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1. 发明专利

JPS6032748A LIQUID CRYSTAL COMPOUND 失效
公开(公告)号：JPS6032748A
公开(公告)日：1985-02-19
申请号：JP13780083
申请日：1983-07-29
申请人： HITACHI LTD , CHISSO CORP
发明人： HATSUTORI SHINTAROU , ISOGAI MASATO , IWASAKI KISHIROU , KITAMURA TERUO , KOUBI AKIO , INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KENJI , SAITOU SHINICHI
IPC分类号： C07C69/90 , C07C69/92 , C07C69/94 , C09K19/20
摘要： NEW MATERIAL:The liquid crystal compound of formula (R is =7). EXAMPLE:p-n-Decyloxybenzoic acid p'-(2-methylbutoxycarbonyl)phenyl ester. USE:A liquid crystal composition stable to water and light and exhibiting ferroelectric liquid crystal phase. PREPARATION:The compound of formula is prepared by reacting a p-hydroxybenzoic acid ester containing optically active group (e.g. 2-methylbutyl, 3-methylpentyl, etc.) with acid halide of the corresponding p-alkoxy or alkylbenzoic acid, etc. in a basic solvent (e.g. pyridine).

2. 发明专利

JPS5998051A LIQUID CRYSTAL COMPOUND AND LIQUID CRYSTAL COMPOSITION 失效
公开(公告)号：JPS5998051A
公开(公告)日：1984-06-06
申请号：JP20610682
申请日：1982-11-26
申请人： HITACHI LTD , CHISSO CORP
发明人： ISOGAI MASATO , HATSUTORI SHINTAROU , IWASAKI KISHIROU , KITAMURA TERUO , KOUBI AKIO , INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KENJI , SAITOU SHINICHI
IPC分类号： C09K19/22 , C07C67/00 , C07C241/00 , C07C251/24 , C09K19/48 , G02F1/13 , G09F9/00
摘要： NEW MATERIAL:The compound of formula (R is alkoxy or alkyl; R* is group containing asymmetric carbon atom). EXAMPLE:P-n-Decyloxybenzylidene-p'-(2-methylbutyloxycarbonyl)aniline. USE:Useful as a component of a ferroelectric liquid crystal composition. It has high light stability. PROCESS:The exemplified compound can be prepared by boiling a (+)-p-amino- benzoic acid 2-methylbutyl ester, p-n-decyloxybenzaldehyde and p-toluenesulfonic acid in toluene using a Dean-Stark reflux condenser to remove the produced water. The (+)-p-aminobenzoic acid 2-methyl-butyl ester used as a raw material can be obtained by reacting (-)-2-methylbutyl alcohol with p-nitrobenzoic acid chloride in pyridine, and reducing the reaction product with hydrogen in the presence of Pd/C catalyst. Another raw material, p-n-decylbenzaldehyde, is obtained by the reaction of p-hydroxybenzaldehyde with n-decyl bromide.

3. 发明专利

JPS60149548A LIQUID CRYSTAL SUBSTANCE AND LIQUID CRYSTAL COMPOSITION 失效
公开(公告)号：JPS60149548A
公开(公告)日：1985-08-07
申请号：JP24647184
申请日：1984-11-21
申请人： CHISSO CORP , HITACHI LTD
发明人： INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KANETSUGU , SAITOU SHINICHI , ISOGAI MASATO , HATSUTORI SHINTAROU , IWASAKI KISHIROU , KITAMURA TERUO , KOUBI AKIO
IPC分类号： C09K19/20 , C07C69/76 , C07C69/773 , C07C69/82 , C07C69/83 , C07C69/92 , C07C69/94 , C09K19/48 , G02F1/13
摘要： NEW MATERIAL:A compound expressed by formula I (R is 1-20C alkyl and alkoxyl); R* is optically active group containing asymmetric carbon atom; m and n are 1 or 2). EXAMPLE:4'-n-Decyl-4-biphenylyl S-p-(2-methylbutoxyacrbonyl)benzoate. USE:One component in liquid crystal compositions, particularly a strongly dielectric liquid crystal compound having improved response to image display, improved light resistance and a wide temperature range (MR) exhibiting strong dielectric property even by itself but capable of exhibiting a wide MR near room temperature by mixing with another strongly dielectric liquid crystal compound. PREPARATION:A compound expressed by formula II as a raw material is converted into an acid chloride expressed by formula III, which is then reacted with an optically active alcohol expressed by the formula ROH to produce a compound expressed by formula IV. The resultant compound expressed by formula IV. The resultant compound expressed by formula IV is then oxidized to give a compound expressed by formula V, which is converted into an acid chloride expressed by formula VI, and finally reacted with a compound expressed by formula VI to afford the aimed compound expressed by formula I .

