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1. 发明申请

WO02055042A2 DEVELOPER/ DEVELOPER HYBRID DYES AND HYBRID DYE PRECURSORS 审中-公开
标题翻译：开发商/开发商杂交染料和杂交染料产品
公开(公告)号：WO02055042A2
公开(公告)日：2002-07-18
申请号：PCT/EP0200016
申请日：2002-01-03
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST , HOLLENBERG DETLEF
发明人： NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST , HOLLENBERG DETLEF
IPC分类号： A61K8/49 , A61Q5/10 , A61K7/13 , C09B57/00
CPC分类号： A61K8/494 , A61K8/4926 , A61Q5/10
摘要： Hybrid dyes of structure (I), X-S-Y (I) in which X and Y are each derived from various oxidation dye precursors of the developer type and S is a direct bond or at least one spacer group, are especially suitable for colouring keratin fibres, in particular, human hair. By the use of colouring agents with the above dyes, a series of problems which occurs with the use of complex dye mixtures, can be avoided or significantly reduced.
摘要翻译：结构（I）的混合染料，XSY（I）其中X和Y各自从显影剂类型的不同的氧化染料前体衍生的，和S代表直接键或至少一个间隔基团，非常适合用于着色角蛋白纤维，特别是人的头发，通过与这些染料一起使用着色剂，使用复杂的Fabstoffmischunchungen时发生的一些问题规避或显着减少。

2. 发明申请

WO0209662A3 AGENT FOR DYEING KERATIN CONTAINING FIBERS 审中-公开
标题翻译：手段垂死角蛋白纤维
公开(公告)号：WO0209662A3
公开(公告)日：2002-06-27
申请号：PCT/EP0108656
申请日：2001-07-26
申请人： HENKEL KGAA , ROSE DAVID , NAUMANN FRANK , MEINIGKE BERND , HOEFFKES HORST
发明人： ROSE DAVID , NAUMANN FRANK , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/49 , A61Q5/10 , D06P1/642 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494
摘要： The invention relates to an agent for dyeing keratin containing fibers which comprises as the developer at least one compound of the general formula (I), wherein R1 and R2 are the same or different and represent hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, and R3 represents a group of the formula (II), wherein R4 represents a piperazinyl group or a group -NR7(CH2)n-NR7, wherein R7 represents hydrogen or C1-4 alkyl and n is an integer of from 1 to 4, R5 and R6 are the same or different and represent hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, or else R3 represents a group (III), or a group (IV), wherein R9 represents hydrogen, C1-4 alkyl or C1-4 hydroxyalkyl, Y represents a direct bond or a straight-chain or branched C1-5 alkylene group, and A represents a saturated or unsaturated 5-, 6- or 7-membered ring optionally containing one or more heteroatoms, a group -CO-NH2, a C1-4 alkoxy group or a C1-4 dialkylamino group, wherein A may be linked with any carbon atom of the alkylene group Y.
摘要翻译：有权利用于着色包含角蛋白的纤维，其包括组合物，如显影剂部件的至少一个具有通式（I）可以是相同的或不同的，其中R1和R2，并且表示氢，C 1-4烷基或C 1-4化合物羟烷基和R 3是具有其中R 4表示哌嗪基或基团的式（II）的基团-NR 7（CH 2）n的NR 7，其中R 7是氢或C 1-4烷基，n是从一个整数 1至4可以是，R 5和R 6可以相同或不同，是氢，C 1-4烷基或C 1-4羟基烷基，基团（III）或一组（IV）其中R9是氢，C1 -4-烷基或C 1-4 - 羟基烷基，Y为直接键或直链或支链C 1-5 - 亚烷基，a是一个为饱和或不饱和的，任选地含有杂原子或更多5,6或7元环中，基团-CO-NH 2，C 1-4烷氧基或一个 ÈC1-4二烷基氨基，其中，A可以被链接到所述的亚烷基Y的任何碳原子

