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    • 2. 发明专利
    • ELECTROCHEMILUMINESCENCE ANALYTICAL EQUIPMENT
    • JPH11352063A
    • 1999-12-24
    • JP16179198
    • 1998-06-10
    • HITACHI LTD
    • TOMITA HIROYUKIMIYAHARA YUJIKAJIYAMA TOMOHARUNINOMIYA TAKESHI
    • G01N21/76
    • PROBLEM TO BE SOLVED: To automatically analyze according to an ECL method with the use of a batch system by using a container, a part of which passes a light and an electrode rod of a shape having a similar section to the container and a front face agreeing with a bottom face of the container. SOLUTION: A working electrode 31, counter electrode 32 are set at a lower face. A reference electrode 33 is preferably set separately to control a potential of the working electrode 31. A reaction vessel 1 and an electrode rod 9 are formed nearly the same in section form. A recess is formed at a central part of the rod 9 for preventing a solution from leaking from the reaction vessel 1, when the electrode rod 9 is pressed to the vessel 1. The electrode 31 and the electrode 32 are connected respectively by a wire 35 to a working electrode terminal 36 and a counter electrode terminal 37. A strut 34 of the electrode rod 9 works also as a terminal for the electrode 33. The strut 34, terminal 36, terminal 37 are separated from each other by an insulating body 38 for preventing short-circuiting. The rod 9 is fixed by forming a hole for the electrodes 31 and 32 in a circular resin bar 39, warming the resin bar 39 and inserting the rod into the hole. The electrodes 31, 32 are preferably flush with each other.
    • 7. 发明专利
    • METHOD AND APPARATUS FOR ANALYZING WITH X-RAYS
    • JPH07318521A
    • 1995-12-08
    • JP10812794
    • 1994-05-23
    • HITACHI LTD
    • HASEGAWA MASAKININOMIYA TAKESHI
    • G01N23/227
    • PURPOSE:To improve energy resolution and to accurately analyze a chemical state by condensing exciting lights in a region of the size of a predetermined diameter or less on a sample surface by using an optical element. CONSTITUTION:In order to fall the entire energy analyzer within the inner diameter of a standard tube which can be connected to an ICF253 flange, the radius of a semispherical grid 2 is set to 40mm, and the diameter of its opening A is set to its 1%, and hence it becomes about 40mum. Then, when a radiant light from a normal deflecting electromagnet is, for example, limited by a pinhole as a light source (size of about 600mumPHI), a Walter reflecting mirror having a contraction ratio of l/30 is used as an exciting light condensing optical element 4, and the light is incident on the surface of a sample S at an angle of 25 degrees, even if an irradiating area is limited to the 1/10 (about 40mum) or less of the diameter of the opening A, sufficient quantity of the exciting light can be radiated to the sample S. Accordingly, the irradiating area can be reduced from the size of the opening A without remarkably attenuating the intensity of the incident exciting light, thereby improving its energy resolution.
    • 8. 发明专利
    • X-RAY ANALYZER
    • JPH07260714A
    • 1995-10-13
    • JP5546694
    • 1994-03-25
    • HITACHI LTD
    • NINOMIYA TAKESHIHASEGAWA MASAKI
    • G01N23/22
    • PURPOSE:To make it possible to execute fine regulation of an optical element for convergence of an X ray easily and in a short time by a method wherein a two-dimensional image detector for detecting a sectional image of a convergent X ray is disposed on the optical axis of the X ray. CONSTITUTION:An image detector 1 and a sample support stage 5 are disposed for the main body of equipment through the intermediary of a moving mechanism 2 or 7 so that they can be inserted into and removed from the focal position of an X ray in a replacing manner. In the case when an imaging system of an optical element 9 is regulated, the sample support stage 5 is withdrawn from the focal position by operating the moving mechanism 7 and then the image detector 1 is inserted into the focal position by operating the moving mechanism 2. Information on a two-dimensional image detected by the image detector 1 is processed by using an image processing device 3 and then displayed as a sectional image of a convergent X ray on the screen of a monitor thereof. By operating a controller 11 while observing the sectional image of the convergent X ray, accordingly, a manufacturer or a user of the equipment can regulate the optical element 9 finely to be in the optimum condition through the intermediary of a regulating mechanism 10.
    • 10. 发明专利
    • METHOD AND APPARATUS FOR ANALYZING SURFACE
    • JPH05126769A
    • 1993-05-21
    • JP28756691
    • 1991-11-01
    • HITACHI LTD
    • HASEGAWA MASAKININOMIYA TAKESHI
    • G01N23/223G01R31/26G01R31/302H01L21/66
    • PURPOSE:To make it possible to perform the automatic focusing of a probe beam on the surface of a sample and to make the analysis of the surface of a minute area highly accurate by detecting the fluorescence region on the surface of the sample, and automatically adjusting the arrangement of each element of an optical system so that the size of the fluorescence region becomes the minimum size. CONSTITUTION:The fluorescence, which is formed by the application of a probe beam on the surface of a sample 3, is condensed with an optical element 2, which is similar to a condensing optical element. The beam is taken out of the optical axis of the element 2 with a reflecting mirror 9. The expanded image of a fluorescence generating region is formed on a detector 10. The two-dimensional image signal is converted into the numerical-value data with a signal processing device 11, and the data are sent into a control device 12. The device 12 moves a sample stage 4 so that the fluorescence region becomes the minimum size based on the diameter of the fluorescence region computed by using the data and the position data of the sample 3 inputted from a controller 6 of a sample moving mechanism 5 and optimizes the position of the sample 3. Thus, the converging point of the probe beam can be automatically focused on the surface of the sample, and the surface of the minute area can be readily analyzed highly accurately.