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1. 发明授权

US4402732A Herbicidally active dihalogenated imidazolecarboxylic acid amides, compositions and use 失效
标题翻译：除草活性二卤代咪唑甲酰胺，组成和用途
公开(公告)号：US4402732A
公开(公告)日：1983-09-06
申请号：US341038
申请日：1982-01-20
申请人： Gunther Beck , Bernd Baasner , Ludwig Eue , Robert Schmidt
发明人： Gunther Beck , Bernd Baasner , Ludwig Eue , Robert Schmidt
IPC分类号： A01N43/50 , C07D233/68 , C07D233/90 , C07D233/04
CPC分类号： C07D233/90 , A01N43/50
摘要： A dihalo-imidazolecarboxylic acid amide of the formula ##STR1## in which X each independently is chlorine or bromine,R.sup.1 is fluoroalkyl or fluorochloroalkyl, andR.sup.2 is hydrogen or alkylwhich possesses herbicidal activity and novel intermediates there
摘要翻译：其中X各自独立地为氯或溴，R 1为氟代烷基或氟氯烷基，R 2为氢或烷基

2. 发明授权

US4465504A Herbicidally active novel N-(2,2,2-trifluoroethyl)-N-alkyl-azolyloxyacetic acid amides and intermediates therefor 失效
标题翻译：除草活性的新型N-（2,2,2-三氟乙基）-N-烷基 - 叠氮基氧基乙酸酰胺及其中间体
公开(公告)号：US4465504A
公开(公告)日：1984-08-14
申请号：US350520
申请日：1982-02-19
申请人： Heinz Forster , Volker Mues , Bernd Baasner , Hermann Hagemann , Ludwig Eue , Robert Schmidt
发明人： Heinz Forster , Volker Mues , Bernd Baasner , Hermann Hagemann , Ludwig Eue , Robert Schmidt
IPC分类号： A01N43/72 , A01N43/74 , A01N43/80 , A01N43/82 , A01N43/836 , C07C67/00 , C07C231/00 , C07C231/02 , C07C235/06 , C07D263/58 , C07D277/20 , C07D277/32 , C07D277/34 , C07D277/56 , C07D277/68 , C07D285/08 , C07D285/12 , C07D285/13 , A01N43/76 , A01N43/78
CPC分类号： C07D263/58 , A01N43/74 , A01N43/80 , A01N43/82 , C07C235/06 , C07D277/34 , C07D277/56 , C07D277/68 , C07D285/08 , C07D285/13
摘要： An N-(2,2,2-trifluoroethyl)-N-alkyl-azolyloxyacetic acid amides of the formula ##STR1## in which R and R.sup.1 have the meaning given in the description, a process for the production of which is described, find use as herbicides. The intermediate products of the general formulae ##STR2## in which R.sup.1 in each case has the same meaning as in formula (I), for the preparation of the compounds (I) are also new.
摘要翻译：式（I）的N-（2,2,2-三氟乙基）-N-烷基 - 叠氮基氧基乙酰胺，其中R和R 1具有说明书中给出的含义，其制备方法为描述，用作除草剂。对于化合物（I）的制备，通式“IMAGE”（IV）和（II）的中间产物在每种情况下具有与式（I）中相同的含义）也是新的。

