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1. 发明专利

JPS6023402A POLYMERIZATION OF ORIENTATED HIGH POLYMER MATERIAL 失效
公开(公告)号：JPS6023402A
公开(公告)日：1985-02-06
申请号：JP12940883
申请日：1983-07-18
申请人： HITACHI LTD
发明人： ARAYA KOUTAROU , TSUNODA ATSUSHI , MORI YASUKI , KOUBI AKIO
IPC分类号： C08F2/00 , C08F2/34 , C08F2/44 , C08F4/639 , C08F4/68 , C08F4/72 , C08F10/00 , C08F10/02 , C08F38/00 , C08F38/02
摘要： PURPOSE:In polymerizing a raw material monomer in a gaseous state at normal temperature under normal pressure by bringing it into contact with a polymerization catalyst, to obtain a novel high polymer material having high degree of orientation and improved characteristics, by carrying out partially polymerization in a state wherein the monomer is in contact with a liquid crystal substance. CONSTITUTION:In polymerizing a raw material monomer (e.g., ethylene, etc.) in a gaseous state at normal temperature under normal pressure by bringing it into contact with a polymerization catalyst (e.g., Ziegler-Natta catalyst, etc.)., the polymerization is at least partially carried out by bringing the gaseous monomer into contact with a liquid crystal substance [e.g., 4-(trans-4-n-propylcyclohexyl)- ethoxybenzene, etc.], to give the desired polymer. The layer of the liquid crystal substance has preferably a free surface.

2. 发明专利

JPS58182640A Electrophotographic receptor of composite type 失效
标题翻译：复合型电摄影受体
公开(公告)号：JPS58182640A
公开(公告)日：1983-10-25
申请号：JP6696482
申请日：1982-04-20
申请人： Hitachi Ltd
发明人： TSUNODA ATSUSHI , OKA HIROYUKI , SUZUKI SHIGEO , ARAYA KOUTAROU , MORI YASUKI , MORISHITA YASUSADA
IPC分类号： C09B23/01 , C09B23/14 , C09B47/30 , C09B67/22 , C09B67/48 , G03G5/047 , G03G5/06
CPC分类号： C09B23/145 , C09B23/0091 , C09B47/30 , C09B67/0025 , C09B67/0035 , G03G5/047 , G03G5/06 , G03G5/0631 , G03G5/0637 , G03G5/067 , G03G5/0696
摘要： PURPOSE: To obtain the entitled photoreceptor having high sensitivity even to long wavelength light, by forming a charge generating substance layer contg. a γ-type or η-type metal-free phthalocyanine and a charge transfer substance layer contg. a styryl type dye on a conductive substrate.
CONSTITUTION: A 0.1W20μm thick charge generating substance layer consisting of 100pts.wt. binder resin, such as phenolic resin, and 20W200pts.wt. γ-type or η-type metal-free phthalocyanine having ≤5μm particle diameter, and a 5W 100μm thick charge transfer substance layer contg. 1pt.wt. binder resin, and 0.5W 4pts.wt. styryl type dye having formula I (X is one of formulae IIWV and an optionally substd. hetero ring; Z is O or S; n is 0, 1, or 2; and R
1 , R
2 are each ≤3C alkyl) are formed on a conductive substrate.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：为了获得即使对于长波长光也具有高灵敏度的标题感光体，通过形成电荷产生物质层， γ型或eta型无金属酞菁和电荷转移物质层，在导电基材上的苯乙烯基型染料。构成：0.1-20μm厚的电荷产生物质层，由100pts.wt。粘合剂树脂，如酚醛树脂，和20-200pts.wt。具有≤5μm粒径的γ型或eta型无金属酞菁，以及5-100μm厚的电荷转移物质层。 1pt.wt. 粘合剂树脂，和0.5-4pts.wt。具有式I的苯乙烯基型染料（X是式II-V和任选取代的杂环之一; Z是O或S; n是0,1或2;并且R 1，R 2各自为<= C 3烷基）形成在导电基板上。

