 , C09B29/24 , C09B29/26 , Y10S8/92
摘要： The present invention relates to dyes of formula (I) wherein R
1 and R
2 are each independently of the other hydrogen, vinyl, allyl or C
1 -C
6 alkyl which is unsubstituted or substituted by cyano, carboxy, hydroxy, C
1 -C
6 alkoxy or C
6 -C
24 aryl, R
3 is hydrogen, C
1 -C
6 alkyl or C
6 -C
24 aryl, R
4 is hydrogen, C
1 -C
6 alkyl or C
6 -C
24 aryl, 2-Cyano-C
1 -C
6 alkyl, 2-Alkoxy-C
1 -C
6 alkyl, 2-Oxo-C
1 -C
6 alkyl, n is 0, 1 or 2, and D denotes a radical of formula (2), (3), (4), (5), (6) or (7) wherein R
5 is hydrogen, nitro, cyano or halogen, R
6 and R
7 are each independently of the other hydrogen, nitro, cyano or halogen, R
8 and R
9 are each independently of the other hydrogen, nitro, cyano or halogen, R
10 and R
11 are each independently of the other nitro, cyano, trifluoromethyl, carboxy, C
1 -C
6 alkyl, C
1 -C
6 alkoxy, C
1 -C
6 acylamino or halogen, R
12 and R
13 are each independently of the other hydrogen, nitro, cyano, trifluoromethyl, carboxy, C
1 -C
6 alkoxycarbonyl, C
1 -C
6 alkylsulfonyl, C
1 -C
6 alkylsulfonylamino, C
1 -C
6 acylamino or halogen, R
14 represents nitro, cyano or halogen and R
15 is C
1 -C
6 alkyl, and R
16 is nitro, cyano, trifluoromethyl, carboxy, C
1 -C
6 alkylsulfonyl, C
1 -C
6 alkylsulfonylamino, C
1 -C
6 acylamino or halogen, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fibre materials, more especially textile materials.

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