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1. 发明授权

US07722947B2 Organic light-emitting diode comprising a doped organic layer 有权
标题翻译：有机发光二极管，包括掺杂的有机层
公开(公告)号：US07722947B2
公开(公告)日：2010-05-25
申请号：US11628294
申请日：2005-05-31
申请人： Gunther Haas , Salvatore Cina
发明人： Gunther Haas , Salvatore Cina
IPC分类号： H01L51/30 , H01L51/05 , H01L51/50 , H01L51/52
CPC分类号： H01L51/5092 , H01L51/5076 , H01L51/5231 , H01L51/5234 , H01L2251/5315 , H01L2251/5353 , Y10T428/26 , Y10T428/31533 , Y10T428/31855
摘要： The invention relates to an organic light-emitting diode comprising, on a substrate, generally one lower electrode followed by a flat conductive organic layer a doped organic layer, upon which an organic light-emitting layer is placed, and an upper electrode, which is placed upon this organic light-emitting layer and which is essentially transparent to the light produced in the light-emitting layer. The lower electrode and the flat organic layer serve as a cathode. The doped layer makes it possible to use a hole-conductive material for the flat layer.
摘要翻译：本发明涉及一种有机发光二极管，其在基板上通常包括一个下电极，随后是平坦的导电有机层，其上放置有机发光层的掺杂有机层和上电极，放置在该有机发光层上，并且对于在发光层中产生的光基本上是透明的。下电极和平面有机层用作阴极。掺杂层可以使用用于平坦层的空穴导电材料。

2. 发明授权

US08124248B2 Light-emissive polymer blends and light-emissive devices made from the same 有权
标题翻译：发光聚合物共混物和由其制成的发光器件
公开(公告)号：US08124248B2
公开(公告)日：2012-02-28
申请号：US11558373
申请日：2006-11-09
申请人： Salvatore Cina
发明人： Salvatore Cina
IPC分类号： H01L51/54 , B32B19/00 , C08G61/00
CPC分类号： H01L51/0036 , C09K11/06 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/5012 , Y10S428/917
摘要： A polymer blend comprising a first, light-emissive polymer comprising substituted or non-substituted units according to formulae (I) and (II) and a second, hole transport polymer comprising substituted or non-substituted fluorene units according to formula (I) and substituted or non-substituted triarylamine units, wherein the molecular weights of the first and second polymers and the blending ratio of the first and second polymers are selected such that, in use in a light-emissive device, the luminance of the emitted light at a bias of 5V is no less than 20,000 cd/m2. wherein R′ is independently in each occurrence H, C1-C20 hydrocarbyl or C1-C20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-C16 hydrocarbyl carbonyloxy, C4-C16 aryl(trialkylsiloxy) or both R′ may form together with the 9-carbon on the fluorene ring a C5-C20 cycloaliphatic structure containing one or more heteroatoms of S, N or O.
摘要翻译：一种聚合物共混物，其包含包含根据式（I）和（II）的取代或未取代的单元的第一发光聚合物和第二空穴传输聚合物，其包含根据式（I）的取代或未取代的芴单元和取代或未取代的三芳基胺单元，其中第一和第二聚合物的分子量和第一和第二聚合物的共混比被选择为使得在使用中在发光装置中发射的光的亮度在 5V的偏压不小于20,000cd / m2。其中R'在每次出现时独立地为H，C 1 -C 20烃基或含有一个或多个S，N，O，P或Si原子的C 1 -C 20烃基，C 4 -C 16烃基羰氧基，C 4 -C 16芳基（三烷基甲硅烷氧基）或R 可以与芴环上的9-碳一起形成含有一个或多个S，N或O的杂原子的C5-C20脂环族结构。

3. 发明申请

US20090072711A1 Organic light-emitting diode (oled) with improved light extraction and corresponding display unit 有权
标题翻译：有机发光二极管（oled），具有改进的光提取和相应的显示单元
公开(公告)号：US20090072711A1
公开(公告)日：2009-03-19
申请号：US11596749
申请日：2005-05-13
申请人： Salvatore Cina , Valter Drazic , Landry Chopin
发明人： Salvatore Cina , Valter Drazic , Landry Chopin
IPC分类号： H01J1/62
CPC分类号： H01L51/5203 , H01L51/5052 , H01L51/5209 , H01L51/5271
摘要： The invention relates to an organic light-emitting diode comprising on a substrate, from the rear face to the front face, at least one so-called rear electrode of a first type surmounted by an organic light-emitting layer, itself surmounted by at least one so-called front electrode of a second type, the organic light-emitting layer producing light when holes and electrons are injected into it by a current flowing through the electrodes, the types corresponding to an anode and a cathode, at least one of the electrodes being substantially transparent for the produced light in order to allow it to escape through one of the faces of said diode, referred to as the exit face. According to the invention, said substantially transparent electrode comprises at least one transparent extraction zone and at least one reflective zone adapted to return the produced light through the light-emitting layer, and said diode also comprises reflector means which are arranged on the opposite side of said substantially transparent electrode from the organic light-emitting layer and are adapted to return the produced light to said substantially transparent electrode through the light-emitting layer. The diode may be configured by embossing, and various embodiments are described.
摘要翻译：本发明涉及一种有机发光二极管，其包括在基板上，从背面到前面，至少一个被有机发光层所覆盖的第一类型的所谓后电极至少被至少覆盖一种所谓的第二类型的前电极，当空穴和电子被流过电极的电流注入到其中时产生光的有机发光层，对应于阳极和阴极的类型，至少一个电极对于所产生的光基本上是透明的，以便允许其通过被称为出射面的所述二极管中的一个面逸出。根据本发明，所述基本上透明的电极包括至少一个透明提取区和至少一个适于使所产生的光通过发光层返回的反射区，并且所述二极管还包括反射器装置，其布置在所述基本上透明的电极从所述有机发光层返回，并且将所产生的光通过所述发光层返回到所述基本上透明的电极。二极管可以通过压花构造，并且描述各种实施例。

