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1. 发明申请

US20050085656A1 Water resistant catalyst for the production of diaryl carbonates via the direct carbonylation of phenolic compounds 失效
标题翻译：通过酚类化合物的直接羰基化生产碳酸二芳基酯的防水催化剂
公开(公告)号：US20050085656A1
公开(公告)日：2005-04-21
申请号：US10687411
申请日：2003-10-15
申请人： Grigorii Soloveichik , Timothy Chuck , Kirill Shalyaev , Eric Pressman , Peter Bonitatebus
发明人： Grigorii Soloveichik , Timothy Chuck , Kirill Shalyaev , Eric Pressman , Peter Bonitatebus
IPC分类号： B01J23/44 , B01J31/22 , C07C68/00 , C07C69/96
CPC分类号： B01J31/0268 , B01J31/0237 , B01J31/0239 , B01J31/2234 , B01J31/26 , B01J2231/34 , B01J2531/16 , B01J2531/46 , B01J2531/824 , C07C68/005 , C07C69/96
摘要： A method of increasing the amount of diphenylcarbonate produced per amount of catalyst consumed in a phenol carbonylation process is described. Phenolic carbonylation produces water as a reaction product which reduces the turnover number (TON) of the catalyst. A mixture of a phenolic precursor, a base containing catalyst and co-catalyst components and at least one chemical additive comprising a halide or hydroxide of alkali metal or alkaline earth metal when carbonylated together under specific conditions increases the turnover number (TON) and water resistivity of a palladium catalyst. The metal halide likely makes the catalyst less susceptible to degradation by water hence increasing the reaction yield per weight of catalyst consumed.
摘要翻译：描述了在苯酚羰基化方法中增加每消耗的催化剂生产的碳酸二苯酯的量的方法。酚醛羰基化产生水作为反应产物，其降低催化剂的周转数（TON）。当在特定条件下一起羰基化时，酚前体，含碱催化剂和助催化剂组分的混合物和至少一种包含碱金属或碱土金属的卤化物或氢氧化物的化学添加剂增加了周转数（TON）和水电阻率的钯催化剂。金属卤化物可能使得催化剂不易受水的降解，因此增加每消耗催化剂重量的反应产率。

2. 发明授权

US08013173B2 Method of purifying dianhydrides, the dianhydrides formed thereby, and polyetherimides formed therefrom 有权
标题翻译：纯化二酸酐的方法，由此形成的二酸酐和由其形成的聚醚酰亚胺
公开(公告)号：US08013173B2
公开(公告)日：2011-09-06
申请号：US12058344
申请日：2008-03-28
申请人： Beatriz Penalver Bernabe , Vijay Gopalakrishnan , Lioba Maria Kloppenburg , Matt Kuhlman , Roy Ray Odle , Eric Pressman , Narayan Ramesh , Harpreet Singh
发明人： Beatriz Penalver Bernabe , Vijay Gopalakrishnan , Lioba Maria Kloppenburg , Matt Kuhlman , Roy Ray Odle , Eric Pressman , Narayan Ramesh , Harpreet Singh
IPC分类号： C07D493/00
CPC分类号： C07D307/89 , C08G73/1053
摘要： A method for purifying an oxydiphthalic anhydride comprises diluting a first mixture comprising an oxydiphthalic anhydride, a solvent, a catalyst, and an inorganic salt with a solvent, to provide a second mixture having a solids content of 10 to 30 percent based on total weight of the second mixture; filtering and washing the solids of the second mixture at a temperature below the crystallization point temperature of the oxydiphthalic anhydride to provide a third mixture; hydrolyzing the third mixture by adding water and a water-soluble acid to form a fourth mixture; heating the fourth mixture; then cooling to provide a solid-liquid mixture, optionally decanting a portion of the liquid, rediluting the remaining solid-liquid mixture, then filtering to provide a solid component; washing the solid component with water to provide a fifth mixture of oxydiphthalic tetraacid and water; ring closing the oxydiphthalic tetraacid to provide oxydiphthalic anhydride, and filtering the oxydiphthalic anhydride.
摘要翻译：一种氧联二邻苯二甲酸酐的纯化方法包括用溶剂将包含氧联二邻苯二甲酸酐，溶剂，催化剂和无机盐的第一混合物稀释，得到固体含量为10-30重量％第二混合物; 在低于氧联二邻苯二甲酸酐的结晶点温度的温度下过滤和洗涤第二混合物的固体以提供第三混合物; 通过加入水和水溶性酸来水解第三混合物以形成第四混合物; 加热第四混合物; 然后冷却以提供固液混合物，任选地倾析一部分液体，重新稀释剩余的固液混合物，然后过滤以提供固体组分; 用水洗涤固体组分以提供氧联二邻苯四酸和水的第五混合物; 闭环氧二邻苯四酸以提供氧联二邻苯二甲酸酐，并过氧化邻苯二甲酸酐。

