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1. 发明授权

US07442447B2 Binaphthol based chromophores for the fabrication of blue organic light emitting diodes 有权
标题翻译：用于制造蓝色有机发光二极管的基于萘酚的发色团
公开(公告)号：US07442447B2
公开(公告)日：2008-10-28
申请号：US10759505
申请日：2004-01-16
申请人： Guillermo C. Bazan , Hadjar Benmansour , Yoshiharu Sato , Takeshi Shioya
发明人： Guillermo C. Bazan , Hadjar Benmansour , Yoshiharu Sato , Takeshi Shioya
IPC分类号： H01J1/62 , C09K11/06
CPC分类号： H05B33/14 , C07C43/202 , C07D209/02 , C07D209/86 , C07D215/14 , C07D217/24 , C07D219/14 , C07D223/26 , C07D235/20 , C07D241/42 , C07D263/57 , C07D265/38 , C07D271/107 , C07D277/66 , C07D321/10 , C07D321/12 , C07D401/10 , C07D471/04 , C09K11/06 , C09K2211/1011 , C09K2211/1029 , C09K2211/1033 , C09K2211/1044 , C09K2211/1048 , H01L51/0052 , H01L51/0053 , H01L51/0054 , H01L51/0055 , H01L51/0058 , H01L51/0062 , H01L51/0067 , H01L51/0071 , H01L51/0072 , H01L51/0078 , H01L51/0081 , H01L51/0094 , H01L51/5012 , H01L2251/308 , Y10S428/917
摘要： A blue electroluminescent material based on a binaphtyl compound of the general formula (I). Particular embodiments having the general formula have good solubilities in common organic solvents, resist crystallization and can be sublimed in a device fabrication process. These properties enable the fabrication of organic electroluminescent devices.
摘要翻译：一种基于通式（I）的二萘基化合物的蓝色电致发光材料。具有通式的具体实施方案在通常的有机溶剂中具有良好的溶解性，抗结晶，并且可以在器件制造过程中升华。这些性质使得能够制造有机电致发光器件。

2. 发明授权

US07232913B2 Paracyclophane molecules for two-photon absorption applications 失效
标题翻译： Paracyclophane分子用于双光子吸收应用
公开(公告)号：US07232913B2
公开(公告)日：2007-06-19
申请号：US10952624
申请日：2004-09-28
申请人： Guillermo C. Bazan , Bernhard Koehler , Hadjar Benmansour , Janice W. Hong , Han Young Woo , Alexander Mikhailovsky , Hideki Gorohmaru , Shuuichi Maeda , T. Kojima , Motoyuki Shigeiwa
发明人： Guillermo C. Bazan , Bernhard Koehler , Hadjar Benmansour , Janice W. Hong , Han Young Woo , Alexander Mikhailovsky , Hideki Gorohmaru , Shuuichi Maeda , T. Kojima , Motoyuki Shigeiwa
IPC分类号： C07D209/94 , C07D209/82 , C07C211/64 , C07C211/54 , G02B5/02 , G02F1/361
CPC分类号： C07D209/86 , C07C211/52 , C07C211/54 , C07C211/63 , G02F1/3611 , G02F1/3612 , G02F1/3613
摘要： Chromophores having two-photon or other multi-photon absorptivity. The chromophores are based on a structure of four stilbenoid groups attached to a paracyclophane core, where each stilbenoid group comprises a nitrogen-containing organic group attached by its nitrogen atom to a stilbenoid arm. In particular embodiments, at least one of the stilbenoid groups includes a sulfonium, ammonium, selenium, iodonium or phosphonium moiety. The chromophores have utility as photo-polymerization initiators and two-photon fluorophores for biological imaging.
摘要翻译：具有双光子或其他多光子吸收性的发色团。发色团基于连接到对环磷烷核心的四个芪基团的结构，其中每个茋基团包含通过其氮原子连接到扼流器臂的含氮有机基团。在具体实施方案中，至少一个芪基包括锍，铵，硒，碘鎓或鏻部分。发色团可用作光聚合引发剂和用于生物成像的双光子荧光团。

3. 发明授权

US07094929B2 Water-soluble distyrylbenzene chromophores for applications in optoelectronic technologies 有权
标题翻译：用于光电子技术的水溶性二苯乙烯苯发色团
公开(公告)号：US07094929B2
公开(公告)日：2006-08-22
申请号：US10801963
申请日：2004-03-15
申请人： Guillermo C. Bazan , Bernhard Koehler , Alexander Mikhailovsky , Hadjar Benmansour , Bin Liu , Janice W. Hong
发明人： Guillermo C. Bazan , Bernhard Koehler , Alexander Mikhailovsky , Hadjar Benmansour , Bin Liu , Janice W. Hong
IPC分类号： C07C211/50 , C07C211/63
CPC分类号： C09B23/141 , C07C211/52
摘要： Two-photon or multi-photon chromophores having a conjugated pi-electron system with donating groups at each end of the pi-electron system providing charge-transfer properties, and having quaternary amine groups that can enhance the solubility of the chromophore in water. In a particular embodiment, the chromophore is based on a distyrylbenzene core, with donor or acceptor groups attached to the central benzene ring.
摘要翻译：具有共轭π-电子系统的双光子或多光子发色团，其具有提供电荷转移性质的π-电子系统的每个末端具有供体基团，并具有可增强发色团在水中的溶解度的季胺基团。在一个具体实施方案中，发色团基于二苯乙烯基核，其中供体或受体基团连接到中心苯环上。

