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1. 发明申请

US20070244345A1 PROCESS FOR TREATING PHENOL 有权
标题翻译：处理酚醛的方法
公开(公告)号：US20070244345A1
公开(公告)日：2007-10-18
申请号：US11736507
申请日：2007-04-17
申请人： Gunther Lohmer , Otto Schnurr , Manfred Weber , Markus Weber
发明人： Gunther Lohmer , Otto Schnurr , Manfred Weber , Markus Weber
IPC分类号： C07C37/82 , C07C37/68
CPC分类号： C07C37/74 , C07C37/08 , C07C37/685 , C07C37/70 , C07C37/82 , C07C45/53 , C07C407/00 , C07C409/10 , C07C49/08 , C07C39/04
摘要： The present invention relates to a continuous method for treating a crude phenol stream comprising methylbenzofuran and hydroxyacetone by passing the crude phenol stream through at least two reactors connected in series the reactors containing an acidic ion exchange resin, whereby the temperature in successive reactors decreases in flow direction of the phenol stream so that the temperature in the first reactor in flow direction of the phenol stream is between 100° C. and 200° C. and the temperature in the last reactor in flow direction of the phenol stream is between 50° C. and 90° C. without a thermal separation step between any of two successive reactors and to the use of this method in a process for making phenol.
摘要翻译：本发明涉及通过使粗苯酚流通过串联连接的含有酸性离子交换树脂的反应器的至少两个反应器来处理包含甲基苯并呋喃和羟基丙酮的粗苯酚流的连续方法，由此连续反应器中的温度降低流动苯酚流的方向，使得苯酚流的流动方向上的第一反应器中的温度在100℃和200℃之间，并且最后的反应器中苯酚流的流动方向的温度为50℃ 和90℃，在两个连续的反应器中的任一个之间没有热分离步骤，并且在制备苯酚的方法中使用该方法。

2. 发明授权

US07544845B2 Process for treating phenol 有权
标题翻译：苯酚处理方法
公开(公告)号：US07544845B2
公开(公告)日：2009-06-09
申请号：US11736507
申请日：2007-04-17
申请人： Gunther Lohmer , Otto Schnurr , Manfred Weber , Markus Weber
发明人： Gunther Lohmer , Otto Schnurr , Manfred Weber , Markus Weber
IPC分类号： C07C37/00
CPC分类号： C07C37/74 , C07C37/08 , C07C37/685 , C07C37/70 , C07C37/82 , C07C45/53 , C07C407/00 , C07C409/10 , C07C49/08 , C07C39/04
摘要： The present invention relates to a continuous method for treating a crude phenol stream comprising methylbenzofuran and hydroxyacetone by passing the crude phenol stream through at least two reactors connected in series the reactors containing an acidic ion exchange resin, whereby the temperature in successive reactors decreases in flow direction of the phenol stream so that the temperature in the first reactor in flow direction of the phenol stream is between 100° C. and 200° C. and the temperature in the last reactor in flow direction of the phenol stream is between 50° C. and 90° C. without a thermal separation step between any of two successive reactors and to the use of this method in a process for making phenol.
摘要翻译：本发明涉及通过使粗苯酚流通过串联连接的含有酸性离子交换树脂的反应器的至少两个反应器来处理包含甲基苯并呋喃和羟基丙酮的粗苯酚流的连续方法，由此连续反应器中的温度降低流动苯酚流的方向，使得苯酚流的流动方向上的第一反应器中的温度在100℃和200℃之间，并且最后的反应器中苯酚流的流动方向的温度为50℃ 和90℃，在两个连续的反应器中的任一个之间没有热分离步骤，并且在制备苯酚的方法中使用该方法。

