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1. 发明授权

US06933371B2 Bisazo dyestuffs based on hydroxynaphthalene carboxylic acid 失效
标题翻译：基于羟基萘羧酸的双偶氮染料
公开(公告)号：US06933371B2
公开(公告)日：2005-08-23
申请号：US10363695
申请日：2001-09-13
申请人： Gunter-Rudolf Schröder , Sophia Ebert , Karl-Heinz Etzbach , Rainer Tresch , Rüdiger Sens
发明人： Gunter-Rudolf Schröder , Sophia Ebert , Karl-Heinz Etzbach , Rainer Tresch , Rüdiger Sens
IPC分类号： C09B35/033 , C09B35/215 , C09B44/06 , D06P1/08 , D21H21/28 , D06P1/41 , D06P1/66
CPC分类号： C09B35/033 , C09B35/215 , C09B44/06 , Y10S8/916 , Y10S8/918 , Y10S8/919 , Y10S8/92
摘要： Disclosed are bisazo compounds of the formula Ia or Ib where R1 is hydrogen or methyl, the X groups are independently —CH2CH2— or —CH2CH2CH2—, R2, R3, and R4 are independently hydrogen or methyl, A is an anion and n corresponds to the valency of A. Also disclosed are the use of the bisazo compounds for dyeing, especially paper, and colorants containing said bisazo compounds.
摘要翻译：公开了式Ia或Ib的双偶氮化合物，其中R 1是氢或甲基，X基团独立地是-CH 2 CH 2 - 或-CH 2 CH 2 CH 2 - ，R 2，R 3， R 4独立地是氢或甲基，A是阴离子，n对应于A的化合价。还公开了双偶氮化合物用于染色的用途，特别是纸和含有所述双偶氮的着色剂化合物。

2. 发明授权

US06903197B2 Azoxy dyes and copper complexes thereof 失效
标题翻译：偶氮染料及其铜络合物
公开(公告)号：US06903197B2
公开(公告)日：2005-06-07
申请号：US10795585
申请日：2004-03-09
申请人： Rainer Tresch , Karl-Heinz Etzbach , Rüdiger Sens , Claudia Kräh
发明人： Rainer Tresch , Karl-Heinz Etzbach , Rüdiger Sens , Claudia Kräh
IPC分类号： C09B35/039 , C09B35/029 , C09B43/10 , C09B43/44 , C09B45/28
CPC分类号： C09B45/28 , C09B43/10 , C09B43/44
摘要： Azoxy dyes of the general formula I in the form of the free acid where n is 0 or 1, each R1 is selected from the group consisting of methoxy, hydroxyl and carboxyl, each R2 is selected from the group consisting of carboxyl, amino, C1-C4-alkylamino, allylamino, benzylamino and methoxycarbonylmethylamino, and the phenyl rings A may additionally be substituted by C1-C8-alkyl, unsubstituted or methyl- or halogen-substituted phenyl, hydroxyl, amino, nitro, halogen, carboxyl, N-benzylcarbamoyl, unsubstituted or nitro-, halogen-, C1-C4-alkoxy- or acetoxy-substituted phenylcarbamoyl and naphthylcarbamoyl or be benzofused, their copper complexes, a process for preparing the copper complex dyes, azoxy dyes of the formula I in their partially or completely deacylated form, their copper complexes, colorants comprising these azoxy dyes and/or their copper complexes and also their use for dyeing and printing natural or synthetic substrates.
摘要翻译： n为0或1的游离酸形式的通式I的芳氧基染料，每个R 1选自甲氧基，羟基和羧基，每个R 2 选自羧基，氨基，C 1 -C 4 - 烷基氨基，烯丙基氨基，苄基氨基和甲氧基羰基甲基氨基，苯基环A可以另外被C 1 -C 8 - 烷基取代，未取代的或甲基或卤素取代的苯基，羟基，氨基，硝基，卤素，羧基，N-苄基氨基甲酰基，未取代的或硝基，卤素，C 1 -C 4 - 烷氧基或乙酰氧基取代的苯基氨基甲酰基和萘基氨基甲酰基或苯并稠合，它们的铜配合物，制备铜的方法复合染料，它们部分或完全脱酰基形式的式I的偶氮染料，它们的铜络合物，包含这些偶氮染料和/或它们的铜络合物的着色剂，以及它们用于染色和印刷的用途 ral或合成底物。

