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    • 7. 发明申请
    • METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARED USING THE METHOD, CATALYSTS COMPOSITION CONTAINING THE COMPLEXES
    • 制备过渡金属配合物的方法,使用该方法制备的过渡金属配合物,含有配合物的催化剂组合物
    • WO2008084931A9
    • 2008-11-13
    • PCT/KR2007006940
    • 2007-12-28
    • LG CHEMICAL LTDLEE CHOONG-HOONLEE EUN-JUNGJUNG SEUNG-WHANLEE JUNG-ALEE BO-RAMLEE BUN-YEOUL
    • LEE CHOONG-HOONLEE EUN-JUNGJUNG SEUNG-WHANLEE JUNG-ALEE BO-RAMLEE BUN-YEOUL
    • C07F7/28
    • C07F17/00C08F4/65908C08F2420/02Y02P20/55C08F210/16C08F210/08C08F2500/08C08F2500/12C08F4/6592
    • The present invention provides a novel transition metal complex where a monocy- clopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by- reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex. When a catalyst composition comprising the transition metal complex is applied in copoly- merization of ethylene and monomers having large steric hindrance, a very low density polyolefin copolymer having a density of less than 0.910 g/cc, in addition to a polyolefin having a high molecular weight and a linear low density, can be prepared. Furthermore, the reactivity is also very high.
    • 本发明提供一种新型的过渡金属配合物,其中引入了酰胺基的单环戊二烯基配体被配位,该配合物的合成方法和使用该配合物的烯烃聚合。 根据本发明的用于制备过渡金属配合物的方法包括使用含有保护基团的化合物阻断氮原子的副反应的步骤,因此可以以更简单的方式制备过渡金属配合物 高产量。 此外,根据本发明的过渡金属配合物具有通过其中在金属位点附近形成稳定键的亚苯基桥连接的具有酰胺基的五边形环结构,因此空间单体可容易地接近转变 金属复合体。 当将包含过渡金属配合物的催化剂组合物用于乙烯和具有大位阻的单体的共聚时,除了具有高分子量的聚烯烃外,密度小于0.910g / cc的极低密度聚烯烃共聚物 重量和线性低密度,可以准备。 而且,反应性也非常高。