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1. 发明申请

WO2008110798A2 IMPROVED AQUEOUS-BASED INSULATING FLUIDS AND RELATED METHODS 审中-公开
标题翻译：改进的基于水性的绝缘油和相关方法
公开(公告)号：WO2008110798A2
公开(公告)日：2008-09-18
申请号：PCT/GB2008/000868
申请日：2008-03-12
申请人： HALLIBURTON ENERGY SERVICES, INC , CURTIS, Philip, Anthony , EZELL, Ryan , MILLER, Jeffrey, J. , PEREZ, Gregory, P.
发明人： EZELL, Ryan , MILLER, Jeffrey, J. , PEREZ, Gregory, P.
IPC分类号： C10M169/04 , C10M173/02 , C09K8/12 , C10N30/08 , C10N40/00 , C10N40/08
CPC分类号： C10M173/02 , C09K8/44 , C10M177/00 , C10M2201/081 , C10M2201/12 , C10M2207/0225 , C10M2207/023 , C10M2207/024 , C10M2207/08 , C10M2207/281 , C10M2207/288 , C10M2209/084 , C10M2215/06 , C10M2215/22 , C10M2217/024 , C10M2217/046 , C10M2221/02 , C10N2210/01 , C10N2210/02 , C10N2220/022 , C10N2220/082 , C10N2250/10 , C10N2260/00 , C10N2270/00 , E21B36/003
摘要： Provided herein are compositions that include an aqueous-based insulating fluid that comprises an aqueous base fluid, a water-miscible organic liquid, and a synthetic polymer. In another embodiment, provided herein is a method of forming an aqueous-based insulating fluid comprising: mixing an aqueous base fluid and a water-miscible organic liquid to form a mixture; adding at least one synthetic polymer to the mixture; allowing the polymer to hydrate; optionally adding a crosslinking agent to the mixture comprising the synthetic polymer to crosslink the synthetic polymer; placing the mixture comprising the synthetic polymer in a chosen location; allowing the mixture comprising the synthetic polymer to activate to form a gel therein.
摘要翻译：本文提供了包括含水基绝缘流体的组合物，其包含碱性水溶液，水混溶性有机液体和合成聚合物。在另一个实施方案中，本文提供了一种形成水性绝缘流体的方法，其包括：将基础水溶液与水混溶性有机液体混合以形成混合物; 向混合物中加入至少一种合成聚合物; 使聚合物水合; 任选地向包含合成聚合物的混合物中加入交联剂以交联合成聚合物; 将包含合成聚合物的混合物置于选定的位置; 允许包含合成聚合物的混合物活化以在其中形成凝胶。

2. 发明申请

WO2006079778A1 METALLIC SOAPS OF MODIFIED TALL OIL ACIDS 审中-公开
标题翻译：改性沥青油的金属粘土
公开(公告)号：WO2006079778A1
公开(公告)日：2006-08-03
申请号：PCT/GB2006/000056
申请日：2006-01-09
申请人： HALLIBURTON ENERGY SERVICES, INC. , CURTIS, Philip, Anthony , MILLER, Jeffrey, J.
发明人： MILLER, Jeffrey, J.
IPC分类号： C09K8/32 , C09K8/36
CPC分类号： C09K8/36 , C09K8/32
摘要： A method and product is disclosed which provides emulsion stability and filtration control to invert emulsion drilling fluids. The product comprises a blend of a carboxylic acid terminated polyamide with distilled and processed tall oil fatty acids and/or distilled and processed tall oil resin acids. The product is extremely effective, even at temperatures as high as 35O 0 F, decreasing by about two-thirds the amount of emulsifÊer generally required to formulate an effective drilling fluid. The product also greatly reduces and in many cases eliminates the need for conventional fluid loss additives, and additionally provides electrical stability. Moreover, the product has a pour point as low as about 20 degrees Fahrenheit with minimal solvents, thereby eliminating the need to ship large amounts of inert material for use, and may be transported in a highly active state.
摘要翻译：公开了一种提供乳化稳定性和过滤控制以反转乳液钻井液的方法和产品。该产品包括羧酸封端的聚酰胺与蒸馏和加工的妥尔油脂肪酸和/或蒸馏和加工的妥尔油树脂酸的共混物。即使在高达350°F的温度下，该产品也是非常有效的，通常减少配制有效钻井液通常需要的乳化剂的三分之二。该产品还大大降低，并且在许多情况下不需要常规的流体损失添加剂，并且还提供电稳定性。此外，该产品的溶剂倾点低至约20华氏度，因此不需要运送大量的惰性物质使用，并且可以以高活性状态运输。