3. 发明授权

US06727351B1 Azoxy dyes and their Cu complexes 失效
标题翻译：偶氮染料及其Cu配合物
公开(公告)号：US06727351B1
公开(公告)日：2004-04-27
申请号：US09936432
申请日：2001-09-13
申请人： Rainer Tresch , Karl-Heinz Etzbach , Rüdiger Sens , Claudia Kräh
发明人： Rainer Tresch , Karl-Heinz Etzbach , Rüdiger Sens , Claudia Kräh
IPC分类号： C09B4310
CPC分类号： C09B45/28 , C09B43/10 , C09B43/44
摘要： Azoxy dyes of the general formula I in the form of the free acid where n is 0 or 1, each R1 is selected from the group consisting of methoxy, hydroxyl and carboxyl, each R2 is selected from the group consisting of carboxyl, amino, C1-C4-alkylamino, allylamino, benzylamino and methoxycarbonylmethylamino, and the phenyl rings A may additionally be substituted by C1-C8-alkyl, unsubstituted or methyl- or halogen-substituted phenyl, hydroxyl, amino, nitro, halogen, carboxyl, N-benzylcarbamoyl, unsubstituted or nitro-, halogen-, C1-C4-alkoxy- or acetoxy-substituted phenylcarbamoyl and naphthylcarbamoyl or be benzofused, their copper complexes, a process for preparing the copper complex dyes, azoxy dyes of the formula I in their partially or completely deacylated form, their copper complexes, colorants comprising these azoxy dyes and/or their copper complexes and also their use for dyeing and printing natural or synthetic substrates.
摘要翻译：游离酸式的通式I的偶氮染料为0或1，每个R 1选自甲氧基，羟基和羧基，每个R 2选自羧基，氨基，C 1 -C 4 - 烷基氨基，烯丙基氨基，苄基氨基和甲氧基羰基甲基氨基，并且苯环A可另外被C 1 -C 8 - 烷基，未取代的或甲基或卤素取代的苯基，羟基，氨基，硝基，卤素，羧基，N - 苄基氨基甲酰基，未取代的或硝基 - ，卤素 - ，C 1 -C 4 - 烷氧基 - 或乙酰氧基取代的苯基氨基甲酰基和萘基氨基甲酰基或被苯并稠合，它们的铜络合物，制备铜络合物染料的方法，式I的氧化偶氮染料在其部分或完全脱酰基形式，它们的铜络合物，包含这些偶氮染料和/或其铜络合物的着色剂，以及它们用于染色和印刷天然或合成底物的用途。

4. 发明授权

US06221114B1 Colorant salts and their use in dyeing polymeric material 失效
标题翻译：着色剂及其在染色聚合物材料中的用途
公开(公告)号：US06221114B1
公开(公告)日：2001-04-24
申请号：US09380620
申请日：1999-09-17
申请人： Frank Würthner , Rüdiger Sens , Günther Seybold , Karl-Heinz Etzbach
发明人： Frank Würthner , Rüdiger Sens , Günther Seybold , Karl-Heinz Etzbach
IPC分类号： C08B6902
CPC分类号： C09D11/328 , C09B47/26 , C09B67/0073 , Y10S8/919
摘要： Dye salts which are free from fiber-reactive radicals and have the formula where Chr is an (m+n)-valent radical of a chromophore from the series of the metal-free or metal-containing phthalocyanines, of the quinacridones, of the mono-, dis- or polyazo dyes, of the anthraquinones or copper formazans, Ar is phenyl or naphthyl each of which is unsubstituted or substituted, x⊕ is a metal cation or ammonium ion, y⊕ is a proton, metal cation or ammonium ion, m is 1 to 6 and n is 1 to 6, the sum of m and n being not more than 7, are used in methods of dyeing or printing polymeric material and in dye preparations.
摘要翻译：不含纤维反应性基团并且具有式（C）的染料盐是来自喹吖啶酮的一系列无金属或金属的酞菁的（m + n）价的基团，蒽醌或铜类的二异或多偶氮染料，Ar是未取代或取代的苯基或萘基，x是金属阳离子或铵离子，y是质子，金属阳离子或铵离子，m是 1至6和n为1至6，m和n的总和不大于7，用于染色或印刷聚合物材料和染料制剂的方法中。

