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1. 发明授权

US5072069A Cycloolefinic complexes of platinum, processes for preparing the same and their use as a catalyst 失效
标题翻译：铂的环状络合物，其制备方法及其作为催化剂的用途
公开(公告)号：US5072069A
公开(公告)日：1991-12-10
申请号：US485704
申请日：1990-02-27
申请人： Guido Wenski , Ludwig Maier , Hans-Jurgen Eberle
发明人： Guido Wenski , Ludwig Maier , Hans-Jurgen Eberle
IPC分类号： B01J31/22 , C07B61/00 , C07C5/03 , C07C5/22 , C07C13/02 , C07C45/50 , C07F7/08 , C07F15/00
CPC分类号： C07F15/0093 , B01J31/2295 , C07F15/0086 , B01J2231/14 , B01J2231/321 , B01J2231/323 , B01J2231/52 , B01J2231/64 , B01J2531/828
摘要： The invention relates to cycloolefinic complexes of platinum, processes for preparing the same from platinum(II) compounds and cyclolefins having at least 12 ring carbon atoms and at least two aliphatic non-cumulated carbon-carbon double bonds and their use as a catalyst for the addition of Si-bonded hydrogen to an aliphatic multiple bond.
摘要翻译：本发明涉及铂的环烯烃络合物，其由铂（II）化合物制备的方法及具有至少12个环碳原子的环烯烃和至少两个脂肪族非累积碳 - 碳双键，以及它们作为催化剂的用途将Si键合的氢加成脂肪族多键。

2. 发明授权

US5009934A Process for preparing poly-(imidesiloxanes) 失效
标题翻译：制备聚（酰亚胺硅氧烷）的方法
公开(公告)号：US5009934A
公开(公告)日：1991-04-23
申请号：US549586
申请日：1990-07-06
申请人： Guido Wenski , Ludwig Maier , Franz-Heinrich Kreuzer
发明人： Guido Wenski , Ludwig Maier , Franz-Heinrich Kreuzer
IPC分类号： B01D71/64 , B01D71/70 , C08G73/10 , C08G77/42 , C08G77/455 , C08G77/54 , C08G77/60 , C08J5/18
CPC分类号： C08G73/106 , B01D71/64 , B01D71/70 , C08G77/54 , C08G77/60
摘要： A process for preparing poly-(imidesiloxanes) which comprises reacting an N,N'-dialkenyldiimide with an organosilicon compound containing two Si-bonded hydrogen atoms in the presence of a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic multiple bond.
摘要翻译：一种制备聚（酰亚胺硅氧烷）的方法，其包括在催化剂存在下使N，N'-二烯基二酰亚胺与含有两个Si键合的氢原子的有机硅化合物反应，该催化剂促进将Si键合的氢加成至脂族多重键。

3. 发明授权

US5567840A Substituted aminoalkylphosphinic acids 失效
标题翻译：取代的氨基烷基次膦酸
公开(公告)号：US5567840A
公开(公告)日：1996-10-22
申请号：US461090
申请日：1995-06-05
申请人： Roger G. Hall , Ludwig Maier , Wolfgang Frostl
发明人： Roger G. Hall , Ludwig Maier , Wolfgang Frostl
IPC分类号： C07F9/30
CPC分类号： C07F9/301
摘要： P-substituted aminoalkylphosphinic acids of the formula ##STR1## wherein R denotes an optionally fluorinated methyl group, R.sub.1 denotes hydrogen, lower alkyl, lower alkoxy, hydroxy, halogen or a fluorinated methyl group and R.sub.2 and R.sub.3 denote hydrogen or R.sub.2 denotes hydroxy, lower alkoxy or halogen and R.sub.3 is hydrogen or R.sub.2 and R.sub.3 together represent an oxo group, and their pharmaceutically acceptable salts are active as GABA.sub.B -agonists and can be used in the treatment of spinal spasticity, multiple sclerosis and cerebral palsy, trigeminus neuralgia, drug withdrawal syndromes and/or conditions of pain. They can be manufactured by methods known per se and suitable such methods are described.
摘要翻译：式（I）的P取代氨基烷基次膦酸其中R表示任意氟化的甲基，R 1表示氢，低级烷基，低级烷氧基，羟基，卤素或氟化甲基，R 2和R 3表示氢或R 2表示羟基，低级烷氧基或卤素，R 3是氢或R 2和R 3一起代表氧基，其药学上可接受的盐作为GABAB-激动剂是有活性的，可用于治疗脊柱痉挛，多发性硬化和脑性麻痹，三叉神经痛神经痛戒毒综合征和/或疼痛状况。它们可以通过本身已知的方法制造，并且描述合适的这种方法。

