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1. 发明申请

WO2010084044A1 REACTIVE DYES, THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：反应性染料及其制备及其使用
公开(公告)号：WO2010084044A1
公开(公告)日：2010-07-29
申请号：PCT/EP2010/050221
申请日：2010-01-11
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH , HILDEBRAND, Rainer , MUELLER, Alexander , PLATTNER, Kurt , DI CESARE, Sandra , SCHOEHN, Damien
发明人： HILDEBRAND, Rainer , MUELLER, Alexander , PLATTNER, Kurt , DI CESARE, Sandra , SCHOEHN, Damien
IPC分类号： C09B62/44 , C09D11/00
CPC分类号： C09B45/16 , C09B62/4416 , C09D11/328
摘要： Reactive dyes of formula (1), wherein R 1 is hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, (R 2 ) s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C 1 -C 4 alkyl, C 2 -C 4 alkanoylamino, C 1 -C 4 alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, Me is chromium, cobalt or iron, E is a bivalent radical of formulae (1a), (1b) or (1c), wherein X denotes chlorine or fluorine, T is a fibre-reactive radical of formula (2a): -NH-(CH 2 ) 2-3 -SO 2 -Z, formula (2b): -NH-(CH 2 ) 2-3 -O-(CH 2 ) 2-3 -SO 2 -Z, formulae (2c), (2d), (2e) or (2f), (R 3 ) 0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy and sulfo, Z is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(HaI)-CH 2 -HaI or -C(HaI)=CH 2 group, s is the number 0, 1, 2 or 3, q is the number 0 or 1, A denotes a bivalent radical of formulae (3a), (3b), (3c) or (3d), wherein R 1 , R 2 , X, T, m, n, q and s are as defined above, R 4 and R 7 denote hydrogen or C 1 -C 4 alkyl, R 5 and R 6 represent, each independently of the other, identical or different substituents from the group hydroxyl, halogen, nitro, unsubstituted or halo-substituted C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, C 1 -C 4 alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, and t and u are each independently of the other the number 0, 1, 2 or 3, are especially suitable for dyeing synthetic polyamide fibre materials and yield dyeings or prints having good wet-fastness properties.
摘要翻译：式（1）的反应性染料，其中R 1是氢或未取代的或取代的C 1 -C 4烷基，（R 2）表示与卤素，硝基，未取代或卤素取代的C 1 -C 4烷基，C 2 -C 4烷酰基氨基， C 1 -C 4烷基磺酰基，氨基甲酰基，氨磺酰基和磺基，Me是铬，钴或铁，E是式（1a），（1b）或（1c）的二价基团，其中X表示氯或氟，T是纤维反应性式（2a）的基团：-NH-（CH2）2-3-SO2-Z，式（2b）：-NH-（CH2）2-3-O-（CH2）2-3-SO2-Z，式（2c），（2d），（2e）或（2f）中，（R3）0-2表示0至2个与卤素，C1-C4烷基，C1-C4烷氧基和磺基相同或不同的取代基，Z是乙烯基或 -CH 2 -CH 2 -U基团，U是在碱性条件下可除去的基团，Q是-CH（H 1）-CH 2 -H a或-C（H 1）= CH 2基团，s是数字0,1,2， 2或3，q是数字0或1，A表示式（3a），（3b），（3c）或（3d）的二价基团，其中R1，R2，X，T，m，n，q和是的如上定义，R 4和R 7表示氢或C 1 -C 4烷基，R 5和R 6各自独立地表示与羟基，卤素，硝基，未取代或卤素取代的C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，C 1 -C 4烷基磺酰基，氨基甲酰基，氨磺酰基和磺基，t和u各自独立地为数字0,1,2或3，特别适用于染色合成聚酰胺纤维材料并产生具有良好的耐湿性能。

