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1. 发明申请

WO2005014512A3 LOW TEMPERATURE PRODUCTION OF 1-CHLORO-3, 3,3-TRIFLUOROPROPENE (HCFC-1233zd) 审中-公开
标题翻译：低温生产1-氯-3,3,3-三氟丙烯（HCFC-1233zd）
公开(公告)号：WO2005014512A3
公开(公告)日：2005-04-14
申请号：PCT/US2004025442
申请日：2004-08-06
申请人： HONEYWELL INT INC , TUNG HSUEHSUNG , MERKEL DANIEL C , UHRICH KEVIN D
发明人： TUNG HSUEHSUNG , MERKEL DANIEL C , UHRICH KEVIN D
IPC分类号： C07C17/20 , C07C17/25 , C07C21/18
CPC分类号： C07C17/206 , C07C17/25 , C07C21/18
摘要： A process for producing 1-chloro-3, 3,3-trifluoropropene (HCFC-1233zd) from 1,1,1-3,3-pentachloropropape (HCC-240fa) by its reaction with hydrogen fluoride, the reactants are reacted in a liquid phase reaction at a temperature of less than 150° C in the presence of a Lewis acid catalyst or mixture of Lewis acid catalysts, and hydrogen chloride and HCFC-1233zd formed in the reaction are continuously removed and the HCFC-12333zd is isolated.
摘要翻译：由1,1,1,3,3-五氯丙烷（HCC-240fa）通过其与氟化氢反应制备1-氯-3,3,3-三氟丙烯（HCFC-1233zd）的方法，反应物在在路易斯酸催化剂或路易斯酸催化剂混合物存在下，在小于150℃的温度下进行液相反应，连续除去反应中形成的氯化氢和HCFC-1233zd，并分离出HCFC-12333zd。

2. 发明申请

WO2005030685B1 METHOD OF MAKING 1,1,3,3,3-PENTAFLUOROPROPENE 审中-公开
公开(公告)号：WO2005030685B1
公开(公告)日：2005-07-14
申请号：PCT/US2004031336
申请日：2004-09-24
申请人： HONEYWELL INT INC , TUNG HSUEHSUNG , SINGH RAJIV R , MERKEL DANIEL C
发明人： TUNG HSUEHSUNG , SINGH RAJIV R , MERKEL DANIEL C
IPC分类号： C07C17/20 , C07C17/23 , C07C17/25 , C07C17/38 , C07C21/18 , C07C17/00
CPC分类号： C07C21/18 , C07C17/206 , C07C17/25 , C07C17/38 , C07C19/08 , C07C19/10
摘要： The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc can also be made: from the dehydrofluorination of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa). HFC-1225zc) is a compound that has the potential to be used as a low Global Warming Potential refrigerant, blowing agent, aerosol propellant, or solvent.

3. 发明申请

WO2005030685A3 METHOD OF MAKING 1,1,3,3,3-PENTAFLUOROPROPENE 审中-公开
标题翻译： 1,1,3,3,3-五氟丙烯的制备方法
公开(公告)号：WO2005030685A3
公开(公告)日：2005-06-09
申请号：PCT/US2004031336
申请日：2004-09-24
申请人： HONEYWELL INT INC , TUNG HSUEHSUNG , SINGH RAJIV R , MERKEL DANIEL C
发明人： TUNG HSUEHSUNG , SINGH RAJIV R , MERKEL DANIEL C
IPC分类号： C07C17/20 , C07C17/23 , C07C17/25 , C07C17/38 , C07C21/18 , C07C17/00
CPC分类号： C07C21/18 , C07C17/206 , C07C17/25 , C07C17/38 , C07C19/08 , C07C19/10
摘要： The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc can also be made: from the dehydrofluorination of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa). HFC-1225zc) is a compound that has the potential to be used as a low Global Warming Potential refrigerant, blowing agent, aerosol propellant, or solvent.
摘要翻译：本发明提供了制造氢氟碳化物1,1,3,3,3-五氟丙烯（HFC-1225zc）的经济方法。 HFC-1225zc可以由1-氯-1,1,3,3,3-五氟丙烷（HCFC-235fa）的脱氯化氢制得。或者，HFC-1225zc也可以由1,1,1,3,3,3-六氟丙烷（HFC-236fa）的脱氟化氢制得。 HFC-1225zc）是一种可用作低全球变暖潜能制冷剂，发泡剂，气溶胶推进剂或溶剂的化合物。