5. 发明授权

US06302924B1 Dye mixtures containing thienyl and/or thiazolazo dyes 失效
标题翻译：包含噻吩和/或噻唑偶氮染料的染料混合物
公开(公告)号：US06302924B1
公开(公告)日：2001-10-16
申请号：US09142172
申请日：1998-09-22
申请人： Karl-Heinz Etzbach , Rüdiger Sens , Claudia Kräh , Frank Wüthner
发明人： Karl-Heinz Etzbach , Rüdiger Sens , Claudia Kräh , Frank Wüthner
IPC分类号： D06P104
CPC分类号： B41M5/3858 , B41M5/3852 , B41M5/3854 , B41M5/388 , C09B67/0041 , C09B67/0051
摘要： Dye mixtures comprising one or more thienyl- and/or thiazole-azo dyes with a coupling component of the aminothiazole, aniline or tetrahydroquinoline series, one or more dyes of the class of the monoazo or disazo dyes, methine dyes, azamethine dyes, anthraquinone dyes, nitro dyes or quinophthalone dyes which have their respective absorption maximum at a wavelength of from 410 to 520 nm and optionally one or more dyes of the class of the monoazo or disazo dyes, methine dyes, azamethine dyes, anthraquinone dyes, nitro dyes or quinophthalone dyes which have their respective absorption maximum at a wavelength of from 600 to 700 nm, the FWHM value of the absorption maximum being at least 2000 cm−1, are useful for thermal transfer and for dyeing or printing synthetic materials.
摘要翻译：包含一种或多种噻吩 - 和/或噻唑 - 偶氮染料与氨基噻唑，苯胺或四氢喹啉系列的偶联组分的一种或多种单偶氮或双偶氮染料类型的一种或多种染料，次甲基染料，azamethine染料，蒽醌染料硝基染料或喹酞酮染料，它们在波长为410-520nm处具有相应的吸收最大值，以及任选的一种或多种单偶氮或双偶氮染料，次甲基染料，氮杂酮染料，蒽醌染料，硝基染料或喹酞酮的一种或多种染料在600-700nm波长处具有各自吸收最大值的吸收最大值的FWHM值至少为2000cm -1的染料可用于热转印和用于染色或印刷合成材料。

6. 发明授权

US6048968A Cationic azo dyes based on aminobenzoic acid 失效
标题翻译：基于氨基苯甲酸的阳离子偶氮染料
公开(公告)号：US6048968A
公开(公告)日：2000-04-11
申请号：US305279
申请日：1999-05-05
申请人： Karl-Heinz Etzbach , Torsten Freund , Rainer Tresch
发明人： Karl-Heinz Etzbach , Torsten Freund , Rainer Tresch
IPC分类号： C07C229/56 , C07C237/34 , C09B35/21 , C09B35/378 , C09B44/02 , C09B44/04 , C09B44/06 , C09B44/08 , C09B67/22 , D06P5/00
CPC分类号： C09B35/378 , C07C229/56 , C07C237/34 , C09B35/21 , C09B44/02 , C09B67/0046
摘要： Cationic azo dyes of the formula I ##STR1## where the variables are as defined in the specification, amines as their intermediates, processes for preparing them, their use for dyeing and printing natural or synthtic substrates, and their mixtures are described.
摘要翻译：描述了式I的阳离子偶氮染料，其中变量如本说明书中所定义，胺作为其中间体，其制备方法，其用于染色和印刷天然或合成底物及其混合物的用途。