3. 发明申请

US20070244346A1 PROCESS FOR REMOVAL OF HYDROXYACETONE FROM PHENOL 审中-公开
标题翻译：从苯酚中除去羟基酮的方法
公开(公告)号：US20070244346A1
公开(公告)日：2007-10-18
申请号：US11736531
申请日：2007-04-17
申请人： Otto Schnurr , Manfred Weber , Markus Weber
发明人： Otto Schnurr , Manfred Weber , Markus Weber
IPC分类号： C07C37/08
CPC分类号： C07C37/08 , C07C39/04
摘要： The present invention relates to method for producing phenol which includes: a) oxidizing cumene to form an oxidation product containing cumene hydroperoxide; b) cleaving the oxidation product using an acidic catalyst to form a cleavage product containing phenol, acetone and impurities; c) neutralizing and washing the cleavage product with a basic aqueous medium to obtain a neutralized cleavage product; d) separating the neutralized cleavage product by at least one distillation step into at least a phenol containing fraction and an aqueous fraction comprising hydroxyacetone; e) treating the aqueous fraction with an oxidizing agent in presence of a base to obtain a basic aqueous medium reduced in hydroxyacetone; f) recycling at least a portion of the basic aqueous medium to the neutralizing and washing step c); and g) recovering phenol from the phenol containing fraction obtained in step d).
摘要翻译：本发明涉及苯酚的制备方法，其包括：a）氧化枯烯以形成含有氢过氧化枯烯的氧化产物; b）使用酸性催化剂切割氧化产物以形成含有苯酚，丙酮和杂质的裂解产物; c）用碱性水性介质中和洗涤裂解产物以获得中和的裂解产物; d）将中和的裂解产物通过至少一个蒸馏步骤分离成至少含苯酚的级分和包含羟基丙酮的含水级分; e）在碱的存在下用氧化剂处理含水部分以获得羟基丙酮中还原的碱性水性介质; f）将至少一部分碱性水性介质再循环到中和和洗涤步骤c）中; 和g）从在步骤d）中获得的含苯酚馏分中回收苯酚。

4. 发明授权

US06555719B2 Process for the thermal after-treatment of cleavage product from the acid-catalyzed cleavage of cumene hydroperoxide 有权
标题翻译：从氢过氧化枯烯的酸催化裂解中裂解产物的热后处理方法
公开(公告)号：US06555719B2
公开(公告)日：2003-04-29
申请号：US09847393
申请日：2001-05-03
申请人： Reinhard Sigg , Uwe Tanger , Manfred Weber , Otto Schnurr , Hugo H.J.M. Liefooghe
发明人： Reinhard Sigg , Uwe Tanger , Manfred Weber , Otto Schnurr , Hugo H.J.M. Liefooghe
IPC分类号： C07C3708
CPC分类号： C07C37/08 , C07C45/53 , Y02P20/52 , C07C49/08 , C07C39/04
摘要： The cleavage product from the acid-catalyzed cleavage of cumene hydroperoxide into phenol and acetone is subjected to thermal after-treatment by a process, which comprises heating the cleavage product in a reactor, wherein the heat supplied for the thermal treatment is the heat generated by at least one exothermic reaction which occurs in the reactor. The exothermic reaction which proceeds in the cleavage product is preferably the cleavage of cumene hydroperoxide.
摘要翻译：将氢过氧化枯烯酸催化裂解成苯酚和丙酮的裂解产物经过热处理后的方法，该方法包括加热反应器中的裂解产物，其中为热处理提供的热量是由在反应器中发生的至少一种放热反应。在切割产物中进行的放热反应优选是氢过氧化枯烯的裂解。