4. 发明申请

WO2011034991A3 PROCESS FOR THE MANUFACTURE OF 1,3,3,3-TETRAFLUOROPROPENE 审中-公开
标题翻译：制备1,3,3,3-四氯丙烯的方法
公开(公告)号：WO2011034991A3
公开(公告)日：2011-07-21
申请号：PCT/US2010049055
申请日：2010-09-16
申请人： HONEYWELL INT INC , TUNG HSUEHSUNG , JOHNSON ROBERT C , MERKEL DANIEL C , WANG HAIYOU
发明人： TUNG HSUEHSUNG , JOHNSON ROBERT C , MERKEL DANIEL C , WANG HAIYOU
IPC分类号： C07C17/25 , C07C17/23 , C07C21/18
CPC分类号： C07C17/21 , B01J21/18 , B01J27/10 , B01J27/138 , C07C17/087 , C07C17/25 , C07C21/18 , C07C19/10 , C07C19/08
摘要： The invention provides an economic process for the manufacture of 1,3,3,3-tetrafluoropropene (HFO-1234ze) by a two stage process. A vapor phase hydrofluorination of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) into 1-chloro-1,3,3,3-tetrafluoropropane (HCFC-244fa) and/or 1,1,1,3,3-pentafluoropropane (HFC-245fa) is conducted, followed by the thermal dehydrochlorination of HCFC-244fa and dehydrofluorination of HFC-245fa into HFO-1234ze in the presence of a catalyst which comprises one or more of alkali metal halides, alkaline earth metal halides, halogenated metal oxides, zero oxidation state metals, zinc halides, palladium halides, and activated carbon.
摘要翻译：本发明提供了通过两阶段方法制备1,3,3,3-四氟丙烯（HFO-1234ze）的经济方法。将1-氯-3,3,3-三氟丙烯（HCFC-1233zd）汽相氢氟化为1-氯-1,3,3,3-四氟丙烷（HCFC-244fa）和/或1,1,1,3 进行3-五氟丙烷（HFC-245fa），随后在含有一种或多种碱金属卤化物，碱土金属的催化剂存在下，将HCFC-244fa的热脱氯化氢和HFC-245fa的脱氟化氢分解成HFO-1234 卤化物，卤化金属氧化物，零氧化态金属，卤化锌，钯卤化物和活性炭。

5. 发明申请

WO2006086057A2 DIRECT ONE-STEP SYNTHESIS OF TRIFLUOROMETHYL IODIDE 审中-公开
标题翻译：直接一步合成三氟甲磺酰碘
公开(公告)号：WO2006086057A2
公开(公告)日：2006-08-17
申请号：PCT/US2005044639
申请日：2005-12-08
申请人： HONEYWELL INT INC , MUKHOPADHYAY SUDIP , TUNG HSUEHSUNG
发明人： MUKHOPADHYAY SUDIP , TUNG HSUEHSUNG
IPC分类号： C07C17/158 , C07C19/16
CPC分类号： C07C19/16 , C07C17/093 , C07C17/361
摘要： A catalytic one-step process for the production of CF 3 I by reacting, in the presence of a source of oxygen, a source of iodine a reactant of the formula: CF 3 R, where R is -COOH, -COX, -CHO, -OOOR 2 and -SO 2 X, where R is an alkyl group and X is selected from chlorine, bromine and iodine. The catalyst may be a metal salt such as salts of Cu, Hg, Pt, Pd, Co, Mn, Rh, Ni, V, TI, Ba, Cs, Ca, K and Ge and mixtures thereof, preferably on a support, such as MgO, BaO and CaO, BaCO 3 , CaNO 3 , Ba (NO 3 ) 2 , activated carbon, basic alumina, and ZrO 2 .
摘要翻译：通过在氧气源的存在下，将碘的反应物与下式反应的反应物进行反应的催化一步法：CF 3 N / > R，其中R是-COOH，-COX，-CHO，-OROR 2和-SO 2 X，其中R是烷基，X选自氯，溴和碘。催化剂可以是金属盐，例如Cu，Hg，Pt，Pd，Co，Mn，Rh，Ni，V，TI，Ba，Cs，Ca，K和Ge的盐及其混合物，优选在载体上作为MgO，BaO和CaO，BaCO 3，CaNO 3，Ba（NO 3 3）2 N，活性炭，碱性氧化铝和ZrO 2 2。