7. 发明授权

US06346609B1 Cationic azo-dyes 失效
标题翻译：阳离子偶氮染料
公开(公告)号：US06346609B1
公开(公告)日：2002-02-12
申请号：US09807999
申请日：2001-05-04
申请人： Karl-Heinz Etzbach , Torsten Freund , Rainer Tresch
发明人： Karl-Heinz Etzbach , Torsten Freund , Rainer Tresch
IPC分类号： C09B35023
CPC分类号： C09B44/02 , C09B67/0046 , Y10S534/03
摘要： Cationic azo dyes of the general formula I where R1, R2, R3, A1, A2, B1, B2, An⊖, n and K have the meaning given in the specification are prepared and used for the dyeing and printing of natural or synthetic substrates and mixtures thereof.
摘要翻译：具有通式I的阳离子偶氮染料，其中R1，R2，R3，A1，A2，B1，B2，An⊖，n和K具有本说明书中给出的含义，并用于天然或合成底物的染色和印刷，其混合物。

8. 发明授权

US06335462B1 Polymerizable oligomesogenes 失效
标题翻译：可聚合低聚单体
公开(公告)号：US06335462B1
公开(公告)日：2002-01-01
申请号：US09308634
申请日：1999-05-27
申请人： Karl-Heinz Etzbach , Karl Siemensmeyer , Peter Schuhmacher
发明人： Karl-Heinz Etzbach , Karl Siemensmeyer , Peter Schuhmacher
IPC分类号： C07C6976
CPC分类号： C07J9/00 , C07C69/90 , C07C69/92 , C07C317/46 , C07C323/62 , C09K19/2007 , C09K19/2014 , C09K19/3068 , C09K19/36 , C09K19/3852 , C09K19/3866 , C09K2019/0448
摘要： The compounds of the formula I X[—Y1—A1—Y2—M—Y3—A2—Z]n I, wherein the variables are as defined in the specification. The compounds are suitable as alignment layers for liquid-crystalline materials, as photocrosslinkable adhesives, as monomers for the production of liquid-crystalline networks, as base material for the preparation of polymerizable liquid-crystal systems which can be doped by chiral compounds, as polymerizable matrix monomers for polymer-dispersed displays or as base material for polymerizable, liquid-crystalline materials for optical components, such as polarizers, retardation plates or lenses.
摘要翻译：变量中的式I化合物如本说明书中所定义。化合物适合作为液晶材料的取向层，作为可光致交联粘合剂，作为制备液晶网络的单体，用作制备可由手性化合物掺杂的可聚合液晶体系，作为聚合物分散显示器的聚合性基体单体，或作为用于光学部件如偏振片，相位差板或透镜的可聚合液晶材料的基材。

9. 发明授权

US6099750A Use of organic compounds in the plastic columnar discotic liquid-crystal phase for transport of electric charges 有权
标题翻译：在塑料柱状盘状液晶相中使用有机化合物来运输电荷
公开(公告)号：US6099750A
公开(公告)日：2000-08-08
申请号：US77167
申请日：1998-11-20
申请人： Jurgen Simmerer , Karl-Heinz Etzbach , Karl Siemensmeyer , Wolfgang Paulus , Peter Schuhmacher , Birgit Glusen , Helmut Ringsdorf , Joachim H. Wendorff , Dietrich Haarer , Andreas Kettner
发明人： Jurgen Simmerer , Karl-Heinz Etzbach , Karl Siemensmeyer , Wolfgang Paulus , Peter Schuhmacher , Birgit Glusen , Helmut Ringsdorf , Joachim H. Wendorff , Dietrich Haarer , Andreas Kettner
IPC分类号： H01L51/50 , C07C63/307 , C07C69/00 , C09K19/32 , G03G5/06 , G03G5/07 , H01B1/12 , H01L51/00 , H01L51/30 , C09K19/58 , G03G15/00
CPC分类号： G03G5/076 , C07C69/00 , C09K19/32 , G03G5/0605 , G03G5/0618 , G03G5/062 , G03G5/075 , H01L51/0054 , H01L51/0076 , C07C2103/00 , C09K2019/328 , Y02E10/549
摘要： Use of compounds in the plastic columnar discotic liquid-crystal phase for transport of electric charges.
摘要翻译： PCT No.PCT / DE96 / 02262 Sec。 371日期：1998年11月20日 102（e）1998年11月20日日期PCT 1996年11月25日PCT PCT。第WO97 / 19142号PCT公告日期1997年5月29日在塑料柱状盘状液晶相中的化合物用于运输电荷。