2. 发明申请

WO2015193104A1 MIXTURES OF REACTIVE DYES 审中-公开
标题翻译：反应性染料的混合物
公开(公告)号：WO2015193104A1
公开(公告)日：2015-12-23
申请号：PCT/EP2015/062253
申请日：2015-06-02
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： MUELLER, Alexander , MUNDLE, Wolfgang , CORTESE, Bruno , DA SILVA SARAIVA, Sandra , PLATTNER, Kurt , ROENTGEN, Georg
IPC分类号： C09B67/22 , C09D11/328 , C09B62/44 , C09B62/513
CPC分类号： C09B67/0059 , C09B62/4415 , C09B62/513 , C09B67/0057 , C09D11/328
摘要： A dye mixture, comprising (A) a dye of the formula (1) wherein D is the radical of a carbocyclic or heterocyclic aromatic diazo component, R 1 and R 2 are each independently of the other hydrogen, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, hydroxy-C 2 -C 6 alkoxy, C 2 -C 6 alkanoylamino, C 1 -C 6 alkylsulfonyl, carbamoyl, sulfamoyl, -SO 3 M or a fibre-reactive group, R 3 and R 4 are each independently of the otherhydrogen, C 1 -C 6 alkyl that is unsubstituted or substituted by hydroxy, sulfo, sulfato, cyano, carboxy, C 1 -C 6 alkoxy or phenyl, C 2 -C 6 alkanoyl, phenyl, sulfomethyl or a group of the formula (3d), Y is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, p is the number 2, 3 or 4, M is hydrogen, Li, Na, K, Mg, Ca or ammonium that is unsubstituted or mono-, di-, tri- or tetra substituted by C 1 -C 6 alkyl, C 2 -C 6 -hydroxyalkyl or mixtures thereof; and (B) at least one navy-blue dyeing dye, provides dyeings on wool with good allround properties and does not require alkaline after-treatment to remove non-fixed dye.
摘要翻译：一种染料混合物，其包含（A）式（1）的染料，其中D是碳环或杂环芳族重氮组分的基团，R 1和R 2各自独立地为另一个氢，C 1 -C 6烷基，C 1 -C 6烷氧基，羟基 C 2 -C 6烷氧基，C 2 -C 6烷酰基氨基，C 1 -C 6烷基磺酰基，氨基甲酰基，氨磺酰基，-SO 3 M或纤维反应性基团，R 3和R 4各自独立地为未被取代或被羟基，磺基，，氰基，羧基，C 1 -C 6烷氧基或苯基，C 2 -C 6烷酰基，苯基，磺基甲基或式（3d）的基团，Y是乙烯基或-CH 2 -CH 2 -U基团，U是在碱性下可除去的基团条件是p是数字2,3或4，M是未被取代的或被C1-C6烷基取代的单，二，三或四取代的氢，Li，Na，K， - 羟烷基或其混合物; 和（B）至少一种海蓝染色剂，在羊毛上提供良好的全面性能的染色，并且不需要碱性后处理以除去非固定染料。

3. 发明申请

WO2014127994A1 MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD OF DI- OR TRICHROMATIC DYEING OR PRINTING 审中-公开
标题翻译：反应性染料的混合物及其在二色或三色染色或印刷方法中的用途
公开(公告)号：WO2014127994A1
公开(公告)日：2014-08-28
申请号：PCT/EP2014/052196
申请日：2014-02-05
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： MUELLER, Alexander , HILDEBRAND, Rainer , DA SILVA SARAIVA, Sandra , MUNDLE, Wolfgang , KNEUBUEHLER, Markus
IPC分类号： C09B67/22
CPC分类号： D06P1/0096 , C09B29/3604 , C09B45/485 , C09B67/0042 , C09B67/0047 , C09B67/0052
摘要： A dye mixture, comprising at least one blue dyeing dye of the formula (1), wherein Q 1 represents a bivalent radical of formula (4a), (4b) or (4c), wherein X 1 denotes chlorine or fluorine, R 1 is hydrogen or C 1 -C 8 alkyl, R 2 is hydrogen, C 1 -C 8 alkyl, C 1 -C 4 alkoxy or sulfo, Y 1 is vinyl or a radical -CH 2 -CH 2 -U and U is a leaving group removable under alkaline conditions, R 3 is hydrogen or C 1 -C 8 alkyl that is unsubstituted or substituted by hydroxy, sulfo, sulfato, cyano, carboxy, C 1 -C 4 alkoxy or phenyl, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 and at least one yellow or red dyeing reactive dye is suitable especially for the dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
摘要翻译：一种染料混合物，其包含至少一种式（1）的蓝染色剂，其中Q1表示式（4a），（4b）或（4c）的二价基团，其中X1表示氯或氟，R1表示氢或C1 -C 8烷基，R 2是氢，C 1 -C 8烷基，C 1 -C 4烷氧基或磺基，Y 1是乙烯基或基团-CH 2 -CH 2 -U，U是在碱性条件下可除去的离去基团，R 3是氢或C 1 -C 8烷基，未取代或被羟基，磺基，硫酸根，氰基，羧基，C 1 -C 4烷氧基或苯基取代的，r和s各自独立地为数字0或1，t是数字0,1或2， r，s和t为2或3，并且至少一种黄色或红色染色活性染料特别适用于天然或合成聚酰胺纤维材料的二色或三色染色或印刷，并且具有良好重现性和良好全面性的产量染色或印花坚牢性。

