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1. 发明申请

WO2019152972A1 GAS PHASE PROCESS FOR CHLOROTRIFLUOROETHYLENE 审中-公开
公开(公告)号：WO2019152972A1
公开(公告)日：2019-08-08
申请号：PCT/US2019/016602
申请日：2019-02-05
申请人： HONEYWELL INTERNATIONAL INC.
发明人： NAIR, Haridasan, K. , SINGH, Rajiv, Ratna , MATTHIES, Glenn
IPC分类号： C07C17/23 , C07C21/18 , B01J27/128 , B01J27/10 , B01J27/12 , B01J23/755
摘要： The present invention relates to a process for the preparation of haloethylenes, and preferably perhaloethylenes, by the gas-phase dechlorination of haloethanes in the presence of a catalyst and optionally in the presence of an alkene or an alkane. In particular aspects, the invention relates to a gas-phase process for preparing chlorotrifluoroethylene (CTFE). More particularly, the present invention relates to a gas-phase process for preparing CTFE from 1,1,2-trichloro- 1,2,2-trifluoroethane (CFC-113) by dechlorination in the presence of an alkene or an alkane and a catalyst.

2. 发明申请

WO2022126111A1 PROCESS FOR PRODUCING TRIFLUOROIODOMETHANE (CF3I) FROM TRIFLUOROACETIC ANHYDRIDE (TFAA) 审中-公开
公开(公告)号：WO2022126111A1
公开(公告)日：2022-06-16
申请号：PCT/US2021/072804
申请日：2021-12-08
申请人： HONEYWELL INTERNATIONAL INC. [US]/[US]
发明人： WANG, Haiyou , NAIR, Haridasan, K.
IPC分类号： C07C17/23 , C07C17/20 , C07C19/16 , B01J19/08
摘要： The present disclosure relates to a method for producing trifluoroiodomethane (CF3I) from iodine (l2) and trifluoroacetic anhydride (TFAA) under photochemical conditions using ultraviolet (UV) light.

3. 发明申请

WO2004026799A2 PROCESS OF MAKING FLUORINATED ALCOHOLS 审中-公开
标题翻译：制备氟化醇的方法
公开(公告)号：WO2004026799A2
公开(公告)日：2004-04-01
申请号：PCT/US2003/029694
申请日：2003-09-18
申请人： HONEYWELL INTERNATIONAL, INC.
发明人： NAIR, Haridasan, K. , POSS, Andrew, J. , NALEWAJEK, David
IPC分类号： C07C29/00
CPC分类号： C07C29/44 , C07C31/34 , C07C31/38
摘要： Provided are methods of producing fluorinated alcohols from non-perfluorinated fluoroolefins and methanol. Certain preferred embodiments of such methods involve advantageously reacting a non-perfluorinated fluoroolefin with methanol under ambient-pressure and/or low-temperature conditions.
摘要翻译：提供从非全氟化氟烯烃和甲醇制备氟化醇的方法。这些方法的某些优选实施方案涉及在环境压力和/或低温条件下有利地使非全氟化氟烯烃与甲醇反应。

4. 发明申请

WO2003095505A1 FLUORINATED POLYMERS 审中-公开
标题翻译：氟化聚合物
公开(公告)号：WO2003095505A1
公开(公告)日：2003-11-20
申请号：PCT/US2003/014298
申请日：2003-05-07
申请人： HONEYWELL INTERNATIONAL INC.
发明人： NAIR, Haridasan, K. , VAN DER PUY, Michael , POSS, Andrew, J. , NALENWAJEK, David
IPC分类号： C08F8/18
CPC分类号： C07D487/08 , C07C17/16 , C07C17/30 , C07C22/02 , C07C33/44 , C07C67/343 , C07C67/347 , C07C2602/42 , C07D493/08 , C08F8/18 , G03F7/0046 , G03F7/0392 , G03F7/0395 , C07C21/18 , C07C23/14 , C07C69/65
摘要： Provided are polymers derived from bridged heterocyclic compounds, fluorinated norbornene compounds, fluorinated alkenes, heterocyclic compounds, and combinations of two or more thereof for use in a wide variety of applications, including photoresist compositions. Also provided are methods for producing the monomer compounds for use in the present polymers.
摘要翻译：提供衍生自桥联杂环化合物，氟化降冰片烯化合物，氟化烯烃，杂环化合物以及其两种或多种的组合的聚合物，用于各种应用中，包括光致抗蚀剂组合物。还提供了用于生产用于本发明聚合物的单体化合物的方法。

