专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US4418143A Color photographic recording material 失效
标题翻译：彩色摄影材料
公开(公告)号：US4418143A
公开(公告)日：1983-11-29
申请号：US351103
申请日：1982-02-22
申请人： Peter Bergthaller , Gunther Schenk , Gerhard Wolfrum , Hans-Volker Runzheimer , Holger Heidenreich
发明人： Peter Bergthaller , Gunther Schenk , Gerhard Wolfrum , Hans-Volker Runzheimer , Holger Heidenreich
IPC分类号： C09B29/01 , C09B29/36 , G03C8/10 , G03C7/00 , G03C1/10 , G03C1/40
CPC分类号： C09B29/36 , G03C8/10
摘要： Azo dyes of formula II are released on development from dye releasers which are associated with a light-sensitive silver halide emulsion layer. The azo dyes are chelatable and form with metal ions blue or cyan dye-metal-complex image dyes. ##STR1## In the formula A.sup.1 and A.sup.2 represent electronegative substituents whose meta-sigma values .sigma..sub.m (according to D. H. McDaniel and H. C. Brown in J. Org. Chem. 23, 420 et seq (1958) conform to at least one of the following three relationships:1. .sigma..sub.m (A.sup.1), .sigma..sub.m (A.sup.2) +0.332. .sigma..sub.m (A.sup.1) +.sigma..sub.m (A.sup.2) +0.75;3. .sigma..sub.m (A.sup.1) +0.33 and A.sup.2 represents--SO.sub.2.sup.XX represents H, --OH, --NH.sub.2, --NH--Y or a cyclic amino group, andY represents alkyl, aryl, alkylsulfonyl, arylsulfonyl or acylQ represents a group for completing a 2-amino-3-hydroxypyridine ring, a 4,5-diphenylimidazole ring or a 4-hydroxyisoquinoline ring which is attached through the 1-position; andG represents a group capable of chelate formation.
摘要翻译：式II的偶氮染料在与感光卤化银乳剂层相关的染料释放剂的显影下释放。偶氮染料是可螯合的，与金属离子形成蓝色或青色染料 - 金属络合物图像染料。式中，A1和A2表示电子负值取代基，其σ-σ值σ（根据DHMandaniel和HCBrown在J.Org.Chem.23,320和seq（1958）中符合以下至少一个）三个关系：1.西格玛（A1），西格玛（A2）+0.33 2.西格玛（A1）+西格玛（A2）+0.75;西格玛（A1）+0.33和A2代表-SO2X H，-OH，-NH 2，-NH-Y或环状氨基，Y表示烷基，芳基，烷基磺酰基，芳基磺酰基或酰基Q表示完成2-氨基-3-羟基吡啶环的基团，二苯基咪唑环或通过1-位连接的4-羟基异喹啉环; G表示能够螯合形成的基团。

2. 发明授权

US4524123A Chelatable 4-thienyl imidazole azo dyes, their use in color photographic recording material 失效
标题翻译：可螯合的4-噻吩基咪唑偶氮染料，它们用于彩色照相记录材料
公开(公告)号：US4524123A
公开(公告)日：1985-06-18
申请号：US593936
申请日：1984-03-27
申请人： Gunther Schenk , Peter Bergthaller , Holger Heidenreich , Gerhard Wolfrum
发明人： Gunther Schenk , Peter Bergthaller , Holger Heidenreich , Gerhard Wolfrum
IPC分类号： C09B29/36 , C09B45/48 , G03C8/10 , G03C1/40 , G03C5/54
CPC分类号： G03C8/10 , C09B29/36 , C09B45/48
摘要： Azo dyes corresponding to the formula (II): ##STR1## wherein G represents a group capable of forming a 5-membered chelate ring and R.sup.5 represents aryl or a thienyl group, combined with metal ions, in particular copper or nickel ions, to form stable azo dye-metal complexes which have advantageous spectral properties. They are therefore particularly suitable for the production of highly light-fast cyan images, e.g. by the Ink-Jet process, in which they may be used directly in the form of colored inks, or by the dye diffusion transfer process, in which they are released image-wise from corresponding dye-releasers in the course of development and transferred to a dye-absorbent layer.
摘要翻译：对应于式（II）的偶氮染料：其中G表示能够形成5元螯合环的基团，R 5表示芳基或噻吩基，与金属离子，特别是铜或镍离子结合以形成具有有利的光谱性质的稳定的偶氮染料 - 金属络合物。因此，它们特别适用于生产高度光快的青色图像，例如，通过喷墨方法，其可以直接以彩色油墨的形式使用，或通过染料扩散转移方法，在显影过程中它们从相应的染料释放剂成像释放并转移到染料吸收层。

