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1. 发明授权

US06679987B1 Process for decreasing the acid content and corrosivity of crudes 失效
标题翻译：降低原油酸度和腐蚀性的工艺
公开(公告)号：US06679987B1
公开(公告)日：2004-01-20
申请号：US09432742
申请日：1999-11-02
申请人： Saul Charles Blum , Guido Sartori , David William Savage , Martin Leo Gorbaty , Bruce Henry Ballinger , Michael Paul Anderson , Trikur Anantharaman Ramanarayanan , David J. Martella
发明人： Saul Charles Blum , Guido Sartori , David William Savage , Martin Leo Gorbaty , Bruce Henry Ballinger , Michael Paul Anderson , Trikur Anantharaman Ramanarayanan , David J. Martella
IPC分类号： C10G2906
CPC分类号： C10G75/02 , C10G19/00 , C10G19/02
摘要： The invention relates to processes for treating acidic crudes or fractions thereof to reduce or eliminate their acidity and corrosivity by addition of suitable amounts of Group IA or Group IIA oxides, hydroxides and hydrates and Group IIA metal naphthenate salts. The process has the additional benefits of reducing materials handling problems associated with treating acidic crude oils using liquid solvents and in reducing emulsion formation.
摘要翻译：本发明涉及通过加入适量的IA族或IIA族氧化物，氢氧化物和水合物以及IIA族金属环烷酸盐来处理酸性原油或其馏分来降低或消除其酸度和腐蚀性的方法。该方法具有减少与使用液体溶剂处理酸性原油相关的材料处理问题并减少乳液形成的附加益处。

2. 发明授权

US6022494A Process for decreasing the acid content and corrosivity of crudes 失效
标题翻译：降低原油酸度和腐蚀性的工艺
公开(公告)号：US6022494A
公开(公告)日：2000-02-08
申请号：US11117
申请日：1998-09-15
申请人： Guido Sartori , David William Savage , Martin Leo Gorbaty , Bruce Henry Ballinger , Saul Charles Blum , Michael Paul Anderson , Trikur Anantharaman Ramanarayanan , David J. Martella
发明人： Guido Sartori , David William Savage , Martin Leo Gorbaty , Bruce Henry Ballinger , Saul Charles Blum , Michael Paul Anderson , Trikur Anantharaman Ramanarayanan , David J. Martella
IPC分类号： C09K15/32 , C09K3/00 , C10G19/00 , C10G19/02 , C10G29/06 , C10G29/16 , C10G75/02
CPC分类号： C10G19/00 , C10G19/02 , C10G75/02 , Y10S507/939
摘要： The invention relates to processes for treating acidic crudes of fractions thereof to reduce or eliminate their acidity and corrosivity by addition of suitable amounts of Group IA of Group IIA oxides, hydroxides and hydrates. The process has the additional benefits of reducing materials handling problems associated with treating acidic crude oils using liquid solvents and in reducing emulsion formation.
摘要翻译： PCT No.PCT / US96 / 13688 Sec。 371日期：1998年9月15日 102（e）1998年9月15日PCT PCT 1996年8月23日PCT公布。公开号WO97 / 08270 日期1997年3月6日本发明涉及通过加入适量的IIA族IIA族氧化物，氢氧化物和水合物来处理其级分的酸性原油以降低或消除其酸度和腐蚀性的方法。该方法具有减少与使用液体溶剂处理酸性原油相关的材料处理问题并减少乳液形成的附加益处。

3. 发明授权

US6054042A Process for neutralization of petroleum acids using overbased detergents 失效
标题翻译：使用高碱性清洁剂中和石油酸的方法
公开(公告)号：US6054042A
公开(公告)日：2000-04-25
申请号：US423
申请日：1998-08-03
申请人： Martin L. Gorbaty , David J. Martella , Guido Sartori , David William Savage , Bruce Henry Ballinger , Saul Charles Blum , Michael Paul Anderson , Trikur Anantharaman Ramanarayanan
发明人： Martin L. Gorbaty , David J. Martella , Guido Sartori , David William Savage , Bruce Henry Ballinger , Saul Charles Blum , Michael Paul Anderson , Trikur Anantharaman Ramanarayanan
IPC分类号： C10G19/073 , C10G19/00 , C10Q17/00
CPC分类号： C10G19/00
摘要： The invention relates to a process for treating naphthenic acid containing whole crudes or fraction thereof to reduce or eliminate their acidity by contacting the acidic whole crude or fractions thereof at a suitable temperature typically of less than 200.degree. C. with a neutralizing amount typically from 0.25:1 up to 10:1 of overbased detergent. The process has the additional benefits of reducing materials handling problems associated with emulsion formation in treated crudes.
摘要翻译： PCT No.PCT / US96 / 13689 Sec。 371日期1998年8月3日 102（e）1998年8月3日PCT PCT 1996年8月23日PCT公布。公开号WO97 / 08275 日期1997年3月6日本发明涉及一种处理含有全原油或其馏分的环烷酸的方法，以通过将典型地低于200℃的合适温度的酸性全部原料或其馏分与中和量通常为0.25:1至高达10:1的高碱性洗涤剂。该方法具有减少与经处理的原油中的乳液形成相关的材料处理问题的附加益处。