3. 发明授权

US09454283B1 Three-dimensional visualization 有权
标题翻译：三维可视化
公开(公告)号：US09454283B1
公开(公告)日：2016-09-27
申请号：US12137130
申请日：2008-06-11
申请人： Jay Ryan Torgerson , Simon Greenwold , Claudia Wey , Eric Pressman , Matthew Englehart
发明人： Jay Ryan Torgerson , Simon Greenwold , Claudia Wey , Eric Pressman , Matthew Englehart
IPC分类号： G06F3/0481
CPC分类号： G06F3/04815 , G06F3/04817 , G06F17/50 , G06T11/60 , G06T19/00
摘要： In an embodiment, a mechanism for visualizing a graphical model in three dimensions is discussed. An executable graphical model is obtained that includes a hierarchy of model levels that include a top level. The hierarchy includes multiple components. A three-dimensional (3D) view of the graphical model is displayed that provides views of a first and second component at a first and second depth. A graphical indicator is generated in the view of the top level of the graphical model that is associated with the first component and also generated in the view of the second component. A control alters a user perspective of a view that includes at least one of the components in the graphical model.
摘要翻译：在一个实施例中，讨论了用于在三维中可视化图形模型的机构。获得可执行图形模型，其包括包括顶级的模型级别的层次结构。层次结构包括多个组件。显示图形模型的三维（3D）视图，其在第一和第二深度处提供第一和第二组件的视图。在与第一组件相关联并且在第二组件的视图中生成的图形模型的顶级视图中生成图形指示符。控件改变视图的用户透视图，该视图包括图形模型中的至少一个组件。

4. 发明授权

US07674920B2 Methods for preparing oxydiphthalic anhydrides, oxydiphthalic anhydrides prepared thereby, and polyetherimides derived therefrom 有权
标题翻译：制备氧联二邻苯二甲酸酐的方法，由此制备的氧联二邻苯二甲酸酐和由其衍生的聚醚酰亚胺
公开(公告)号：US07674920B2
公开(公告)日：2010-03-09
申请号：US12058331
申请日：2008-03-28
申请人： Beatriz Penalver Bernabe , Lioba Maria Kloppenburg , Matt Kuhlman , Roy Ray Odle , Eric Pressman , Narayan Ramesh , Harpreet Singh
发明人： Beatriz Penalver Bernabe , Lioba Maria Kloppenburg , Matt Kuhlman , Roy Ray Odle , Eric Pressman , Narayan Ramesh , Harpreet Singh
IPC分类号： C07D307/89
CPC分类号： C07D307/88 , C07D307/89 , C08G73/1046
摘要： A method for preparing an oxydiphthalic anhydride comprises contacting, under reactive and substantially anhydrous conditions in a reactor, at least one halophthalic anhydride containing more than 250 ppm chlorophthalide impurity with a carbonate of the formula M2CO3, wherein M is an alkali metal, in the presence of a catalytic proportion of at least one phase transfer catalyst selected from the group consisting of hexaalkylguanidinium halides and alpha,omega-bis(pentaalkylguanidinium)alkane salts, phosphonium salts, phosphazenium salts, pyridinium salts, phosphazenium salts, ammonium salts, and combinations thereof. The phase transfer catalyst is present in a sufficient amount to prepare the oxydiphthalic anhydride when the chlorophthalide is present in an amount that is more than 250 ppm, and the oxydiphthalic anhydride is produced in a yield, based on the carbonate, of at least 70%.
摘要翻译：一种制备氧联二邻苯二甲酸酐的方法包括在反应器和反应性基本上无水的条件下，在反应器中使至少一种含有多于250ppm氯酞酸盐杂质的卤代邻苯二甲酸酐与式M2CO3的碳酸酯（其中M为碱金属）在存在下选自六烷基卤化镓和α，ω-双（五烷基胍）烷烃盐，鏻盐，磷氮烯基鏻盐，吡啶鎓盐，磷氮烯基鏻盐，铵盐及其组合的至少一种相转移催化剂的催化剂比例。当氯代苯酞以250ppm以上的量存在时，相转移催化剂的存在量足以制备氧联二邻苯二甲酸酐，并且基于碳酸酯的产率以氧化邻苯二甲酸酐的产率为至少70％。

