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1. 发明公开

EP2109592A1 METHOD OF MAKING HEAT TREATED COATED ARTICLE USING DIAMOND-LIKE CARBON (DLC) COATING AND PROTECTIVE FILM 有权
标题翻译：用于生产具有保护涂层类金刚石经热处理的涂覆制品（DLC）
公开(公告)号：EP2109592A1
公开(公告)日：2009-10-21
申请号：EP08712928.4
申请日：2008-01-03
申请人： Guardian Industries Corp. , Centre Luxembourgeois de Recherches pour le Verre et la Céramique S.A.
发明人： MURPHY, Nestor, P. , FRATI, Maximo , PETRMICHL, Rudolph, Hugo , WANG, Jiangping , MULLER, Jens-Peter , LAGE, Herbert
IPC分类号： C03C17/34 , C03C23/00
CPC分类号： C03C17/3441 , C03B27/012 , C03C17/3423 , C03C23/007 , C03C2217/78 , C03C2217/91 , C03C2218/322 , C03C2218/328 , C03C2218/355
摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include an oxide of zinc. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.
摘要翻译：在淋浴门的应用程序，窗口的应用程序，或其中透明涂覆制品是期望的任何其他合适的应用中使用处理制造的热（HT）涂覆的制品的方法。对于实施例，本发明的某些实施例涉及一种制造涂覆制品包括的热处理涂覆的至少一个层或包含类金刚石碳（DLC）和在其上在覆盖保护膜的玻璃基板的工序的方法。在实施例的某些实施例中，保护膜可以是或包括锌的氧化物。以下和/或在热处理过程中（E. G.，热回火，或类似物）的保护膜可以被去除。本发明的其它实施方案涉及与预HT涂布制品，或后HT涂层制品。

2. 发明申请

WO2006057829A2 SCRATCH RESISTANT COATED GLASS ARTICLE INCLUDING LAYER(S) RESISTANT TO FLUORIDE-BASED ETCHANT(S), AND METHOD OF MAKING ARTICLE USING COMBUSTION CVD 审中-公开
标题翻译：耐刮涂玻璃制品，包括耐氟化物基质的层（S），以及使用燃烧CVD制备物品的方法
公开(公告)号：WO2006057829A2
公开(公告)日：2006-06-01
申请号：PCT/US2005/040974
申请日：2005-11-14
申请人： GUARDIAN INDUSTRIES CORP. , THOMSEN, Scott, V. , PETRMICHL, Rudolph, Hugo , MURPHY, Nestor, P. , VEERASAMY, Vijayen, S.
发明人： THOMSEN, Scott, V. , PETRMICHL, Rudolph, Hugo , MURPHY, Nestor, P. , VEERASAMY, Vijayen, S.
IPC分类号： C23C14/00 , B32B9/00 , C23C14/32 , C23C16/00 , H01L21/4763 , G21H5/00 , B05D3/00 , C08J7/18
CPC分类号： C23C14/06 , C03C17/22 , C03C17/225 , C03C17/23 , C03C17/245 , C03C17/2453 , C03C17/3417 , C03C17/3435 , C03C17/3441 , C03C17/3452 , C03C2217/215 , C03C2217/218 , C03C2217/228 , C03C2217/281 , C03C2217/282 , C03C2217/285 , C03C2218/15 , C03C2218/154 , C23C14/024 , C23C14/0635 , C23C14/08 , C23C14/086 , C23C14/58 , Y10T428/265 , Y10T428/30 , Y10T428/31612
摘要： A scratch resistant coated article is provided which is also resistant to attacks by at least some fluoride-based etchant(s) for at least a period of time. In certain example embodiments, an anti-etch layer(s) is provided on a glass substrate in order to protect the glass substrate from attacks by fluoride-based etchant(s), and an underlayer(s) deposited by flame pyrolysis may be provided under at least the antietch layer(s).
摘要翻译：提供了耐刮擦涂层制品，其还耐受至少一些基于氟化物的蚀刻剂至少一段时间的攻击。在某些示例性实施例中，在玻璃基板上提供防蚀刻层，以便保护玻璃基板免受基于氟化物的蚀刻剂的攻击，并且可以提供通过火焰热解沉积的底层在至少防反射层之下。

