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1. 发明授权

US5034481A Avoidance of colored impurities in the preparation of ultrahigh molecular weight ethylene polymers by means of a titanium-containing catalyst system 失效
标题翻译：通过含钛催化剂体系制备超高分子量乙烯聚合物时避免有色杂质
公开(公告)号：US5034481A
公开(公告)日：1991-07-23
申请号：US409343
申请日：1989-09-19
申请人： Guido Funk , Siegfried Weber , Juergen Kerth , Rainer Hemmerich
发明人： Guido Funk , Siegfried Weber , Juergen Kerth , Rainer Hemmerich
IPC分类号： C08F2/00 , C08F2/34 , C08F4/60 , C08F4/64 , C08F10/02 , C08F110/02
CPC分类号： C08F10/02 , Y10S526/901
摘要： Ultrahigh molecular weight ethylene polymers are prepared in the gas phase in a thoroughly mixed bed of finely divided polymer by continuous introduction of the monomer into a polymerization system at 60.degree.-120.degree. C. and 5-60 bar in the presence of a reaction product of a titanium-containing catalyst and an antistat.
摘要翻译：超细分子量乙烯聚合物在气相中通过在60-120℃和5-60巴的反应产物存在下将聚合体系连续引入聚合体系中，在细分聚合物的充分混合床中制备的含钛催化剂和抗静电剂。

2. 发明授权

US4857613A Preparation of homopolymers and copolymers of propene using a Ziegler-Natta catalyst system 失效
标题翻译：使用齐格勒 - 纳塔催化剂体系制备丙烯的均聚物和共聚物
公开(公告)号：US4857613A
公开(公告)日：1989-08-15
申请号：US236213
申请日：1988-08-25
申请人： Ralf Zolk , Juergen Kerth , Rainer Hemmerich
发明人： Ralf Zolk , Juergen Kerth , Rainer Hemmerich
IPC分类号： C08F4/58 , C08F4/60 , C08F4/64 , C08F10/06
CPC分类号： C08F10/06
摘要： Polymers of propene are prepared using a Ziegler-Natta catalyst system consisting of (1) a titanium component which is based on a finely divided, shape-imparting silica gel and contains titanium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component. In the process, a titanium component (1) is employed which is obtained by (1.1) first preparing (I) a carrier from (Ia) a silica gel which has a relatively high moisture content, (Ib) an organomagnesium compound and (Ic) a gaseous chlorinating agent by a method in which (1.1.1) first (Ia) is reacted with (Ib), (1.1.2) then (Ic) is passed into the mixture obtained in (1.1.1), and (I) is isolated, (1.2) thereafter a solid-phase intermediate is prepared from (I), (II) an alkanol, (III) titanium tetrachloride and (IV) a phthalic acid derivative by a procedure in which (1.2.1) first (I) is reacted with (II), (1.2.2) then (III) is introduced into the mixture resulting from (1.2.1), with the proviso that (IV) is also introduced during (1.2.1) and/or (1.2.2), (1.3) then the solid-phase product resulting from (1.2) is extracted with titanium tetrachloride or a titanium tetrachloride/hydrocarbon mixture, and (1.4) finally the solid-phase product resulting from (1.3) is washed with a liquid hydrocarbon.
摘要翻译：丙烯聚合物使用齐格勒 - 纳塔催化剂体系制备，该催化剂体系由（1）基于精细分散的形状赋予硅胶并含有钛，镁，氯和苯甲酸衍生物的钛组分组成，（2）铝成分和（3）硅烷成分。在该方法中，使用钛成分（1），其通过（1.1）首先制备（I）来自（Ia）具有较高水分含量的硅胶的载体（Ib）有机镁化合物和（Ic））气态氯化剂，其中（1.1.1）第一（Ia）与（Ib），（1.1.2）反应，然后将（Ic）转化为（1.1.1）中获得的混合物和（ I）分离，（1.2）之后，通过（I），（II）烷醇，（III）四氯化钛和（Ⅳ）邻苯二甲酸衍生物，通过步骤（1.2.1）制备固相中间体，第一（I）与（II），（1.2.2）反应，然后将（III）引入由（1.2.1）得到的混合物中，条件是在（1.2.1）期间引入（IV）和 /或（1.2.2），（1.3），然后用四氯化钛或四氯化碳/烃混合物萃取由（1.2）得到的固相产物，（1.4）最后由（1.3）得到的固相产物用液体水溶液洗涤碳。