3. 发明申请

WO0076977A3 OXIDATION COLORANT STARTING PRODUCTS 审中-公开
标题翻译：氧化染料前体
公开(公告)号：WO0076977A3
公开(公告)日：2002-05-02
申请号：PCT/EP0005151
申请日：2000-06-06
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： C07D213/74 , A61K7/13
CPC分类号： C07D213/74 , A61K8/4926 , A61Q5/10
摘要： The invention relates to oxidation colorants for coloring keratin fibers, especially human hair. The inventive colorants contain, dissolved in a medium that is appropriate for coloring, at least one 2,5-diaminopyridine derivative of the general formula (I) wherein R and R may independently represent hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group or, together with the nitrogen atom to which they are bound, form an optionally substituted, saturated heterocyclic 5- or 6-membered ring that may contain another nitrogen atom or an oxygen atom, R is hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group, R and R independently represent hydrogen, a C1 to C4 alkyl group or a C3 to C8 cycloalkyl group, R and R independently represent hydrogen, a halogen atom, a C1 to C4 alkyl group, a C1 to C4 hydroxyalkyl group, a C1 to C4 aminoalkyl group or a C1 to C4 alkoxy group and n is 1 or 2, or a physiologically acceptable salt of the above compounds. The inventive agents are characterized by intense colorations especially in the red/brown range and by excellent color fastness properties.
摘要翻译：本发明涉及角蛋白纤维，特别是人的头发，在介质中的适当的染色，在通式（I），其中R <1>和R <2>独立地表示氢中的至少一种2,5-二氨基吡啶衍生物的氧化染色，站立或一个C1至C4烷基或与氮原子一C 1至C 4羟烷基一起形成它们所连接形成任选取代的饱和杂环含有一个额外的氮原子的5元或6元环，或一个可含有氧原子，R <3>代表氢，C1至C4烷基或C1-至C4-羟烷基是，R <4>和R <5>独立地为氢，C1至C4烷基或包括C3〜C8环烷基，R <6>和R <7>独立地是氢，卤原子，C1-C4烷基，一个C 1至C 4羟烷基，C1 至C4氨基烷基，或C1-C4烷氧基，n为1或2，或含有这些化合物的生理学上可接受的盐中的一种。新型组合物的特征在于强烈着色，尤其是在棕红色范围内具有优异的坚牢度性能，从。

4. 发明申请

WO0100142A3 DEVELOPER-COUPLER COMBINATIONS 审中-公开
标题翻译：开发商耦合器组合
公开(公告)号：WO0100142A3
公开(公告)日：2002-03-28
申请号：PCT/EP0005155
申请日：2000-06-06
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
发明人： NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10 , A61K7/13
CPC分类号： A61K8/347 , A61K8/415 , A61K8/4926 , A61Q5/10
摘要： The invention relates to oxidation colorants, used to colour keratin fibres, in particular, human hair, which contain the following in a medium suitable for coloration: (a) at least one pyridine derivative of the general formula (I), or one of the physiologically compatible salts of these compounds as the developer component; in said formula, R and R represent, independently of one another, hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group, or together with the nitrogen atom, to which they are bonded, form an optionally substituted, saturated heterocyclic 5 or 6 membered ring which can contain an additional nitrogen atom or an oxygen atom, R represents hydrogen, a C1 to C4 alkyl group or a C1 to C4 hydroxyalkyl group, R and R represent, independently of one another, hydrogen, a C1 to C4 alkyl group or a C3 to C8 cycloalkyl group, R and R represent, independently of one another, hydrogen, a halogen atom, a C1 to C4 alkyl group, a C1 to C4 hydroxyalkyl group, a C1 to C4 aminoalkyl group or a C1 to C4 alkoxy group and n is a whole number from 1 to 8; and (b) at least one specific coupler component.
摘要翻译：主题vorgliegenden发明涉及角蛋白纤维，特别是人的头发，在介质中的适合于染色的氧化染色：（1）通式（I），其中R <1>和R <2>独立地表示氢中的至少一种吡啶衍生物，站立或一个C1至C4烷基或与氮原子一C 1至C 4羟烷基一起形成它们所连接形成任选取代的饱和杂环含有一个额外的氮原子的5元或6元环，或一个 [R <3>代表氢，C1至C4烷基或C1可以含有氧原子，代表到C4羟烷基的基团R <4>和R <5>独立地为氢，C1至C4烷基或 C3是〜C8环烷基，R <6>和R <7>独立地是氢，卤原子，C1-C4烷基，一个C 1至C 4 - 羟烷基，C1至C4 氨基烷基基团或C1-C4烷氧基，n是从1到8，或这些化合物作为主要中间体和（b）至少一种特别的偶合剂成分的生理学上相容的盐之一的整数。

