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1. 发明授权

US07652116B2 Fluorochemical urethane-silane compounds and aqueous compositions thereof 有权
标题翻译：含氟化学氨基甲酸酯 - 硅烷化合物及其含水组合物
公开(公告)号：US07652116B2
公开(公告)日：2010-01-26
申请号：US11765914
申请日：2007-06-20
申请人： Gregory D. Clark , Patrick J. Hager , Jay S. Schlechte , John C. Clark
发明人： Gregory D. Clark , Patrick J. Hager , Jay S. Schlechte , John C. Clark
IPC分类号： C08G77/04
CPC分类号： C08G18/3825 , C07F7/1804 , C08G18/0823 , C08G18/671 , C08G18/792 , C08G18/837 , C09D175/04
摘要： Fluorochemical urethane compounds and coating compositions derived therefrom are described. The compounds and composition may be used in treating substrates, in particular substrates having a hard surfaces such as ceramics or glass, to render them hydrophilic, oleophobic and easy to clean.
摘要翻译：描述了衍生自其的氟化学氨基甲酸酯化合物和涂料组合物。化合物和组合物可用于处理基材，特别是具有硬表面如陶瓷或玻璃的基材，使其具有亲水性，疏油性并且易于清洁。

2. 发明申请

US20080319153A1 FLUOROCHEMICAL URETHANE COMPOUNDS AND AQUEOUS COMPOSITIONS THEREOF 有权
标题翻译：氟化脲类化合物及其水性组合物
公开(公告)号：US20080319153A1
公开(公告)日：2008-12-25
申请号：US11765938
申请日：2007-06-20
申请人： Gregory D. Clark , Patrick J. Hager , Jay S. Schlechte , John C. Clark
发明人： Gregory D. Clark , Patrick J. Hager , Jay S. Schlechte , John C. Clark
IPC分类号： C08G77/26 , C08G77/04
CPC分类号： C08G18/2885 , C07F7/1804 , C08G18/283 , C08G18/6715 , C08G18/792 , C08G18/837 , C09D175/04
摘要： Fluorochemical urethane compounds and coating compositions derived therefrom are described. The compounds and composition may be used in treating substrates, in particular substrates having a hard surfaces such as ceramics or glass, to render them hydrophilic, oleophobic and easy to clean.
摘要翻译：描述了衍生自其的氟化学氨基甲酸酯化合物和涂料组合物。化合物和组合物可用于处理基材，特别是具有硬表面如陶瓷或玻璃的基材，使其具有亲水性，疏油性并且易于清洁。

3. 发明授权

US07652117B2 Fluorochemical urethane compounds and aqueous compositions thereof 有权
标题翻译：氟化学氨基甲酸酯化合物及其含水组合物
公开(公告)号：US07652117B2
公开(公告)日：2010-01-26
申请号：US11765938
申请日：2007-06-20
申请人： Gregory D. Clark , Patrick J. Hager , Jay S. Schlechte , John C. Clark
发明人： Gregory D. Clark , Patrick J. Hager , Jay S. Schlechte , John C. Clark
IPC分类号： C08G77/04
CPC分类号： C08G18/2885 , C07F7/1804 , C08G18/283 , C08G18/6715 , C08G18/792 , C08G18/837 , C09D175/04
摘要： Fluorochemical urethane compounds and coating compositions derived therefrom are described. The compounds and composition may be used in treating substrates, in particular substrates having a hard surfaces such as ceramics or glass, to render them hydrophilic, oleophobic and easy to clean.
摘要翻译：描述了衍生自其的氟化学氨基甲酸酯化合物和涂料组合物。化合物和组合物可用于处理基材，特别是具有硬表面如陶瓷或玻璃的基材，使其具有亲水性，疏油性并且易于清洁。