3. 发明专利

JPS58182639A Electrophotographic receptor 失效
标题翻译：电子摄影受体
公开(公告)号：JPS58182639A
公开(公告)日：1983-10-25
申请号：JP6696382
申请日：1982-04-20
申请人： Hitachi Ltd , Toyo Ink Mfg Co Ltd
发明人： TSUNODA ATSUSHI , OKA HIROYUKI , SUZUKI SHIGEO , ARAYA KOUTAROU , MORI YASUKI , MORISHITA YASUSADA , TAKANO SHIGEMASA , SAWADA MANABU , KUMANO ISAO
IPC分类号： C09B23/06 , C09B23/14 , C09B47/04 , C09B47/073 , C09B47/10 , C09B47/16 , C09B47/26 , C09B47/30 , C09B67/12 , C09B67/22 , C09B67/50 , G03G5/06
CPC分类号： C09B47/30 , C09B23/06 , C09B23/145 , C09B47/073 , C09B47/10 , C09B47/16 , C09B47/26 , C09B67/0016 , C09B67/0026 , C09B67/0035 , G03G5/0696
摘要： PURPOSE: To obtain the entitled photoreceptor high in sensitivity to long wavelength light, by forming a layer consisting of a charge generating substance and a charge transfer substance contg. a γ-type and/or a η-type metal-free phthalocyanine on a conductive substrate.
CONSTITUTION: A mixture of (A) 100pts.wt. metal-free phthalocyanine, and (B) 0W50pts.wt. metal-free phthalocyanine having substituents on benzene rings, phthalocyanine nitrogen compd. having same structure, and benzene rings optionally substd., and/or metallophthalocyanine is dispersed into a liquid dispersion medium, and their crystalline structures are converted by applying mechanical shearing force while heating them below the decomposition temp. of the component (A) or said mixture, to convert the crystalline structures and to obtain a γ-type or η-type metal-free phthalocyanine (C). A 0.1W20μm thick charge generating layer contg. the component (C), and a 5W100μm thick charge transfer layer contg. a compd. having formula I (X is a hetero ring of one of formulae IIWV; Z is O or S; n is 0,1, or 2; and R
1 , R
2 ) are formed on a conductive substrate.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：通过形成由电荷产生物质和电荷转移物质组成的层，以获得对长波长光的敏感度高的标签感光体。导电基底上的γ型和/或eta型无金属酞菁。构成：（A）100pts.wt。无金属酞菁，（B）0-50pts.wt。在苯环上具有取代基的无金属酞菁，酞菁氮化合物具有相同的结构，并且苯环任选被分解，和/或金属酞菁分散到液体分散介质中，并且通过施加机械剪切力同时将它们的结晶结构加热到分解温度以下来转化。的组分（A）或所述混合物，以转化晶体结构并获得γ型或eta型无金属酞菁（C）。 0.1-20μm厚的电荷产生层，组分（C）和5-100μm厚的电荷转移层，一个compd 具有式I（X是式II-V之一的杂环; Z是O或S; n是0,1或2;以及R 1，R 2）形成在导电基底上。

4. 发明专利

JPS60255806A PRODUCTION OF ACETYLENE POLYMER 失效
公开(公告)号：JPS60255806A
公开(公告)日：1985-12-17
申请号：JP11077584
申请日：1984-06-01
申请人： HITACHI LTD
发明人： ARAYA KOUTAROU , KOUBI AKIO , TSUNODA ATSUSHI , MORI YASUKI
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F4/659 , C08F4/80 , C08F38/00 , C08F138/02
摘要： PURPOSE:To produce a uniaxially orientated acetylene high polymer having electrical and optical anisotropy, by polymerizing acetylene on the free surface of an orientated liquid crystal substance containing a Zoegler-Natta catalyst. CONSTITUTION:A Ziegler-Natta catalyst is added to a liquid crystal substance, e.g., a mixture of 4-(trans-4-propyl-cyclohexyl)ethoxybenzene with 4-(trans-4-n- propylcyclohexyl)-butoxybenzene, so that the resulting mixture may contain 0.001-0.1mol/l of the transition metal compound. This mixture is added dropwise to a substrate having an adherent polymer film subjected to unidirectional rubbing to orientate the liquid crystal substance. Acetylene gas is polymerized by contact with the surface of this liquid crystal substance.