3. 发明申请

WO2008143756A1 METHOD OF MAKING HEAT TREATED COATED ARTICLE USING DIAMOND-LIKE CARBON (DLC) COATING AND PROTECTIVE FILM 审中-公开
标题翻译：使用金刚石碳（DLC）涂层和保护膜制备热处理涂层制品的方法
公开(公告)号：WO2008143756A1
公开(公告)日：2008-11-27
申请号：PCT/US2008/005266
申请日：2008-04-24
申请人： GUARDIAN INDUSTRIES CORP. , PETRMICHL, Rudolph, Hugo , WANG, Jiangping , MURPHY, Nestor, P. , FRATI, Maximo , NUNEZ-REGUEIRO, Jose
发明人： PETRMICHL, Rudolph, Hugo , WANG, Jiangping , MURPHY, Nestor, P. , FRATI, Maximo , NUNEZ-REGUEIRO, Jose
IPC分类号： C03C17/34 , C03C23/00
CPC分类号： C03C17/3435 , C03C17/3423 , C03C17/3441 , C03C23/007 , C03C2217/78 , C03C2217/91 , C03C2218/322 , C03C2218/328 , C03C2218/355
摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the pos-t HT coated article.
摘要翻译：提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。继续和/或在热处理（例如热回火等）期间，可以去除保护膜。本发明的其它实施方案涉及预HT涂覆的制品，或者是HT涂覆制品。

4. 发明申请

WO2006055323A2 SCRATCH RESISTANT COATED GLASS ARTICLE INCLUDING CARBIDE LAYER(S) RESISTANT TO FLUORIDE-BASED ETCHANT(S) 审中-公开
标题翻译：耐刮涂层玻璃制品，包括耐氟化物基层的碳化物层（S）
公开(公告)号：WO2006055323A2
公开(公告)日：2006-05-26
申请号：PCT/US2005/040317
申请日：2005-11-08
申请人： GUARDIAN INDUSTRIES CORP. , MURPHY, Nestor, P. , PETRMICHL, Rudolph, Hugo , VEERASAMY, Vijayen, S.
发明人： MURPHY, Nestor, P. , PETRMICHL, Rudolph, Hugo , VEERASAMY, Vijayen, S.
IPC分类号： C23C14/00
CPC分类号： C23C14/58 , C03C17/22 , C03C17/23 , C03C17/3441 , C03C2217/282 , C03C2217/78 , C03C2218/155 , C03C2218/156 , C23C14/0057 , C23C14/024 , C23C14/06 , C23C14/0635 , C23C14/08 , C23C14/086
摘要： A scratch resistant coated article is provided which is also resistant to attacks by at least some fluoride-based etchant(s) for at least a period of time. In certain example embodiments, an anti-etch layer(s) is provided on a glass substrate in order to protect the glass substrate from attacks by fluoride-based etchant(s). In certain example embodiments, a DLC layer(s) may be provided over the anti-etch layer. An underlayer may be provided under the anti-etch layer(s) in certain example embodiments. In certain example embodiments, the anti-etch layer(s) may be of or include a carbide and/or oxycarbide of Zr, Sn or the like.
摘要翻译：提供了耐刮擦涂层制品，其还耐受至少一些基于氟化物的蚀刻剂至少一段时间的侵袭。在某些示例性实施例中，在玻璃基板上提供防蚀刻层以保护玻璃基板免受基于氟化物的蚀刻剂的攻击。在某些示例性实施例中，可以在抗蚀刻层上提供DLC层。在某些示例性实施例中，可以在抗蚀刻层下面设置底层。在某些示例性实施例中，抗蚀刻层可以是或包括Zr，Sn等的碳化物和/或碳氧化物。

5. 发明申请

WO2010024960A1 METHOD OF MAKING HEAT TREATED COATED ARTICLE USING DIAMOND-LIKE CARBON (DLC) COATING AND PROTECTIVE FILM 审中-公开
标题翻译：使用金刚石碳（DLC）涂层和保护膜制备热处理涂层制品的方法
公开(公告)号：WO2010024960A1
公开(公告)日：2010-03-04
申请号：PCT/US2009/047172
申请日：2009-06-12
申请人： GUARDIAN INDUSTRIES CORP. , PETRMICHL, Rudolph, Hugo , WANG, Jiangping , MURPHY, Nestor, P. , FRATI, Maximo , NUNEZ-REGUEIRO, Jose
发明人： PETRMICHL, Rudolph, Hugo , WANG, Jiangping , MURPHY, Nestor, P. , FRATI, Maximo , NUNEZ-REGUEIRO, Jose
IPC分类号： C03C17/34
CPC分类号： C03C17/3441 , C03C17/22 , C03C2217/282 , C03C2217/78 , C03C2217/91 , C03C2218/328 , C03C2218/33 , C03C2218/355 , Y10T428/30
摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post- HT coated article.
摘要翻译：提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。继续和/或在热处理（例如热回火等）期间，可以去除保护膜。本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