3. 发明授权

US4579817A Color photographic recording material containing dye-releasers releasing 6-arylazo-2-amino-3-pyridinol dyes which are chelatable with metal ions 失效
标题翻译：含有与金属离子螯合的6-芳基偶氮-2-氨基-3-吡啶酚染料的染料释放剂的彩色照相记录材料
公开(公告)号：US4579817A
公开(公告)日：1986-04-01
申请号：US638965
申请日：1984-08-08
申请人： Peter Bergthaller , Gerhard Wolfrum , Holger Heidenreich
发明人： Peter Bergthaller , Gerhard Wolfrum , Holger Heidenreich
IPC分类号： C09B29/00 , G03C8/10 , G03C1/40 , G03C5/54
CPC分类号： G03C8/10 , C09B29/00
摘要： Dyes corresponding to general formula (I) are released imagewise from corresponding dye-releasers in the dye diffusion transfer process. They react with nickel ions to form lightfast, cyan dye-metal complexes having advantageous spectral properties: ##STR1## wherein Q represents the group required for completing an optionally substituted phenyl or naphthyl group;X represents --S--, --SO.sub.2 --, --SO.sub.2 --NR.degree.-- or --SO.sub.2 --O--;R.degree. represents H or alkyl; andR.sup.1 represents an aliphatic, araliphatic or a carbocyclic or heterocyclic aromatic group or, when X represents --SO.sub.2 --NR.degree.--, R.sup.1 represents hydrogen.
摘要翻译：对应于通式（I）的染料在染料扩散转移过程中从相应的染料释放剂成像释放。它们与镍离子反应形成具有优异光谱性质的耐光青色染料 - 金属络合物：其中Q表示完成任选取代的苯基或萘基所需的基团; X表示-S - ， - SO 2 - ， - SO 2 -NR 6 - 或-SO 2 -O-; R DEG表示H或烷基; 并且R 1表示脂族，芳脂族或碳环或杂环芳基，或当X表示-SO 2 -NR D - 时，R 1表示氢。

