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    • 3. 发明授权
    • Atomic absorption photometer
    • 原子吸收光电测定仪
    • US3680960A
    • 1972-08-01
    • US3680960D
    • 1971-05-25
    • HITACHI LTD
    • UCHINO KOICHIINOMATA HIROSHI
    • G01N21/31G01J3/42
    • G01N21/3103
    • An atomic absorption photometer in which an electrical signal representative of the beam of light passed through a flame is integrated by an integrator, and an electrical signal representative of the emission spectrum peculiar to the flame is differentiated by a differentiator to be utilized as an integration starting signal. The photometer is provided with means for generating an electrical signal in response to the introduction of a standard sample into the flame and ceasing to generate the electrical signal in response to the introduction of a sample to be examined into the flame due to the fact that the emission spectrum of a particular substance in the sample to be examined appears when it is introduced into the flame. The photometer is further provided with means which generates an electrical signal in response to the application of both the electrical signal generated by said means and the output from the differentiator thereby offering a zero adjustment of the light absorbance.
    • 其中表示通过火焰的光束的电信号被积分器集成的原子吸收光度计,并且表示火焰特有的发射光谱的电信号被微分器区分,以用作积分开始 信号。 光度计具有用于响应于将标准样品引入火焰而产生电信号的装置,并且响应于将要检查的样品引入到火焰中而停止产生电信号,这是由于以下事实: 待检查的样品中的特定物质的发射光谱在其被引入火焰中时出现。 光度计进一步具有响应于由所述装置产生的电信号和微分器的输出两者产生电信号的装置,从而提供光吸收率的零调整。
    • 8. 发明专利
    • ATOMIC ABSORPTION ANALYZER
    • JPS63118636A
    • 1988-05-23
    • JP1201286
    • 1986-01-24
    • HITACHI LTDHITACHI INSTRUMENTS ENG
    • OISHI KONOSUKEUCHINO KOICHIYAMADA HIDEOKAMITAKE SEIGOHASHIMOTO MASAO
    • G01N21/31
    • PURPOSE:To permit analysis of a high-concn. sample by obtaining an atomic absorbancy versus time curve, preliminarily determining the time width at 1/2 the max. value of the absorbancy of that curve, measuring the arbitrary absorbancy of a sample and making computation. CONSTITUTION:A sample is heated by a graphite tube to form atomic vapor and a luminous flux is passed through the vapor. The absorbancy by the atomic vapor is detected and the absorbancy versus time curve P is is obtd. The half- amplitude level (w) of the time at the absorbancy of 1/2 the max. value (h) of the absorbancy in the absorbancy versus time curve P is constant regardless of an element concn. The arbitrary absorbancy (k) and time width (v) of the absorbancy versus time curve P is determined with respect to a desired element and the true max. value (h) of the absorbancy is computed by the equation to analyze the concn. The computation is made by using the half-amplitude level (w) even if the concn. of the desired element is high and the high absorbancy of the absorbancy versus time width curve rolls over; therefore, the measurable upper limit concn. of the element is increased.
    • 9. 发明专利
    • JPH0310075B2
    • 1991-02-12
    • JP5217784
    • 1984-03-21
    • HITACHI LTD
    • UCHINO KOICHIHAMANO YOSHIMASA
    • B01D15/08G01N30/86
    • In a method of analyzing a sample by measuring retention time of the components of the sample, a method of ananlysis by chromatogram which displays schematic chromatograms related to particular fillers and particular object components to be analyzed, relying upon the retention time and half widths of various object components to be analyzed that have been stored and are related to various fillers to be charged into the separation column. The invention further deals with a chromatogram analysis apparatus comprising means which stores the retention time and half widths of objects components to be analyzed related to various fillers that are to be charged into the separation column, and means which prepares schematic chromatograms related to particular fillers. Schematic chromatograms are displayed to efficiently and quickly select a filler that is suited for the analysis of saccharide. The apparatus for analysis can be used independently, or as a component of the chromatograph data processor.
    • 10. 发明专利
    • FLUORESCENT ANALYSIS INSTRUMENT
    • JPS6212842A
    • 1987-01-21
    • JP15024985
    • 1985-07-10
    • HITACHI LTD
    • UCHINO KOICHIMINEGISHI HISAKO
    • G01N21/64G01N21/65
    • PURPOSE:To make exact measurement by executing normalization with the peak value of Raman light as a reference. CONSTITUTION:The ray radiated from a light source 1 is divided by an optical pumping side spectroscope 2 and is irradiated to the pure water of a sample cell 3. The fluorescence and Raman light generated from the pure water are made incident on a fluorescent side spectroscope 4. The light divided by the same is detected by a detector 5. The spectroscope 4 has a wavelength scanning function, by which the intended wavelength range is scanned. The spectral intensities at the respective wavelengths are stored in a storage device 6. The normalization over the entire part of the spectra is executed by an arithmetic unit 7 with the peak value of the Raman spectra of the water as the reference when the scanning in the intended wavelength region ends. Since the fluorescence is measured with the Raman light intensity as a reference in the above- mentioned manner, the influence by equipment factors such as the intensity of the light source lamp and detector sensitivity is eliminated and the concn. of the org. impurities in the pure water is exactly measured.