3. 发明授权

US4459151A Herbicidally active fluorine-containing 4,6-diamino-s-triazines 失效
标题翻译：除草活性的含氟4,6-二氨基-s-三嗪
公开(公告)号：US4459151A
公开(公告)日：1984-07-10
申请号：US408082
申请日：1982-08-13
申请人： Engelbert Kuhle , Bernd Baasner , Hermann Hagemann , Ludwig Eue , Robert R. Schmidt
发明人： Engelbert Kuhle , Bernd Baasner , Hermann Hagemann , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/70 , C07D251/44 , C07D251/50 , C07D251/52 , C07D251/70 , C07D251/66
CPC分类号： A01N43/70 , C07D251/44 , C07D251/50 , C07D251/52 , C07D251/70
摘要： Fluorine-containing 4,6-diamino-s-triazines of the formula ##STR1## wherein X is a chlorine atom, an alkoxy radical having 1 to 4 carbon atoms, an alkylthio radical having 1 to 4 carbon atoms or the azide radical,R.sup.1, R.sup.2 and R.sup.3 each independently is a hydrogen atom or an aliphatic radical, andR.sup.4 is a fluoroalkyl or fluorochloroalkyl radical,which possess herbicidal activity. Intermediates wherein X is chlorine and --NR.sup.1 R.sup.2 is replaced by chlorine are also new.
摘要翻译：含氟的4,6-二氨基-s-三嗪，其中X是氯原子，具有1至4个碳原子的烷氧基，具有1至4个碳原子的烷硫基或叠氮基，R1 R 2和R 3各自独立地为氢原子或脂族基，R 4为具有除草活性的氟烷基或氟氯烷基。其中X是氯和-NR1R2被氯取代的中间体也是新的。

4. 发明授权

US5066681A 1-trifluoromethyl-1-nitro-2-alkoxy-2-aryl-ethanes, their preparation and antimycotic agents containing them 失效
标题翻译： 1-三氟甲基-1-硝基-2-烷氧基-2-甲醛，其制备和含有它们的抗菌剂
公开(公告)号：US5066681A
公开(公告)日：1991-11-19
申请号：US409909
申请日：1989-09-20
申请人： Bernd Baasner , Gunther Beck , Helmut Heitzer , Klaus Scaller
发明人： Bernd Baasner , Gunther Beck , Helmut Heitzer , Klaus Scaller
IPC分类号： A01N33/20 , A01N35/04 , A01N43/78 , C07C205/31 , C07C205/34 , C07C205/44 , C07D277/24 , C07D277/32 , C07D277/34 , C07D277/58
CPC分类号： C07D277/24 , A01N33/20 , A01N35/04 , A01N43/78 , C07C205/31 , C07C205/34 , C07C205/44
摘要： 1-Trifluoromethyl-1-nitro-2-alkoxy-2-aryl-ethanes of the formula ##STR1## in which R.sup.1 represents a straight-chain or branched alkyl radical andR.sup.2 represents an optionally substituted aryl or hetaryl radical,their preparation from an aldehyde of the formula R.sup.2 -CHO, an alcohol of the formula R.sup.1 -OH and trifluoromethylnitromethane in the presence of a compound containing basic groups and antimycotic agents containing these compounds.
摘要翻译：式（I）的1-三氟甲基-1-硝基-2-烷氧基-2-芳基乙烷，其中R 1表示直链或支链烷基，R 2表示任选取代的芳基或杂芳基，它们在含有碱性基团的化合物和含有这些化合物的抗真菌剂的存在下，由式R 2-CHO的醛，式R 1 -OH的三氟甲基硝基甲烷制得。

5. 发明授权

US4960899A N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides, their use, process for their preparation, and the intermediates 2,4-dichlorothiazole-sulphonyl chloride and 2-amino-4-chloro-thiazole-sulphonamides 失效
标题翻译： N-磺基化的2-氨基-4-氯 - 噻唑磺酰胺，它们的用途及其制备方法，和中间体2,4-二氯噻唑 - 磺酰氯和2-氨基-4-氯 - 噻唑 - 磺酰胺
公开(公告)号：US4960899A
公开(公告)日：1990-10-02
申请号：US487679
申请日：1990-03-02
申请人： Gunther Beck , Bernd Baasner , Michael Schwamborn , Wilheim Brandes
发明人： Gunther Beck , Bernd Baasner , Michael Schwamborn , Wilheim Brandes
IPC分类号： C07D277/20 , A01N47/04 , C07D277/36 , C07D277/42 , C07D277/52 , C07D277/54 , C07D417/12
CPC分类号： C07D417/12 , A01N47/04 , C07D277/36 , C07D277/42 , C07D277/52
摘要： The fungicidally active N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another denote hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, aryl, aralkyl or an aromatic or a non-aromatic heterocyclic radical andR.sup.3 and R.sup.4 independently of one another stand for hydrogen, alkyl, cycloalkyl, aryl or aralkyl or for the dichlorohalogenomethyl-sulphenyl radical --S--CCl.sub.2 X, in which X denotes fluorine, chlorine or bromine, and where furthermore one of the pairs of substitutents R.sup.1 and R.sup.3 or R.sup.2 and R.sup.4 together with the nitrogen atom which they substitute can denote morpholino or thiomorpholino, with at least one of the radicals R.sup.3 and R.sup.4 standing for the radical --S--CCl.sub.2 X,can be prepared in a process in which, in a first step, 2,4-dichloro-thiazole is reacted with chlorosulphonic acid to give 2,4-dichloro-thiazole-sulphonyl chloride, in which, in a second step, the 2,4-dichloro-thiazole-sulphonyl chloride is reacted with primary amines or with a primary and a secondary amine to give 2-amino-4-chloro-thiazolesulphonamides, and in which, in a third step, the sulphonamides mentioned are reacted with dichlorohalogenomethylsulphenyl chlorides to give the substances of the formula (I).