4. 发明授权

US5300679A Substituted propane-phosphinic acid compounds 失效
标题翻译：取代的丙烷 - 次膦酸化合物
公开(公告)号：US5300679A
公开(公告)日：1994-04-05
申请号：US968101
申请日：1992-10-29
申请人： Eric K. Baylis , Helmut Bittiger , Wolfgang Frostl , Roger G. Hall , Ludwig Maier , Stuart J. Mickel , Hans-Rudolf Olpe
发明人： Eric K. Baylis , Helmut Bittiger , Wolfgang Frostl , Roger G. Hall , Ludwig Maier , Stuart J. Mickel , Hans-Rudolf Olpe
IPC分类号： C07F9/30 , C07F9/48 , A61K31/13 , A61K31/185
CPC分类号： C07F9/301 , C07F9/48 , Y02P20/55
摘要： Compounds of the formula I ##STR1## wherein R denotes an aliphatic, cycloaliphatic, cycloaliphatic-aliphatic or araliphatic radical having 2 or more carbon atoms, and wherein one of the groups R.sup.1, R.sup.2 and R.sup.3 represents hydrogen or an aliphatic, cycloaliphatic, araliphatic or aromatic radical, another one of R.sup.1, R.sup.2 and R.sup.3 is hydrogen or, in the case of R.sup.1 and R.sup.2, is hydroxy, and the remaining one of R.sup.1, R.sup.2 and R.sup.3 is hydrogen, or wherein R denotes methyl, R.sub.1 denotes hydrogen or hydroxy, R.sub.2 denotes an aromatic radical and R.sub.3 represents hydrogen, and their salts have GABA.sub.B -antagonistic properties and can be used as GABA.sub.B -antagonists. They are obtained when in a compound of formula II ##STR2## in which R, R.sup.1, R.sup.2 and R.sup.3 have their previous significances, Z represents --NH.sub.2 and R.sup.4 denotes a hydroxy-protective group R.sup.5 or, when R.sup.1 and R.sup.3 denote hydrogen and R.sup.2 denotes hydrogen or alkyl, denotes an alkali metal or ammonium ion R.sup.6, or Z represents a protected or latent amino group Z.sup.o and R.sup.4 denotes hydrogen or a hydroxy-protective group R.sup.5, any group R.sup.5 or R.sup.6 is replaced by hydrogen, and/or any group Z.sup.o is converted into --NH.sub.2.
摘要翻译：式I的化合物（I）其中R表示具有2个或更多个碳原子的脂族，脂环族，脂环族 - 脂族或芳脂族基团，其中R1，R2和R3中的一个表示氢或脂族，脂环族，芳脂族或芳族基团，R 1，R 2和R 3中的另一个为氢，或在R 1和R 2的情况下为羟基，其余的R 1，R 2和R 3为氢，或其中R为甲基，R 1为氢或羟基，R 2表示芳族基团，R 3表示氢，并且它们的盐具有GABAB拮抗性质，可用作GABAB-拮抗剂。当其中R，R 1，R 2和R 3具有其先前含义的式II化合物（II）时，它们是得到的，Z表示-NH 2，R4表示羟基保护基R5，或者当R1和R3表示氢和R2表示氢或烷基，表示碱金属或铵离子R6，或Z表示保护或潜在氨基Zo，R4表示氢或羟基保护基R5，任何基团R5或R6被氢代替，以及 /或任何基团Zo被转化为-NH 2。

5. 发明授权

US5189030A 1-amino-2-phenylethanephosphonic acids as microbiocides 失效
标题翻译： 1-氨基-2-苯基乙基膦酸作为杀微生物剂
公开(公告)号：US5189030A
公开(公告)日：1993-02-23
申请号：US827547
申请日：1992-01-29
申请人： Ludwig Maier
发明人： Ludwig Maier
IPC分类号： A01N57/22 , C07F9/30 , C07F9/38 , C07F9/40 , C07F9/53
CPC分类号： C07F9/5333 , A01N57/22 , C07F9/301 , C07F9/306 , C07F9/3808 , C07F9/3882 , C07F9/4006 , C07F9/4056 , C07F9/5304
摘要： Compounds of formula I ##STR1## wherein R and R.sub.1 are each independently C.sub.1 -C.sub.4 alkoxy or hydroxy and X and Y are as defined herein, as well as the metal, ammonium or substituted ammonium salts thereof, are useful insecticides, acaricides and, in particular, fungicides. They can be applied to plants or to the locus thereof in the form of compositions or used as seed dressings.
摘要翻译：式I的化合物其中R和R 1各自独立地为C 1 -C 4烷氧基或羟基，X和Y如本文所定义，以及其金属，铵或取代的铵盐是有用的杀虫剂，杀螨剂特别是杀真菌剂。它们可以以组合物的形式施用于植物或其基因座，或用作种子敷料。