3. 发明授权

US5288824A Preparation of homo- and copolymers of propene by means of a Ziegler-Natta catalyst system 失效
标题翻译：通过齐格勒 - 纳塔催化剂体系制备丙烯的均聚物和共聚物
公开(公告)号：US5288824A
公开(公告)日：1994-02-22
申请号：US934848
申请日：1992-08-25
申请人： Juergen Kerth , Rainer Hemmerich , Peter Koelle , Patrik Mueller
发明人： Juergen Kerth , Rainer Hemmerich , Peter Koelle , Patrik Mueller
IPC分类号： C08F4/658 , C08F4/02 , C08F4/60 , C08F4/647 , C08F4/652 , C08F10/00 , C08F10/06 , C08F4/64
CPC分类号： C08F10/06
摘要： Polymers of propene are prepared using a Ziegler-Natta catalyst system comprising (1) titanium component which is based on a finely divided, shape-imparting silica gel and contains titan- ium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component. The process employs a titanium component (1) which is obtained by a method in which (1.1) first (I) a carrier is prepared from (Ia) a silica gel which has a relatively high moisture content, (Ib) an organomagnesium compound and (Ic) a gaseous chlorinating agent in a manner such that (1.1.1) first (Ia) is reacted with (Ib), (1.1.2) then (Ic) is passed into the mixture obtained from (1.1.1), (1.2) then a solid-phase intermediate is prepared from (I), (II) an alkanol, (III) titanium tetrachloride and (IV) a phthalic acid derivative in a manner such that (1.2.1) first (I) is reacted with (II), (1.2.2) then (III) is introduced into the mixture resulting from (1.2.1), with the proviso that (IV) is also introduced in (1.2.1) or (1.2.2), (1.3) then the solid-phase intermediate resulting from (1.2) is extracted with titanium tetrachloride or with a titanium tetrachloride/-hydrocarbon mixture and (1.4) finally the solid-phase product resulting from (1.3) is washed with a liquid hydrocarbon.
摘要翻译：使用齐格勒 - 纳塔催化剂体系制备丙烯聚合物，该催化剂体系包括（1）基于精细分散的形状赋予硅胶并含有钛，镁，氯和苯甲酸衍生物的钛组分，（2）铝成分和（3）硅烷成分。该方法采用通过以下方法得到的钛组分（1）：其中（1.1）第一（I）载体由（Ia）由具有相对高的水分含量的硅胶制备，（Ib）有机镁化合物和（Ic）气态氯化剂，使得（1.1.1）第一（Ia）与（Ib），（1.1.2）反应，然后（Ic）进入从（1.1.1）获得的混合物中，（1.2），然后以（I），（II）烷醇，（III）四氯化钛和（IV）邻苯二甲酸衍生物的方式制备固相中间体，使得（1.2.1）第一（I）为与（II）反应，（1.2.2）然后将（III）引入由（1.2.1）得到的混合物中，条件是（IV）也引入（1.2.1）或（1.2.2），（1.3），然后用四氯化钛或四氯化钛/ - 烃混合物萃取由（1.2）得到的固相中间体，（1.4）最后将由（1.3）得到的固相产物用液体烃。