5. 发明申请

US20050034970A1 Process for the preparation of phenolic compounds, for separating phenol from cleavage product mixtures, and an apparatus 有权
标题翻译：酚类化合物的制备方法，用于从分离产物混合物中分离苯酚和设备
公开(公告)号：US20050034970A1
公开(公告)日：2005-02-17
申请号：US10888533
申请日：2004-07-09
申请人： Christoph Schwarz , Markus Weber , Manfred Weber
发明人： Christoph Schwarz , Markus Weber , Manfred Weber
IPC分类号： B01D3/14 , B01D3/32 , C07C37/08 , C07C37/74 , C07C39/04 , C07C45/53 , C07C45/82 , B01D3/00 , B01D3/02 , C07C27/26 , C07C29/74
CPC分类号： C07C45/82 , B01D3/146 , B01D3/322 , C07C37/08 , C07C37/74 , C07C45/53 , C07C49/17 , C07C49/08 , C07C39/04
摘要： To improve energy efficiency of prior art processes while preserving the standards of quality and total yield of desired end products, a process for the preparation of phenolic compounds is proposed. The process of the invention comprises working-up of the cleavage product mixtures by distillation, which comprises resolving the cleavage product mixture into at least three fractions in a single distillation step by feeding the cleavage product mixture to the side of a distillation column, removing a first fraction comprising the ketone at the top of the distillation column, removing a second fraction comprising the phenolic compound at the bottom of the distillation column, and removing a third fraction comprising unreacted the alkylaryl compound and the hydroxy ketone, and water, as side stream, whereby the side stream take-off is situated above the feed of cleavage product mixture to the distillation column, characterized by removing heat from the distillation column, whereby the heat take-off is situated above the side stream take-off of the third fraction, and a process for separating phenol from cleavage product mixtures, wherein the cleavage product mixture prior feeding into the distillation column, is preheated to a temperature of above 70° C. at standard pressure, preferably to a temperature of above 100° C., more preferably to a temperature between 110° C. and 180° C., most preferred to a temperature of about 140° C. to 146° C., and an apparatus suitable therefore.
摘要翻译：为了提高现有技术工艺的能量效率，同时保持所需最终产品的质量和总产量的标准，提出了制备酚类化合物的方法。本发明的方法包括通过蒸馏处理裂解产物混合物，其包括在单一蒸馏步骤中将裂解产物混合物分解成至少三个级分，将裂解产物混合物加入到蒸馏塔的侧面，除去在蒸馏塔顶部包含酮的第一馏分，在蒸馏塔的底部除去包含酚类化合物的第二级分，并除去包含未反应的烷基芳基化合物和羟基酮的第三馏分和水作为侧流，由此侧流起飞位于裂解产物混合物的进料到蒸馏塔的上方，其特征在于从蒸馏塔除去热量，由此该热量取出位于第三馏分的侧流起飞之上以及从裂解产物混合物中分离苯酚的方法，其中先前加入的裂解产物混合物蒸馏塔在标准压力下预热至高于70℃的温度，优选至高于100℃的温度，更优选至110℃至180℃的温度，最优选为温度为约140℃至146℃，因此适用的装置。

6. 发明授权

US07626060B2 Process for the preparation of phenolic compounds, for separating phenol from cleavage product mixtures, and an apparatus 有权
标题翻译：酚类化合物的制备方法，用于从分离产物混合物中分离苯酚和设备
公开(公告)号：US07626060B2
公开(公告)日：2009-12-01
申请号：US10888533
申请日：2004-07-09
申请人： Christoph Schwarz , Markus Weber , Manfred Weber
发明人： Christoph Schwarz , Markus Weber , Manfred Weber
IPC分类号： C07C37/00 , C07C37/68
CPC分类号： C07C45/82 , B01D3/146 , B01D3/322 , C07C37/08 , C07C37/74 , C07C45/53 , C07C49/17 , C07C49/08 , C07C39/04
摘要： To improve energy efficiency of prior art processes while preserving the standards of quality and total yield of desired end products, a process for the preparation of phenolic compounds is proposed. The process of the invention comprises working-up of the cleavage product mixtures by distillation, which comprises resolving the cleavage product mixture into at least three fractions in a single distillation step by feeding the cleavage product mixture to the side of a distillation column, removing a first fraction comprising the ketone at the top of the distillation column, removing a second fraction comprising the phenolic compound at the bottom of the distillation column, and removing a third fraction comprising unreacted the alkylaryl compound and the hydroxy ketone, and water, as side stream, whereby the side stream take-off is situated above the feed of cleavage product mixture to the distillation column, characterized by removing heat from the distillation column, whereby the heat take-off is situated above the side stream take-off of the third fraction, and a process for separating phenol from cleavage product mixtures, wherein the cleavage product mixture prior feeding into the distillation column, is preheated to a temperature of above 70° C. at standard pressure, preferably to a temperature of above 100° C., more preferably to a temperature between 110° C. and 180° C., most preferred to a temperature of about 140° C. to 146° C., and an apparatus suitable therefore.
摘要翻译：为了提高现有技术工艺的能量效率，同时保持所需最终产品的质量和总产量的标准，提出了制备酚类化合物的方法。本发明的方法包括通过蒸馏处理裂解产物混合物，其包括在单一蒸馏步骤中将裂解产物混合物分解成至少三个级分，通过将裂解产物混合物加入到蒸馏塔的侧面，除去在蒸馏塔顶部包含酮的第一馏分，在蒸馏塔的底部除去包含酚类化合物的第二级分，并除去包含未反应的烷基芳基化合物和羟基酮的第三馏分和水作为侧流，由此侧流起飞位于裂解产物混合物的进料到蒸馏塔的上方，其特征在于从蒸馏塔除去热量，由此该热量取出位于第三馏分的侧流起飞之上以及从裂解产物混合物中分离苯酚的方法，其中先前加入的裂解产物混合物蒸馏塔在标准压力下预热至高于70℃的温度，优选至高于100℃的温度，更优选至110℃至180℃的温度，最优选为温度为约140℃至146℃，因此适用的装置。