4. 发明授权

US4396710A Photographic recording material with metal complexable, heterocyclic azo dye 失效
标题翻译：摄影记录材料与金属络合，杂环偶氮染料
公开(公告)号：US4396710A
公开(公告)日：1983-08-02
申请号：US367761
申请日：1982-04-12
申请人： Peter Bergthaller , Gunther Schenk , Gerhard Wolfrum , Hans-Volker Runzheimer
发明人： Peter Bergthaller , Gunther Schenk , Gerhard Wolfrum , Hans-Volker Runzheimer
IPC分类号： G03C7/26 , C07D471/04 , C09B27/00 , C09B29/36 , C09B45/00 , G03C8/10 , G03C1/40 , G03C1/10 , G03C5/54
CPC分类号： C09B27/00 , C09B29/3647 , C09B45/00 , G03C8/10
摘要： Cyan images may be prepared by the dye diffusion transfer process, using dye-releasers which on development release diffusible dyes capable of forming light-fast cyan metal-dye-complexes particularly with copper or nickel ions. As also the dye-releasers are capable of complexation, cyan images can be prepared not only from the released dyes but also from the dye-releasers ("retained image"). Released dyes and dye-releasers of the present invention contain a chromophor of the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents --H, --F, --Cl, --Br, --CN, --NO.sub.2, --CF.sub.3, --OCF.sub.3, --SCF.sub.3, alkyl, alkoxy, alkylthio, acylamino, alkylsulfonyl, arylsulfonyl, --CO--X or --SO.sub.2 --Y or two adjacent groups R.sup.1 -R.sup.4 together constitute a condensed benzene ring which may contain further substituents;R.sup.5 represents hydrogen or a substituent having an electron donor character;R.sup.6 represents hydrogen, halogen or alkyl;G represents a group capable of chelate formation;X represents --OH, alkoxy, an amino group optionally substituted by alkyl or aryl, or a cyclic amino group;Y represents --H, --OH, an amino group optionally substituted by alkyl or aryl, a cyclic amino group or a group corresponding to the following general formula: --NH--So.sub.2 --R.sup.7 ;R.sup.7 represents alkyl, aryl, an amino group optionally disubstituted by alkyl or a cyclic amino group; andn represents 0 or 1.
摘要翻译：青色图像可以通过染料扩散转移法制备，使用染料释放剂，其在显影时释放能够形成特别是铜或镍离子的快速青色金属 - 染料 - 络合物的扩散染料。染料释放剂也能够络合，不仅可以从释放的染料中制备青色图像，而且可以从染料释放剂（“保留图像”）制备青色图像。本发明的释放的染料和染料释放剂含有下式的发色团：其中R1，R2，R3和R4可以相同或不同，表示-H，-F，-Cl， - Br，-CN，-NO 2，-CF 3，-OCF 3，-SCF 3，烷基，烷氧基，烷硫基，酰氨基，烷基磺酰基，芳基磺酰基，-CO-X或-SO 2 -Y或两个相邻基团R 1 -R 4一起构成稠合苯可以含有其它取代基的环; R5表示氢或具有电子供体特性的取代基; R6表示氢，卤素或烷基; G表示能够螯合形成的基团; X表示-OH，烷氧基，任选被烷基或芳基取代的氨基或环状氨基; Y表示-H，-OH，任选被烷基或芳基取代的氨基，环状氨基或对应于以下通式的基团：-NH-SO 2 -R 7; R7表示烷基，芳基，任选被烷基或环氨基二取代的氨基; n表示0或1。

5. 发明授权

US4393132A Photographic recording material with arylazocyanoacetic ester dye releasers 失效
标题翻译：具有芳基氮杂乙酸酯染料释放剂的摄影记录材料
公开(公告)号：US4393132A
公开(公告)日：1983-07-12
申请号：US371076
申请日：1982-04-23
申请人： Gunther Schenk , Peter Bergthaller , Gerhard Wolfrum , Rudolf Stolzenburg
发明人： Gunther Schenk , Peter Bergthaller , Gerhard Wolfrum , Rudolf Stolzenburg
IPC分类号： C09B29/32 , C09B45/14 , G03C8/10 , G03C5/54 , G03C1/10 , G03C1/40 , G03C7/00
CPC分类号： C09B45/14 , G03C8/10
摘要： For the production of light-fast yellow images (transfer images and retained images) by the dye diffusion transfer process dye-releasers are useful which on development release diffusible azo dyes which can complex with nickel or copper ions and which in one of their tautomeric forms correspond to the general formula: ##STR1## wherein R.sup.1 represents alkyl, alkenyl or cycloalkyl having up to 8 carbon atoms,Z represents a radical required for completing a benzene or naphthalene ring; andL represents a substituent having a group which results from the splitting from a carrier radical.
摘要翻译：为了通过染料扩散转移法生产快速黄色图像（转印图像和保留的图像），染料释放剂可用于显影释放可与镍或铜离子复合的可扩散偶氮染料，并且以其互变异构形式之一对应于以下通式：其中R 1表示具有至多8个碳原子的烷基，烯基或环烷基，Z表示完成苯或萘环所需的基团; L表示具有由载体自由基分裂产生的基团的取代基。