6. 发明申请

WO2006063069A3 CATALYTIC CONVERSION OF HYDROFLUOROALKANOL TO HYDROFLUOROALKENE 审中-公开
标题翻译：氢氟烷醇对氢氟酸的催化转化
公开(公告)号：WO2006063069A3
公开(公告)日：2006-08-17
申请号：PCT/US2005044298
申请日：2005-12-09
申请人： HONEYWELL INT INC , MUKHOPADHYAY SUDIP , NAIR HARIDASAN K , TUNG HSUEHSUNG
发明人： MUKHOPADHYAY SUDIP , NAIR HARIDASAN K , TUNG HSUEHSUNG
IPC分类号： C07C17/00 , C07C21/18
CPC分类号： C07C17/00 , C07C17/25 , C07C21/18
摘要： Methane is used as the selective dehydrating agent for the production of 2,3,3,3-tetrafluoro-l-propene (R1234yf) from 2,2,3,3,3-pentafluoro-l-propanol. Supported transition metal catalysts are prepared and used for this reaction with high activity. Almost 58% selectivity to R1234yf is obtained at an alcohol conversion level of 60% using unsupported Ni-mesh as the catalyst. Pd and Pt show almost similar level of conversion; however, the selectivity to the desired product is low. The activity of the metal catalyst was found to be a function of the type of support material, activated carbon showing better activity than alumina. Different important process parameters such as temperature, pressure, and contact time are studied to optimize the process. High pressure and temperature are deleterious to the rate of 1234yf formation; yet, the highest yield to 1234yf is obtained while performing a reaction at 494°C with a contact time of 23 sec.
摘要翻译：甲烷被用作从2,2,3,3,3-五氟-1-丙醇制备2,3,3,3-四氟-1-丙烯（R1234yf）的选择性脱水剂。制备负载型过渡金属催化剂，并以高活性用于该反应。使用未负载的Ni-网作为催化剂，在60％的醇转化率下获得对R1234yf几乎58％的选择性。 Pd和Pt显示几乎相似的转化水平; 然而，对所需产物的选择性低。发现金属催化剂的活性是支撑材料的类型的函数，活性炭表现出比氧化铝更好的活性。研究了不同的重要工艺参数，如温度，压力和接触时间，以优化工艺。高压和高温对于1234yf的形成是有害的; 而在494℃下以23秒的接触时间进行反应，得到最高的1234yf产率。

7. 发明专利

AU2004245538A1 Pentafluorobutane-based compositions 未知
公开(公告)号：AU2004245538A1
公开(公告)日：2004-12-16
申请号：AU2004245538
申请日：2004-06-03
申请人： HONEYWELL INT INC
发明人： BEMENT LESLIE , PHAM HANG T , TUNG HSUEHSUNG , WILLIAMS DAVID J , BOGDAN MARY C
IPC分类号： C08J9/14 , C11D17/00
摘要： The present invention provides compositions comprising pentafluorobutane, a butane and optionally water. The present invention further provides for refrigerants, blowing agents, foam compositions, polyol premixes, closed-cell foams, sprayable compositions, and the like, comprising the present composition.

8. 发明专利

AT556043T 未知
公开(公告)号：AT556043T
公开(公告)日：2012-05-15
申请号：AT05779894
申请日：2005-03-31
申请人： HONEYWELL INT INC
发明人： MERKEL DANIEL , SHANKLAND IAN , TUNG HSUEHSUNG
IPC分类号： C07C17/20 , B01J21/18 , B01J23/20 , B01J23/22 , B01J27/08 , B01J27/125 , B01J27/135 , B01J37/26 , C07C17/21 , C07C19/08
摘要： A process for the production of 1,1-difluoroethane (HFC-152a) comprises: (a) providing a reaction vessel, (b) providing in the reaction vessel activated carbon impregnated with a strong Lewis acid fluorination catalyst wherein the strong Lewis acid catalyst is selected from the group consisting of halides of As, Sb, Al, Tl, In, V, Nb, Ta, Ti, Zr and Hf, (c) activating the catalyst by passing through the activated carbon impregnated with a strong Lewis acid fluorination catalyst anhydrous hydrogen fluoride gas and chlorine gas, (d) contacting, in a vapor state in the reaction vessel containing the activated catalyst, hydrogen fluoride and one or more halogenated hydrocarbons selected from the group consisting of chlorofluoromethane, dichloromethane, 1,1,1-trichloroethane, vinyl chloride, 1,1-dichloroethylene, 1,2-dichloroethylene, 1,2-dichloroethane, and 1,1-dichloroethane for a time and at a temperature to produce a product stream comprising hydrofluorocarbon product(s) corresponding to the chlorinated hydrocarbon reactant(s), and one or more of hydrogen chloride, unreacted chlorinated hydrocarbon fluoride, and (e) separating the hydrofluorocarbon product(s) from the product stream.

9. 发明专利

DE602005023650D1 KATALYTISCHE UMWANDLUNG VON HYDROFLUORALKANOL IN HYDROFLUORALKEN 未知
公开(公告)号：DE602005023650D1
公开(公告)日：2010-10-28
申请号：DE602005023650
申请日：2005-12-09
申请人： HONEYWELL INT INC
发明人： MUKHOPADHYAY SUDIP , NAIR HARIDASAN K , TUNG HSUEHSUNG
IPC分类号： C07C17/00 , C07C21/18

10. 发明专利

ES2282882T3 COMPOSICIONES BASADAS EN PENTAFLUOROBUTANO. 未知
公开(公告)号：ES2282882T3
公开(公告)日：2007-10-16
申请号：ES04754150
申请日：2004-06-03
申请人： HONEYWELL INT INC
发明人： BOGDAN MARY C , WILLIAMS DAVID J , TUNG HSUEHSUNG , PHAM HANG T , BEMENT LESLIE
IPC分类号： C08J9/14 , C11D17/00
摘要： Una composición semejante a azeótropo que comprende 1, 1, 1, 3, 3-pentafluorobutano y n-butano.

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