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    • 8. 发明专利
    • BINDER COMPOSITION FOR SELF-CURING MOLD
    • JPS6216844A
    • 1987-01-26
    • JP15497585
    • 1985-07-12
    • HITACHI CHEMICAL CO LTD
    • SUGITANI HATSUOMUKOYAMA YOSHIYUKIOWADA YOSHIROKASHIWAGI MITSUYOSHI
    • B22C1/22
    • PURPOSE:To obtain the titled binder compsn. consisting of the specific compsn. having an excellent shelf life at a low temp. by successively bringing urea, formaldehyde and furfuryl alcohol into reaction in the presence of a basic catalyst and acidic catalyst under specific conditions. CONSTITUTION:The urea, formaldehyde and about 1/3-2/3 the total amt. of the furfuryl alcohol to be used are mixed and the mixture is brought into reaction for about 0.3-2hr at about 85-95 deg.C in the presence of the basic catalyst at about 0.001-0.5wt% of the total weight of such mixture. The mixture is then brought into reaction at about 85-95 deg.C in the presence of the acidic catalyst at about 0.01-0.1wt% of the total weight of the mixture. The mixture is concd. by dehydration at the point of the time when about 1-3hr elapse to decrease the moisture in the reaction liquid to about 10wt%. The remaining furfuryl alcohol is added to the liquid and the liquid is brought into reaction for about 0.5-2hr at about 85-95 deg.C. The binder compsn. for a self-curing mold consisting of the compd. which is expressed by formula I (n is>=2 integer) and contains 30-70wt% furfuryl alcohol monomer and the balance the compd. expressed by formula II is thus obtd.