6. 发明授权

US5051524A Substituted propane-phosphinic acid compounds 失效
公开(公告)号：US5051524A
公开(公告)日：1991-09-24
申请号：US484716
申请日：1990-02-26
申请人： Eric K. Baylis , Helmut Bittiger , Wolfgang Frostl , Roger G. Hall , Ludwig Maier , Stuart J. Mickel , Hans-Rudolf Olpe
发明人： Eric K. Baylis , Helmut Bittiger , Wolfgang Frostl , Roger G. Hall , Ludwig Maier , Stuart J. Mickel , Hans-Rudolf Olpe
IPC分类号： A61K31/66 , A61P25/20 , A61P25/24 , A61P25/26 , A61P25/28 , A61P39/02 , A61P43/00 , C07F9/30 , C07F9/48
CPC分类号： C07F9/48 , C07F9/301 , Y02P20/55
摘要： Compounds of the formula I ##STR1## wherein R denotes an aliphatic, cycloaliphatic, cycloaliphatic-aliphatic or araliphatic radical having 2 or more carbon atoms, and wherein one of the groups R.sup.1, R.sup.2 and R.sup.3 represents hydrogen or an aliphatic, cycloaliphatic, araliphatic or aromatic radical, another one of R.sup.1, R.sup.2 and R.sup.3 is hydrogen or, in the case of R.sup.1 and R.sup.2, is hydroxy, and the remaining one of R.sup.1, R.sup.2 and R.sup.3 is hydrogen, or wherein R denotes methyl, R.sub.1 denotes hydrogen or hydroxy, R.sub.2 denotes an aromatic radical and R.sub.3 represents hydrogen, and their salts have GABA.sub.B -antagonistic properties and can be used as GABA.sub.B -antagonists. They are obtained when in a compound of formula II ##STR2## in which R, R.sup.1, R.sup.2 and R.sup.3 have their previous significances, Z represents --NH.sub.2 and R.sup.4 denotes a hydroxy-protective group R.sup.5 or, when R.sup.1 and R.sup.3 denote hydrogen and R.sup.2 denotes hydrogen or alkyl, denotes an alkali metal or ammonium ion R.sup.6, or Z represents a protected or latent amino group Z.degree. and R.sup.4 denotes hydrogen or a hydroxy-protective group R.sup.5, any group R.sup.5 or R.sup.6 is replaced by hydrogen, and/or any group Z.degree. is converted into --NH.sub.2.

7. 发明授权

US4618358A Herbicidal N-2-(nitro-5-phenoxy-phenyl)-aminoalkylphosphonic acid and esters 失效
标题翻译：除草剂N-2-（硝基-5-苯氧基 - 苯基） - 氨基烷基膦酸和酯
公开(公告)号：US4618358A
公开(公告)日：1986-10-21
申请号：US651968
申请日：1984-09-19
申请人： Ludwig Maier
发明人： Ludwig Maier
IPC分类号： A01N57/22 , A01N57/24 , C07F9/30 , C07F9/32 , C07F9/38 , C07F9/40 , C07F9/48 , C07F9/58 , A01N57/06 , A01N57/08
CPC分类号： C07F9/588 , A01N57/22 , A01N57/24 , C07F9/301 , C07F9/3211 , C07F9/3808 , C07F9/383 , C07F9/4006 , C07F9/4018 , C07F9/4816
摘要： The present invention relates to (2-nitro-5-aryloxyphenylamino)alkylphosphonic, -alkylphosphinic and -alkylphosphonous acid derivatives of the general formula I ##STR1## wherein X is halogen, CF.sub.3, NO.sub.2, CN, CONH.sub.2 or CSNH.sub.2,Y is nitrogen or --CH.dbd.,R is hydrogen, C.sub.1 -C.sub.4 alkyl or aralkyl containing 1 to 4 carbon atoms in the alkyl moiety,R.sub.1 is C.sub.1 -C.sub.4 alkyl,R.sub.2 is C.sub.1 -C.sub.4 alkyl, phenyl or --PO(OR.sub.6).sub.2,R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl or a cation,R.sub.5 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, hydroxyl or an --O-cation group,R.sub.6 is hydrogen or C.sub.1 -C.sub.4 alkyl,m is a value from 0 to 3,n is 0 or 1,p is a value from 0 to 3, andq is 0 or 1,with the proviso that R.sub.1 and R.sub.3 taken together may also be an unsubstituted or substituted C.sub.1 -C.sub.3 alkylene chain and at least one of the symbols n, p and q is a value different from 0.These compounds have useful herbicidal properties.
摘要翻译：本发明涉及通式I（I）的（2-硝基-5-芳氧基苯基氨基）烷基膦酸烷基亚膦酸和烷基亚膦酸衍生物，其中X是卤素，CF 3，NO 2，CN，CONH 2或CSNH 2，Y R1是C1-C4烷基，R2是C1-C4烷基，苯基或-PO（OR6）2，R3是氮或-CH =，R是氢，C1-C4烷基或在烷基部分含有1至4个碳原子的芳烷基氢或C1-C4烷基，R4是氢，C1-C4烷基或阳离子，R5是氢，C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，羟基或-O-阳离子基团，R6是氢或C1-C4烷基， m为0至3的数，n为0或1，p为0至3，q为0或1，条件是R 1和R 3一起也可以是未取代或取代的C 1 -C 3亚烷基链和n，p和q中的至少一个符号是不同于0的值。这些化合物具有有用的除草性质。