3. 发明申请

WO2006092547A3 METHODS OF USING DRILLING FLUIDS CONTAINING BIODEGRADABLE ORGANOPHILIC CLAY 审中-公开
公开(公告)号：WO2006092547A3
公开(公告)日：2006-09-08
申请号：PCT/GB2006/000057
申请日：2006-01-09
申请人： HALLIBURTON ENERGY SERVICES, INC. , CURTIS, Philip, Anthony , MILLER, Jeffrey, J.
发明人： MILLER, Jeffrey, J.
IPC分类号： C09K8/14 , C09K8/32
摘要： Methods of treating a wellbore comprise displacing a drilling fluid comprising an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage into the wellbore. Methods of drilling a wellbore comprise: applying torque to a bit within the wellbore and concurrently applying force to urge the bit to extend through the wellbore; and circulating a drilling fluid past the bit to remove cuttings therefrom, the drilling fluid comprising an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage. Methods of preparing a drilling fluid comprise: forming an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage; and combining the organophilic clay with an oil-based fluid.

4. 发明申请

WO2006079775A1 DRILLING FLUIDS CONTAINING BIODEGRADABLE ORGANOPHILIC CLAY 审中-公开
标题翻译：含有生物可降解有机粘土的钻井液
公开(公告)号：WO2006079775A1
公开(公告)日：2006-08-03
申请号：PCT/GB2006/000049
申请日：2006-01-09
申请人： HALLIBURTON ENERGY SERVICES, INC , CURTIS, Philip, Anthony , MILLER, Jeffrey, J.
发明人： MILLER, Jeffrey, J.
IPC分类号： C09K8/14 , C09K8/36
CPC分类号： C09K8/36 , C09K8/145
摘要： Drilling fluids are provided that comprise an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage. The quaternary ammonium surfactant may comprise a compound generally represented by formula (I); where M" is an anion such as a chloride, methyl sulfate, bromide, acetate, or iodide ion; R 1 is an alkyl group such as a saturated hydrocarbon with 10 or more carbons; R 2 , R 3 , and R 4 are the same or different alkyl groups such as a methyl, ethyl, or benzyl group, and x is greater than or equal to 1. The organophilic clay treated in this manner is substantially biodegradable. In embodiments, the drilling fluids comprise the foregoing organophilic clay, an oil-based fluid and a weighting agent. In still more embodiments, the drilling fluids comprise the foregoing organophilic clay, an invert emulsion, an emulsifier, and a weighting agent.
摘要翻译：提供钻井液，其包含用具有酰胺键的季铵表面活性剂处理的亲有机物质粘土。季铵表面活性剂可以包含通常由式（I）表示的化合物; 其中M“是阴离子如氯化物，甲基硫酸盐，溴化物，乙酸盐或碘离子; R 1是烷基，例如具有10个或更多个碳的饱和烃; R 1， R 2，R 3和R 4是相同或不同的烷基，例如甲基，乙基或苄基，x大于或以这种方式处理的亲有机质的粘土基本上是可生物降解的，在实施方案中，钻井流体包括上述亲有机粘土，油基流体和加重剂。在更多实施方案中，钻井液包含上述亲有机质的粘土，反相乳液，乳化剂和加重剂。

5. 发明申请

WO2005085386A1 METALLIC SOAPS OF MODIFIED FATTY ACIDS AND ROSIN ACIDS AND METHODS OF MAKING AND USING SAME 审中-公开
标题翻译：改性脂肪酸和罗辛酸的金属皂化物及其制备和使用方法
公开(公告)号：WO2005085386A1
公开(公告)日：2005-09-15
申请号：PCT/GB2005/000474
申请日：2005-02-10
申请人： HALLIBURTON ENERGY SERVICES, INC. , WAIN, Chrsitopher, Paul , MILLER, Jeffrey, J.
发明人： WAIN, Chrsitopher, Paul , MILLER, Jeffrey, J.
IPC分类号： C09K7/02
CPC分类号： B01F17/0085 , C09K8/32 , C09K8/36
摘要： A superior powder form of a metallic soap for enhancing the properties of an invert emulsion drilling fluid may be prepared by a dry process saponification reaction. The process includes mixing a source of metal cations with the product of a Diels-Alder reaction of dienophiles with fatty acids and/or resin acids and allowing the mixture to react. Heating the mixture increases the rate of reaction. The solid product is ground to form a powder. The properties of the drilling fluid that may be improved by adding the soap include filtration control, fluid loss control, emulsification and emulsion stability, and electrical stability.
摘要翻译：可以通过干法皂化反应来制备用于提高反相乳液钻井液的性质的金属皂的优良粉末形式。该方法包括将金属阳离子源与亲二烯体的Diels-Alder反应与脂肪酸和/或树脂酸的产物混合并使混合物反应。加热混合物会增加反应速度。将固体产物研磨成粉末。通过添加皂可以改善的钻井液的性质包括过滤控制，流失控制，乳化和乳化稳定性以及电稳定性。