4. 发明专利

JPS60149547A LIQUID CRYSTAL SUBSTANCE AND LIQUID CRYSTAL COMPOSITION 失效
公开(公告)号：JPS60149547A
公开(公告)日：1985-08-07
申请号：JP24647084
申请日：1984-11-21
申请人： CHISSO CORP , HITACHI LTD
发明人： INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KANETSUGU , SAITOU SHINICHI , ISOGAI MASATO , HATSUTORI SHINTAROU , IWASAKI KISHIROU , KITAMURA TERUO , KOUBI AKIO
IPC分类号： C09K19/20 , C07C69/76 , C07C69/773 , C07C69/82 , C07C69/83 , C07C69/92 , C07C69/94 , C09K19/48 , G02F1/13
摘要： NEW MATERIAL:A compound expressed by formula I (X is -CH2O- or -OCH2-; R is 1-22C alkyl and alkoxyl; R* is optically active group containing asymmetric carbon atom; m and n are 1 or 2). EXAMPLE:2-Methylbutyl S-4-(p-octyloxygenzoyloxy)-4-biphenylcarboxylate. USE:One component in liquid crystal compositions, particularly a strongly dielectric liquid drystal compound having improve response to image display, improved light resistance and a wide temperature range (MR) exhibiting strong dielectric property even by itself but capable of exhibiting a wide MR near room temperature by mixing with another strongly dielectric liquid crystal. PREPARATION:For example, a compound expressed by formula II as a raw material is halogenated to give a halide expressed by formula III (Hal is halogen), which is then reacted with an optically active compound expressed by formula IV to afford the aimed compound expressed by formula I (X is -CH2O-).

5. 发明专利

JPS59118744A Liquid crystal substance and liquid crystal composition 失效
标题翻译：液晶物质和液晶组合物
公开(公告)号：JPS59118744A
公开(公告)日：1984-07-09
申请号：JP23456182
申请日：1982-12-25
申请人： Chisso Corp , Hitachi Ltd
发明人： INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KENJI , SAITOU SHINICHI , ISOGAI MASATO , HATSUTORI SHINTAROU , IWASAKI KISHIROU , KITAMURA TERUO , KOUBI AKIO
IPC分类号： C07C69/94 , C09K19/12 , C09K19/46 , G02F1/13 , G09F9/00
摘要： NEW MATERIAL:The compound of formula (R is alkyl; R* is optically active group having asymmetric carbon atom).
EXAMPLE: 4-Octyloxy-4-biphenylcarboxylic acid 2-methylbutyl ester.
USE: A ferroelectric liquid crystal component having photochemical and chemical stability. When mixed with other liquid crystal compound, the temperature range of the composition exhibiting ferroelectricity can be lowered near to room temperature. The ferroelectric composition can be utilized for a display device taking advantage of the photo-switching phenomenon of ferroelectric liquid crystal, and a high-speed photo-switching having a response time of about 1 m-sec can be attained.
PROCESS: The compound of formula I can be prepared by converting 4-alkyloxy- 4'-biphenylcarboxylic acid to an acid halide with a halogenation agent such as thionyl chloride, phosphorus pentachloride, etc., and reacting the halide with an optically active alcohol in e.g. pyridine.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：式（R是烷基; R *是具有不对称碳原子的光学活性基团）的化合物。实施例：4-辛氧基-4-联苯基羧酸2-甲基丁酯。用途：具有光化学稳定性和化学稳定性的铁电液晶成分。当与其它液晶化合物混合时，显示铁电性的组合物的温度范围可以接近于室温降低。利用铁电液晶的光电转换现象，可以将铁电体组合物用于显示装置，并且可以获得响应时间约1m-sec的高速光电转换。方法：式I化合物可以通过用卤化剂如亚硫酰氯，五氯化磷等将4-烷氧基-4'-联苯羧酸转化为酰卤，并将卤化物与光学活性醇反应制备例如吡啶。

