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1. 发明申请

US20070259970A1 Method for Dispersing and Passivating Particulate Powders in Water and Aqueous Media 审中-公开
标题翻译：在水和水介质中分散和钝化颗粒状粉末的方法
公开(公告)号：US20070259970A1
公开(公告)日：2007-11-08
申请号：US11568374
申请日：2005-04-13
申请人： Gottfried Boden , Sven Thiele , Manfred Nebelung
发明人： Gottfried Boden , Sven Thiele , Manfred Nebelung
IPC分类号： B01F17/00
CPC分类号： B01F17/005
摘要： The invention relates to a method for dispersing and passivating particulate powders in water and aqueous media. It is particularly advantageously applicable in the handling and processing of non-oxidic powders, e.g., in the ceramic and hard-metal industry. In the method claimed auxiliaries are added due to the process. According to the invention this method is characterized in that polyvinylamines and/or the initial products thereof are used as these auxiliaries.
摘要翻译：本发明涉及在水和水介质中分散和钝化颗粒粉末的方法。特别有利地适用于非氧化性粉末的处理和加工，例如在陶瓷和硬金属工业中。在所要求的方法中，由于该方法，添加了助剂。根据本发明，该方法的特征在于使用聚乙烯胺和/或其初始产物作为这些助剂。

2. 发明授权

US07445763B2 Coating powder of Cr or V doped titanium suboxides 失效
标题翻译：涂覆粉末的Cr或V掺杂的低价铬
公开(公告)号：US07445763B2
公开(公告)日：2008-11-04
申请号：US10469935
申请日：2002-03-04
申请人： Lutz-Michael Berger , Sven Thiele , Manfred Nebelung
发明人： Lutz-Michael Berger , Sven Thiele , Manfred Nebelung
IPC分类号： C23C4/10
CPC分类号： C23C4/11
摘要： A coating powder based on chemically modified titanium suboxides, for use in various coating techniques. Coatings produced from this powder are characterized by high electroconductivity, good solid lubricating properties and resistance to wear. For these reasons, there are numerous possibilities of use of components which were coated by suitable processes with this powder, especially as functional layers for fuel cells in electrochemical installations, in the new car industry, in mechanical engineering and in other economic activities. The coating powder based on titanium suboxides having a defined defect structure is characterized in that it is modified by at least one metallic alloying element and described by general formula: Tin-2Me2O2n-1.
摘要翻译：一种基于化学改性的低价氧化物的涂料粉末，用于各种涂料技术。由该粉末制成的涂层的特征在于高导电性，良好的固体润滑性能和耐磨性。由于这些原因，使用通过合适的方法涂覆这种粉末的组分的许多可能性，特别是作为电化学装置中的燃料电池，新型汽车工业，机械工程和其它经济活动中的功能层。具有确定的缺陷结构的基于低氧化钛的涂料粉末的特征在于其被至少一种金属合金元素改性并通过以下通式描述：Ti 2 n 2 Me 2 2n-2n-1。

3. 发明授权

US09683066B2 Modified polymer compositions 有权
公开(公告)号：US09683066B2
公开(公告)日：2017-06-20
申请号：US14385565
申请日：2012-03-20
申请人： Silvia Valenti , Evemarie Hamann , Norbert Jantsch , Sven Thiele
发明人： Silvia Valenti , Evemarie Hamann , Norbert Jantsch , Sven Thiele
IPC分类号： C08F236/10 , C08F36/06 , C08C19/25 , C08C19/44 , C08K5/548 , B60C1/00 , C08L47/00
CPC分类号： C08F236/10 , B60C1/0016 , B60C1/0025 , C08C19/25 , C08C19/44 , C08F36/06 , C08K5/548 , C08L47/00 , Y10T428/139 , C08F4/48
摘要： A process for the continuous preparation of modified elastomeric polymers includes (i) providing and polymerizing at least one conjugated diene monomer and, optionally, one or more aromatic vinyl monomer in the presence of an anionic initiator and a compound according to Formula 1, e.g. 2,2-di-(2-oxolanyl)propane or a derivative thereof, to provide a living anionic polymer; and (ii) adding a “sulfanylsilane” compound to the living anionic polymer. Elastomeric polymers obtainable according to the above process and compositions including the elastomeric polymer and, optionally, further constituents such as oil, filler and/or vulcanizing agent are described. A process for the preparation of a cross-linked elastomeric polymer that includes adding a vulcanizing agent to the elastomeric polymer, as well as articles and compositions that include the elastomeric polymer, the cross-linked elastomeric polymer or both are described.

