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    • 5. 发明专利
    • AMINE-MODIFIED EPOXY RESIN COMPOSITION
    • JPH1060079A
    • 1998-03-03
    • JP18866497
    • 1997-07-14
    • HOECHST AG
    • MARTEN MANFREDGODAU CLAUS
    • C08G18/32C08G18/58C08G59/10C08G59/50C09D175/04C09J175/04
    • PROBLEM TO BE SOLVED: To obtain the subject resin composition capable of developing excellent processability, storage quality, reactivity, flexibility, tear strength, adhesiveness, low-temperature elasticity and useful as an adhesive, etc., by formulating a reaction product of a specific epoxyamine adduct with a polyisocyanate. SOLUTION: This resin composition comprises (A) a compound having two or more 1,2-epoxy groups which is a reaction product of an epoxy-amine adduct obtained by reacting a compound (A1 ) having two or more 1,2-epoxy groups in the molecule with amines (A2 ) which are compounds, etc., of formula I [R is a 1-30C (branched)aliphatic or aromatic hydrocarbon residue, etc., and R and R are each H or R , with the proviso that when R and R are H, R is a group, etc., of formula II (R and R are each R ); amino group is directly not bonded to an aromatic residue; R and R may form a is H] with a polyisocyanate (A3 ) such as an aromatic or cyclic aliphatic acid polyisocyanate, (B) a 1,2-epoxy compound which is the component A1 , etc., and (C) a curing agent and as necessary, further (D) other additive.
    • 8. 发明专利
    • DE19628409A1
    • 1998-01-22
    • DE19628409
    • 1996-07-15
    • HOECHST AG
    • MARTEN MANFREDGODAU CLAUS
    • C08G18/32C08G18/58C08G59/10C08G59/50C09D175/04C09J175/04C08L63/02C08K5/17C09J163/02
    • Epoxy resin compositions (ERC), consisting of (A) compounds with at least two 1,2-epoxide groups, comprising epoxide-amine adducts obtained by reacting (A1) compounds with at least two epoxide groups on average, optionally mixed with mono-epoxides, (A2) amine(s) selected from (A21) sterically hindered mono-amines of formula R -C(R )(NH2)-R -NH-R -NH-R (II) and (A23) di-prim. diamines of formula H2N-C(R )(R )-R -C(R )(R )-NH2 (III); and (A3) polyfunctional aromatic, linear, branched or cyclic aliphatic, or aromatic-aliphatic isocyanates with at least 2 isocyanate groups; (B) optionally 1,2-epoxide compounds other than (A1), and/or the unreacted residues of (A1) from the production of (A); (C) hardeners and (D) optionally other additives. In (I)-(III), R = 1-30C (cyclo)aliphatic, araliphatic or aromatic hydrocarbyl, optionally substituted with OH, alkoxy or halogen; R , R = H or R , preferred R is H; the amino groups in (I) are not directly attached to an aromatic ring; if R = R = H, then R = -CHR R (7), -CR R R (8), -CH2-CHR R (9) or -CH2-CR R R (10), with R -R = as for R ; R may also form an optionally substituted cycloaliphatic ring with up to 8C atoms, in which case R = H; R = optionally substituted hydrocarbyl (as for R ) with 2-30C, or (poly)oxyalkylene with 1-200 units; R = optionally substituted hydrocarbyl as for R with 1-20C; at least one carbon directly attached to nitrogen in formula (II) is a sec. or tert. carbon; R -R = H or 1-8C alkyl; R = direct bond, optionally substituted alkylene, or arylene or heteroarylene; at least one of the groups R -R is alkyl if R is a direct bond or linear alkylene, and R can form a cycloaliphatic, aromatic or heteroaromatic ring with R or R and the linking atoms.