4. 发明授权

US5162465A Preparation of homopolymers and copolymers of propene using a Ziegler-Natta catalyst system 失效
标题翻译：使用齐格勒 - 纳塔催化剂体系制备丙烯的均聚物和共聚物
公开(公告)号：US5162465A
公开(公告)日：1992-11-10
申请号：US646493
申请日：1991-01-28
申请人： Juergen Kerth , Ralf Zolk , Rainer Hemmerich
发明人： Juergen Kerth , Ralf Zolk , Rainer Hemmerich
IPC分类号： C08F4/58 , C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00 , C08F10/06
CPC分类号： C08F10/06 , Y10S526/901
摘要： Polymers of propene are prepared using a Ziegler-Natta catalyst system consisting of (1) a titanium component which is based on a finely divided, shape-imparting silica gel and contains, in addition to titanium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component. In this process, a titanium component (1) is used which is obtained by a method in which (1.1) first (I) a carrier is prepared from (Ia) a silica gel, (Ib) an alkanol, (Ic) an organomagnesium compound and (Id) a gaseous chlorinating agent by a procedure in which (1.1.1) first (Ia) is reacted with (Ib), (1.1.2) then the mixture obtained in (1.1.1) is combined with (Ic), (1.1.3) then (Id) is passed into the mixture obtained in (1.1.2) and (I) is isolated, (1.2) thereafter a solid-phase intermediate is prepared from (I), (II) an alkanol, (III) titanium tetrachloride and (IV) a phthalic acid drivative by a procedure in which (1.2.1) first (I) is reacted with (II), (1.2.2) then (III) is introduced into the mixture resulting from (1.2.1), with the proviso that (IV) is also introduced during (1.2.1) and/or (1.2.2), (1.3) then the solid-phase product resulting from (1.2) is extracted with titanium tetrachloride and (1.4) finally the solid-phase product resulting from (1.3) is washed with a liquid hydrocarbon.
摘要翻译：丙烯聚合物使用齐格勒 - 纳塔催化剂体系制备，该催化剂体系由以下组成：（1）基于精细分散的形状赋予硅胶的钛组分，除钛，镁，氯和苯甲酸衍生物外，（2）铝成分和（3）硅烷成分。在该方法中，使用通过以下方法获得的钛组分（1）：其中（1.1）第一（I）载体由（Ia）硅胶制备，（Ib）烷醇，（Ic）有机镁化合物和（Id）气态氯化剂，其中（1.1.1）第一（Ia）与（Ib），（1.1.2）反应，然后将（1.1.1）中获得的混合物与（Ic ），（1.1.3）然后（Id）进入（1.1.2）中获得的混合物中，（I）分离，（1.2）之后，从（I），（II）制备固相中间体链烷醇，（III）四氯化钛和（IV）通过其中（1.2.1）第一（I）与（II），（1.2.2）然后（III）反应的方法将邻苯二甲酸驱动物引入混合物（1.2.1）产生，条件是在（1.2.1）和/或（1.2.2），（1.3）中也引入了（IV），则从（1.2）得到的固相产物用四氯化钛和（1.4）最后由（1.3）产生的固相产物用液体洗涤加油

5. 发明授权

US5006620A Preparation of homopolymers and copolymers of propene by means of a Ziegler-Natta catalyst system 失效
标题翻译：通过齐格勒 - 纳塔催化剂体系制备丙烯的均聚物和共聚物
公开(公告)号：US5006620A
公开(公告)日：1991-04-09
申请号：US400350
申请日：1989-08-30
申请人： Ralf Zolk , Juergen Kerth , Rainer Hemmerich
发明人： Ralf Zolk , Juergen Kerth , Rainer Hemmerich
IPC分类号： C08F4/658 , C08F4/02 , C08F4/58 , C08F4/60 , C08F4/64 , C08F4/646 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00 , C08F10/06 , Y10S526/909
摘要： Polymers of propene are prepared by means of a Ziegler-Natta catalyst system composed of (1) a titanium component based on a finely divided shape-dictating silica gel and containing titanium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component, the titanium component (1) being obtained by (1.1) first preparing (I) a carrier material from (Ia) a silica gel, (Ib) an organomagnesium compound (Ic) a gaseous chlorinating agent and (Id) a specific phthalic acid derivative by (1.1.1) first reacting (Ia) with (Ib), then (1.1.2) passing (Ic) into the product of (1.1.1) together with the phthalic acid derivative (Id) and isolating (I), (1.2) preparing a solid-phase intermediate from (I), (II) an alkanol and (III) titanium tetrachloride by (1.2.1) first reacting (I) with (II), then (1.2.2) introducing (III) into the product resulting from (1.2.1), then (1.3) extracting the solid-phase result from (1.2) with titanium tetrachloride or a titanium tetrachloride/ethylbenzene mixture, and finally (1.4) washing the solid-phase result from (1.3) with a liquid hydrocarbon.
摘要翻译：丙烯聚合物通过齐格勒 - 纳塔催化剂体系制备，该催化剂体系由（1）基于精细分散形状的硅胶组成的钛组分，含有钛，镁，氯和苯甲酸衍生物，（2）铝组分和（3）硅烷组分，钛组分（1）通过（1.1）首先制备（I）载体材料从（Ia）硅胶获得，（Ib）有机镁化合物（Ic），气态氯化剂和（Id）通过（1.1.1）首先使（Ia）与（Ib）反应的（1.1.1）特定的邻苯二甲酸衍生物，然后（1.1.2）将（Ic）与（1.1.1）的产物一起与邻苯二甲酸衍生物（I）和（II），（I）与（II）反应制备（I），（1.2）从（I），（II）烷基醇和（III）四氯化钛制备固相中间体（1.2.1）然后（1.2.2）将（III）引入到由（1.2.1）得到的产物中，然后（1.3）从（1.2）中提取四氯化钛的固相或四氯化钛/乙苯混合物，最后（1.4）用液态烃洗涤（1.3）的固相结果。