4. 发明申请

WO2013182349A1 REACTIVE DYES, THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：反应性染料及其制备及其使用
公开(公告)号：WO2013182349A1
公开(公告)日：2013-12-12
申请号：PCT/EP2013/058565
申请日：2013-04-25
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： MUELLER, Alexander , PLATTNER, Kurt , SCHOEHN, Damien , HILDEBRAND, Rainer
IPC分类号： C09B62/44 , D06P1/38 , D06P3/24
CPC分类号： C09B62/095 , C07F11/005 , C09B62/4416 , D06P1/38 , D06P1/384 , D06P3/248 , D06P3/66 , D06P5/30
摘要： Reactive dyes of formula (1), wherein Me is chromium, cobalt or iron, R 1 is hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, E is a bivalent radical of formula (1a), (1b) or (1c) wherein X denotes chlorine or fluorine, T es a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e), or (2f), (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy and sulfo, Z is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(Hal)-CH 2 -Hal or -C(Hal)=CH 2 group, q is the number 0 or 1, G is a bivalent radical of formula (1d) or (1e) wherein (R 2 )s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C 1 -C 4 alkyl, C 2 -C 4 alkanoylamino, C 1 -C 4 alkylsulfonyl, carbamoyl, sulfamoyl, sulfo and -E-T, wherein E and T are as defined above, s is the number 0, 1, 2 or 3, A denotes a bivalent radical of formula (3a), (3b) or (3c), wherein R 1 , R 2 , X, T, q and s are as defined above, R 4 and R 7 denote hydrogen, C 1 -C 4 alkyl, -COOH or -COO- C 1 -C 4 alkyl, R 5 and R 6 represent, each independently of the other, identical or different substituents from the group hydroxyl, halogen, nitro, unsubstituted or halo-substituted C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, C 1 -C 4 alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, and t and u are each independently of the other the number 0, 1, 2 or 3, are especially suitable for dyeing synthetic polyamide fibre materials and yield dyeings or prints having good wet-fastness properties.
摘要翻译：式（1）的活性染料其中Me为铬，钴或铁，R1为氢或未取代或取代的C1-C4烷基，E为式（1a），（1b）或（1c）的二价基团，其中X表示氯（2a），（2b），（2c），（2d），（2e）或（2f）所示的纤维反应性基团，（R3）0-2表示0至2个相同或不同的取代基为卤素，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z为乙烯基或-CH 2 -CH 2 -U基，U为在碱性条件下可除去的基团，Q为-CH（Hal） - CH 2 Hal或-C（Hal）= CH 2基，q是数字0或1，G是式（1d）或（1e）的二价基团，其中（R2）s表示与基团卤素相同或不同的取代基，硝基，未取代或卤素取代的C 1 -C 4烷基，C 2 -C 4烷酰基氨基，C 1 -C 4烷基磺酰基，氨基甲酰基，氨磺酰基，磺基和-ET，其中E和T如上所定义，s为数0,1,2或3， A表示式（3a），（3b）或（3c）的二价基团，其中R1，R2， X，T，q和s如上所定义，R 4和R 7表示氢，C 1 -C 4烷基，-COOH或-COO-C 1 -C 4烷基，R 5和R 6各自独立地表示与基团相同或不同的取代基羟基，卤素，硝基，未取代或卤素取代的C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，C 1 -C 4烷基磺酰基，氨基甲酰基，氨磺酰基和磺基，t和u各自独立地为数个0,1,2 或3，特别适用于染色合成聚酰胺纤维材料，并产生具有良好耐湿性能的染色或印花。