4. 发明申请

US20080118724A1 Organic Light-Emitting Diode Having Doped Layers 有权
标题翻译：具有掺杂层的有机发光二极管
公开(公告)号：US20080118724A1
公开(公告)日：2008-05-22
申请号：US11667646
申请日：2005-11-24
申请人： Salvatore Cina , Benoit Racine , Christophe Fery
发明人： Salvatore Cina , Benoit Racine , Christophe Fery
IPC分类号： B32B7/02
CPC分类号： H01L51/5012 , H01L51/5032 , H01L51/5052 , H01L2251/5315 , Y10S428/917 , Y10T428/2495
摘要： Organic light-emitting diode comprising a lower electrode and an upper electrode, an organic electroluminescent layer and at least one doped organic layer in contact with one of said electrodes. According to the invention, the doping level of this organic layer is higher at the interface with the electrode than in the core of this layer. Thanks to the invention, the luminous efficiency of the diode is very substantially improved.
摘要翻译：包括下电极和上电极的有机发光二极管，有机电致发光层和与所述电极之一接触的至少一个掺杂有机层。根据本发明，该有机层的掺杂水平在与电极的界面处比在该层的核心上更高。由于本发明，二极管的发光效率大大提高。

5. 发明授权

US08395313B2 Light-emitting organic diode comprising not more than two layers of different organic materials 有权
公开(公告)号：US08395313B2
公开(公告)日：2013-03-12
申请号：US11921706
申请日：2006-06-09
申请人： David Vaufrey , Jean-Claude Martinez , Salvatore Cina
发明人： David Vaufrey , Jean-Claude Martinez , Salvatore Cina
IPC分类号： H01L51/54
CPC分类号： H01L51/5052
摘要： The diode comprises: a first layer based on a first organic material, which is n-doped in a zone of this layer that is in contact with a cathode, a second layer based on a second organic material, which is p-doped in a zone of this layer that is in contact with an anode, and an electroluminescent zone which is incorporated in one of the layers and is in contact with the other layer, and which is neither n-doped nor p-doped. A high-yield diode is thus obtained in a particularly economical way.

6. 发明授权

US07833812B2 Process for forming optical device having electron injection layer comprising barium 有权
标题翻译：用于形成具有包含钡的电子注入层的光学器件的工艺
公开(公告)号：US07833812B2
公开(公告)日：2010-11-16
申请号：US12033726
申请日：2008-02-19
申请人： Salvatore Cina
发明人： Salvatore Cina
IPC分类号： H01L21/00
CPC分类号： C09K11/06 , C09K2211/1416 , C09K2211/1433 , C09K2211/1483 , H01L51/0036 , H01L51/0037 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/5012 , H01L51/5036 , H01L51/5048 , H01L51/5092 , H01L51/5234 , H05B33/14 , Y02E10/549
摘要： An optical device comprising an anode, a cathode, an organic semiconducting material between the anode and the cathode, and an electron transport layer between the cathode and the organic semiconducting material wherein the organic semiconducting material comprises sulfur and the electron transport layer containing barium.
摘要翻译：包括阳极，阴极，阳极和阴极之间的有机半导体材料以及阴极和有机半导体材料之间的电子传输层的光学器件，其中有机半导体材料包含硫和含有钡的电子传输层。