6. 发明授权

US6034023A Preparation of Ziegler-Natta catalyst systems 失效
标题翻译：齐格勒 - 纳塔催化剂体系的制备
公开(公告)号：US6034023A
公开(公告)日：2000-03-07
申请号：US943025
申请日：1992-09-10
申请人： Meinolf Kersting , Juergen Kerth , Klaus-Dieter Hungenberg , Peter Koelle
发明人： Meinolf Kersting , Juergen Kerth , Klaus-Dieter Hungenberg , Peter Koelle
IPC分类号： C08F4/654 , C08F4/60 , C08F4/642 , C08F4/646 , C08F4/648 , C08F4/651 , C08F4/657 , C08F10/00 , C08F4/64
CPC分类号： C08F10/00
摘要： A novel process for the preparation of Ziegler-Natta catalyst systems containing, as active components,a) a titanium-containing solid component which contains titanium, magnesium, halogen and a carboxylic ester and, as a cocatalyst,b) an aluminum compound andc) if required, a further electron donor is described. Ziegler-Natta catalyst systems which are obtainable by this process, the preparation of polymers of propylene with the aid of these catalyst systems, the polymers obtainable thereby and films and moldings of these polymers are also described.
摘要翻译：一种用于制备齐格勒 - 纳塔催化剂体系的新方法，其包含作为活性组分的a）含钛，镁，卤素和羧酸酯的含钛固体组分，并且作为助催化剂，b）铝化合物和c ）如果需要，描述另一电子给体。也可以通过该方法获得的齐格勒 - 纳塔催化剂体系，借助于这些催化剂体系制备丙烯的聚合物，由此得到的聚合物以及这些聚合物的膜和模制品。

7. 发明授权

US5773537A Ziegler-natta catalyst systems containing specific organosilicon compounds 失效
标题翻译：含有特定有机硅化合物的齐格勒 - 纳塔催化剂体系
公开(公告)号：US5773537A
公开(公告)日：1998-06-30
申请号：US579890
申请日：1995-12-28
申请人： Patrik Mueller , Klaus-Dieter Hungenberg , Juergen Kerth , Ralf Zolk
发明人： Patrik Mueller , Klaus-Dieter Hungenberg , Juergen Kerth , Ralf Zolk
IPC分类号： C08F4/646 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00
摘要： Catalyst systems of the Ziegler-Natta type contain, as active components a) a titanium-containing solid component in whose preparation a titanium compound, a compound of magnesium, a halogenating agent and an electron donor component are used, b) an aluminum compound and c) as a further electron donor component, an organosilicon compound of the formula (I) R.sup.1 R.sup.2 Si(OR.sup.3).sub.2 (I) where R.sup.1 is C.sup.1 -C.sub.10 -alkyl or C.sub.3 -C.sub.8 -cycloalkyl, excluding sec-butyl, R.sup.2 is sec-butyl and R.sup.3 is C.sub.1 -C.sub.8 -alkyl. The catalyst systems are particularly suitable for the preparation of polymers of C.sub.2 -C.sub.10 -alk-1-enes.
摘要翻译：齐格勒 - 纳塔型催化剂体系包含作为活性组分的a）其中使用钛化合物，镁化合物，卤化剂和电子给体组分的含钛固体组分，b）铝化合物和 c）作为另外的电子给体组分，式（I）的有机硅化合物R1R2Si（OR3）2（Ⅰ）其中R1是C1-C10-烷基或C3-C8-环烷基，不包括仲丁基，R2是仲 - 丁基，R 3为C 1 -C 8 - 烷基。催化剂体系特别适用于制备C 2 -C 10 - 烷-1-烯的聚合物。