6. 发明申请

WO2006030184A1 SUBTERRANEAN FLUIDS HAVING IMPROVED ENVIRONMENTAL CHARACTERISTICS AND METHODS OF USING THESE FLUIDS IN SUBTERRANEAN FORMATIONS 审中-公开
标题翻译：具有改进的环境特性的亚流体流体和在这些流体中使用这些流体的方法
公开(公告)号：WO2006030184A1
公开(公告)日：2006-03-23
申请号：PCT/GB2005/003473
申请日：2005-09-08
申请人： HALLIBURTON ENERGY SERVICES, INC. , WAIN, Christopher, Paul , BROTHERS, Lance, E. , MILLER, Jeffrey, J.
发明人： BROTHERS, Lance, E. , MILLER, Jeffrey, J.
IPC分类号： C09K8/467 , C04B28/02
CPC分类号： C09K8/467 , C04B28/02 , C04B28/12 , C04B2103/0072 , C04B2103/0074 , C04B2111/00146 , C09K8/424 , Y02W30/92 , C04B24/10 , C04B2103/40 , C04B7/02 , C04B14/108 , C04B18/08 , C04B24/34
摘要： Subterranean fluids are provided that have improved environmental characteristics, and more particularly, subterranean fluids are provided that include a hydraulic cement in an invert emulsion. Methods of using such fluids in subterranean operations also are provided. An example of a method is a method of using a fluid in a subterranean formation. An example of a composition is a fluid comprising a hydraulic cement and an invert emulsion of an oleaginous fluid, a nonoleaginous fluid, and an emulsifying surfactant, wherein the emulsifying surfactant: has an LC 50 or EC 50 that is greater than about 10 milligrams/liter with respect to Skeletonema costatum, Acartia tonsa, Scopthalmus maximus (juvenile), or Corophium volutator; and demonstrates a biodegradability of: greater than about 70% biodegradation in 28 days when tested according to method OECD 301A or 301E; or greater than about 60% biodegradation in 28 days when tested according to method OECD 301B, 301C; 301F, or 306.
摘要翻译：提供具有改善的环境特性的地下流体，更具体地说，提供了包括反相乳液中的水硬性水泥的地下流体。还提供了在地下操作中使用这种流体的方法。方法的一个实例是在地层中使用流体的方法。组合物的实例是包含水硬性水泥和油性流体，非油性流体和乳化表面活性剂的反相乳液的流体，其中所述乳化表面活性剂具有LC 50或EC 大于约10毫克/升，相对于骷髅毛癣菌，Ac a a，，，，，us（or or or;;;;;;;;;;;;;;;; 并证实了生物降解性：当根据方法OECD 301A或301E测试时，在28天内大于约70％的生物降解; 或者根据方法OECD 301B，301C测试，在28天内大于约60％的生物降解; 301F或306。

7. 发明申请

WO2009130439A1 DRILLING FLUIDS CONTAINING BIODEGRADABLE ORGANOPHILIC CLAY 审中-公开
标题翻译：含有生物可降解有机粘土的钻井液
公开(公告)号：WO2009130439A1
公开(公告)日：2009-10-29
申请号：PCT/GB2009/000924
申请日：2009-04-08
申请人： HALLIBURTON ENERGY SERVICES, INC. , MILLER, Jeffrey, J. , TURNER, Craig, Robert
发明人： MILLER, Jeffrey, J.
IPC分类号： C09K8/34 , C09K8/36
CPC分类号： C09K8/34 , C01B33/44 , C09K8/145 , C09K8/36 , Y10S507/905 , Y10S507/91
摘要： Methods are provided including methods of treating a well bore with drilling fluids comprising organophilic clays treated with quaternary ammonium surfactants having at least two amide linkages. In some embodiments, the methods comprise: providing a drilling fluid comprising a nonaqueous phase and an organophilic clay treated with a quaternary ammonium surfactant having at least two amide linkages; and placing at least a portion of the drilling fluid into the well bore. In other embodiments, the methods comprise combining an organophilic clay with a quaternary ammonium surfactant having at least one amide linkage to form a mixture, and combining the mixture with a fluid comprising a nonaqueous phase to form a drilling fluid. Additional methods are also provided.
摘要翻译：提供的方法包括用钻井液处理井眼的方法，所述钻井流体包括用具有至少两个酰胺键的季铵表面活性剂处理的亲有机粘土。在一些实施方案中，所述方法包括：提供包含用具有至少两个酰胺键的季铵表面活性剂处理的非水相和亲有机物的钻井液; 并将钻井液的至少一部分放入井眼中。在其它实施方案中，所述方法包括将有机粘土与具有至少一个酰胺键的季铵表面活性剂组合以形成混合物，并将该混合物与包含非水相的流体混合以形成钻井液。还提供了附加的方法。