5. 发明申请

WO0121144A3 NEW DIRECT HAIR COLORANTS 审中-公开
标题翻译：新的直接染发剂
公开(公告)号：WO0121144A3
公开(公告)日：2001-10-11
申请号：PCT/EP0008774
申请日：2000-09-08
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
发明人： NAUMANN FRANK , ROSE DAVID , MEINIGKE BERND , HOEFFKES HORST
IPC分类号： A61K8/41 , A61Q5/06 , C07C211/29 , A61K7/13
CPC分类号： A61K8/418 , A61Q5/065
摘要： The invention relates to agents for dyeing and coloring keratin fibers, especially human hair. Said agents contain as the direct colorant at least one 2-nitro-p-phenylene diamine derivative of the formula (I), wherein R to R independently represent hydrogen, a C1-4 hydroxyalkyl group or a saturated, a mono- or polyunsaturated C7-8 ring that is optionally substituted with a C1-4 alkyl group, a halogen atom, a hydroxy group or an amino group, and X represents hydrogen or a halogen atom, with the proviso that at least one of the substituents R to R is a C7-8 ring. The inventive agents facilitate intensive colorations with excellent color fastness properties.
摘要翻译：本发明的目的是用于着色和着色角蛋白纤维，更具体地讲人的毛发，如直接染料，式（I）中的至少一种2-硝基 - 对苯二胺衍生物剂是在R <1>至R <4>彼此独立地代表氢，C 1-4羟烷基或可任选地用C 1-4烷基，卤素原子，羟基或氨基取代的饱和的，单或多不饱和的C 7-8环，X是氢或卤素原子，含有其条件是取代基R <1>至R中的至少一个<4>是一个C7-8环。根据本发明的装置使密集的颜色具有优异的牢度性能。

6. 发明申请

WO0197756A3 NOVEL COUPLING COMPONENT FOR OXIDATIVE HAIR DYES 审中-公开
标题翻译：新偶联剂成分氧化染料
公开(公告)号：WO0197756A3
公开(公告)日：2002-06-20
申请号：PCT/EP0106556
申请日：2001-06-09
申请人： HENKEL KGAA , NAUMANN FRANK , KLEEN ASTRID , HOEFFKES HORST , MEINIGKE BERND
发明人： NAUMANN FRANK , KLEEN ASTRID , HOEFFKES HORST , MEINIGKE BERND
IPC分类号： A61K8/00 , A61K8/41 , A61K8/49 , A61K8/66 , A61K8/67 , A61Q5/04 , A61Q5/08 , A61Q5/10 , D06P3/08 , A61K7/06 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/673 , A61Q5/04 , A61Q5/08
摘要： The invention relates to a method for dyeing keratin fibers, especially human hair. The inventive method comprises the following steps: optionally applying a pretreatment agent M1 to the fiber, using a dye M2 on the fiber which is optionally mixed immediately before application to the fiber from a component M2a, containing at least one oxidative dye pre-product of the developer type and/or an indole and/or indole derivative and a component M2b, containing an oxidative dye and/or an enzyme. If desired, a third agent M3 is added to the individual agents M2a or M2b before mixing them or to the mixture M2, and said dye M2 is rinsed from the fiber after a period of 5-30 minutes. At least one of the agents M1, M2a, M2b or M3 contains a compound from the vitamin B6 group. The invention further relates to hair pretreatment agents, to agents for dyeing keratin fibers, to their packing in corresponding kits and to the use thereof. The inventive compounds of the vitamin B6 group and their physiologically acceptable salts are useful as coupling components in the production of oxidative dyes that contain conventional developer and/or coupling compounds and/or indole and/or indole derivatives in a substrate appropriate for dyeing. The inventive compounds are further useful as active substances that improve the hair structure.
摘要翻译：本发明提供了一种用于染色角蛋白纤维，特别是人的头发，其中，如果需要，一个预处理装置（M1）被施加到纤维上，然后将着色剂（M2）发生在使用，任选立即应用程序之前，所述纤维从一个组分，其包含所述显影剂的类型和/或吲哚中的至少一种氧化染料前体纤维（M2A）和/或吲哚啉衍生物和组分（M2b的）含有氧化剂和/或酶进行混合，如果需要的话，个别装置（M2A）或（M2b型）混合或加入的混合物（M2）的另一装置（M3），该着色剂（M2）之前的从纤维5-30分钟的时间后退绕，其特征在于至少一个包括装置（M1，M2A，M2b的或M3）从维生素B6组中的至少一种化合物。本发明的另一个目的是一种毛发预处理剂，用于染色角蛋白纤维，和它们在相应的试剂盒和其用途的包装。维生素B6组的和新化合物及其生理上可接受的盐是作为用于生产氧化着色剂与常规的开发者和/或成色剂化合物和/或吲哚和/或二氢吲哚衍生物在适当的染色介质中的内容耦合部件是有用的。此外，本发明的化合物作为用于改善毛发结构剂。