8. 发明授权

US5476905A Grafted, crosslinked and crosslinkable 失效
标题翻译：接枝交联和交联丙烯共聚物
公开(公告)号：US5476905A
公开(公告)日：1995-12-19
申请号：US725870
申请日：1991-07-10
申请人： Harald Schwager , Thomas Muehlenbernd , Bernd L. Marczinke , Juergen Kerth , Hans-Joachim Mueller
发明人： Harald Schwager , Thomas Muehlenbernd , Bernd L. Marczinke , Juergen Kerth , Hans-Joachim Mueller
IPC分类号： C08F8/42 , C08F255/02 , C08F265/02 , C08F265/04
CPC分类号： C08F255/02 , C08F8/42
摘要： Propylene copolymers grafted with .alpha.,.beta.-ethylenically unsaturated carboxylic acids or derivatives and containing up to 35% by weight of other C.sub.2 - to C.sub.10 -alk-1-enes are obtainable by reacting the monomer to be grafted with a propylene copolymer at from 1 to 500 bar, where, in the absence of a free-radical initiator, from 0.01 to 1.0% by weight, based on the propylene copolymer, of the monomer to be grafted are admixed with the molten propylene copolymer, and the grafting reaction is carried out at from 210.degree. to 350.degree. C.The propylene copolymers according to the invention can be converted into crosslinked or crosslinkable propylene copolymers by admixing organic crosslinking agents.
摘要翻译：用α，β-烯键式不饱和羧酸或衍生物接枝并含有至多35重量％的其它C 2 -C 10 - 烷-1-烯的丙烯共聚物可通过将待接枝的单体与丙烯共聚物在1 至500巴，其中在不存在自由基引发剂的情况下，基于丙烯共聚物，待接枝的单体的0.01至1.0重量％与熔融丙烯共聚物混合，并进行接枝反应在210℃至350℃下进行。根据本发明的丙烯共聚物可以通过混合有机交联剂转化成交联或交联的丙烯共聚物。

9. 发明授权

US5077322A Foams based on an olefin copolymer 失效
标题翻译：基于烯烃共聚物的FOAMS
公开(公告)号：US5077322A
公开(公告)日：1991-12-31
申请号：US684277
申请日：1991-04-12
申请人： Isidoor De Grave , Joachim Fischer , Wolfram Koegel , Hermann Tatzel , Onno Graalmann , Juergen Kerth , Rainer A. Werner
发明人： Isidoor De Grave , Joachim Fischer , Wolfram Koegel , Hermann Tatzel , Onno Graalmann , Juergen Kerth , Rainer A. Werner
IPC分类号： C08J9/14 , C08J9/16 , C08J9/18
CPC分类号： C08J9/18 , C08J9/141 , C08J2323/16
摘要： Novel foams having a density of from 0.01 to 0.1 g/cm.sup.3, based on a copolymer comprising ethylene, propylene and a C.sub.4 - to C.sub.8 -.alpha.-olefin, and having a torsion modulus of from 100 to 800 N/mm.sup.2 have high tensile, compressive and flexural strengths and at the same time high elongation at break.
摘要翻译：基于包含乙烯，丙烯和C 4 -C 8α-烯烃的共聚物，并且具有100至800N / mm 2的扭转模量的密度为0.01至0.1g / cm 3的新型泡沫具有高拉伸强度，压缩和弯曲强度，同时高断裂伸长率。

10. 发明授权

US5166113A Zieger-natta-type catalyst systems 失效
标题翻译：齐格纳塔型催化剂体系
公开(公告)号：US5166113A
公开(公告)日：1992-11-24
申请号：US759980
申请日：1991-09-17
申请人： Harald Schwager , Peter Koelle , Juergen Kerth , Ralf Zolk
发明人： Harald Schwager , Peter Koelle , Juergen Kerth , Ralf Zolk
IPC分类号： C08F10/00
CPC分类号： C08F10/00
摘要： Ziegler-Natta-type catalyst systems containing, as active constituents,a) a titanium-containing solid component which also contains magnesium, halogen and a carboxylic acid ester, and, as cocatalyst,b) an aluminum compound,wherein the carboxylic acid ester in the solid component is a diester of a carboxylic acid of the formula Ia or Ib ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and are hydrogen, C.sub.1 - to C.sub.15 -alkyl, C.sub.7 - to C.sub.15 -alkylaryl, or 5- to 7-membered cycloalkyl, which may itself carry C.sub.1 - to C.sub.10 -alkyl groups, are particularly suitable for the preparation of polypropylene and copolymers of propylene containing minor amounts of other .alpha.,.beta.-unsaturated olefinic compounds having from 2 to 12 carbon atoms.
摘要翻译：含有作为活性成分的齐格勒 - 纳塔型催化剂体系a）含镁，卤素和羧酸酯的含钛固体组分，和作为助催化剂的b）铝化合物，其中羧酸酯在固体组分是式Ia或Ib的羧酸的二酯（Ia）其中R 1，R 2，R 3和R 4相同或不同，为氢，C 1至C 15 - 烷基可以自身携带C1-至C10烷基的C 7 -C 15烷基芳基或5-至7-元环烷基特别适用于制备聚丙烯和含有少量其它α，β- 具有2至12个碳原子的不饱和烯烃化合物。

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