6. 发明专利

JPS60199865A LIQUID CRYSTAL COMPOUND 失效
公开(公告)号：JPS60199865A
公开(公告)日：1985-10-09
申请号：JP5587484
申请日：1984-03-23
申请人： HITACHI LTD , CHISSO CORP
发明人： HATSUTORI SHINTAROU , ISOGAI MASATO , IWASAKI KISHIROU , KITAMURA TERUO , KOUBI AKIO , INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KENJI , SAITOU SHINICHI
IPC分类号： C09K19/22 , C07C67/00 , C07C241/00 , C07C251/24 , C09K19/48 , G02F1/13
摘要： NEW MATERIAL:A liquid crystal compound of the formula (R is alkyl, alkoxy of 20 or less carbon atoms; R* is optically active group including asymmetric carbon; m, n are natural numbers). EXAMPLE:p-(2-Methylbutoxycarbonyl)-benzylidene-p'-methylaniline. USE:A component of liquid crystal: it shows ferroelectric liquid crystal and has high stability to light and high-speed response. PREPARATION:For example, an acid chloride is obtained from 4-formylbenzoic acid and thionyl chloride and the product is allowed to react with S(-)-2-methylbutanol in pyridine to give p-(2-methylbutoxycarbonyl)-benzaldehyde. The reaction of the product with p-n-tetradecyloxyaniline gives the compound shown in the formula.

7. 发明专利

JPS59219251A LIQUID CRYSTAL SUBSTANCE AND LIQUID CRYSTAL COMPOSITION 失效
公开(公告)号：JPS59219251A
公开(公告)日：1984-12-10
申请号：JP7859483
申请日：1983-05-04
申请人： CHISSO CORP
发明人： INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KENJI , SAITOU SHINICHI
IPC分类号： C07C69/017 , C09K19/12 , C09K19/20 , C09K19/30 , C09K19/46 , G02F1/13
摘要： NEW MATERIAL:The compound of formula (m is 0, 1 or 2; R labelled with *is optically active alkyl; ring A is 1,4-phenylene or 1,4-transsubstituted cyclohexylene; X is 1-18C straight- or branched-chain alkyl or alkoxy). EXAMPLE:4'-(2-Methylbutyloxy)-4-n-pentanoyloxybiphenyl. USE:Chiral smectic liquid crystal substance. PREPARATION:The objective compound can be prepared by converting 4,4'- dihydroxybiphenyl to its monoether with an optically active alkyl halide or an optically active alkyl p-toluenesulfonate, and reacting the obtained monoether with a fatty acid halide, p-alkylbenzoyl halide, etc. corresponding to the objective compound, in a basic solvent such as pyridine.