5. 发明申请

WO2005110957A2 FLUORINATED ETHERS 审中-公开
标题翻译：氟化的ETHERS
公开(公告)号：WO2005110957A2
公开(公告)日：2005-11-24
申请号：PCT/US2005/016382
申请日：2005-05-11
申请人： HONEYWELL INTERNATIONAL INC. , NAIR, Haridasan, K. , SINGH, Rajiv, R.
发明人： NAIR, Haridasan, K. , SINGH, Rajiv, R.
IPC分类号： C07C43/00
CPC分类号： C07C41/06 , A62D1/0057 , C07C43/123 , C08J2203/146 , C09K5/045 , C09K5/10 , C09K2205/112 , C11D7/28 , C11D7/5018
摘要： Present invention relates to novel fluorinated ethers and to a process for producing such fluorinated ethers. Such fluorinated ethers find use in as solvents, anesthetics, refrigerants, cleaning compositions, dry cleaning compositions, blowing agents, flame retardants, formulations of dyes used in optical recording media, microemulsions, and heat transfer compositions. The fluorinated ethers have the formula R-O-R 1 wherein R = CF 3 -CXH-CYZ wherein each of X, Y and Z are independently H or halogen; and R 1 is a C 1 to C 16 alkyl group or a halogen substituted C 1 to C 16 alkyl group.
摘要翻译：本发明涉及新型氟化醚和制备这种氟化醚的方法。这种氟化醚可用作溶剂，麻醉剂，致冷剂，清洁组合物，干洗组合物，发泡剂，阻燃剂，用于光学记录介质的染料配方，微乳液和传热组合物。氟化醚具有式R-O-R 1其中R = CF 3 -CXH-CYZ其中X，Y和Z各自独立地为H或卤素; 且R 1是C 1至C 16烷基或卤素取代的C 1至C _16烷基。

6. 发明申请

WO2003045880A1 PHOTOCHLORINATION OF 1,1,1,3,3-PENTAFLUOROPROPANE 审中-公开
标题翻译： 1,1,1,3,3-三氟硼酸的光合作用
公开(公告)号：WO2003045880A1
公开(公告)日：2003-06-05
申请号：PCT/US2002/037557
申请日：2002-11-22
申请人： HONEYWELL INTERNATIONAL INC.
发明人： NAIR, Haridasan, K. , SHANKLAND, Ian, R. , BRADLEY, David, E. , CHENEY, Martin, E. , POSS, Andrew, J. , DEMMIN, Timothy, R. , NALEWAJEK, David , VAN DER PUY, Michael
IPC分类号： C07C17/10
CPC分类号： C07C17/10 , C07C19/10
摘要： A process for preparing 1-chloro-1,1,3,3,3-pentafluoropropane, CF 3 CH 2 CF 2 Cl, comprising contacting in a reaction zone in the substantial absence of oxygen, reactants comprising chlorine and 1,1,1,3,3-pentafluoropropane, CF 3 CH 2 CHF 2 (also referred to as HFC-245fa), and subjecting the reactants to actinic radiation, such as UV light at about 2,000 to 4,000 Angstroms, wherein: (1) inert gas is present at a concentration equal to or less than about 5 wt.% of the total weight of reactants; (2) the molar ratio of chlorine to CF 3 CH 2 CHF 2 is from about 0.2:1 to about 1.5:1; and (3) the concentration of chlorinated product produced having greater than one chlorine present in the molecule is less than or equal to about 10 wt.%.
摘要翻译：制备1-氯-1,1,3,3,3-五氟丙烷CF 3 CH 2 CF 2 Cl的方法，包括在基本不存在氧的反应区中接触，包含氯的反应物和1,1,1,3,3-五氟丙烷，CF 3 CH 2 CHF 2（也称为HFC-245fa），并使反应物进行光化辐射，例如约2,000至4,000埃的紫外光，其中：（1）惰性气体的存在浓度等于或小于约5 反应物总重量的重量％; （2）氯与CF 3 CH 2 CHF 2的摩尔比为约0.2:1至约1.5:1; 和（3）分子中存在的具有大于一个氯的氯化产物的浓度小于或等于约10重量％。