6. 发明申请

WO2008147488A1 METHOD OF MAKING HEAT TREATED COATED ARTICLE USING DIAMOND-LIKE CARBON (DLC) COATING AND PROTECTIVE FILM 审中-公开
标题翻译：使用金刚石碳（DLC）涂层和保护膜制备热处理涂层制品的方法
公开(公告)号：WO2008147488A1
公开(公告)日：2008-12-04
申请号：PCT/US2008/004707
申请日：2008-04-11
申请人： GUARDIAN INDUSTRIES CORP. , KRASNOV, Alexey , PETRIMIL, Rudolph, Hugo , WANG, Jiangping , MURPHY, Nestor, P. , FRATI, Maximo , NUNEZ-REGUEIRO, Jose
发明人： KRASNOV, Alexey , PETRIMIL, Rudolph, Hugo , WANG, Jiangping , MURPHY, Nestor, P. , FRATI, Maximo , NUNEZ-REGUEIRO, Jose
IPC分类号： C03C17/34 , C03C23/00
CPC分类号： C03C17/3441 , C03C23/007 , C03C2217/78 , C03C2218/322 , C03C2218/328 , C03C2218/355
摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. The method may include heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) or other type of carbon, with a protective film thereon. In certain example embodiments, the protective film may be of or include a layer of or including SnO x prior to HT. Optionally, a release layer of a material such as zinc oxide may be provided between the SnO x and the DLC. Following and/or during heat treatment the SnOx transforms into SnO y (y > x) so that stress is created due to the SnO x to SnO y transition. Then, during quenching, stress relief may occur which causes the layer to buckle, creating cracks which may act as liquid channels that permit the sacrificial film to be easily removed via washing or the like.
摘要翻译：提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。该方法可以包括用至少一层或类金刚石碳（DLC）或其他类型的碳涂覆的玻璃基板与其上的保护膜进行热处理。在某些示例性实施方案中，保护膜可以是HT之前的或包括SnOx层或包括SnOx层。任选地，可以在SnO x和DLC之间提供诸如氧化锌的材料的剥离层。跟随和/或在热处理期间，SnOx转变成SnOy（y> x），从而由于SnOx至SnOy转变而产生应力。然后，在淬火期间，可能发生应力消除，这导致该层弯曲，产生可能作为允许通过洗涤等容易地除去牺牲膜的液体通道的裂纹。

7. 发明申请

WO2008094382A1 METHOD OF MAKING HEAT TREATED COATED ARTICLE USING DIAMOND-LIKE CARBON (DLC) COATING AND PROTECTIVE FILM 审中-公开
标题翻译：使用金刚石（DLC）涂层和保护膜制备热处理涂层制品的方法
公开(公告)号：WO2008094382A1
公开(公告)日：2008-08-07
申请号：PCT/US2008/000017
申请日：2008-01-03
申请人： GUARDIAN INDUSTRIES CORP. , CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A. (C.R.V.C.) , MURPHY, Nestor, P. , FRATI, Maximo , PETRMICHL, Rudolph, Hugo , WANG, Jiangping , MULLER, Jens-Peter
发明人： MURPHY, Nestor, P. , FRATI, Maximo , PETRMICHL, Rudolph, Hugo , WANG, Jiangping , MULLER, Jens-Peter
IPC分类号： C03C17/34 , C03C23/00
CPC分类号： C03C17/3441 , C03B27/012 , C03C17/3423 , C03C23/007 , C03C2217/78 , C03C2217/91 , C03C2218/322 , C03C2218/328 , C03C2218/355
摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include an oxide of zinc. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.
摘要翻译：提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，其包括用至少一层或类金刚石碳（DLC）涂覆的玻璃基板和其上覆盖的保护膜进行热处理的步骤。在某些示例性实施方案中，保护膜可以是或包括锌的氧化物。继续和/或在热处理（例如，热回火等）期间，可以去除保护膜。本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