5. 发明专利

JPS6019153A ELECTROPHOTOGRAPHIC SENSITIVE BODY 失效
公开(公告)号：JPS6019153A
公开(公告)日：1985-01-31
申请号：JP12619483
申请日：1983-07-13
申请人： HITACHI LTD , TOYO INK MFG CO
发明人： TSUNODA ATSUSHI , OKA HIROYUKI , SUZUKI SHIGEO , ARAYA KOUTAROU , MORI YASUKI , MORISHITA YASUSADA , TAKANO SHIGEMASA , SAWADA MANABU , KUMANO ISAO
IPC分类号： C09B47/30 , G03G5/06 , H01L31/08
摘要： PURPOSE:To form an electrophotographic sensitive body high in sensitivity to semiconductor laser beams by using specified deformed metal-free phthalocyanine as an electrostatic charge generating substance. CONSTITUTION:An electrophotographic sensitive body is obtained by laminating on a conductive substrate a

6. 发明专利

JPS58184948A Electrophotographic organic photoconductive composition 失效
标题翻译：电子有机光电复合材料
公开(公告)号：JPS58184948A
公开(公告)日：1983-10-28
申请号：JP6742582
申请日：1982-04-23
申请人： Hitachi Ltd
发明人： SUZUKI SHIGEO , TSUNODA ATSUSHI , OKA HIROYUKI , ARAYA KOUTAROU , MORI YASUKI , MORISHITA YASUSADA
IPC分类号： C09K3/16 , G03G5/06
CPC分类号： G03G5/0609 , G03G5/0664
摘要： PURPOSE:To obtain an electrophotographic organic photoconductive compsn. having superior chargeability and sensitivity characteristics and no doubt of carcinogenicity, by mixing an electron acceptor having reduction potential in a specified range, and a phthalocyanine pigment with an electron donative org. polymer photoconductor each in a specified range of proportion. CONSTITUTION:Poly-N-vinyl carbazole is superior economically, mechanically, chemically, and electrically and it is preferable as an org. polymer photoconductor having electron donative property. As an electron acceptor, a compd. represented by general formula I or II having a reduction potential of -0.3-10V is used in an amt. of 0.8-8pts.wt. per 10pts.wt. of the org. polymer photoconductor. Above or below this range, especially photosensitivity is deteriorated. Hydrogen in the formulae may be substd. by Cl, Br, NO,
摘要翻译：目的：获得电子照相有机光电导体。通过混合具有规定范围的还原电位的电子受体和具有电子给体组合物的酞菁颜料，具有优异的带电性和灵敏度特性，无疑具有致癌性。聚合物感光体各自以规定的比例范围。构成：聚-N-乙烯基咔唑的经济性，机械性，化学性和电学性优越，优选作为组织。具有电子供体性质的聚合物感光体。作为电子受体，由具有-0.3-10V的还原电位的通式I或II表示。为0.8-8pts.wt。每10pts.wt 的组织。聚合物感光体。高于或低于该范围，特别是光敏性恶化。式中的氢可以被取代。通过Cl，Br，NO，<= 4C烷基等。向该电荷转移络合物中进一步加入0.06-6pts.wt。酞菁颜料/ 10pts.wt。的光电导体，并且低于0.06pt.wt.，灵敏度降低，并且高于6pts.wt。电晕充电后黑暗中的电荷保持性降低。

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