7. 发明申请

WO2006073850A1 FLUORINE-CONTAINING COATINGS 审中-公开
标题翻译：含氟的涂料
公开(公告)号：WO2006073850A1
公开(公告)日：2006-07-13
申请号：PCT/US2005/046505
申请日：2005-12-20
申请人： HONEYWELL INTERNATIONAL INC. , NAIR, Haridasan, K. , SINGH, Rajiv, R. , SHIA, George, A.
发明人： NAIR, Haridasan, K. , SINGH, Rajiv, R. , SHIA, George, A.
IPC分类号： G11B7/24 , B41M5/26
CPC分类号： B41M5/529 , C09D11/033 , G11B7/266
摘要： The present invention provides an ink for recordable media comprising a coating moiety and at least one fluorinated alcohol solvent for said at least one coating moiety, the fluorinated alcohol solvent preferably having a surface tension of not greater than about 27 dynes/cm. In certain preferred embodiments the fluorinated alcohol has the structure R f -OH, wherein R f is selected from the group consisting of H-[CX 2 ] n ; Z-[CX 2 -CX 2 ] n ; Z-[CZX-CX 2 ] n ; Z-[CZX-CZX] n -; CZ 2 CH-; Z-[CX=CX] ri ; Z-[CZ=CX] n ; Z-[CZ=CZ] n ; Z-[CX 2 ] n CX 2 =CX-[CX 2 ] n - and Z-CZX-CX(CZX 2 )-, wherein Z is independently -CF 3 , -CHF 2 , - CH 2 F; -R-CF 3 , -R-CHF 2 , or -R-CH 2 F, wherein R is a substituted or unsubstituted C 1 -C 12 alkyl radical, or a substituted or unsubstituted fluorinated C 1 -C 12 alkyl radical; X is independently hydrogen, Cl, Br, F, I, or Z; and n is an integer from 1 to 20.
摘要翻译：本发明提供了一种用于可记录介质的油墨，其包含涂层部分和用于所述至少一个涂层部分的至少一种氟化醇溶剂，所述氟化醇溶剂优选具有不大于约27达因/厘米3的表面张力。在某些优选的实施方案中，氟化醇具有结构R 5 -OH，其中R f选自H- [CX 2 >] Z- [CX 2 -CX 2] n < Z- [CZX-CX 2] n < Z- [CZX-CZX] _{名词 - ; CZ _{2 CH-; Z- [CX = CX] Z- [CZ = CX] n < Z- [CZ = CZ] n < Z- [CX 2] N 2 CX 2 = CX- [CX 2] n 2 F; -R-CF 3，-R-CHF 2或-R-CH 2 F，其中R是取代或未取代的C 1 -C 6烷基，或者取代或未取代的氟代C 1 -C 12烷基;或者取代或未取代的氟代C 1 -C 12烷基; X独立地为氢，Cl，Br，F，I或Z; n为1〜20的整数。}}