5. 发明申请

US20050075519A1 Process for the recovery of dihydroxybiaryl compounds 有权
标题翻译：二羟基联芳基化合物的回收方法
公开(公告)号：US20050075519A1
公开(公告)日：2005-04-07
申请号：US10680776
申请日：2003-10-07
申请人： John Ofori , Ben Patel , Eric Pressman
发明人： John Ofori , Ben Patel , Eric Pressman
IPC分类号： C07C37/00 , C07C37/055 , C07C37/18 , C07C37/84 , C07C29/10
CPC分类号： C07C37/84 , C07C37/055 , C07C37/18 , C07C37/64 , C07C39/235 , C07C39/15
摘要： A method for preparing and isolating dihydroxybiaryl compounds, such as 4,4′-dihydroxybiphenyl, is disclosed. The alkali metal salt of the dihydroxybiaryl compound is protonated with the monohydroxyaryl halide compound initially used in the reductive coupling reaction which produced the alkali metal salt. In addition, the alkali metal salt of the monohydroxyaryl halide compound is produced by the process, which can then be recycled as the base and monohydroxyaryl halide in a further reductive coupling reaction to form the alkali metal salt of the dihydroxybiaryl compound.
摘要翻译：公开了一种制备和分离二羟基联芳基化合物如4,4'-二羟基联苯的方法。二羟基联芳基化合物的碱金属盐用最初用于生成碱金属盐的还原偶联反应中的单羟基芳基卤化合物进行质子化。此外，单羟基芳基卤化合物的碱金属盐通过该方法制备，然后可以将其作为碱和单羟基芳基卤化物在进一步还原偶联反应中再循环以形成二羟基联芳基化合物的碱金属盐。

6. 发明申请

US20050059843A1 Method for preparation of para-brominated hydroxyaromatic compounds 失效
标题翻译：对溴代羟基芳族化合物的制备方法
公开(公告)号：US20050059843A1
公开(公告)日：2005-03-17
申请号：US10664093
申请日：2003-09-17
申请人： Eric Pressman , Jonathan Male , Ryan Mills , John Ofori
发明人： Eric Pressman , Jonathan Male , Ryan Mills , John Ofori
IPC分类号： B01J31/40 , B01J38/48 , C07C37/00 , C07C37/62 , C07C37/68 , C07C39/24 , C07C39/34
CPC分类号： B01J31/2234 , B01J23/72 , B01J27/122 , B01J31/28 , B01J31/34 , B01J31/4015 , B01J31/403 , B01J38/48 , B01J2231/4277 , B01J2231/52 , B01J2531/16 , B01J2531/46 , B01J2531/56 , C07C37/00 , C07C37/62 , C07C37/68 , C07C37/72 , Y02P20/582 , Y02P20/584 , C07C39/27
摘要： A method for preparing hydroxyaromatic compounds brominated in the para-position, such as p-bromophenol, is disclosed. The method yields overall high process selectivity through isomeric equilibration and separation of the brominated products, thereby eliminating the need for high para selectivity in the products of catalytic oxybromination reactions of hydroxyaromatic compounds using oxygen, a bromine source, and an acidic medium in the presence of a metal catalyst. Furthermore, the invention provides an efficient method for recycling the metal catalyst, as well as reagents used in the bromination, to further reactions.
摘要翻译：公开了一种制备在对位溴化的羟基芳族化合物的方法，例如对溴苯酚。该方法通过异构平衡和溴化产物的分离产生总体高的工艺选择性，从而消除了在存在有氧，溴源和酸性介质的情况下，使用氧，芳族化合物和酸性介质的羟基芳族化合物的催化氧溴化反应的产物中对高选择性的需要金属催化剂。此外，本发明提供了将金属催化剂以及用于溴化的试剂再循环到进一步反应的有效方法。

7. 发明授权

US4728675A Modified flame retardant polyphenylene ether resins having improved foamability and molded articles made therefrom 失效
公开(公告)号：US4728675A
公开(公告)日：1988-03-01
申请号：US62891
申请日：1987-06-16
申请人： Eric Pressman
发明人： Eric Pressman
IPC分类号： C08J9/08
CPC分类号： C08J9/08 , C08J2371/12 , Y10S521/907 , Y10S521/908 , Y10S521/909
摘要： Polyphenylene ether compositions rendered flame retardant with bromine-containing compounds can be foam molded into shaped articles free of streaking and without the generation of odors if the foaming agent comprises citric acid and sodium bicarbonate.