4. 发明授权

US09017766B2 Methods and devices comprising soluble conjugated polymers 有权
标题翻译：包含可溶共轭聚合物的方法和装置
公开(公告)号：US09017766B2
公开(公告)日：2015-04-28
申请号：US10595179
申请日：2004-09-17
申请人： Guillermo C. Bazan , Bin Liu , Xiong Gong , Alan J. Heeger , Wanli Ma , Parameswar K. Iyer
发明人： Guillermo C. Bazan , Bin Liu , Xiong Gong , Alan J. Heeger , Wanli Ma , Parameswar K. Iyer
IPC分类号： B05D3/02 , H01L51/00 , C08G61/02 , C08G61/10 , C08G61/12 , C08G73/02 , C08G73/08 , H01B1/12 , H01L51/56 , H01S3/16
CPC分类号： H01L51/0003 , C08G61/02 , C08G61/10 , C08G61/123 , C08G61/126 , C08G73/02 , C08G73/08 , H01B1/127 , H01B1/128 , H01L51/0007 , H01L51/0036 , H01L51/0038 , H01L51/0039 , H01L51/0043 , H01L51/56 , H01S3/168 , Y10T428/31504
摘要： Methods, compositions and articles of manufacture involving soluble conjugated polymers are provided. The conjugated polymers have a sufficient density of polar substituents to render them soluble in a polar medium, for example water and/or methanol. The conjugated polymer may desirably comprise monomers which alter its conductivity properties. In some embodiments, the inventors have provided cationic conjugated polymers (CCPs) comprising both solubilizing groups and conductive groups, resulting in conductive conjugated polymers soluble in polar media. The different solubility properties of these polymers allow their deposition in solution in multilayer formats with other conjugated polymers. Also provided are articles of manufacture comprising multiple layers of conjugated polymers having differing solubility characteristics. Embodiments of the invention are described further herein.
摘要翻译：提供涉及可溶性共轭聚合物的方法，组合物和制品。共轭聚合物具有足够的极性取代基密度，使其可溶于极性介质，例如水和/或甲醇。共轭聚合物可以理想地包括改变其导电性能的单体。在一些实施方案中，本发明人提供了包含增溶基团和导电基团的阳离子共轭聚合物（CCPs），导致可溶于极性介质的导电共轭聚合物。这些聚合物的不同溶解度特性允许它们以多层形式沉积在其它共轭聚合物中。还提供了包含具有不同溶解度特性的多层共轭聚合物的制品。本文进一步描述本发明的实施例。

5. 发明授权

US08993335B2 Methods for detection and analysis of polynucleotide-binding protein interactions 有权
标题翻译：检测和分析多核苷酸结合蛋白相互作用的方法
公开(公告)号：US08993335B2
公开(公告)日：2015-03-31
申请号：US10779412
申请日：2004-02-13
申请人： Guillermo C. Bazan , Shu Wang , Bin Liu
发明人： Guillermo C. Bazan , Shu Wang , Bin Liu
IPC分类号： G01N33/00 , C12Q1/68 , C07K1/00 , C07H21/02
CPC分类号： C12Q1/6818 , Y10T436/143333 , C12Q2565/101
摘要： Methods, compositions and articles of manufacture for assaying a sample for a target polynucleotide are provided. A sample suspected of containing the target polynucleotide is contacted with a polycationic multichromophore and a sensor PBP that can bind to the target polynucleotide. The sensor PBP comprises a signaling chromophore to absorb energy from the excited multichromophore and emit light in the presence of the target polynucleotide. The methods can be used in multiplex form. Kits comprising reagents for performing such methods are also provided.
摘要翻译：提供了用于测定靶多核苷酸样品的方法，组合物和制品。将怀疑含有靶多核苷酸的样品与聚阳离子多重色素和可与靶多核苷酸结合的传感器PBP接触。传感器PBP包括信号发色团，以吸收来自激发的多色素的能量并在靶多核苷酸的存在下发光。该方法可以多路复用形式使用。还提供了包含用于执行这些方法的试剂的试剂盒。