4. 发明申请

US20080314287A1 FLUOROCHEMICAL URETHANE-SILANE COMPOUNDS AND AQUEOUS COMPOSITIONS THEREOF 有权
标题翻译：氟化脲 - 硅烷化合物及其水性组合物
公开(公告)号：US20080314287A1
公开(公告)日：2008-12-25
申请号：US11765914
申请日：2007-06-20
申请人： Gregory D. Clark , Patrick J. Hager , Jay S. Schlechte , John C. Clark
发明人： Gregory D. Clark , Patrick J. Hager , Jay S. Schlechte , John C. Clark
IPC分类号： C08G18/28
CPC分类号： C08G18/3825 , C07F7/1804 , C08G18/0823 , C08G18/671 , C08G18/792 , C08G18/837 , C09D175/04
摘要： Fluorochemical urethane compounds and coating compositions derived therefrom are described. The compounds and composition may be used in treating substrates, in particular substrates having a hard surfaces such as ceramics or glass, to render them hydrophilic, oleophobic and easy to clean.
摘要翻译：描述了衍生自其的氟化学氨基甲酸酯化合物和涂料组合物。化合物和组合物可用于处理基材，特别是具有硬表面如陶瓷或玻璃的基材，使其具有亲水性，疏油性并且易于清洁。

5. 发明授权

US09845216B2 Web conveyance method and apparatus using same 有权
公开(公告)号：US09845216B2
公开(公告)日：2017-12-19
申请号：US13498058
申请日：2010-09-24
申请人： Kevin B. Newhouse , Bruce E. Tait , John C. Clark
发明人： Kevin B. Newhouse , Bruce E. Tait , John C. Clark
IPC分类号： B65H27/00
CPC分类号： B65H27/00 , B65H2404/114 , B65H2701/1752
摘要： A method for conveying a web using an engagement cover (10) comprising resilient looped pile (16) engagement surface. Also, web conveying roller (12) having an engagement cover thereon.

6. 发明授权

US07851387B2 Fluoroacrylate-multifunctional acrylate copolymer compositions 有权
标题翻译：氟丙烯酸酯 - 多官能丙烯酸酯共聚物组合物
公开(公告)号：US07851387B2
公开(公告)日：2010-12-14
申请号：US12028589
申请日：2008-02-08
申请人： Zai-Ming Qiu , George G. I. Moore , John C. Clark , Ramesh C. Kumar
发明人： Zai-Ming Qiu , George G. I. Moore , John C. Clark , Ramesh C. Kumar
IPC分类号： B32B27/04
CPC分类号： C08F220/38 , Y10T428/3154 , Y10T442/2311 , Y10T442/232 , Y10T442/2754
摘要： A composition comprises a copolymer comprising repeating units derived from at least one co-reactant comprising two or more acrylate groups and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf═CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion; wherein the composition is coatable.
摘要翻译：组合物包含共聚物，其包含衍生自至少一种包含两个或更多个丙烯酸酯基团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，所述重复单元包含以下反应产物：（a）至少一种由式C4F9- X-OH其中：R =氢或1至4个碳原子的烷基，m = 2至8，Rf = C n F 2n + 1，n = 1至5，y = 0至6，q = 1至8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2-30个碳原子的2-氟丙烯酸酯单体; 其中所述组合物是可涂覆的。

7. 发明授权

US07411020B2 Water-based release coating containing fluorochemical 有权
标题翻译：含氟化合物的水性防粘涂层
公开(公告)号：US07411020B2
公开(公告)日：2008-08-12
申请号：US11027606
申请日：2004-12-28
申请人： James G. Carlson , John C. Clark , James P. DiZio , David J. Kinning , Ramesh C. Kumar , Chetan P. Jariwala
发明人： James G. Carlson , John C. Clark , James P. DiZio , David J. Kinning , Ramesh C. Kumar , Chetan P. Jariwala
IPC分类号： C09D133/00 , B32B33/00
CPC分类号： C09D133/02 , Y10S525/902 , Y10T428/14
摘要： In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.
摘要翻译：一方面，本发明提供了一种水性防粘涂料组合物，其包含以下混合物：A.从0.1至约5wt％的氟（甲基）丙烯酸酯（共）聚合物或含有至少一个氟化基团的含氟氨基甲酸酯化合物具有式 - （CF 2）n CF 3，其中n为1至3的整数; B.约5至约99.9重量％的包含a的反应产物的共聚物。约40至约70重量％的（甲基）丙烯酸烷基酯，其中烷基含有16至22个碳原子，b。约3至约20重量％的（甲基）丙烯酸，c。约20至约40重量％的丙烯腈，以及d。 0至约15重量％的乙烯基单体，除了丙烯腈，其中a。通过d。等于100％; 和C.0至约94.9重量％的增量聚合物，其中A.，B.和C.的总和为100％，wt％基于组合物中固体的总量。