6. 发明授权

US4461827A Color photographic recording material containing a non-diffusible dye releaser from which a complexible azo dye is released during development 失效
标题翻译：包含非扩散性染料释放剂的彩色照相记录材料，在显影过程中从其中释放可络合的偶氮染料
公开(公告)号：US4461827A
公开(公告)日：1984-07-24
申请号：US455319
申请日：1983-01-03
申请人： Peter Bergthaller , Gunther Schenk , Gerhard Wolfrum
发明人： Peter Bergthaller , Gunther Schenk , Gerhard Wolfrum
IPC分类号： C09B29/01 , C09B29/36 , C09B45/14 , G03C8/10 , G03C5/54 , G03C1/40 , G03C7/00
CPC分类号： C09B29/36 , C09B29/0007 , C09B45/14 , G03C8/10
摘要： Metal complexes, particularly copper and nickel complexes, of azo dyes corresponding to formula suitable for use as magenta-colored image dyes for the production of colored images by the dye diffusion transfer process. The dyes are linked (in non-metallized form) to a carrier radical provided with a ballast group as so-called color-providing compounds which are associated with a photosensitive silver halide emulsion layer. During development, the metallizable dyes are released imagewise and, after diffusion into an image-receiving layer, are converted into the corresponding metal complexes. ##STR1## In formula II, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent H, F, Cl, Br, --CN, --NO.sub.2, --CF.sub.3, --OCH.sub.3, --SCF.sub.3, alkyl, alkoxy, alkylthio, acylamino, alkyl sulphonyl, aryl sulphonyl, --CO--X or --SO.sub.2 Y; or two adjacent radicals from the group of radicals R.sup.1 to R.sup.4 together represent a fused benzene ring;R.sup.5 represents H, alkyl, alkoxy, aryl, alkoxy carbonyl, carbamoyl or cyano,R.sup.6 and R.sup.7 represent H, halogen, alkyl, --CF.sub.3 or --SO.sub.2 --Y,G represents --OH or a hydrolyzable precursor thereof,X represents --OH, alkoxy or an amino group;Y represents H, --OH, an amino group or a group of the formula --NH--SO.sub.2 --R.sup.8 whereR.sup.8 represents alkyl, aryl or an amino group; andm=0 or 1.
摘要翻译：金属络合物，特别是铜和镍络合物，对应于适合用作品红色图像染料的式的偶氮染料，用于通过染料扩散转移方法生产彩色图像。将染料以非金属化形式连接到具有镇流器基团的载体基团上，所述载体基团与感光卤化银乳剂层相关联的所谓的提供色彩的化合物。在显影过程中，金属化染料被成像释放，并且在扩散到图像接收层中后，转化成相应的金属络合物。式II中，R 1，R 2，R 3和R 4表示H，F，Cl，Br，-CN，-NO 2，-CF 3，-OCH 3，-SCF 3，烷基，烷氧基，烷硫基，酰氨基，烷基磺酰基，芳基磺酰基，-CO-X或-SO 2 Y; 或者R 1〜R 4基团的两个相邻基团一起表示稠合苯环; R5代表H，烷基，烷氧基，芳基，烷氧基羰基，氨基甲酰基或氰基，R6和R7表示H，卤素，烷基，-CF3或-SO2-Y，G表示-OH或其可水解的前体，X表示-OH，烷氧基或氨基; Y表示H，-OH，氨基或式-NH-SO 2 -R 8的基团，其中R 8表示烷基，芳基或氨基; m = 0或1。