4. 发明授权

US06583247B1 Process for producing free radical polymerized copolymers 有权
标题翻译：制备自由基聚合共聚物的方法
公开(公告)号：US06583247B1
公开(公告)日：2003-06-24
申请号：US09270376
申请日：1999-03-16
申请人： Ariel Alvarino , Ricardo A. Bloch , David J. Martella , John V. Redpath , James M. Gardiner , Steven W. McKeown , Arunas T. Lapinas
发明人： Ariel Alvarino , Ricardo A. Bloch , David J. Martella , John V. Redpath , James M. Gardiner , Steven W. McKeown , Arunas T. Lapinas
IPC分类号： C08J428
CPC分类号： C10L1/1963 , C10L1/1966 , C10L1/1973 , C10M143/02 , C10M145/08 , C10M145/14 , C10M145/16 , C10M2205/022 , C10M2209/062 , C10M2209/084 , C10M2209/086
摘要： Process for the copolymerization of free radical polymerizable comonomers such as vinyl acetate with an unsaturated diester such as diakyl fumarate which is carried out in the presence of water to produce copolymers such as fumarate vinyl acetate copolymers useful as lubricating oil and fuel oil additives, for example, as wax crystal modifiers and flow improvers.
摘要翻译：用于将可自由基聚合的共聚单体如乙酸乙烯酯与不饱和二酯如富马酸二戊酯共聚的方法，其在水存在下进行，以产生共聚物，例如用作润滑油的富马酸乙酸乙烯酯共聚物和燃料油添加剂，例如，作为蜡晶体改性剂和流动改进剂。

5. 发明授权

US5939365A Lubricant with a higher molecular weight copolymer lube oil flow improver 失效
标题翻译：润滑剂具有较高分子量共聚物润滑油流动改进剂
公开(公告)号：US5939365A
公开(公告)日：1999-08-17
申请号：US771791
申请日：1996-12-20
申请人： John V. Redpath , Arunas T. Lapinas , David J. Martella , Albert Rossi , William M. Davis
发明人： John V. Redpath , Arunas T. Lapinas , David J. Martella , Albert Rossi , William M. Davis
IPC分类号： C10M101/00 , C10M145/14 , C10M157/00 , C10M169/04 , C10N20/04 , C10N30/02 , C10N40/04 , C10M157/10
CPC分类号： C10M157/00 , C10M169/04 , C10M2203/10 , C10M2203/1006 , C10M2203/102 , C10M2203/1025 , C10M2203/1045 , C10M2203/1065 , C10M2203/1085 , C10M2205/00 , C10M2205/022 , C10M2205/024 , C10M2205/04 , C10M2209/06 , C10M2209/084 , C10M2209/086 , C10N2240/00 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/14 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： A lubricant which comprises: a mineral oil basestock which has been dewaxed via catalytic cracking and/or catalytic isomerization; an alkylene-alkylene copolymer; and a lubricating oil flow improver formed from the reaction product of: (a) an unsaturated carboxy ester formed via the esterification of an unsaturated carboxylic acid or its corresponding anhydride with a monohydric aliphatic alcohol having an average carbon number of between about 10 to 18, the unsaturated carboxy ester having the formula: ##STR1## wherein R' is selected from the group consisting of hydrogen and COOR and wherein R is a C.sub.6 to C.sub.22 alkyl group; and (b) a monomer selected from the group consisting of(i) a vinyl ester having the formula: ##STR2## wherein R.sub.1 comprises an alkyl group containing from 1 to 18 carbon atoms;(ii) an olefin having the formula ##STR3## wherein R.sub.1 and R.sub.2 can independently be hydrogen, an alkyl having from 1 to 28 carbon atoms, or a substituted aryl group, provided both R.sub.1 and R.sub.2 are not hydrogen,the reaction product having a specific viscosity in the range between about 0.3 to 1.5, or a weight average molecular weight of between about 50,000 to 350,000 Daltons.
摘要翻译：一种润滑剂，其特征在于，包括：通过催化裂化和/或催化异构化脱蜡的矿物油基料; 亚烷基 - 亚烷基共聚物; 和由以下反应产物形成的润滑油流动改进剂：（a）通过不饱和羧酸或其相应的酸酐与平均碳数为约10至18的一元脂族醇的酯化形成的不饱和羧酸酯，所述不饱和羧酸酯具有下式：其中R'选自氢和COOR，并且其中R是C6至C22烷基; 和（b）选自（i）具有下式的乙烯基酯的单体：其中R 1包含含有1至18个碳原子的烷基; （ii）具有下式的烯烃：其中R 1和R 2可以独立地为氢，具有1至28个碳原子的烷基或取代的芳基，只要R1和R2都不为氢，反应产物的比粘度约0.3至1.5的范围，或重量平均分子量在约50,000至350,000道尔顿之间。