5. 发明申请

WO2013087400A3 AZO DYES 审中-公开
公开(公告)号：WO2013087400A3
公开(公告)日：2013-06-20
申请号：PCT/EP2012/073572
申请日：2012-11-26
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： MUELLER, Alexander , HILDEBRAND, Rainer , DALLE-NOGARE, Siro
IPC分类号： C09B33/06 , C09B67/00 , D06P1/06 , D06P3/06 , D06P3/24 , D06P3/32
摘要： The present invention relates to dyes of formula (1), wherein each of the residues D 1 and D 2 represents a radical of formula (2), wherein Ar 1 represents the tetravalent radical of a carbocylic or heterocyclic aromatic compound, R 1 , R 2 and R 3 are each independently of the other hydrogen, C 1 -C 12 alkyl, C 1 -C 12 alkoxy, halogen, -OH, -CN, -NO 2 , -CF 3 , -SO 3 H, -NHCOR 4 , -COOR 5 , −CONR 6 R 7 , -SO 2 NR 8 R 9 , -NR 10 SO 2 R 11 , -SO 2 R 13 - or −ZCH 2 CH 2 Q, wherein Z is -O-, -SO 2 -, -NR 12 -, -CONH- or -NHCO-, Q represents −OH, C 1 -C 12 alkyl, -SO 2 R 13 -, -NHR 14 -, −OCH 2 CH 2 OH, −SO 2 CH 2 CH 2 OH or -NHCH 2 CH 2 OH, R 4 is C 1 -C 12 alkyl, R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 12 , R 13 and R 14 are each independently of the others hydrogen or C 1 -C 12 alkyl, and R 11 is C 1 -C 12 2alkyl, with the proviso that at least one of the residues D 1 and D 2 is a radical of formula (2) wherein R 3 is -COOR 5 , -SO 2 NR 8 R 9 , -SO 2 R 13 - or −ZCH 2 CH 2 Q, dichromatic and trichromatic mixtures containing these dyes and the use of these dyes for dyeing or printing hydroxyl group-containing or nitrogen-containing fibre materials.

6. 发明授权

EP2855597B1 REACTIVE DYES, THEIR PREPARATION AND THEIR USE 有权转让
标题翻译：活性染料，它们的制备和它们的用途
公开(公告)号：EP2855597B1
公开(公告)日：2017-06-07
申请号：EP13723425.8
申请日：2013-04-25
申请人： Huntsman Advanced Materials (Switzerland) GmbH
发明人： MUELLER, Alexander , PLATTNER, Kurt , SCHOEHN, Damien , HILDEBRAND, Rainer
IPC分类号： C09B62/44 , D06P1/38 , D06P3/24
CPC分类号： C09B62/095 , C07F11/005 , C09B62/4416 , D06P1/38 , D06P1/384 , D06P3/248 , D06P3/66 , D06P5/30