4. 发明授权

US08921502B2 Modified polymer compositions 有权
标题翻译：改性聚合物组合物
公开(公告)号：US08921502B2
公开(公告)日：2014-12-30
申请号：US13517151
申请日：2010-12-20
申请人： Sven Thiele , Sascha Rulhoff , Susanne Knoll
发明人： Sven Thiele , Sascha Rulhoff , Susanne Knoll
IPC分类号： C08F36/04 , C08C19/44 , C08F236/14 , C08F4/48 , C08L9/00 , C08L9/06 , C08F136/14 , B60C1/00
CPC分类号： C08F236/14 , B60C1/00 , C08C19/44 , C08F4/48 , C08F36/04 , C08F136/14 , C08L9/00 , C08L9/06 , C08L2205/02 , C08L2314/00 , Y10T428/139
摘要： The invention provides a first composition comprising at least the following: i) a modified polymer comprising at least one branched modified polymer macromolecule (b1) and at least one linear modified polymer macromolecule (a1), and wherein the at least one branched modified polymer macromolecule and the at least one linear modified polymer macromolecule each, independently, comprises at least one amine group selected from the group consisting of formulas (1A-1F), each as described above: and combinations thereof; and wherein the at least one branched modified polymer macromolecule further comprises one of the structures (ib1-ib4) as described above, and the at least one linear modified polymer macromolecule further comprises one of the structures (iib1) as described above (see Formula 3A).
摘要翻译：本发明提供了至少包含以下的第一组合物：i）包含至少一种支化改性聚合物高分子（b1）和至少一种线性改性聚合物高分子（a1）的改性聚合物，其中所述至少一种支化改性聚合物高分子并且所述至少一种线性改性聚合物高分子各自独立地包含至少一种选自如上所述的式（1A-1F）的胺基团及其组合; 并且其中所述至少一种支化改性聚合物高分子还包含如上所述的结构（ib1-ib4）之一，并且所述至少一种线性改性聚合物高分子还包含如上所述的结构（iib1）之一（参见式3A ）。

5. 发明授权

US08895684B2 Modified polymer compositions 有权
标题翻译：改性聚合物组合物
公开(公告)号：US08895684B2
公开(公告)日：2014-11-25
申请号：US13517144
申请日：2010-12-20
申请人： Sven Thiele , Sascha Rulhoff
发明人： Sven Thiele , Sascha Rulhoff
IPC分类号： C08F36/06 , C08F236/10 , B60C1/00 , C08C19/44 , C08F36/04 , C08L15/00 , C08K5/548 , C08K3/36 , C08L9/00
CPC分类号： C08C19/44 , B60C1/00 , C08F36/04 , C08F236/10 , C08K3/36 , C08K5/548 , C08L9/00 , C08L15/00 , Y02T10/862 , C08F4/48 , C08L2666/08
摘要： The invention provides a first composition comprising at least the following: i) a modified polymer comprising at least one branched modified polymer macromolecule (b1) and at least one linear modified polymer macromolecule (a1), and wherein the at least one branched modified polymer macromolecule and the at least one linear modified polymer macromolecule each, independently, comprises at least one amine group selected from the group consisting of formulas (1A-1F), each as described above Formula 1A, Formula 1B, Formula 1C, Formula 1D, Formula 1E, Formula 1F, and combinations thereof; and wherein the at least one branched modified polymer macromolecule further comprises one of the structures (ib1-ib4) as described above, and the at least one linear modified polymer macromolecule further comprises one of the structures (iib1-iib2) as described above.
摘要翻译：本发明提供了至少包含以下的第一组合物：i）包含至少一种支化改性聚合物高分子（b1）和至少一种线性改性聚合物高分子（a1）的改性聚合物，其中所述至少一种支化改性聚合物高分子并且所述至少一种线性改性聚合物高分子各自独立地包含至少一种选自式（1A-1F）的胺基，其各自如上述式1A，式1B，式1C，式1D，式1E ，式1F及其组合; 并且其中所述至少一种支化改性聚合物高分子还包含如上所述的结构之一（ib1-ib4），并且所述至少一种线性改性聚合物高分子还包含如上所述的结构之一（iib1-iib2）。