7. 发明授权

US4579805A Color photographic recording material containing a thiophene azo dye releaser for cyan dyes 失效
标题翻译：含有用于青色染料的噻吩偶氮染料释放剂的彩色照相记录材料
公开(公告)号：US4579805A
公开(公告)日：1986-04-01
申请号：US674221
申请日：1984-11-23
申请人： Peter Bergthaller , Hauke Furstenwerth , Rudolf Stolzenburg , Paul Marx , Holger Heidenreich
发明人： Peter Bergthaller , Hauke Furstenwerth , Rudolf Stolzenburg , Paul Marx , Holger Heidenreich
IPC分类号： G03C7/00 , C09B29/00 , G03C8/10 , G03C1/40 , G03C5/54
CPC分类号： G03C8/10 , C09B29/0059
摘要： Dyes corresponding to formula I may be released imagewise from dye releasers in the dye diffusion transfer process. The dyes obtained are lightfast cyan dyes with improved spectral properties and reduced sensitivity to reducing agents ##STR1## the meanings of symbols given in formula I (A, A', G, R.sup.1, R.sup.2, R.sup.3 and R.sup.4) are indicated in the description.
摘要翻译：对应于式I的染料可以在染料扩散转移过程中从染料释放剂成像释放。所得到的染料是具有改进的光谱性质和对还原剂的敏感性降低的耐光青色染料（I）式I（A，A'，G，R 1，R 2，R 3和R 4）中给出的符号的含义在说明。

8. 发明授权

US4600681A Color photographic material with azo dicyanoimidazole dyes 失效
标题翻译：彩色照相材料与偶氮二氰基咪唑染料
公开(公告)号：US4600681A
公开(公告)日：1986-07-15
申请号：US748837
申请日：1985-06-26
申请人： Peter Bergthaller , Jurgen Strauss , Hans-Volker Runzheimer , Gerhard Wolfrum
发明人： Peter Bergthaller , Jurgen Strauss , Hans-Volker Runzheimer , Gerhard Wolfrum
IPC分类号： C09B29/09 , C09B29/00 , G03C7/00 , G03C8/10 , G03C1/40 , G03C5/54
CPC分类号： G03C8/10 , C09B29/0037
摘要： Metal complexes, particularly copper and nickel complexes of azo dyes corresponding to general formula (I) are suitable as color dyes for the production of color images by the dye diffusion transfer process. The dyes are (in non-metallized form), in the form of so-called "dye-releasers", bound to a redox-active carrier radical provided with a ballast group, which dye-releasers are associated to a light-sensitive silver halide emulsion layer. During development, the metallizable dyes are image-wise released and are converted, after diffusion into a light-receiving layer, into the corresponding metal complexes ##STR1## wherein E represents an electron acceptor radical; andK represents the radical of an azo coupler component, derived from an open-chain or closed ring ketomethylene compound, a cyclic enamine compound or a phenolic compound.
摘要翻译：金属络合物，特别是对应于通式（I）的偶氮染料的铜和镍络合物适用于通过染料扩散转移法生产彩色图像的彩色染料。染料以所谓的“染料释放剂”的形式（非金属化形式）结合到具有镇流器基团的氧化还原活性载体基团上，该染料释放剂与感光银相关联卤化物乳剂层。在显影过程中，金属化染料成像释放并在扩散到光接收层之后转化成相应的金属络合物，其中E表示电子受体基团; 并且K表示衍生自开链或闭环酮亚甲基化合物，环状烯胺化合物或酚类化合物的偶氮成色剂组分的基团。