6. 发明授权

US4906650A N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides, their use, process for their preparation, and the intermediates 2,4-dichlorothiazole-sulphonyl chloride and 2-amino-4-chloro-thiazole-sulphonamides 失效
标题翻译： N-磺基化的2-氨基-4-氯 - 噻唑磺酰胺，它们的用途及其制备方法，和中间体2,4-二氯噻唑 - 磺酰氯和2-氨基-4-氯 - 噻唑 - 磺酰胺
公开(公告)号：US4906650A
公开(公告)日：1990-03-06
申请号：US308180
申请日：1989-02-08
申请人： Gunther Beck , Bernd Baasner , Michael Schwamborn , Wilhelm Brandes
发明人： Gunther Beck , Bernd Baasner , Michael Schwamborn , Wilhelm Brandes
IPC分类号： C07D277/20 , A01N47/04 , C07D277/36 , C07D277/42 , C07D277/52 , C07D277/54 , C07D417/12
CPC分类号： C07D417/12 , A01N47/04 , C07D277/36 , C07D277/42 , C07D277/52
摘要： The fungicidally active N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another denote hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, aryl, aralkyl or an aromatic or a non-aromatic heterocyclic radical andR.sup.3 and R.sup.4 independently of one another stand for hydrogen, alkyl, cycloalkyl, aryl or aralkyl or for the dichlorohalogenomethyl-sulphenyl radical --S--CCl.sub.2 X, in which X denotes fluorine, chlorine or bromine, and where furthermore one of the pairs of substituents R.sup.1 and R.sup.3 or R.sup.2 andR.sup.4 together with the nitrogen atom which they substitute can denote morpholino or thiomorpholino, with at least one of the radicals R.sup.3 and R.sup.4 standing for the radical --S--CCl.sub.2 X,can be prepared in a process in which, in a first step, 2,4-dichloro-thiazole is reacted with chlorosulphonic acid to give 2,4-dichloro-thiazole-sulphonyl chloride, in which, in a second step, the 2,4-dichloro-thiazole-sulphonyl chloride is reacted with primary amines or with a primary and a secondary amine to give 2-amino-4-chloro-thiazole-sulphonamides, and in which, in a third step, the sulphonamides mentioned are reacted with dichlorohalogenomethylsulphenyl chlorides to give the substances of the formula (I).
摘要翻译：式（I）的杀真菌活性N-磺基化2-氨基-4-氯 - 噻唑 - 磺酰胺其中R 1和R 2彼此独立地表示氢，烷基，烯基，炔基，环烷基，芳基，芳烷基或芳族或非芳香族杂环基，R 3和R 4彼此独立地代表氢，烷基，环烷基，芳基或芳烷基或二氯卤代甲基 - 磺酰基-S-CCl 2 X，其中X表示氟，氯或溴，以及此外，取代基R 1和R 3或R 2和R 4中的一个与它们所取代的氮原子一起可以表示吗啉代或硫代吗啉基，其中R3和R4中至少一个代表基团-S-CCl 2，可以是其中在第一步中将2,4-二氯 - 噻唑与氯磺酸反应，得到2,4-二氯 - 噻唑 - 磺酰氯，其中在第二步中，2,4-二氯 - 二氯 - 噻唑 - 磺酰氯与伯胺反应胺或与伯胺和仲胺反应，得到2-氨基-4-氯 - 噻唑 - 磺酰胺，其中在第三步中，所述磺酰胺与二氯卤代甲基亚磺酰氯反应，得到式（I）的物质，。