8. 发明授权

US08019579B1 Graphical user interface for viewing or editing an executable block diagram model 有权
标题翻译：用于查看或编辑可执行框图模型的图形用户界面
公开(公告)号：US08019579B1
公开(公告)日：2011-09-13
申请号：US11974740
申请日：2007-10-16
申请人： Claudia Wey , John Ciolfi , Len Conte , Eric Pressman , Pieter J. Mosterman , Jay Ryan Torgerson , Murali Yeddanapudi
发明人： Claudia Wey , John Ciolfi , Len Conte , Eric Pressman , Pieter J. Mosterman , Jay Ryan Torgerson , Murali Yeddanapudi
IPC分类号： G06G7/48
CPC分类号： G06F8/10 , G06F9/451
摘要： In one embodiment, a method for displaying elements of an attribute in an executable block diagram model is provided. The method may include displaying an executable block diagram model in a first window and receiving a first input from an input device, wherein the first input associates with a first parameter of a block diagram modeling component in the executable block diagram model, the first parameter is represented in the executable block diagram model by a first graphical affordances. The method may include triggering the display of a value of a first parameter in a first user interface widget in the first window.
摘要翻译：在一个实施例中，提供了一种用于在可执行框图模型中显示属性的元素的方法。该方法可以包括在第一窗口中显示可执行框图模型并从输入设备接收第一输入，其中第一输入与可执行框图模型中的框图建模组件的第一参数相关联，第一参数是在可执行框图模型中通过第一图形提供来表示。该方法可以包括在第一窗口中触发在第一用户界面小部件中显示第一参数的值。

9. 发明申请

US20070117990A1 Method of purifying dianhydrides 有权
标题翻译：二酸酐的纯化方法
公开(公告)号：US20070117990A1
公开(公告)日：2007-05-24
申请号：US11286190
申请日：2005-11-22
申请人： Eric Pressman , Albert Stella , Beatriz Bernabe , Lioba Kloppenburg , Lee Bergman
发明人： Eric Pressman , Albert Stella , Beatriz Bernabe , Lioba Kloppenburg , Lee Bergman
IPC分类号： C07D405/02
CPC分类号： C07D307/89
摘要： Disclosed herein is a method for purification of dianhydrides comprising a substantial amount (10000 ppm or more) of at least one metal salt. In one aspect the method is useful for the purification of dianhydrides prepared by the reaction of a halophthalic anhydride with a metal carbonate and may be optionally catalyzed by a phase transfer catalyst. The purification of the dianhydrides may be accomplished by hydrolyzing the dianhydride metal salt mixture directly to a tetraacid with an inorganic acid, followed by separating the impurities from an aqueous phase, and subsequently heating the tetraacid to effect ring closure to form a purified dianhydride having less than 50 parts per million metal halide and lower levels of other residual impurities. In one aspect the method is highly effective in removing phase transfer catalyst impurities such as hexalkylguanidinium halides initially present in the dianhydride undergoing purification.
摘要翻译：本文公开了包含大量（10000ppm或更多）至少一种金属盐的二酸酐的纯化方法。在一个方面，该方法可用于纯化通过卤代邻苯二甲酸酐与金属碳酸盐的反应制备的二酐，并且可任选地通过相转移催化剂催化。二酸酐的纯化可以通过用无机酸将二酐金属盐混合物直接水解成四元酸，然后从水相中分离出杂质，随后加热四酸以实现闭环以形成具有较少量的纯化二酐超过50ppm的金属卤化物和较低水平的其他残留杂质。在一个方面，该方法在除去最初存在于经过纯化的二酐中的相转移催化剂杂质如六烷基卤化镓中是非常有效的。

10. 发明授权

US4791145A Modified flame retardant polyphenylene ether resins having improved foamability and molded articles made therefrom 失效
标题翻译：具有改进的发泡性的改性阻燃聚苯醚树脂和由其制成的模塑制品
公开(公告)号：US4791145A
公开(公告)日：1988-12-13
申请号：US162696
申请日：1988-03-01
申请人： Eric Pressman
发明人： Eric Pressman
IPC分类号： C08J9/08
CPC分类号： C08J9/08 , C08J2371/02
摘要： Polyphenylene ether compositions rendered flame retardant with bromine-containing compounds can be foam molded into shaped articles free of streaking and without the generation of odors if the foaming agent comprises citric acid and sodium bicarbonate.
摘要翻译：使用含溴化合物阻燃的聚苯醚组合物可以发泡成型为不含条纹的成型制品，如果发泡剂包含柠檬酸和碳酸氢钠，则不产生气味。

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