8. 发明申请

WO2008069893A1 METHOD OF MAKING IG WINDOW UNIT AND FORMING SILICON OXIDE BASED HYDROPHILIC COATING USING CHLOROSILANE VAPOR DEPOSITION 审中-公开
标题翻译：制造IG窗单元的方法和使用氯硅烷蒸气沉积形成基于氧化硅的水解涂料
公开(公告)号：WO2008069893A1
公开(公告)日：2008-06-12
申请号：PCT/US2007/023696
申请日：2007-11-13
申请人： GUARDIAN INDUSTRIES CORP. , MURPHY, Nestor, P.
发明人： MURPHY, Nestor, P.
IPC分类号： E06B3/00
CPC分类号： C03C17/36 , C03C17/245 , C03C17/3618 , C03C17/3644 , C03C17/366 , C03C2217/75 , C03C2218/365
摘要： A method of making an insulating glass (IG) window unit is provided. The IG window unit includes at least two spaced apart substrates that are separated from one another by at least one seal and/or spacer, wherein a first one of the substrates supports a hydrophilic coating (e.g., silicon oxide) on the surface facing the building exterior and either of the substrates supports a solar management coating (e.g., a low-emissivity coating) for blocking infrared radiation.
摘要翻译：提供了制作中空玻璃（IG）窗单元的方法。 IG窗单元包括通过至少一个密封和/或间隔件彼此分开的至少两个间隔开的基板，其中第一个基板在面向建筑物的表面上支撑亲水涂层（例如，氧化硅）外部和任一个基板支持用于阻挡红外辐射的太阳能管理涂层（例如，低辐射涂层）。

9. 发明申请

WO2008036266A2 ION SOURCE AND METALS USED IN MAKING COMPONENTS THEREOF AND METHOD OF MAKING SAME 审中-公开
标题翻译：用于制造其组件的离子源和金属及其制造方法
公开(公告)号：WO2008036266A2
公开(公告)日：2008-03-27
申请号：PCT/US2007/020208
申请日：2007-09-17
申请人： GUARDIAN INDUSTRIES CORP. , MURPHY, Nestor, P. , ROCK, David, E. , WALTON, Hugh, A. , FRATI, Maximo
发明人： MURPHY, Nestor, P. , ROCK, David, E. , WALTON, Hugh, A. , FRATI, Maximo
IPC分类号： H01J3/14
CPC分类号： H01J27/143
摘要： An ion source is capable of generating and/or emitting an ion beam which may be used to deposit a layer on a substrate or to perform other functions. In certain example embodiments, techniques for reducing the costs associated with producing ion sources and/or elements thereof are provided. Such techniques may include, for example, forming the inner and/or outer cathode(s) from 1018 mild steel and/or segmented pieces. Such techniques also or instead include, for example, forming the ion source body from a single steel U-channel, or from segmented pieces making up the same. These techniques may be used alone or in various combinations.
摘要翻译：离子源能够产生和/或发射离子束，该离子束可以用于在衬底上沉积层或执行其他功能。在某些示例实施例中，提供了用于降低与生产离子源和/或其元件相关的成本的技术。这种技术可以包括例如由1018软钢和/或分段件形成内部和/或外部阴极。这些技术还包括或者代之以包括例如由单个钢U形通道形成离子源体，或者由构成该通道的分段件形成离子源体。这些技术可以单独使用或以各种组合使用。

10. 发明申请

WO2008010882A2 ION SOURCE WITH RECESS IN ELECTRODE 审中-公开
标题翻译：离子源与电极接触
公开(公告)号：WO2008010882A2
公开(公告)日：2008-01-24
申请号：PCT/US2007/013717
申请日：2007-06-12
申请人： GUARDIAN INDUSTRIES CORP. , MURPHY, Nestor, P. , ROCK, David
发明人： MURPHY, Nestor, P. , ROCK, David
IPC分类号： C23C16/00
CPC分类号： H01J37/08 , H01J27/024 , H01J27/143 , H01J2237/31
摘要： An ion source capable of generating and/or emitting an ion beam which may be used to deposit a layer on a substrate or to perform other functions is provided. The ion source includes at least one anode and at least one cathode. In certain example embodiments, the anode may. have a recess formed therein in which ions to be included in the ion beam may accelerate. Walls of the recess optionally may be insulated using, for example, ceramic. One or more holes may be provided to allow a supply of gas to flow into the recess, and those holes optionally may be tapered such that they narrow towards the recess. Thus, certain example embodiments produce an ion source having a higher energy efficiency (e.g., having increasing ion energy).
摘要翻译：提供了能够产生和/或发射可用于沉积衬底上的层或执行其它功能的离子束的离子源。离子源包括至少一个阳极和至少一个阴极。在某些示例性实施例中，阳极可以。其中形成有其中包含在离子束中的离子可以加速的凹陷。凹部的壁可以任选地使用例如陶瓷绝缘。可以设置一个或多个孔以允许气体供应流入凹部，并且这些孔任选地可以是锥形的，使得它们朝向凹部变窄。因此，某些示例性实施例产生具有较高能量效率（例如具有增加的离子能量）的离子源。

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