8. 发明申请

WO2005108334A1 PROCESSES FOR SYNTHESIS OF 1,3,3,3-TETRAFLUOROPROPENE AND 2,3,3,3-TETRAFLUOROPROPENE 审中-公开
标题翻译：合成1,3,3,3-四氯丙烯和2,3,3,3-四氯丙烯的方法
公开(公告)号：WO2005108334A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/015125
申请日：2005-04-29
申请人： HONEYWELL INTERNATIONAL, INC. , TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip, S.M. , VAN DER PUY, Michael
发明人： TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip, S.M. , VAN DER PUY, Michael
IPC分类号： C07C21/18
CPC分类号： C07C17/06 , C07C17/04 , C07C17/206 , C07C17/21 , C07C17/25 , C07C21/18 , C07C19/14 , C07C19/16 , C07C19/01 , C07C19/10
摘要： Disclosed in one embodiment is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises (a) reacting a compound of formula (I) X 1 X 2 with a compound of formula (II) CF 3 CH=CH 2 to produce a reaction product comprising a compound of formula (III) CF 3 CHX 1 CH 2 X 2 , wherein X 1 and X 2 are each independently selected from the group consisting of hydrogen, chlorine, bromine and iodine, provided that X 1 and X 2 are not both hydrogen; (b) when X 2 in formula (III) is not fluorine, fluorinating the compound of formula (III) to produce a reaction product comprising a compound of formula (III) wherein X 1 is as described above and X 2 is fluorine; and (c) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3,-tetrafluoropropene. In another embodiment, the process comprises (a) reacting chlorine with a compound of formula ( I) CH 3 CH=CH 2 to produce a reaction product comprising a compound of formula ( II) CCI 3 CHC1CH 2 C1; (b) fluorinating the compound of formula ( II) to produce a reaction product comprising a compound of formula ( III ) CF 3 CHC1CH 2 F; and (c) exposing said compound of said formula ( III ) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
摘要翻译：在一个实施方案中公开了一种用于合成1,3,3,3-四氟丙烯的方法，其包括（a）使式（I）X 1 X 2的化合物与式（II）的化合物与CF 3 CH = CH 2，以产生包含式（III）化合物的反应产物，其中X 1和X 2各自独立地选自氢，氯，溴和碘条件是X 1和X 2不同时为氢; （b）当式（III）中的X 2不是氟时，氟化式（III）化合物以产生包含其中X 1如上所述的式（III）化合物的反应产物， 2>是氟; 和（c）将所述式（III）化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。在另一个实施方案中，该方法包括（a）使氯与式（I）CH 3 CH = CH 2的化合物反应以产生包含式（II）化合物的反应产物：CCI 3 CHClCH 2 Cl; （b）氟化式（II）化合物以产生包含式（III）化合物的反应产物：CF 3 CHClCH 2 F; 和（c）将所述式（III）的所述化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。

9. 发明申请

WO2003073169A3 FLUORINATED MOLECULES AND METHODS OF MAKING AND USING SAME 审中-公开
公开(公告)号：WO2003073169A3
公开(公告)日：2003-09-04
申请号：PCT/US2003/005142
申请日：2003-02-21
申请人： HONEYWELL INTERNATIONAL INC.
发明人： POSS, Andrew , NALEWAJEK, David , DEMMIN, Timothy, R. , NAIR, Haridasan, K.
IPC分类号： G03F7/039
摘要： Provided are polymers derived from fluoroalkyl norbornenes, fluorinated crotonates, fluorinated allyl alcohols, and combinations of two or more thereof for use in a wide variety of applications, including photoresist compositions. Also provided are methods for producing the fluoroalkyl norbornenes, fluorinated crotonates, and fluorinated allyl alcohols for use in the present polymers.

10. 发明申请

WO2003073169A2 FLUORINATED MOLECULES AND METHODS OF MAKING AND USING SAME 审中-公开
标题翻译：氟化分子及其制备和使用方法
公开(公告)号：WO2003073169A2
公开(公告)日：2003-09-04
申请号：PCT/US2003/005142
申请日：2003-02-21
申请人： HONEYWELL INTERNATIONAL INC.
发明人： POSS, Andrew , NALEWAJEK, David , DEMMIN, Timothy, R. , NAIR, Haridasan, K.
IPC分类号： G03F7/039
CPC分类号： G03F7/0397 , C07C29/147 , C07C67/307 , C07C67/317 , C07C67/343 , C07C2602/42 , C08F16/04 , C08F20/10 , C08F32/08 , C08G61/06 , C08G61/08 , G03F7/0046 , C07C69/63 , C07C69/65 , C07C69/753 , C07C33/44
摘要： Provided are polymers derived from fluoroalkyl norbornenes, fluorinated crotonates, fluorinated allyl alcohols, and combinations of two or more thereof for use in a wide variety of applications, including photoresist compositions. Also provided are methods for producing the fluoroalkyl norbornenes, fluorinated crotonates, and fluorinated allyl alcohols for use in the present polymers.
摘要翻译：提供了衍生自氟烷基降冰片烯，氟化巴豆酸酯，氟化烯丙醇及其两种或更多种的组合的聚合物，用于包括光致抗蚀剂组合物在内的各种应用。还提供了用于生产用于本发明聚合物的氟代烷基降冰片烯，氟化巴豆酸酯和氟化烯丙基醇的方法。

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