8. 发明授权

US4451284A Derivatives of 2-nitro-4- or -5-pyridyloxyphenylphosphonic acid, the preparation thereof, the use thereof as herbicides and/or plant growth regulators 失效
标题翻译： 2-硝基-4-或-5-吡啶氧基苯基膦酸的衍生物，其制备方法，其作为除草剂和/或植物生长调节剂的用途
公开(公告)号：US4451284A
公开(公告)日：1984-05-29
申请号：US399504
申请日：1982-07-19
申请人： Ludwig Maier , Hermann Rempfler , Dieter Durr
发明人： Ludwig Maier , Hermann Rempfler , Dieter Durr
IPC分类号： A01N57/24 , C07D213/64 , C07D213/643 , C07F9/58 , A01N43/40 , A61K31/44
CPC分类号： C07D213/643 , A01N57/24 , C07F9/582
摘要： The invention relates to novel 2-nitro-4- or -5-pyridyloxyphenylphosphonic acid derivatives of the formula ##STR1## wherein X is halogen or trifluoromethyl, Y is hydrogen or halogen, one of the two substituents A and E is a phosphonate group ##STR2## wherein R is C.sub.1 -C.sub.4 alkyl or hydrogen, and the other is a nitro group, including the metal salts thereof and the salts thereof with ammonium and organic nitrogen bases, and to the preparation and use thereof. These compounds may be used for controlling weeds, regulating plant growth, or as microbicides.
摘要翻译：本发明涉及下式的新的2-硝基-4-或5-吡啶氧基苯基膦酸衍生物，其中X是卤素或三氟甲基，Y是氢或卤素，两个取代基A和E之一是膦酸酯基，其中R是C1-C4烷基或氢，另一个是硝基，包括其金属盐及其与铵和有机氮碱的盐，以及其制备和用途。这些化合物可用于控制杂草，调节植物生长或作为杀微生物剂。