6. 发明申请

US20150018259A1 Lubricant Composition Comprising a Bi-Modal Side-Chain Distribution LOFI 审中-公开
标题翻译：包含双模态侧链分布的润滑剂组合LOFI
公开(公告)号：US20150018259A1
公开(公告)日：2015-01-15
申请号：US13937387
申请日：2013-07-09
申请人： Ricardo A. Bloch , Doyle H. Boese , David J. Martella
发明人： Ricardo A. Bloch , Doyle H. Boese , David J. Martella
IPC分类号： C10M157/10
CPC分类号： C10M157/10 , C10M169/041 , C10M2203/1025 , C10M2205/022 , C10M2205/028 , C10M2209/062 , C10M2209/084 , C10M2209/086 , C10N2230/02 , C10N2220/022
摘要： A lubricant composition is disclosed. The lubricant composition is made up of (a) an API Group III base stock; (b) one or more semi-crystalline viscosity modifier; and (c) one or more LOFIs having a side-chain distribution which satisfies the following requirements: (1) the distribution contains side chains ranging from C8 to C18 with an average carbon number ranging from 12.4 to 14.4; (2) the side chain distribution is bi-modal with a lower portion of the bi-modal distribution made up primarily of C12 and an upper portion of the distribution made up primarily of C16, C18 or combinations thereof; (3) the total mole % of the upper portion of the distribution must be less than that of the lower portion of the distribution; and (4) the amount of C12 on the side chain must be at least 40 mole % of the total side chain distribution.
摘要翻译：公开了一种润滑剂组合物。润滑剂组合物由（a）API第III类原料组成; （b）一种或多种半结晶粘度调节剂; （c）一种或多种具有侧链分布的LOFI，其满足以下要求：（1）分布包含C8至C18的侧链，平均碳数为12.4至14.4; （2）侧链分布是双模式的，其中双组分分布的下部主要由C12构成，分布的上部主要由C16，C18或其组合构成; （3）分布上部的总摩尔％必须小于分布下部的总摩尔％; 和（4）侧链上的C12的量必须为总侧链分布的至少40摩尔％。