7. 发明授权

US5258394A 1-trifluoromethyl-1-nitro-2-alkoxy-2-aryl-ethanes, their preparation and antimycotic agents containing them 失效
标题翻译： 1-三氟甲基-1-硝基-2-烷氧基-2-芳基乙烷，其制备物和含有它们的抗真菌剂
公开(公告)号：US5258394A
公开(公告)日：1993-11-02
申请号：US824614
申请日：1992-01-23
申请人： Bernd Baasner , Gunther Beck , Helmut Heitzer , Klaus Schaller
发明人： Bernd Baasner , Gunther Beck , Helmut Heitzer , Klaus Schaller
IPC分类号： A01N33/20 , A01N35/04 , A01N43/78 , C07C201/12 , C07C205/31 , C07C205/34 , C07C205/44 , C07D277/24 , C07D277/34 , C07D277/28
CPC分类号： A01N43/78 , A01N33/20 , A01N35/04 , C07C205/31 , C07C205/34 , C07C205/44 , C07D277/24
摘要： 1-Trifluoromethyl-1-nitro-2-alkoxy-2-aryl-ethanes of the formula ##STR1## in which R.sup.1 represents a straight-chain or branched alkyl radical andR.sup.2 represents an optionally substituted aryl or hetaryl radical,their preparation from an aldehyde of the formula R.sup.2 --CHO, an alcohol of the formula R.sup.1 --OH and trifluoromethylnitromethane in the presence of a compound containing basic groups and antimycotic agents containing these compounds.
摘要翻译：式（I）的1-三氟甲基-1-硝基-2-烷氧基-2-芳基乙烷，其中R 1表示直链或支链烷基，R 2表示任选取代的芳基或杂芳基，它们在含有碱性基团的化合物和含有这些化合物的抗真菌剂的存在下，由式R 2-CHO的醛，式R 1 -OH的三氟甲基硝基甲烷制得。

8. 发明授权

US6034116A Mixtures of substituted benzimidazoles with polyether antibiotics or synthetic coccidiostats as agents for use against parasitic protozoa 失效
标题翻译：取代的苯并咪唑与聚醚抗生素或合成球虫抑制剂的混合物作为用于抵抗寄生原虫的药剂
公开(公告)号：US6034116A
公开(公告)日：2000-03-07
申请号：US952758
申请日：1997-11-19
申请人： Lutz Assmann , Bernd Baasner , Axel Haberkorn , Folker Lieb , Winfried Lunkenheimer , Norbert Lui
发明人： Lutz Assmann , Bernd Baasner , Axel Haberkorn , Folker Lieb , Winfried Lunkenheimer , Norbert Lui
IPC分类号： C07D235/10 , A61K31/415 , A61K31/4184 , A61K45/06 , A61P33/02 , C07D235/22 , C07D409/12 , C07D413/12 , C07D491/056
CPC分类号： A61K45/06
摘要： The present invention relates to mixtures of substituted benzimidazoles and polyether antibiotics or synthetically prepared coccidiostats for controlling parasitic protozoa in livestock.
摘要翻译： PCT No.PCT / EP96 / 02164 Sec。 371日期：1997年11月19日 102（e）日期1997年11月19日PCT提交1996年5月20日PCT公布。出版物WO96 / 38140 日期1996年12月5日本发明涉及取代的苯并咪唑和聚醚抗生素的混合物或用于控制家畜中的寄生原虫的合成制备的球虫抑制剂。