9. 发明授权

US4434108A Herbicidally active 2-nitro-5-(2'-chloro-4'-trifluoromethylphenoxy)phenylphosphinic acid derivatives 失效
标题翻译：除草活性2-硝基-5-（2'-氯-4'-三氟甲基苯氧基）苯基次膦酸衍生物
公开(公告)号：US4434108A
公开(公告)日：1984-02-28
申请号：US280388
申请日：1981-07-06
申请人： Ludwig Maier
发明人： Ludwig Maier
IPC分类号： A01N57/22 , A01N57/30 , A01N57/34 , C07F9/30 , C07F9/32 , C07F9/34 , C07F9/36 , C07F9/46
CPC分类号： A01N57/34 , A01N57/22 , A01N57/30 , C07F9/304 , C07F9/3229 , C07F9/34 , C07F9/36
摘要： The invention relates to novel herbicidally active and plant-growth regulating 2-substituted 5-phenoxyphenylphosphinic acid derivatives of the formula ##STR1## wherein R.sub.1 is an unsubstituted or substituted alkyl or aryl radical, R.sub.2 is a hydroxyl group, lower alkoxy, alkylthio, alkylamino, dialkylamino or chlorine, X is halogen or is selected from the group consisting of --CF.sub.3, --NO.sub.2 or --CN, n is 0 to 3, and Y is selected from the group consisting of --NO.sub.2, --NH.sub.2, --OH, --CN, or is halogen. Preferred compounds are 2-nitro-5-(2'-chloro-4'-trifluoromethylphenoxy)phenylalkylphosphinic acids and lower alkyl esters thereof. The invention also relates to the production of the novel phosphinic acid derivatives, starting from a 3,4-dinitrodiphenyl ether and reaction with a O,O-dialkylalkyl- or -arylphosphonite as first step. The invention further relates to herbicidal and plant growth regulating compositions which contain one of these novel compounds as active component, and also to the use of these compounds and compositions for controlling weeds (also selectively), for inhibiting plant growth and desiccating parts of plants above the ground, as well as for totally destroying existing plant growth.
摘要翻译：本发明涉及新颖的除草活性和植物生长调节式（I）的2-取代的5-苯氧基苯基次膦酸衍生物，其中R1是未取代或取代的烷基或芳基，R2是羟基，低级烷氧基，烷硫基，烷基氨基，二烷基氨基或氯，X为卤素或选自-CF 3，-NO 2或-CN，n为0至3，Y选自-NO 2，-NH 2， OH，-CN或卤素。优选的化合物是2-硝基-5-（2'-氯-4'-三氟甲基苯氧基）苯基烷基次膦酸及其低级烷基酯。本发明还涉及从3,4-二硝基二苯醚开始并与O，O-二烷基烷基 - 或芳基亚膦酸酯反应的新的次膦酸衍生物的制备作为第一步。本发明还涉及含有这些新化合物之一作为活性组分的除草和植物生长调节组合物，还涉及这些化合物和组合物用于控制杂草（也是选择性的）的用途，用于抑制上述植物的植物生长和干燥部分地面，以及完全破坏现有的植物生长。

10. 发明授权

US5064819A Substituted propane-phosphinic acid compounds 失效
标题翻译：取代的丙酸 - 磷酸化合物
公开(公告)号：US5064819A
公开(公告)日：1991-11-12
申请号：US502399
申请日：1990-03-30
申请人： Eric K. Baylis , Helmut Bittiger , Wolfgang Frostl , Roger G. Hall , Ludwig Maier , Stuart J. Mickel , Hans-Rudolf Olpe
发明人： Eric K. Baylis , Helmut Bittiger , Wolfgang Frostl , Roger G. Hall , Ludwig Maier , Stuart J. Mickel , Hans-Rudolf Olpe
IPC分类号： A61K31/66 , A61P25/20 , A61P25/24 , A61P25/26 , A61P25/28 , A61P39/02 , A61P43/00 , C07F9/30 , C07F9/48
CPC分类号： C07F9/48 , C07F9/301 , Y02P20/55
摘要： Compounds of the formula I ##STR1## wherein R denotes an aliphatic, cycloaliphatic, cycloaliphatic-aliphatic or araliphatic radical having 2 or more carbon atoms, and wherein one of the groups R.sup.1, R.sup.2 and R.sup.3 represents hydrogen or an aliphatic, cycloaliphatic, araliphatic or aromatic radical, another one of R.sup.1, R.sup.2 and R.sup.3 is hydrogen or, in the case of R.sup.1 and R.sup.2, is hydroxy, and the remaining one of R.sup.1, R.sup.2 and R.sup.3 is hydrogen, or wherein R denotes methyl, R.sub.1 denotes hydrogen or hydroxy, R.sub.2 denotes an aromatic radical and R.sub.3 represents hydrogen, and their salts have GABA.sub.B -antagonistic properties and can be used as GABA.sub.B -antagonists. They are obtained when in a compound of formula II ##STR2## in which R, R.sup.1, R.sup.2 and R.sup.3 have their previous significances, Z represents --NH.sub.2 and R.sup.4 denotes a hydroxy-protective group R.sup.5 or, when R.sup.1 and R.sup.3 denote hydrogen and R.sup.2 denotes hydrogen or alkyl, denotes an alkali metal or ammonium ion R.sup.6, or Z represents a protected or latent amino group Z.sup.0 and R.sup.4 denotes hydrogen or a hydroxy-protective group R.sup.5, any group R.sup.5 or R.sup.6 is replaced by hydrogen, and/or any group Z.sup.0 is converted into --NH.sub.2.

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