7. 发明授权

US5454961A Substituted fullerenes as flow improvers 失效
标题翻译：取代富勒烯作为流动改进剂
公开(公告)号：US5454961A
公开(公告)日：1995-10-03
申请号：US229499
申请日：1994-04-19
申请人： George W. Schriver , Abhimanyu O. Patil , David J. Martella , Kenneth Lewtas
发明人： George W. Schriver , Abhimanyu O. Patil , David J. Martella , Kenneth Lewtas
IPC分类号： C10G73/04 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/238 , C10L1/24 , C10M127/02 , C10M133/06 , C10M127/00
CPC分类号： C10L1/198 , C10G73/04 , C10L1/143 , C10L1/1683 , C10L1/1691 , C10L1/238 , C10L1/2475 , C10M127/02 , C10M133/06 , C10L1/1616 , C10L1/1641 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1981 , C10L1/1983 , C10L1/1985 , C10L1/206 , C10L1/224 , C10L1/2383 , C10L1/2387 , C10L1/2481 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2207/04 , C10M2215/04 , C10M2215/06 , C10M2215/26 , C10M2217/046 , C10M2217/06 , C10M2219/082 , C10N2270/02 , Y10S977/736
摘要： The present invention relates to novel compositions that contain a base oil and certain substituted fullerenes effective to improve the cold flow properties of the base oil. Typically the substituted fullerenes have the general formula:C.sub.Fn (GR.sub.y).sub.xIn the formula C.sub.Fn is a fullerene or mixture of fullerenes, n is the number of carbon atoms in the fullerene, x is an integer from 1 up to the maximum number of sites on the fullerene molecule available for adding substituent groups, G is a linking group that may be absent or present, and when present is an oxygen, sulfur, nitrogen, phenol, aniline, Mannich base or diazocarboxylate-derived group, y is an integer determined by the identity of G and equals 1 when G is absent or when present and selected from the group consisting of oxygen, sulfur and diazocarboxylate-derived linking groups, and equals 1 or 2 when G is a phenol or aniline linking group, and equals 2 when G is a nitrogen linking group, and when y equals 1 R is a substituted or unsubstituted hydrocarbyl group and when y equals 2 at most one R may be hydrogen while the remainder are hydrocarbyl groups, and the R group may be the same or different, and wherein when x is greater than 1 the GR.sub.y may be the same or different and at most one R may be hydrogen. Preferred are substituted fullerenes that are alkylamino-substituted fullerenes. The compositions are useful as flow-improvers properties.
摘要翻译：本发明涉及含有基础油和有效改善基础油的冷流特性的某些取代的富勒烯的新型组合物。通常，取代的富勒烯具有以下通式：CFn（GRy）x在式中，CFn是富勒烯或富勒烯的混合物，n是富勒烯中的碳原子数，x是从1到最大位数的整数在可用于加成取代基的富勒烯分子上，G是可能不存在或存在的连接基团，并且当存在氧，硫，氮，苯酚，苯胺，曼尼希碱或重氮羧酸酯衍生基团时，y是确定的整数当G不存在或当存在并选自氧，硫和重氮羧酸衍生的连接基团时，G的等同性等于1，当G是苯酚或苯胺连接基时，等于1或2，等于2 当G是氮连接基团时，当y等于1时，R是取代或未取代的烃基，当y等于2时，最多一个R可以是氢，而余数是烃基，R基可以相同或不同，和w 当x大于1时，GRy可以相同或不同，并且至多一个R可以是氢。优选的是烷基氨基取代的富勒烯的取代的富勒烯。组合物可用作流动改进剂性质。

8. 发明授权

US5236608A Alkyl phenol-sulfur condensates as fuel and lubricating oil additives 失效
标题翻译：烷基酚 - 硫缩合物作为燃料和润滑油添加剂
公开(公告)号：US5236608A
公开(公告)日：1993-08-17
申请号：US561895
申请日：1990-08-02
申请人： David J. Martella , John J. Jaruzelski
发明人： David J. Martella , John J. Jaruzelski
IPC分类号： C08G75/14 , C10L1/24 , C10M151/04
CPC分类号： C10L1/2475 , C08G75/14 , C10M151/04 , C10M2203/10 , C10M2203/102 , C10M2221/04 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/06 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2240/40
摘要： Additives for improving the low temperature flow properties and oxidative stability of hydrocarbon oils are disclosed, which comprise the condensation reaction product of alkylated phenol and sulfurizing agent, wherein:(a) the polymer composition has a number average molecular weight of at least about 3,000 and a molecular weight distribution of at least about 1.5;(b) in the alkylated phenol reactant the alkyl groups (i) are essentially linear; (ii) have between 6 and 50 carbon atoms; and (iii) have an average number of carbon atoms between about 12 and 26; and(c) not more than about 10 mole percent of the alkyl groups on the alkylated phenol have less than 12 carbon atoms and not more than about 10 mole percent of the alkyl groups on the alkylated phenol have more than 26 carbon atoms. The additives may also be produced in a branched backbone form in which monomer reactants are compolymerized with certain tri- or tetrafunctional comonomers. Blends of these additives with various hydrocarbon oils, and particularly various middle distillates and lubricating oil compositions, whose low temperature flow properties and oxidative stability are significantly improved thereby, are also disclosed.
摘要翻译：公开了用于改进烃油的低温流动性能和氧化稳定性的添加剂，其包括烷基化苯酚和硫化剂的缩合反应产物，其中：（a）聚合物组合物的数均分子量为至少约3,000，分子量分布至少约1.5; （b）在烷基化酚反应物中，烷基（i）基本上是线性的; （ii）具有6至50个碳原子; 和（iii）平均碳原子数在约12和26之间; 和（c）不超过约10摩尔％的烷基化苯酚上的烷基具有小于12个碳原子，不超过约10摩尔％的烷基化苯酚上的烷基具有多于26个碳原子。添加剂也可以以支链骨架形式制备，其中单体反应物与某些三官能或四官能团共聚单体共聚。还公开了这些添加剂与各种烃油的混合物，特别是各种中间馏分和润滑油组合物，其低温流动性能和氧化稳定性由此显着提高。