6. 发明授权

US08669055B2 Methods and articles for strand-specific polynucleotide detection with conjugated polymers 有权
标题翻译：用共轭聚合物进行链特异性多核苷酸检测的方法和文章
公开(公告)号：US08669055B2
公开(公告)日：2014-03-11
申请号：US12903176
申请日：2010-10-12
申请人： Guillermo C. Bazan , Bin Liu
发明人： Guillermo C. Bazan , Bin Liu
IPC分类号： C12Q1/68 , C12M1/34 , C07H19/00 , C07H21/04 , C07H21/02 , G01N21/64
CPC分类号： C12Q1/6818 , C12Q2563/119 , C12Q2565/101 , C12Q2565/519 , C12Q2565/607 , C12Q2523/313
摘要： The invention further relates to conjugated polymers, and methods, articles and compositions employing them as described herein. In some aspects, the invention relates to methods, articles and compositions for the detection and analysis of biomolecules in a sample. Provided assays include those determining the presence of a target biomolecule in a sample or its relative amount, or the assays may be quantitative or semi-quantitative. The methods can be performed on a substrate. The methods can be performed in an array format on a substrate, which can be a sensor. In some embodiments, detection assays are provided employing sensor biomolecules that do not comprise a fluorophore that can exchange energy with the cationic multichromophore. In some aspects biological assays are provided in which energy is transferred between one or more of the multichromophore, a label on the target biomolecule, a label on the sensor biomolecule, and/or a fluorescent dye specific for a polynucleotide, in all permutations. The multichromophore may interact at least in part electrostatically with the sensor and/or the target, and an increase in energy transfer with the polymer may occur upon binding of the sensor and the target. Other variations of the inventions are described further herein.
摘要翻译：本发明还涉及共轭聚合物，以及如本文所述使用它们的方法，制品和组合物。在一些方面，本发明涉及用于检测和分析样品中生物分子的方法，制品和组合物。提供的测定包括确定样品中靶生物分子的存在或其相对量的那些，或者测定可以是定量或半定量的。该方法可以在衬底上进行。这些方法可以以阵列格式在基底上进行，其可以是传感器。在一些实施方案中，使用不包含能够与阳离子多重色素交换能量的荧光团的传感器生物分子来提供检测测定。在一些方面，提供生物测定，其中在所有置换中，能量在一个或多个多色素，目标生物分子上的标记，传感器生物分子上的标记和/或多核苷酸特异的荧光染料之间转移。多重色淀可以至少部分地与传感器和/或靶相互作用，并且当传感器和目标物结合时，聚合物的能量传递的增加可能发生。本文进一步描述了本发明的其它变型。

7. 发明授权

US08617814B2 Methods and compositions for detection and analysis of polynucleotides using light harvesting multichromophores 有权
公开(公告)号：US08617814B2
公开(公告)日：2013-12-31
申请号：US13544303
申请日：2012-07-09
申请人： Guillermo C. Bazan , Brent S. Gaylord , Shu Wang
发明人： Guillermo C. Bazan , Brent S. Gaylord , Shu Wang
IPC分类号： C12Q1/68 , C07H21/00 , C07H21/02 , C07H21/04 , C07H19/04
CPC分类号： C12Q1/6834 , C12Q1/6813 , C12Q1/6818 , C12Q1/6825 , Y10T436/143333 , C12Q2565/107 , C12Q2563/107 , C12Q2523/313
摘要： Methods, compositions and articles of manufacture for assaying a sample for a target polynucleotide are provided. A sample suspected of containing the target polynucleotide is contacted with a polycationic multichromophore and a sensor polynucleotide complementary to the target polynucleotide. The sensor polynucleotide comprises a signaling chromophore to receive energy from the excited multichromophore and increase emission in the presence of the target polynucleotide. The methods can be used in multiplex form. Kits comprising reagents for performing such methods are also provided.

8. 发明授权

US08101416B2 Compositions for detection and analysis of polynucleotides using light harvesting multichromophores 有权
标题翻译：用于使用光收获多色素探测和分析多核苷酸的组合物
公开(公告)号：US08101416B2
公开(公告)日：2012-01-24
申请号：US11746055
申请日：2007-05-08
申请人： Guillermo C. Bazan , Brent S. Gaylord
发明人： Guillermo C. Bazan , Brent S. Gaylord
IPC分类号： C12Q1/68 , G01N21/63
CPC分类号： C12Q1/6818 , C12Q1/682 , Y10T436/143333 , C12Q2565/107 , C12Q2525/107 , C12Q2527/125
摘要： Methods, compositions and articles of manufacture for assaying a sample for a target polynucleotide are provided. A sample suspected of containing the target polynucleotide is contacted with a polycationic multichromophore and a sensor PNA complementary to the target polynucleotide. A signaling chromophore absorbs energy from the excited multichromophore and emits light in the presence of the target polynucleotide. The methods can be used in multiplex form. Kits having reagents for performing such methods are also provided.
摘要翻译：提供了用于测定靶多核苷酸样品的方法，组合物和制品。将涉及含有靶多核苷酸的样品与聚阳离子多重色素和与靶多核苷酸互补的传感器PNA接触。信号发色团从被激发的多色素吸收能量并在靶多核苷酸存在下发光。该方法可以多路复用形式使用。还提供了具有用于执行这些方法的试剂的试剂盒。