7. 发明申请

WO02055609A2 INDOLE/INDOLINE BASED HYBRID DYES AND INDOLE/INDOLINE BASED HYBRID DYE INTERMEDIATE PRODUCTS 审中-公开
标题翻译：吲哚/吲哚啉混合染料和-HYBRIDFARBSTOFFVORPRODUKTE
公开(公告)号：WO02055609A2
公开(公告)日：2002-07-18
申请号：PCT/EP0200013
申请日：2002-01-03
申请人： HENKEL KGAA , HOLLENBERG DETLEF , NAUMANN FRANK , HOEFFKES HORST , ROSE DAVID
发明人： HOLLENBERG DETLEF , NAUMANN FRANK , HOEFFKES HORST , ROSE DAVID
IPC分类号： C07D401/04 , A61K8/00 , A61K8/18 , A61K8/46 , A61K8/49 , A61Q1/00 , A61Q1/02 , A61Q5/00 , A61Q5/10 , C07D209/08 , C09B57/00 , C09B67/42 , C09B69/00 , D06P1/32 , D06P3/08 , C09B
CPC分类号： A61K8/492 , A61K8/4926 , A61Q5/10 , C09B69/00
摘要： The invention relates to indole and indoline based hybrid dyes and indole and indoline based hybrid dye intermediate products having a structure (I): X - S - Y; wherein X represents a group which is derived from a derivative of indole or indoline as a precursor of melanin; Y represents a group which is derived from an oxidation dye based intermediate product of a coupler or developer variety, or a derivative of indole or indoline as a precursor of melanin; and S represents a structural element which is a common component of groups X and Y, a direct bond or at least one spacer group. The inventive products are particularly suitable for dyeing keratin fibres, particularly human hair. By using colouring agents with said dye, a series of problems which occur when using complex dye mixtures are avoided or significantly reduced
摘要翻译：吲哚和二氢吲哚混合染料和-hybridfarbstoffvorprodukte结构（I）：X - S - ÿ; 其中X是从吲哚或二氢吲哚作为黑色素前体的衍生物衍生的基团; Y表示选自氧化染料耦合器或初级中间类型，或吲哚或二氢吲哚作为黑色素前体的衍生物衍生的基团; 和S代表的是基团X和Y，直接键合或至少一个间隔基团的共同的构成的结构元件，非常适合用于着色角蛋白纤维，特别是人的头发。通过使用含有这些染料的颜色的产品，与使用复杂的染料混合物的发生许多问题离开，旁路或显著最小化。

8. 发明申请

WO0100152A8 NEW COUPLING COMPONENTS FOR OXIDATION HAIR COLORANTS 审中-公开
标题翻译：新合剂成分氧化发色
公开(公告)号：WO0100152A8
公开(公告)日：2001-04-05
申请号：PCT/EP0005156
申请日：2000-06-06
申请人： HENKEL KGAA , NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST
发明人： NAUMANN FRANK , ROSE DAVID , HOEFFKES HORST
IPC分类号： D06P3/10 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/415
摘要： The invention relates to oxidation colorants for coloring keratin fibers, especially human hair. The inventive colorants contain, dissolved in a medium that is appropriate for coloring, at least one developer component and at least one m-aminophenol derivative of formula (I), wherein R and R independently represent hydrogen, a C1-C4 alkyl group or a C1-C4 hydroxyalkyl group or, together with the nitrogen atom to which they are bound, form an optionally substituted, saturated heterocyclic 5- or 6-membered ring that may contain another nitrogen atom or an oxygen atom, R represents hydrogen, a C1-C4 alkyl group or a C1-C4 hydroxyalkyl group, R represents hydrogen, a C1-C4 alkyl group or a C3-C8 cycloalkyl group and R and R independently represent hydrogen, a halogen atom, a C1-C4 alkyl group, a C1-C4 hydroxyalkyl group, a C1-C4 aminoalkyl group or a C1-C4 alkoxy group and n is an integer from 1 to 8, or they contain a physiologically acceptable salt of one of these compounds, with the proviso that, if a tetraaminopyrimidine is used as the developer component, at least one additional colorant precursor is present. The inventive agents are characterized by intense colorations especially in the brown range and by excellent color fastness properties.
摘要翻译：本发明涉及角蛋白纤维，特别是人的毛发的氧化染色，含有在适当的染色的介质中的至少一种显色剂组分和式（I）中的至少一种间氨基苯酚衍生物，其中R <1>和R <2>各自独立地是氢，C1至C4烷基或C1-至C4羟烷基，或一起与氮原子到它们所连接形成任选取代的饱和杂环含有一个额外的氮原子的5-或6-元环或可以含有氧原子，R <3>代表氢，C1至C4烷基或C1-至C4-羟烷基是，R <4>为氢，C1至C4烷基或C3至C8 环烷基，并且R <5>和R <6>独立地为氢，卤原子，C1-C4烷基，一个C 1至C 4羟烷基，C1 是C4-氨基烷基，或C1-C4烷氧基，n是从1到8的整数，或含有这些化合物的生理学上可接受的盐中的一种，其条件是，当四氨基被用作显影剂的部件，至少一个另外的是染料前体存在。本发明的组合物的特征在于强烈着色，尤其是在具有优异的牢度性能棕色区域。