9. 发明授权

US5863933A Substituted benzimidazoles 失效
标题翻译：取代的苯并咪唑
公开(公告)号：US5863933A
公开(公告)日：1999-01-26
申请号：US822565
申请日：1997-03-19
申请人： Winfried Lunkenheimer , Bernd Baasner , Folker Lieb , Stefan Bohm , Albrecht Marhold , Ulrich Gorgens , Wilhelm Stendel , Heinz-Wilhelm Dehne , Hans-Joachim Santel
发明人： Winfried Lunkenheimer , Bernd Baasner , Folker Lieb , Stefan Bohm , Albrecht Marhold , Ulrich Gorgens , Wilhelm Stendel , Heinz-Wilhelm Dehne , Hans-Joachim Santel
IPC分类号： A01N43/52 , A01N43/90 , A01N47/12 , A01N47/18 , A01N47/20 , A01N47/30 , A01N47/34 , A01N57/24 , C07D235/10 , C07D405/12 , C07D491/04 , C07D491/056 , C07F9/6506
CPC分类号： C07D405/12 , A01N43/52 , A01N43/90 , A01N47/12 , A01N47/18 , A01N47/20 , A01N47/30 , A01N47/34 , C07D235/10 , C07D491/04 , C07F9/65068
摘要： The invention relates to new substituted benzimidazole of the general formula (I) ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkoxy or optionally substituted aryl,R.sup.2 represents hydroxyl, cyano or in each case optionally substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkinyloxy, alkylthio, amino, aminocarbonyl, alkylcarbonyl, alkoxycarbonyl, alkoxycarbonyloxy, dialkoxyphosphonyl, (hetero)aryl, (hetero)arylcarbonyl, (hetero)aryloxycarbonyl, (hetero)arylcarbonyloxy or (hetero)arylaminocarbonylaminocarbonyloxy, andR.sup.3 represents fluoroalkyl,X.sup.1, X.sup.2, X.sup.3 and X.sup.4 independently of one another in each case represent hydrogen, halogen, cyano, nitro, in each case optionally substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl or cycloalkyl, optionally substituted, fused dioxyalkylene, or represent hydroxycarbonyl, alkylcarbonyl, alkoxycarbonyl or cycloalkyloxycarbonyl, in each case optionally substituted amino or aminocarbonyl or in each case optionally substituted aryl, aryloxy, arylthio, arylsulphinyl, arylsulphonyl, arylsulphonyloxy, arylcarbonyl, aryloxycarbonyl, arylazo or arylthiomethylsulphonyl, but where at least one of the substituents X.sup.1, X.sup.2, X.sup.3 or X.sup.4 represents halogenoalkyl, with the exception of the chloromethyl radical, halogenoalkoxy, halogenoalkylthio, halogenoalkylsulphinyl, halogenoalkylsulphonyl or alkylsulphonyl, optionally substituted, fused dioxyalkylene, or represent hydroxycarbonyl, alkylcarbonyl, alkoxycarbonyl or cycloalkyloxycarbonyl, in each case optionally substituted amino or aminocarbonyl, or in each case optionally substituted aryl, arylthio, arylsulphinyl, arylsulphonyl, arylsulphonyloxy, arylcarbonyl, aryloxycarbonyl, arylazo or arylthiomethylsulphonyl,their preparation and use as pesticides, and intermediates for their preparation.
摘要翻译：本发明涉及通式（I）的新取代的苯并咪唑，其中R 1表示氢，烷基，烷氧基或任选取代的芳基，R 2表示羟基，氰基或在各种情况下任选取代的烷基，烯基，炔基（杂）芳基羰基，（杂）芳基羰基氧基或（杂）芳基氨基羰基氨基羰基氧基，R3代表氟代烷基，芳基羰氧基，在各种情况下，X1，X2，X3和X4彼此独立地表示氢，卤素，氰基，硝基，在各种情况下均为任选取代的烷基，烷氧基，烷硫基，烷基亚磺酰基，烷基磺酰基或环烷基，任选取代的稠合二氧亚烷基，或代表羟基羰基，烷基羰基，烷氧基羰基或环烷氧基羰基，在每种情况下均为任选取代的氨基或氨基羰基，或在每种情况下任选取代芳基，芳氧基，芳硫基，芳基亚磺酰基，芳基磺酰基，芳基磺酰氧基，芳基羰基，芳氧基羰基，芳基偶氮或芳基硫代甲基磺酰基，但其中至少一个取代基X1，X2，X3或X4表示卤代烷基，除了氯甲基，卤代烷氧基，卤代烷硫基，卤代烷基亚磺酰基，卤代烷基磺酰基或烷基磺酰基，任选取代的稠合的二氧亚烷基，或代表羟基羰基，烷基羰基，烷氧基羰基或环烷氧基羰基，在各种情况下均为任选取代的氨基或氨基羰基，或在每种情况下均为任选取代的芳基，芳硫基，芳基亚磺酰基，芳基磺酰基，芳基磺酰氧基，芳基羰基，芳氧基羰基，芳基偶氮或芳基硫代甲基磺酰基，它们的制备和用作农药，以及其制备中间体。