8. 发明专利

JPS6092276A PYRAZINE DERIVATIVE 失效
公开(公告)号：JPS6092276A
公开(公告)日：1985-05-23
申请号：JP20142983
申请日：1983-10-27
申请人： CHISSO CORP
发明人： INOUE HIROMICHI , SAITOU SHINICHI , TERAJIMA KENJI , INUKAI TAKASHI , FURUKAWA KENJI
IPC分类号： C09K19/34 , C07D241/18 , C09K19/42 , G02F1/13
摘要： NEW MATERIAL:The compound of formula I (R is 1-18C straight or branched chain alkyl; j, k, l and m are 0 or 1; n is 1, 2 or 3; formula II is optically active carbon atom). EXAMPLE:(S)2-p-Octylbenzoyloxy-5-(2-methylbutyloxyphenyl)pyrazine. USE:A liquid crystal substance exhibiting chiral smectic phase and suitable as a display system utilizing the ferroelectric property, e.g. optical switching element, etc. It can be mixed to another compound to expand the temperature range exhibiting chiral smectic phase, adjust the pitch of the chiral smectic crystal or prevent the formation of reverse domain. PREPARATION:The compound of formula I can be produced by (1) reacting the compound of formula II with an alkyl halide having optically active carbon atom, (2) oxidizing the resultant compound of formula III to obtain the compound of formula IV, (3) reacting the product with glycinamide hydrochloride, and (4) reacting the obtained compound of formula V with the compound of formula VI.

9. 发明专利

JPS59128357A Liquid crystal substance and liquid crystal composition 失效
标题翻译：液晶物质和液晶组合物
公开(公告)号：JPS59128357A
公开(公告)日：1984-07-24
申请号：JP64083
申请日：1983-01-06
申请人： Chisso Corp
发明人： INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KANEFUMI , SAITOU SHINICHI
IPC分类号： C07C69/773 , C07C69/92 , C07C69/94 , C09K19/20 , C09K19/42 , G02F1/13 , G09F9/00
摘要： NEW MATERIAL:A compound shown by the formula (m is 1 or 2; X is 4W18C alkoxy when m is 1, and 1W18C alkoxy or alkyl when m is 2; * is optically active carbon).
EXAMPLE: p-n-Dodecyloxybenzoic acid-p'-(2-methylbutyloxy) phenyl ester.
USE: A liquid crystal substance. Having an optically active group, showing chiralsmectic A phase and C phase. Having high-speed response properties, improved light switching effect, suitable for graphic display.
PROCESS: Hydroquinone mono(optically active 2-methylbutyl)ether is treated with a p-alkoxybenzoic acid halide, 4-(p-alkoxyphenyl) benzoic acid halide or 4-(p- alkylphenyl)benzoic acid halide in a basic solvent such as pyridine, etc., to give a compound shown by the formula I .
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：当m为1时，式（m为1或2; X为4-18C烷氧基，m为2时为1-18C烷氧基或*为光学活性碳）为一种化合物。实施例：对 - 正十二烷氧基苯甲酸-p' - （2-甲基丁氧基）苯酯。用途：液晶物质。具有光学活性基团，显示出致动脉粥样硬化A期和C期。具有高速响应特性，改善了光切换效果，适合图形显示。方法：在碱性溶剂如吡啶中用对烷氧基苯甲酰卤，4-（对烷基苯基）苯甲酰卤或4-（对烷基苯基）苯甲酸卤化物处理氢醌单（光学活性2-甲基丁基）醚等，得到式I所示的化合物。

10. 发明专利

JPS60163845A LIQUID CRYSTAL CARBONIC ACID ESTER DERIVATIVE 失效
公开(公告)号：JPS60163845A
公开(公告)日：1985-08-26
申请号：JP1808684
申请日：1984-02-03
申请人： CHISSO CORP
发明人： INOUE HIROMICHI , SAITOU SHINICHI , TERAJIMA KENJI , INUKAI TAKASHI , FURUKAWA KENJI
IPC分类号： C09K19/20 , C07C69/96 , G02F1/13
摘要： NEW MATERIAL:A compound shown by the formula I (R1* is 4-8C optically active alkyl; R2 is 1-18C alkyl or alkoxy; l and m are 1 or 2). EXAMPLE:S-(p-2-Methylbutyloxycarboxyloxy)benzoic acid-p-nonyloxy-p'-biphenyl ester. USE:A chiral smectic liquid crystal substance. PREPARATION:A compound shown by the formula II is reacted with a compound shown by the formula III in the presence of pyridine to give a compound shown by the formula IV, group CHO is converted into COOH, and then into COCl, and the resultant compound is reacted with a compound shown by the formula V in the presence of pyridine to give a compound shown by the formula I where l=1.

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