9. 发明申请

WO0232383A3 NOVEL USE OF SHORT-CHAINED CARBOXYLIC ACIDS 审中-公开
标题翻译：短链羧酸的新用途
公开(公告)号：WO0232383A3
公开(公告)日：2002-10-10
申请号：PCT/EP0111698
申请日：2001-10-10
申请人： HENKEL KGAA , KLEEN ASTRID , HOEFFKES HORST , HOLLENBERG DETLEF , BRABAENDER OLIVER , NAUMANN FRANK
发明人： KLEEN ASTRID , HOEFFKES HORST , HOLLENBERG DETLEF , BRABAENDER OLIVER , NAUMANN FRANK
IPC分类号： A61K8/36 , A61K8/362 , A61K8/64 , A61K8/81 , A61Q5/04 , A61Q5/06 , A61Q5/10 , A61Q17/04 , A61K7/06 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/36 , A61K8/362 , A61K8/365 , A61K8/368 , A61K8/64 , A61K8/645 , A61K8/8158 , A61Q5/04 , A61Q5/065 , A61Q17/04
摘要： According to the invention, short-chained carboxylic acids are used to significantly optimise the restructuring of fibres, especially keratinous fibres.
摘要翻译：短链羧酸的使用显着改善了纤维的重构，特别是角蛋白纤维。

10. 发明申请

WO0197760A8 STRUCTURE-IMPROVING HAIR CARE AGENTS CONTAINING VITAMIN B6 AND DERIVATIVES 审中-公开
标题翻译：结构增强护发产品含维生素B6及其衍生物
公开(公告)号：WO0197760A8
公开(公告)日：2002-03-07
申请号：PCT/EP0106557
申请日：2001-06-09
申请人： HENKEL KGAA , KLEEN ASTRID , NAUMANN FRANK , HOEFFKES HORST , BRABAENDER OLIVER
发明人： KLEEN ASTRID , NAUMANN FRANK , HOEFFKES HORST , BRABAENDER OLIVER
IPC分类号： A61K8/00 , A61K8/49 , A61K8/67 , A61K8/92 , A61Q5/00 , A61Q5/04 , A61Q5/08 , A61Q5/10 , A61K7/06 , A61K7/13 , A61K7/135
CPC分类号： A61Q5/10 , A61K8/673 , A61Q5/04 , A61Q5/08
摘要： Vitamin B6 derivatives, preferably pyrodixine, pyrodixal, pyridoxal-5'-phosphate and pyridoxamine, are suitable for use as structure-improving components in hair care agents, especially for post-treating hair following an oxidative or reductive treatment method, e.g. oxidation dyeing or permanent wave fixing. The inventive treatment raises the melting point of the hair keratin and improves the washing fastness of hair dyes.
摘要翻译：维生素B6衍生物，优选吡哆素，吡哆醛，吡哆醛-5'-磷酸吡哆胺和适合作为头发处理组合物的结构改善成分，特别是用于毛发后处理氧化或还原处理的方法，例如后后氧化性毛发着色或烫发定影。通过处理头发角蛋白和染发剂的耐洗涤性提高的熔点。

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