10. 发明授权

US5962691A Methine and azamethine dyes based on trifluoromethylpyridones 失效
标题翻译：基于三氟甲基吡啶的甲基和azamethine染料
公开(公告)号：US5962691A
公开(公告)日：1999-10-05
申请号：US817929
申请日：1997-05-09
申请人： Andreas Johann Schmidt , Rudiger Sens , Karl-Heinz Etzbach
发明人： Andreas Johann Schmidt , Rudiger Sens , Karl-Heinz Etzbach
IPC分类号： B41M5/385 , B41M5/388 , B41M5/39 , C07D213/69 , C07D213/74 , C07D213/85 , C07D213/90 , C07D401/04 , C07D417/04 , C07D417/06 , C07D417/12 , C09B23/00 , C09B23/04 , C09B23/16 , C09B55/00 , C09B57/00 , D06P1/13 , D06P3/52 , D06P5/13 , G03G9/09 , B41M5/24 , B41M5/26
CPC分类号： B41M5/385 , C09B23/04 , C09B55/009 , G03G9/0906 , B41M5/3854 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： Pyridone dyes of the formula I ##STR1## where X is nitrogen or CH,R.sup.1 is a 5-membered or 6-membered carbocyclic or heterocyclic radical,R.sup.2 is cyano, carbamoyl, C.sub.1 -C.sub.6 -alkoxycarbonyl or C.sub.1 -C.sub.4 -alkanoyl andR.sup.3 is unsubstituted or substituted C.sub.1 -C.sub.13 -alkyl, unsubstituted or substituted phenyl or unsubstituted or substituted amino,a method for their thermal transfer and a method for coloring or printing synthetic materials by means of the novel dyes.The invention concerns pyridone dyes of the formula (I) in which X is nitrogen or CH, R.sup.1 is a five-membered or six-membered carbocyclic or heterocyclic group, R.sup.2 is cyano, carbamoyl, C.sub.1 -C.sub.6 alkoxycarboyl or C.sub.1 -C.sub.4 alkanoyl and R.sup.3 is optionally substituted C.sub.1 -C.sub.13 alkyl, optionally substituted phenyl or optionally substituted amino. The invention also concerns a method for the thermal transfer of such dyes as well as a method for dyeing or printing on synthetic materials using the dyes.
摘要翻译： PCT No.PCT / EP95 / 04267 371日期1997年5月9日 102（e）日期1997年5月9日PCT提交1995年10月31日PCT公布。公开号WO96 / 15195 日期：1996年5月23日式I的吡啶酮染料其中X是氮或CH，R 1是5元或6元碳环或杂环基，R 2是氰基，氨基甲酰基，C 1 -C 6 - 烷氧基羰基或C 1 -C 4 - 烷酰基， R3是未取代或取代的C1-C13 - 烷基，未取代或取代的苯基或未取代或取代的氨基，其热转移方法和通过新型染料着色或印刷合成材料的方法。本发明涉及式（I）的吡啶酮染料，其中X是氮或CH，R 1是五元或六元碳环或杂环基，R 2是氰基，氨基甲酰基，C 1 -C 6烷氧基羰基或C 1 -C 4烷酰基， R 3是任选取代的C 1 -C 13烷基，任选取代的苯基或任选取代的氨基。本发明还涉及这种染料的热转移方法以及使用染料在合成材料上进行染色或印刷的方法。

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