8. 发明授权

US07291688B2 Fluoroacrylate-mercaptofunctional copolymers 有权
标题翻译：氟丙烯酸酯 - 巯基官能共聚物
公开(公告)号：US07291688B2
公开(公告)日：2007-11-06
申请号：US11027605
申请日：2004-12-28
申请人： Zai-Ming Qiu , John C. Clark , Ramesh C. Kumar
发明人： Zai-Ming Qiu , John C. Clark , Ramesh C. Kumar
IPC分类号： C08F12/20 , C08G75/04
CPC分类号： C08F220/38
摘要： A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译：共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，该重复单元包含以下反应产物：（a）至少一种由下式表示的含氟醇： -line-formula description =“In-line Formulas”end =“lead”？> C 3 -X-OH <？in-line-formula description = “直链式”末端=“尾”→其中：R =氢或1至4个碳原子的烷基，m = 2至8，R f = C n n = 1〜5，y = 0〜6，q = 1〜8; （b）至少一种非支化的对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。

9. 发明授权

US07199197B2 Water- and oil-repellent fluoroacrylates 有权
标题翻译：拒水拒油氟代丙烯酸酯
公开(公告)号：US07199197B2
公开(公告)日：2007-04-03
申请号：US11027604
申请日：2004-12-28
申请人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G. I. Moore , Zai-Ming Qiu , Richard B. Ross
发明人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G. I. Moore , Zai-Ming Qiu , Richard B. Ross
IPC分类号： C08F12/20
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译：氟丙烯酸酯包含反应产物

10. 发明授权

US07078454B2 Repellent fluorochemical compositions 失效
标题翻译：排斥含氟组成
公开(公告)号：US07078454B2
公开(公告)日：2006-07-18
申请号：US10124523
申请日：2002-04-17
申请人： Malcolm B. Burleigh , David P. Cheatham , John C. Clark , A. Dale Otteson
发明人： Malcolm B. Burleigh , David P. Cheatham , John C. Clark , A. Dale Otteson
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , B05D3/02 , B32B27/00
CPC分类号： C08F214/186 , C08G18/2885 , D06M15/27 , D06M15/277 , D06M15/576 , D06M2200/11 , D06M2200/12 , Y10T428/31551
摘要： This invention provides compositions for treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising a 1) fluorochemical urethane formed by reacting a tri- or higher order isocyanate with a fluorochemical monofunctional compound and optionally a non-fluorinated aliphatic monofunctional compound; and 2) a fluorochemical polymeric surfactant.The present invention also provides a method of treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising application of the aforementioned composition to a fibrous substrate with optionally one or more stainblocker compounds such as acrylic and methacrylic acid polymers and copolymers, sulfonated phenol-formaldehyde resins, and styrene-maleic anhydride polymers and copolymers, said application of the composition taking place either coincident with or following application of the hydrophilic anti-staining compound or compounds to the substrate. Fibrous substrates treated according to this method and fibrous substrates treated with the aforementioned compositions are also disclosed.
摘要翻译：本发明提供了用于处理纤维基材以使这些基材耐久地驱除水和油并且耐受干土的耐久性的组合物，其包含1）通过使三价或更高级异氰酸酯与含氟单官能化合物和任选的非官能化合物反应形成的含氟氨基甲酸酯，氟化脂肪族单官能化合物; 和2）含氟聚合物表面活性剂。本发明还提供了一种处理纤维基材以使这些基材耐久地驱除水和油并且耐久干燥的土壤的方法，其包括将上述组合物施用到纤维基材中，任选地包含一种或多种着色剂化合物如丙烯酸和甲基丙烯酸聚合物和共聚物，磺化酚醛树脂和苯乙烯 - 马来酸酐聚合物和共聚物，所述组合物的应用与亲水性抗染色化合物或化合物一起施加或者应用于底物。还公开了根据该方法处理的纤维基材和用上述组合物处理的纤维基材。

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