9. 发明授权

US4521506A Monoazo pyridinol dyes chelated or capable of being chelated with metal ions and their use for image production 失效
标题翻译：螯合或能够与金属离子螯合的单偶氮吡啶酚染料及其用于图像生产
公开(公告)号：US4521506A
公开(公告)日：1985-06-04
申请号：US617499
申请日：1984-06-05
申请人： Rudolf Stolzenburg , Peter Bergthaller , Gerhard Wolfrum , Jurgen Strauss
发明人： Rudolf Stolzenburg , Peter Bergthaller , Gerhard Wolfrum , Jurgen Strauss
IPC分类号： C09B29/42 , G03C8/10 , G03C1/40
CPC分类号： C09B29/3639 , G03C8/10
摘要： Azo dyes corresponding to the formula (I): ##STR1## wherein R.sup.1 represents a releasable group, R.sup.2 represents H, halogen or sulphonyl, R.sup.3 and R.sup.4 represent H or groups not capable of chelate formation, and Q represents a group for completing a phenyl or naphthyl group,combine with nickel ions to form stable azo dye-metal complexes which have advantageous spectral properties. They are therefore particularly suitable for the production of highly light-fast magenta images, e.g. by the ink jet process, in which they may be used directly in the form of colored inks, or by the dye diffusion transfer process, in which they are released imagewise from suitable dye-releasers in the course of development and transferred to a dye-receptive layer.
摘要翻译：对应于式（I）的偶氮染料：其中R1表示可释放基团，R 2表示H，卤素或磺酰基，R 3和R 4表示H或不能螯合形成的基团，Q表示完成苯基或萘基，与镍离子结合形成具有有利光谱性质的稳定的偶氮染料 - 金属络合物。因此，它们特别适用于生产高度光鲜的品红色图像，例如，通过喷墨方法，其可以直接以彩色油墨的形式使用，或通过染料扩散转移方法使用，其中它们在显影过程中从合适的染料释放剂成像释放并转移到染料 - 接受层

10. 发明授权

US06498003B2 Photographic silver halide material 失效
标题翻译：摄影卤化银材料
公开(公告)号：US06498003B2
公开(公告)日：2002-12-24
申请号：US09915687
申请日：2001-07-26
申请人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst
发明人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst
IPC分类号： G03C1005
CPC分类号： G03C1/28
摘要： A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula and/or wherein R1 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R2 denotes OH, NH2, NHR7, NR8R9 or R1 together with R2, denotes the atoms necessary for the completion of a heteroaliphatic ring, R3 denotes OH, NH2, NHR7, NR8R9, R4 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R5, R6 independently of each other, denote OH, NH2, NHR10, NR11R12, or R4 together with R5, or R4 together with R6, denote the atoms necessary for the completion of a heteroaliphatic ring, and the R5 or R6 radical, which is not part of a ring, denotes OH, NH2, NHR10 or NR11R12, R7, R10 denote alkyl, aryl, aralkyl, heterocyclyl, R8, R9 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R8 together with R9, denotes the atoms necessary for the completion of a heteroaliphatic ring, and R11, R12 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R11 together with R12, denote the atoms necessary for the completion of a heterocyclic ring, and wherein only one of the radicals R2 and R3 and only one of the radicals R5 and R6 can denote OH or NH2, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.
摘要翻译：包含载体和至少一层包含至少一种光谱增感的卤化银乳剂的照相材料，其特征在于所述材料含有至少一种式和/或其中的R 1表示H，烷基，芳基，芳烷基，烯基，杂环基，R 2 表示OH，NH2，NHR7，NR8R9或R1与R2一起表示完成杂脂肪族环所需的原子，R3表示OH，NH2，NHR7，NR8R9，R4表示H，烷基，芳基，芳烷基，烯基，杂环基，R5 ，R6彼此独立地表示OH，NH2，NHR10，NR11R12或R4以及R5或R4与R6一起表示完成杂脂肪族环所必需的原子，以及不是部分的R5或R6基团表示OH，NH2，NHR10或NR11R12，R7，R10表示烷基，芳基，芳烷基，杂环基，R8，R9彼此独立地表示烷基，芳基，芳烷基，杂环基或R8与R9一起表示原子完成杂合子所必需的芳基，R 11，R 12彼此独立地表示烷基，芳基，芳烷基，杂环基或R 11与R 12一起表示完成杂环所必需的原子，并且其中仅一个基团R 2和R 3以及仅一个基团R5和R6可以表示OH或NH2，其特征在于增加的光谱灵敏度，高灵敏度/起雾比和在潮湿条件下的良好保质期。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式