7. 发明授权

EP2958962B1 MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD OF DI- OR TRICHROMATIC DYEING OR PRINTING 有权转让
标题翻译：活性染料混合物及其在染色或印染方法中的应用
公开(公告)号：EP2958962B1
公开(公告)日：2018-01-10
申请号：EP14702847.6
申请日：2014-02-05
申请人： Huntsman Advanced Materials (Switzerland) GmbH
发明人： MUELLER, Alexander , HILDEBRAND, Rainer , DA SILVA SARAIVA, Sandra , MUNDLE, Wolfgang , KNEUBUEHLER, Markus
IPC分类号： C09B67/22
CPC分类号： D06P1/0096 , C09B29/3604 , C09B45/485 , C09B67/0042 , C09B67/0047 , C09B67/0052
摘要： A dye mixture, comprising at least one blue dyeing dye of the formula (1), wherein Q1 represents a bivalent radical of formula (4a), (4b) or (4c), wherein X1 denotes chlorine or fluorine, R1 is hydrogen or C1-C8 alkyl, R2 is hydrogen, C1-C8alkyl, C1-C4alkoxy or sulfo, Y1 is vinyl or a radical —CH2—CH2—U and U is a leaving group removable under alkaline conditions, R3 is hydrogen or C1-C8alkyl that is unsubstituted or substituted by hydroxy, sulfo, sulfato, cyano, carboxy, C1-C4alkoxy or phenyl, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 and at least one yellow or red dyeing reactive dye is suitable especially for the dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.

8. 发明公开

EP2855597A1 REACTIVE DYES, THEIR PREPARATION AND THEIR USE 有权转让
标题翻译：风靡一时的FARBSTOFFE SOWIE IHRE HERSTELLUNG UND VERWENDUNG
公开(公告)号：EP2855597A1
公开(公告)日：2015-04-08
申请号：EP13723425.8
申请日：2013-04-25
申请人： Huntsman Advanced Materials (Switzerland) GmbH
发明人： MUELLER, Alexander , PLATTNER, Kurt , SCHOEHN, Damien , HILDEBRAND, Rainer
IPC分类号： C09B62/44 , D06P1/38 , D06P3/24
CPC分类号： C09B62/095 , C07F11/005 , C09B62/4416 , D06P1/38 , D06P1/384 , D06P3/248 , D06P3/66 , D06P5/30
摘要： Reactive dyes of formula (1), wherein Me is chromium, cobalt or iron, R
1 is hydrogen or unsubstituted or substituted C
1 -C
4 alkyl, E is a bivalent radical of formula (1a), (1b) or (1c) wherein X denotes chlorine or fluorine, T es a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e), or (2f), (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C
1 -C
4 alkyl, C
1 -C
4 alkoxy and sulfo, Z is vinyl or a -CH
2 -CH
2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(Hal)-CH
2 -Hal or -C(Hal)=CH
2 group, q is the number 0 or 1, G is a bivalent radical of formula (1d) or (1e) wherein (R
2 )s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C
1 -C
4 alkyl, C
2 -C
4 alkanoylamino, C
1 -C
4 alkylsulfonyl, carbamoyl, sulfamoyl, sulfo and -E-T, wherein E and T are as defined above, s is the number 0, 1, 2 or 3, A denotes a bivalent radical of formula (3a), (3b) or (3c), wherein R
1 , R
2 , X, T, q and s are as defined above, R
4 and R
7 denote hydrogen, C
1 -C
4 alkyl, -COOH or -COO- C
1 -C
4 alkyl, R
5 and R
6 represent, each independently of the other, identical or different substituents from the group hydroxyl, halogen, nitro, unsubstituted or halo-substituted C
1 -C
4 alkyl, C
1 -C
4 alkoxy, C
2 -C
4 alkanoylamino, C
1 -C
4 alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, and t and u are each independently of the other the number 0, 1, 2 or 3, are especially suitable for dyeing synthetic polyamide fibre materials and yield dyeings or prints having good wet-fastness properties.
摘要翻译：特别适用于染色合成聚酰胺纤维材料并且产生具有良好耐湿性的染色或印花的式（101）的活性染料及其制备方法。