7. 发明申请

US20080160341A1 Organic Light-Emitting Diode With Doped Layers 有权
标题翻译：具有掺杂层的有机发光二极管
公开(公告)号：US20080160341A1
公开(公告)日：2008-07-03
申请号：US11884837
申请日：2006-02-21
申请人： Salvatore Cina , Henri Doyeux , David Vaufrey , Armand Bettinelli
发明人： Salvatore Cina , Henri Doyeux , David Vaufrey , Armand Bettinelli
IPC分类号： B32B9/00 , B05D5/06
CPC分类号： H01L51/002 , H01L51/0026 , H01L51/5052 , H01L51/5092
摘要： The invention concerns an organic light-emitting diode comprising a lower electrode (2) and an upper electrode (8), an electroluminescent organic layer (5), and at least one doped organic layer (3; 7) in contact with one of said electrodes. The invention is characterized in that the doping is carried out using an alkaline-earth element or lanthanide, and the diode is heat-treated at temperature preferably not less than 60° C. for more than one hour. The invention enables the lighting performance of the diode to be considerably improved.
摘要翻译：本发明涉及一种有机发光二极管，包括下电极（2）和上电极（8），电致发光有机层（5）和至少一个掺杂的有机层（3; 7）电极。本发明的特征在于，使用碱土元素或镧系元素进行掺杂，并且将二极管在优选不低于60℃的温度下热处理超过1小时。本发明能够显着提高二极管的照明性能。

8. 发明申请

US20080145648A1 Organic Light-Emitting Diode Comprising a Doped Organic Layer 有权
标题翻译：有机发光二极管包含掺杂的有机层
公开(公告)号：US20080145648A1
公开(公告)日：2008-06-19
申请号：US11628294
申请日：2005-05-31
申请人： Guther Haas , Salvatore Cina
发明人： Guther Haas , Salvatore Cina
IPC分类号： H01L51/30
CPC分类号： H01L51/5092 , H01L51/5076 , H01L51/5231 , H01L51/5234 , H01L2251/5315 , H01L2251/5353 , Y10T428/26 , Y10T428/31533 , Y10T428/31855
摘要： The invention relates to an organic light-emitting diode comprising, on a substrate, generally one lower electrode followed by a flat conductive organic layer a doped organic layer, upon which an organic light-emitting layer is placed, and an upper electrode, which is placed upon this organic light-emitting layer and which is essentially transparent to the light produced in the light-emitting layer. The lower electrode and the flat organic layer serve as a cathode. The doped layer makes it possible to use a hole-conductive material for the flat layer.
摘要翻译：本发明涉及一种有机发光二极管，其在基板上通常包括一个下电极，随后是平坦的导电有机层，其上放置有机发光层的掺杂有机层和上电极，放置在该有机发光层上，并且对于在发光层中产生的光基本上是透明的。下电极和平面有机层用作阴极。掺杂层可以使用用于平坦层的空穴导电材料。

9. 发明申请

US20070120122A1 Optical device 审中-公开
标题翻译：光学装置
公开(公告)号：US20070120122A1
公开(公告)日：2007-05-31
申请号：US11605129
申请日：2006-11-28
申请人： Salvatore Cina
发明人： Salvatore Cina
IPC分类号： H01L51/00 , H01L51/54
CPC分类号： C09K11/06 , C09K2211/1416 , C09K2211/1433 , C09K2211/1483 , H01L51/0036 , H01L51/0037 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/5012 , H01L51/5036 , H01L51/5048 , H01L51/5092 , H01L51/5234 , H05B33/14 , Y02E10/549
摘要： An optical device comprising an anode, a cathode, an organic semiconducting material between the anode and the cathode, and an electron transport layer between the cathode and the organic semiconducting material wherein the organic semiconducting material comprises sulfur and the electron transport layer containing barium.
摘要翻译：包括阳极，阴极，阳极和阴极之间的有机半导体材料以及阴极和有机半导体材料之间的电子传输层的光学器件，其中有机半导体材料包含硫和含有钡的电子传输层。

10. 发明授权

US09496499B2 Organic light-emitting diode with doped layers 有权
标题翻译：有机发光二极管掺杂层
公开(公告)号：US09496499B2
公开(公告)日：2016-11-15
申请号：US11884837
申请日：2006-02-21
申请人： Salvatore Cina , Henri Doyeux , David Vaufrey , Armand Bettinelli
发明人： Salvatore Cina , Henri Doyeux , David Vaufrey , Armand Bettinelli
IPC分类号： H01L51/00 , H01L51/50
CPC分类号： H01L51/002 , H01L51/0026 , H01L51/5052 , H01L51/5092
摘要： The invention concerns an organic light-emitting diode comprising a lower electrode (2) and an upper electrode (8), an electroluminescent organic layer (5), and at least one doped organic layer (3; 7) in contact with one of said electrodes. The invention is characterized in that the doping is carried out using an alkaline-earth element or lanthanide, and the diode is heat-treated at temperature preferably not less than 60° C. for more than one hour. The invention enables the lighting performance of the diode to be considerably improved.
摘要翻译：本发明涉及一种有机发光二极管，包括下电极（2）和上电极（8），电致发光有机层（5）和至少一个掺杂的有机层（3; 7）电极。本发明的特征在于，使用碱土元素或镧系元素进行掺杂，并且将二极管在优选不低于60℃的温度下热处理超过1小时。本发明能够显着提高二极管的照明性能。

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