7. 发明授权

US06489518B1 Process for reducing the salt content of fractions comprising high boilers obtained in the preparation of phenol from cumene, by extraction 有权
$Process for reducing the salt content of fractions comprising high boilers obtained in the preparation of phenol from cumene, by extraction$
标题翻译：通过萃取，还原包含从异丙苯制备苯酚得到的高锅炉馏分的盐含量的方法
公开(公告)号：US06489518B1
公开(公告)日：2002-12-03
申请号：US09709353
申请日：2000-11-13
申请人： Manfred Weber , Markus Weber , Heinrich van Barneveld , Peter Bickert , Wilfried Jordan
发明人： Manfred Weber , Markus Weber , Heinrich van Barneveld , Peter Bickert , Wilfried Jordan
IPC分类号： C07C3768
CPC分类号： C07C37/72 , C07C39/04
摘要： A process for reducing the salt content of fractions comprising high boilers obtained in the preparation of phenol from cumene, by extraction, is claimed. In the preparation of phenol from cumene, not only phenol and acetone but also by-products such as dimethyl phenyl carbinol or acetophenone are formed in the cleavage of cumene hydroperoxide. In the work-up of the cleavage product phase by distillation, these by-products are obtained as a fraction which boils only at high temperatures. These fractions further comprise alkali metal in the form of salts as a result of the neutralization by means of aqueous sodium hydroxide after the acid catalyzed cleavage. The presence of salt in this phase makes the work-up of this phase considerably more difficult. The salt is usually removed from the fraction by extraction of the fraction with water. However, considerable problems can occur if the aqueous phase cannot be cleanly separated from the organic phase. According to the invention, not only water but also an organic liquid is added to the fractions comprising high boilers for the purposes of extraction. This aids and accelerates the subsequent phase separation. The organic liquid to be added to the fractions comprising high boilers can be removed again from the treated fractions by simple distillation. Furthermore, the process of the invention lowers the phenol content of the fractions comprising high boilers and phenol is recovered. Fractions comprising high boilers which have been treated according to the invention can be used as starting material for the production of carbon black.
摘要翻译：要求保护包含从异丙苯制备苯酚得到的高沸点馏分的馏分的盐含量的方法。在从异丙基苯制备苯酚时，在氢过氧化枯烯的裂解中不仅形成苯酚和丙酮，而且还产生二甲基苯基甲醇或苯乙酮等副产物。在通过蒸馏处理裂解产物相时，这些副产物作为仅在高温下沸腾的馏分获得。由于在酸催化裂解后通过氢氧化钠水溶液中和，这些级分还包含盐形式的碱金属。在这一阶段盐的存在使得这一阶段的后处理更加困难。盐通常通过用水萃取级分从馏分中除去。然而，如果水相不能与有机相清洁分离，则可能会发生相当大的问题。根据本发明，为了提取的目的，不仅将水，而且有机液体加入到包含高锅炉的馏分中。这有助于并加速随后的相分离。通过简单蒸馏，可以从经处理的馏分再次除去加入到包含高锅炉的馏分中的有机液体。此外，本发明的方法降低了包含高锅炉和苯酚的馏分的苯酚含量。根据本发明已经处理的包含高锅炉的馏分可以用作生产炭黑的起始原料。

8. 发明授权

US06444861B1 Process for the cleavage of alkylaryl hydroperoxides 有权
公开(公告)号：US06444861B1
公开(公告)日：2002-09-03
申请号：US09978718
申请日：2001-10-18
申请人： Uwe Tanger , Manfred Weber
发明人： Uwe Tanger , Manfred Weber
IPC分类号： C07C3708
CPC分类号： C07C37/08 , Y02P20/52 , Y02P20/582 , C07C39/04
摘要： A process for the cleavage of alkylaryl hydroperoxides includes steps for producing a mixture of a concentrate that contains at least one alkylaryl hydroperoxide to be cleaved and a cleavage product obtained from the cleavage of an alkylaryl hydroperoxide, dividing this mixture into at least two parts and cleaving the alkylaryl hydroperoxides in parallel at different temperatures. One of the two parts is treated at a temperature sufficiently high for an integrated thermal post-treatment to be achieved. The process consumes less energy since less steam has to be used. Problems which can result from fouling in heat exchangers are largely prevented. No second feed point for alkylaryl hydroperoxide has to be provided. The process can be used in the preparation of phenol and acetone by the Hock method.

