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    • 6. 发明授权
    • Textile optical brighteners
    • 纺织光亮剂
    • US3629241A
    • 1971-12-21
    • US3629241D
    • 1969-06-26
    • HENKEL & CIE GMBH
    • KRAUSE HORST-JURGENDOHR MANFRED
    • C07D231/06C07D231/14D06L3/12C07D49/10
    • C07D231/06C07C251/72D06L4/657
    • WHEREIN X IS -SO2NH2, -SO2R, -SO2-OR, -COOR, -CONH2, -CN, -CF3, HALOGEN, -OR, OR -R; X'' IS HALOGEN, -OR OR -R; Y IS

      PYRAZOLE A(-)

      1-(4-X-PHENYL),3-(4-X''-PHENYL),4-Z,4-Z'',5-Y(+),5-Y''-

      AN OPTICAL BRIGHTENER FOR TEXTILES HAVING THE FORMULA
      Y'' IS H, -R OR PHENYL; Z IS H OR Y; Z'' IS H OR R; R IS ALKYL HAVING 1 TO 4 CARBON ATOMS; R'' IS H OR R; R'''' IS R OR -(CH2)N-1-CH2OH; N IS AN INTEGER FROM 2 TO 4; AND A IS AN ANION OF AN ACID.

      -COO-(CH2)N-N(+)(-R")(-R)2 OR -(CH2)N-N(+)(-R)(-R")2

      -CO-N(-R'')-(CH2)N-N(-R'')-(CH2)N-N(+)(-R)(-R")2;

      -CO-N(-R1)-(CH2)N-N(+)(-R)(-R")2;
    • 1,242,019。 处理纺织品。 HENKEL&CIE G.m.b.H. 1969年7月2日[1968年7月2日],第33308/69号。 标题D1P。 [也在C2部分]用于棉花,交联棉,用合成树脂完成的棉,粘胶人造丝,乙酸酯人造丝和混合棉/聚丙烯纤维的荧光增白剂具有下式其中X是SO 2 NH 2,SO 2 R, SO 2 OR,CO 2 R,CONH 2,CN,CF 3,卤素,OR或R,X 1 是卤素,OR或R,Y是CONR'(CH 2)n NRR“R “CONR'(CH 2)n NR'(CH 2)n NRR”R“CO 2(CH 2)n NRR”R“或(CH 2)n NRR''R”,Y'是H,R 或Ph,Z为H或Y,Z'为H或R,R为C 1-4烷基,R'为H或R,R“为R或(CH 2)n-1 CH 2 OH,n为2 ,3或4,A-是酸的阴离子,3-对氯苯基-5-三甲基氨基磷酰氨基甲酰基-1-对 - 磺酰基苯基-ΔSP 2 - 吡唑啉甲磺酸盐。
    • 9. 发明授权
    • Detergent compositions containing a textile softener
    • 含有纺织肥皂的洗涤剂组合物
    • US3676338A
    • 1972-07-11
    • US3676338D
    • 1970-01-14
    • HENKEL & CIE GMBH
    • FRIES WALTERBERG MARKUSDOHR MANFREDKIRSTAHLER ALFRED
    • C11D1/00C11D1/04C11D1/10C11D1/14C11D1/22C11D1/29C11D1/52C11D1/83C11D1/88C11D1/90C11D1/92C11D3/00C11D3/32C11D3/386C11D9/00C11D10/04C11D17/00D06M13/02D06M13/184D06M13/188D06M13/248D06M13/256D06M13/322D06M13/342D06M13/345D06M13/20
    • C11D10/042C11D1/10C11D1/14C11D1/22C11D1/29C11D1/525C11D1/528C11D1/83C11D1/90C11D1/92C11D3/001C11D3/0026C11D10/04
    • This invention relates to a combination of surface-active compounds utilizable in neutral to alkaline textile washing baths which comprises (a) from 20 to 90 percent by weight of customary surface-active compounds utilizable in neutral to alkaline textile washing baths selected from the group consisting of anionic surface-active compounds, amphoteric surface-active compounds, non-ionic surface-active compounds and mixtures thereof and (b) from 80 to 10% by weight of a textile softener selected from the group consisting of (1) compounds of the formula WHEREIN R1 and R2 are alkyl having from six to 18 carbon atoms and X is a trivalent link selected from the group consisting of WHERE N REPRESENTS AN INTEGER FROM 0 TO 2, M REPRESENTS AN INTEGER FROM 1 TO 2 AND P REPRESENTS AN INTEGER FROM 2 TO 3, COMPOUNDS OF THE FORMULA WHEREIN R3 and R4 are members selected from the group consisting of alkyl having from one to 23 carbon atoms and cycloalkylalkyl having from seven to 23 carbon atoms and R5 is a member selected from the group consisting of hydrogen, alkyl having from one to 23 carbon atoms and cycloalkylalkyl having from seven to 23 carbon atoms, with the proviso that the total number of carbon atoms in R1, R2 and R3 is from six to 24 carbon atoms and (2) water soluble salts thereof. Textile washing agents and textile auxiliary washing agents containing the above combinations of surface-active compounds, with or without a content of enzymes are also part of the invention.
    • 本发明涉及可用于中性至碱性织物洗涤浴的表面活性化合物的组合,其包含(a)20-90%重量的可用于中性至碱性纺织品洗涤浴中的常规表面活性化合物,其选自 的阴离子表面活性化合物,两性表面活性化合物,非离子表面活性化合物及其混合物,和(b)80至10重量%的纺织柔软剂,其选自(1) 式WHEREIN R1和R2是具有6至18个碳原子的烷基,X是选自下列的三价连接:从0到2的整数,M代表从1到2的整数和P代表整数从 2〜3的化合物,其中R 3和R 4为选自具有1至23个碳原子的烷基和具有7至23个碳原子的环烷基烷基和R 2 5是选自氢,具有1至23个碳原子的烷基和具有7至23个碳原子的环烷基烷基的成员,条件是R1,R2和R3中的碳原子总数为6至 24个碳原子和(2)其水溶性盐。 含有上述组合的表面活性化合物的织物洗涤剂和纺织辅助洗涤剂,具有或不含有酶的含量也是本发明的一部分。