9. 发明公开

EP2791249A2 AZO DYES 审中-公开
标题翻译：偶氮染料
公开(公告)号：EP2791249A2
公开(公告)日：2014-10-22
申请号：EP12791177.4
申请日：2012-11-26
申请人： Huntsman Advanced Materials (Switzerland) GmbH
发明人： MUELLER, Alexander , HILDEBRAND, Rainer , DALLE-NOGARE, Siro
IPC分类号： C09B33/06 , C09B67/00 , D06P1/06 , D06P3/06 , D06P3/24 , D06P3/32
CPC分类号： D06P1/06 , C09B33/06 , C09B67/0041 , C09B67/0046 , D06P1/0096 , D06P1/02
摘要： The present invention relates to dyes of formula (1), wherein each of the residues D
1 and D
2 represents a radical of formula (2), wherein Ar
1 represents the tetravalent radical of a carbocylic or heterocyclic aromatic compound, R
1 , R
2 and R
3 are each independently of the other hydrogen, C
1 -C
12 alkyl, C
1 -C
12 alkoxy, halogen, -OH, -CN, -NO
2 , -CF
3 , -SO
3 H, -NHCOR
4 , -COOR
5 , −CONR
6 R
7 , -SO
2 NR
8 R
9 , -NR
10 SO
2 R
11 , -SO
2 R
13 - or −ZCH
2 CH
2 Q, wherein Z is -O-, -SO
2 -, -NR
12 -, -CONH- or -NHCO-, Q represents −OH, C
1 -C
12 alkyl, -SO
2 R
13 -, -NHR
14 -, −OCH
2 CH
2 OH, −SO
2 CH
2 CH
2 OH or -NHCH
2 CH
2 OH, R
4 is C
1 -C
12 alkyl, R
5 , R
6 , R
7 , R
8 , R
9 , R
10 , R
12 , R
13 and R
14 are each independently of the others hydrogen or C
1 -C
12 alkyl, and R
11 is C
1 -C
12 2alkyl, with the proviso that at least one of the residues D
1 and D
2 is a radical of formula (2) wherein R
3 is -COOR
5 , -SO
2 NR
8 R
9 , -SO
2 R
13 - or −ZCH
2 CH
2 Q, dichromatic and trichromatic mixtures containing these dyes and the use of these dyes for dyeing or printing hydroxyl group-containing or nitrogen-containing fibre materials.

10. 发明公开

EP2389416A1 REACTIVE DYES, THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：活性染料，生产和使用
公开(公告)号：EP2389416A1
公开(公告)日：2011-11-30
申请号：EP10700843.5
申请日：2010-01-11
申请人： Huntsman Advanced Materials (Switzerland) GmbH
发明人： HILDEBRAND, Rainer , MUELLER, Alexander , PLATTNER, Kurt , DA SILVA SARAIVA, Sandra , SCHOEHN, Damien
IPC分类号： C09B62/44 , C09D11/00
CPC分类号： C09B45/16 , C09B62/4416 , C09D11/328
摘要： Reactive dyes of formula (1), wherein R
1 is hydrogen or unsubstituted or substituted C
1 -C
4 alkyl, (R
2 )
s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C
1 -C
4 alkyl, C
2 -C
4 alkanoylamino, C
1 -C
4 alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, Me is chromium, cobalt or iron, E is a bivalent radical of formulae (1a), (1b) or (1c), wherein X denotes chlorine or fluorine, T is a fibre-reactive radical of formula (2a): -NH-(CH
2 )
2-3 -SO
2 -Z, formula (2b): -NH-(CH
2 )
2-3 -O-(CH
2 )
2-3 -SO
2 -Z, formulae (2c), (2d), (2e) or (2f), (R
3 )
0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C
1 -C
4 alkyl, C
1 -C
4 alkoxy and sulfo, Z is vinyl or a -CH
2 -CH
2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(HaI)-CH
2 -HaI or -C(HaI)=CH
2 group, s is the number 0, 1, 2 or 3, q is the number 0 or 1, A denotes a bivalent radical of formulae (3a), (3b), (3c) or (3d), wherein R
1 , R
2 , X, T, m, n, q and s are as defined above, R
4 and R
7 denote hydrogen or C
1 -C
4 alkyl, R
5 and R
6 represent, each independently of the other, identical or different substituents from the group hydroxyl, halogen, nitro, unsubstituted or halo-substituted C
1 -C
4 alkyl, C
1 -C
4 alkoxy, C
2 -C
4 alkanoylamino, C
1 -C
4 alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, and t and u are each independently of the other the number 0, 1, 2 or 3, are especially suitable for dyeing synthetic polyamide fibre materials and yield dyeings or prints having good wet-fastness properties.

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