9. 发明授权

US5753746A Formaldehyde-free aqueous synthetic resin dispersions 失效
标题翻译：无甲醛水溶性合成树脂分散体
公开(公告)号：US5753746A
公开(公告)日：1998-05-19
申请号：US806758
申请日：1997-03-03
申请人： Robert Rupaner , Karl-Heinz Schumacher , Manfred Weber
发明人： Robert Rupaner , Karl-Heinz Schumacher , Manfred Weber
IPC分类号： C08L25/08 , C08F2/22 , C08F6/00 , C08F212/00 , C08F212/08 , C08F220/12 , C08F220/58 , C08F246/00 , C08L25/00 , C08L31/02 , C08L31/04 , C08L33/04 , C08L33/08 , C08L33/18 , D04H1/4258 , D04H1/435 , D04H1/587 , D04H1/64 , D06M15/233 , D06M15/263 , D06M15/285 , D06M15/31 , D06M15/333 , B32B27/00
CPC分类号： D04H1/587 , C08F220/12 , C08F220/58 , C08F246/00 , C08F6/006 , D04H1/4258 , D04H1/435 , D04H1/64 , D06M15/233 , D06M15/263 , D06M15/285 , D06M15/31 , D06M15/333 , Y10T442/2738
摘要： Formaldehyde-free aqueous synthetic resin dispersions are obtainable by single-stage emulsion polymerization of monomer mixtures containing (A) from 50 to 99% by weight of at least one monomer selected from the group consisting of the acrylic and methacrylic esters of C.sub.1 -C.sub.14 -alkanols, the vinyl esters of monocarboxylic acids having up to 5 carbon atoms, and styrene (monomer A), (B) from 0.5 to 40% by weight of at least one of the monomers acrylonitrile and methacrylonitrile (monomer B), (C) from 0.5 to 10% by weight of at least one monomer of the general formula I ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2 and R.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl (monomer C), (D) from 0 to 5% by weight of at least one monomer selected from the group consisting of the 3 carbon to 5 carbon .alpha.,.beta.-unsaturated mono- and dicarboxylic acids and their amides and anhydrides (monomer D), and (E) from 0 to 3% by weight of at least one further bifunctional monomer (monomer E).
摘要翻译：不含甲醛的水性合成树脂分散体可通过单体乳液聚合获得，该单体混合物含有（A）50-99重量％的至少一种选自下组的单体：C1-C14- 链烷醇，具有至多5个碳原子的单羧酸的乙烯基酯和苯乙烯（单体A），（B）0.5至40重量％的至少一种单体丙烯腈和甲基丙烯腈（单体B），（C） 0.5至10重量％的至少一种通式I的单体，其中R 1是氢或甲基，R 2和R 3各自独立地是氢或C 1 -C 4 - 烷基（单体C），（ D）0至5重量％的至少一种选自3碳至5碳α，β-不饱和一羧酸和二羧酸及其酰胺和酸酐（单体D）的单体，和（E） 0至3重量％的至少一种另外的双官能单体（单体E）。

10. 发明授权

US06875898B2 Process for preparing phenols 有权
标题翻译：酚类制备方法
公开(公告)号：US06875898B2
公开(公告)日：2005-04-05
申请号：US10408152
申请日：2003-04-04
申请人： Manfred Weber , Reinhard Sigg , Michael Lausmann , Siegmund Greschek
发明人： Manfred Weber , Reinhard Sigg , Michael Lausmann , Siegmund Greschek
IPC分类号： C07C37/08
CPC分类号： C07C37/08 , C07C37/72 , C07C39/04
摘要： The present invention relates to a process for preparing phenols by adding an aqueous base to the reaction product from the acid-catalyzed cleavage of alkylaryl hydroperoxides while maintaining a homogeneous phase prior to the work-up of the product.
摘要翻译：本发明涉及通过在烷基芳基氢过氧化物的酸催化裂解的同时向反应产物中加入碱的水溶液制备酚的方法，同时在产品的后处理过程中保持均相。

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