8. 发明公开

EP1856225A1 DRILLING FLUIDS CONTAINING BIODEGRADABLE ORGANOPHILIC CLAY 有权
标题翻译：可生物降解有机粘土含钻井液
公开(公告)号：EP1856225A1
公开(公告)日：2007-11-21
申请号：EP06700321.0
申请日：2006-01-09
申请人： HALLIBURTON ENERGY SERVICES, INC.
发明人： MILLER, Jeffrey, J.
IPC分类号： C09K8/36
CPC分类号： C09K8/36 , C09K8/145
摘要： Drilling fluids are provided that comprise an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage. The quaternary ammonium surfactant may comprise a compound generally represented by formula (I); where M' is an anion such as a chloride, methyl sulfate, bromide, acetate, or iodide ion; R1 is an alkyl group such as a saturated hydrocarbon with 10 or more carbons; R2, R3, and R4 are the same or different alkyl groups such as a methyl, ethyl, or benzyl group, and x is greater than or equal to 1. The organophilic clay treated in this manner is substantially biodegradable. In embodiments, the drilling fluids comprise the foregoing organophilic clay, an oil-based fluid and a weighting agent. In still more embodiments, the drilling fluids comprise the foregoing organophilic clay, an invert emulsion, an emulsifier, and a weighting agent.

9. 发明授权

EP1877511B1 METHOD OF USING DRILLING FLUIDS CONTAINING BIODEGRADABLE ORGANOPHILIC CLAY 有权
标题翻译：使用方法无聊流体的可生物降解有机土的
公开(公告)号：EP1877511B1
公开(公告)日：2013-09-18
申请号：EP06743860.6
申请日：2006-01-09
申请人： HALLIBURTON ENERGY SERVICES, INC.
发明人： MILLER, Jeffrey, J.
IPC分类号： C09K8/36 , C09K8/14
CPC分类号： C01B33/44 , C09K8/32 , Y10S507/901 , Y10S507/905 , Y10S507/91

10. 发明公开

EP2126016A2 IMPROVED AQUEOUS-BASED INSULATING FLUIDS AND RELATED METHODS 审中-公开
标题翻译：改进的含水绝缘及相关手续
公开(公告)号：EP2126016A2
公开(公告)日：2009-12-02
申请号：EP08718710.0
申请日：2008-03-12
申请人： Halliburton Energy Services, Inc.
发明人： EZELL, Ryan , MILLER, Jeffrey, J. , PEREZ, Gregory, P.
IPC分类号： C10M173/02 , C09K8/12
CPC分类号： C10M173/02 , C09K8/44 , C10M177/00 , C10M2201/081 , C10M2201/12 , C10M2207/0225 , C10M2207/023 , C10M2207/024 , C10M2207/08 , C10M2207/281 , C10M2207/288 , C10M2209/084 , C10M2215/06 , C10M2215/22 , C10M2217/024 , C10M2217/046 , C10M2221/02 , C10N2210/01 , C10N2210/02 , C10N2220/022 , C10N2220/082 , C10N2250/10 , C10N2260/00 , C10N2270/00 , E21B36/003
摘要： Provided herein are compositions that include an aqueous-based insulating fluid that comprises an aqueous base fluid, a water-miscible organic liquid, and a synthetic polymer. In another embodiment, provided herein is a method of forming an aqueous-based insulating fluid comprising: mixing an aqueous base fluid and a water-miscible organic liquid to form a mixture; adding at least one synthetic polymer to the mixture; allowing the polymer to hydrate; optionally adding a crosslinking agent to the mixture comprising the synthetic polymer to crosslink the synthetic polymer; placing the mixture comprising the synthetic polymer in a chosen location; allowing the mixture comprising the synthetic polymer to activate to form a gel therein.

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