10. 发明授权

US5656649A Substituted benzimidazoles 失效
公开(公告)号：US5656649A
公开(公告)日：1997-08-12
申请号：US428087
申请日：1995-05-25
申请人： Winfried Lunkenheimer , Bernd Baasner , Folker Lieb , Stefan Bohm , Albrecht Marhold , Ulrich Gorgens , Wilhelm Stendel , Heinz-Wilhelm Dehne , Hans-Joachim Santel
发明人： Winfried Lunkenheimer , Bernd Baasner , Folker Lieb , Stefan Bohm , Albrecht Marhold , Ulrich Gorgens , Wilhelm Stendel , Heinz-Wilhelm Dehne , Hans-Joachim Santel
IPC分类号： A01N43/52 , A01N43/90 , A01N47/12 , A01N47/18 , A01N47/20 , A01N47/30 , A01N47/34 , A01N57/24 , C07D235/10 , C07D405/12 , C07D491/04 , C07D491/056 , C07F9/6506
CPC分类号： C07D405/12 , A01N43/52 , A01N43/90 , A01N47/12 , A01N47/18 , A01N47/20 , A01N47/30 , A01N47/34 , C07D235/10 , C07D491/04 , C07F9/65068
摘要： The invention relates to new substituted benzimidazoles of the general formula (I) ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkoxy or optionally substituted aryl,R.sup.2 represents hydroxyl, cyano or in each case optionally substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkinyloxy, alkylthio, amino, aminocarbonyl, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy, dialkoxyphosphonyl, (hetero)aryl, (hetero)arylcarbonyl, (hetero)aryloxycarbonyl, (hetero)arylcarbonyloxy or (hetero)arylaminocarbonylaminocarbonyloxy, andR.sup.3 represents fluoroalkyl,X.sup.1, X.sup.2, X.sup.3 and X.sup.4 independently of one another in each case represent hydrogen, halogen, cyano, nitro, in each case optionally substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl or cycloalkyl, optionally substituted, fused dioxyalkylene, or represent hydroxycarbonyl, alkylcarbonyl, alkoxycarbonyl or cycloalkyloxycarbonyl, in each case optionally substituted amino or aminocarbonyl or in each case optionally substituted aryl, aryloxy, arylthio, arylsulphinyl, arylsulphonyl, arylsulphonyloxy, arylcarbonyl, aryloxycarbonyl, arylazo or arylthiomethylsulphonyl, but where at least one of the substituents X.sup.1, X.sup.2, X.sup.3 or X.sup.4 represents halogenoalkyl, with the exception of the chloromethyl radical, halogenoalkoxy, halogenoalkylthio, halogenoalkylsulphinyl, halogenoalkylsulphonyl or alkylsulphonyl, optionally substituted, fused dioxyalkylene, or represent hydroxycarbonyl, alkylcarbonyl, alkoxycarbonyl or cycloalkyloxycarbonyl, in each case optionally substituted amino or aminocarbonyl, or in each case optionally substituted aryl, arylthio, arylsulphinyl, arylsulphonyl, arylsulphonyloxy, arylcarbonyl, aryloxycarbonyl, arylazo or arylthiomethylsulphonyl,their preparation and use as pesticides, and intermediates for their preparation.

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