9. 发明授权

US5118875A Method of preparing alkyl phenol-formaldehyde condensates 失效
标题翻译：制备烷基酚 - 甲醛缩合物的方法
公开(公告)号：US5118875A
公开(公告)日：1992-06-02
申请号：US595228
申请日：1990-10-10
申请人： David J. Martella , John J. Jaruzelski , Frank J. Chen
发明人： David J. Martella , John J. Jaruzelski , Frank J. Chen
IPC分类号： C08G8/04 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/24 , C10L1/26 , C10L1/30 , C10M145/20 , C10M151/04
CPC分类号： C10L1/1981 , C08G8/04 , C10L1/143 , C10L1/2493 , C10M145/20 , C10M151/04 , C10L1/1616 , C10L1/1641 , C10L1/165 , C10L1/1658 , C10L1/1666 , C10L1/1814 , C10L1/1828 , C10L1/1881 , C10L1/1883 , C10L1/1886 , C10L1/189 , C10L1/1963 , C10L1/1966 , C10L1/198 , C10L1/207 , C10L1/223 , C10L1/2364 , C10L1/2368 , C10L1/238 , C10L1/2383 , C10L1/2412 , C10L1/2425 , C10L1/2437 , C10L1/2481 , C10L1/265 , C10L1/2691 , C10L1/301 , C10L1/303 , C10M2209/101 , C10M2221/00 , C10M2221/041 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106
摘要： Additives of improving the low temperature flow properties and oxidative stability of hydrocarbon oils are disclosed, which comprise the alkylation of a phenol in the presence of a polar aprotic cosolvent to produce an essentially linear alkylated phenol which is condensed with an aldehyde to produce the low temperature flow improver wherein:(a) the polymer composition has a number average molecular weight of at least about 3,000 and a molecular weight distribution of at least about 1.5;(b) in the alkylated phenol reactant the alkyl groups (i) are essentially linear; (ii) have between 6 and 50 carbon atoms; and (iii) have an average number of carbon atoms between about 12 and 26; and(c) not more than about 10 mole percent of the alkyl groups on the alkylated phenol have less than 12 carbon atoms and not more than about 10 mole percent of the alkyl groups on the alkylated phenol have more than 26 carbon atoms. The additives may also be produced in a branched backbone form in which monomer reactants are copolymerized with certain tri- or tetrafunctional comonomers. Blends of these additives with various hydrocarbon oils, and particularly various middle distillates and lubricating oil compositions, whose low temperature flow properties and oxidative stability are significantly improved thereby, are also disclosed.
摘要翻译：公开了改进烃油的低温流动性能和氧化稳定性的添加剂，其包括在极性非质子共溶剂存在下苯酚的烷基化以产生基本上线性的烷基化苯酚，其与醛缩合以产生低温流动改进剂，其中：（a）聚合物组合物具有至少约3,000的数均分子量和至少约1.5的分子量分布; （b）在烷基化酚反应物中，烷基（i）基本上是线性的; （ii）具有6至50个碳原子; 和（iii）平均碳原子数在约12和26之间; 和（c）不超过约10摩尔％的烷基化苯酚上的烷基具有小于12个碳原子，不超过约10摩尔％的烷基化苯酚上的烷基具有多于26个碳原子。添加剂也可以以支链骨架形式制备，其中单体反应物与某些三官能或四官能团共聚单体共聚。还公开了这些添加剂与各种烃油的混合物，特别是各种中间馏分和润滑油组合物，其低温流动性能和氧化稳定性由此显着提高。

10. 发明授权

US4632674A Diesel fuel containing a tetrazole or triazole cetane improver 失效
标题翻译：含有四唑或三唑十六烷改进剂的柴油
公开(公告)号：US4632674A
公开(公告)日：1986-12-30
申请号：US813988
申请日：1985-12-27
申请人： David J. Martella
发明人： David J. Martella
IPC分类号： C07D257/04 , C10L1/22 , C10L1/232 , F02B1/04 , F02B3/06 , C10L1/10
CPC分类号： C07D257/04 , C10L1/232 , F02B1/04 , F02B3/06
摘要： There is disclosed a diesel fuel containing a cetane number improving additive such as 5-propyl-1,2,3,4-tetraazacyclopenta-2,4-diene.
摘要翻译：公开了含有十六烷值改进添加剂如5-丙基-1,2,3,4-四氮杂环戊二烯-2,4-二烯的柴油燃料。

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