9. 发明授权

US08076842B2 Multilayer polymer light-emitting diodes for solid state lighting applications 有权
标题翻译：用于固态照明应用的多层聚合物发光二极管
公开(公告)号：US08076842B2
公开(公告)日：2011-12-13
申请号：US11366186
申请日：2006-03-01
申请人： Xiong Gong , Alan J. Heeger , Daniel Moses , Guillermo C. Bazan , Shu Wang
发明人： Xiong Gong , Alan J. Heeger , Daniel Moses , Guillermo C. Bazan , Shu Wang
IPC分类号： H01L51/54 , H01L51/56
CPC分类号： H01L51/50 , H01L51/0003 , H01L51/0037 , H01L51/0039 , H01L51/0042 , H01L51/0043 , H01L51/007 , H01L51/0085 , H01L51/5012 , H01L51/5016 , H01L51/5036 , H01L51/5048 , H01L51/5088 , Y10S428/917 , Y10T428/24942
摘要： Multilayer polymer light-emitting diodes (PLEDs) are demonstrated using semiconducting polymers blended with organometallic emitters as the emissive layer and one or both of an electron transport layer and a hole transparent layer on the appropriate electron injection and hole injection sides of the emissive layer. The transport layers reduce energy potential gaps between the hole injection electrode and the emissive polymer and between the electron injection electrode and the emissive polymer. A solvent-processing based procedure for preparing these devices is also disclosed It uses nonpolar solvent-based solutions of emissive polymers to form the emissive layer and polar solvent-based solutions to form the transport layers to minimize etching and other undesirable interactions as the multiple layers are being laid down. Illumination quality white light can be obtained with stable Commission Internationale de l'Eclairage coordinates, stable color temperatures, and stable color rendering indices, all close to those of “pure” white light. These multilayer white light-emitting PLEDs are useful as backlights for liquid crystal displays and for solid state lighting applications.
摘要翻译：使用与有机金属发射体混合的半导体聚合物作为发射层和在发射层的合适的电子注入和空穴注入侧的电子传输层和空穴透明层中的一个或两个的多层聚合物发光二极管（PLED）。传输层减少空穴注入电极和发射聚合物之间以及电子注入电极和发射聚合物之间的能量势隙。还公开了用于制备这些装置的基于溶剂处理的方法。它使用发射聚合物的非极性溶剂型溶液形成发射层和极性溶剂型溶液以形成传输层，以使蚀刻和其它不希望的相互作用最小化，因为多层正在放下照明质量白光可以通过稳定的国际照明坐标，稳定的色温和稳定的显色指数获得，均接近于“纯”白光。这些多层白色发光PLED可用作液晶显示器和固态照明应用的背光。

10. 发明申请

US20110282019A1 ZWITTERIONIC GROUP VIII TRANSITION METAL INITIATORS SUPPORTED BY OLEFIN LIGANDS 有权
标题翻译：由OleFIN LiganDS支持的第八组过渡金属开关
公开(公告)号：US20110282019A1
公开(公告)日：2011-11-17
申请号：US11519618
申请日：2006-09-12
申请人： Guillermo C. Bazan , Yaofeng Chen
发明人： Guillermo C. Bazan , Yaofeng Chen
IPC分类号： C08F4/80 , C08F10/06 , C09B55/00 , C08F10/02
CPC分类号： C07F15/04 , C08F10/00 , C08F110/02 , C08F110/06 , C08F2500/03 , C08F4/7022
摘要： A zwitterionic Group VIII transition metal complex containing the simple and relatively small 3-(arylimino)-but-1-en-2-olato ligand that catalyzes the formation of polypropylene and high molecular weight polyethylene. A novel feature of this catalyst is that the active species is stabilized by a chelated olefin adduct. The present invention also provides methods of polymerizing olefin monomers using zwitterionic catalysts, particularly polypropylene and high molecular weight polyethylene.
摘要翻译：含有简单且相对较小的3-（芳基亚氨基） - 丁-1-烯-2-醇配体的两性离子第VIII族过渡金属络合物，其催化聚丙烯和高分子量聚乙烯的形成。该催化剂的一个新特征是活性物质被螯合烯烃加合物稳定。本发明还提供使用两性离子催化剂，特别是聚丙烯和高分子量聚乙烯聚合烯烃单体的方法。

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