6. 发明申请

US20120252952A1 Vulcanized Elastomeric Compositions 有权
标题翻译：硫化弹性组合物
公开(公告)号：US20120252952A1
公开(公告)日：2012-10-04
申请号：US13493428
申请日：2012-06-11
申请人： Sven Thiele , Joachim Kiesekamp , Norbert Jantsch , Thomas Knispel
发明人： Sven Thiele , Joachim Kiesekamp , Norbert Jantsch , Thomas Knispel
IPC分类号： C08L47/00 , C08K3/34 , C08K3/26
CPC分类号： C08C19/44 , B60C1/0016 , C08F8/42 , C08K3/013 , C08K5/01 , C08L15/00
摘要： A vulcanized elastomeric composition includes (i) a polymer reaction product of an anionic elastomeric polymer and a silane-sulfide modifier and (ii) a second elastomeric polymer different from the polymer reaction product such that the polymer reaction product comprises at least 30 weight percent of a total amount of the polymer reaction product and the second elastomeric polymer. Methods are described for making the polymer reaction product, their use in preparing vulcanized elastomeric compositions, and articles made from such compositions, including pneumatic tires, tire treads, belts, and the like.
摘要翻译：硫化弹性体组合物包括（i）阴离子弹性体聚合物和硅烷硫化物改性剂的聚合物反应产物和（ii）不同于聚合物反应产物的第二弹性体聚合物，使得聚合物反应产物包含至少30重量％聚合物反应产物和第二弹性体聚合物的总量。描述了制备聚合物反应产物的方法，它们在制备硫化弹性体组合物中的用途以及由这种组合物制成的制品，包括充气轮胎，轮胎胎面，皮带等。

7. 发明申请

US20110082253A1 MODIFIED ELASTOMERIC POLYMERS 有权
标题翻译：改性弹性体聚合物
公开(公告)号：US20110082253A1
公开(公告)日：2011-04-07
申请号：US12996200
申请日：2009-05-29
申请人： Sven Thiele , Evemarie Hamann , Joachim Kiesekamp
发明人： Sven Thiele , Evemarie Hamann , Joachim Kiesekamp
IPC分类号： C08L9/00 , C08F236/10 , C08F136/06 , C08F236/08 , C08F136/08
CPC分类号： C08C19/44 , Y02T10/862
摘要： The invention provides a elastomeric polymer composition comprising the reaction product of at least the following: i) a living anionic elastomeric polymer; ii) a silane modifier compound represented by the Formula I or Formula 2: (RIO)3Si—R4—S—SiR33, Formula 1 (R13O)3Si—R9-N(SiR10R11R12 Formula 2 iii) a modifier compound represented by one of the following Formulas 3 to 6: (R1O)x(R2)ySi—R4—S—SiR33, Formula 3 (R13O)P(R14)qSi—R9—N(SiR10R11R12)2 Formula 4, Formule 5, Formule 6
摘要翻译：本发明提供了包含至少以下物质的反应产物的弹性体聚合物组合物：i）活性阴离子弹性体聚合物; ii）由式I或式2表示的硅烷改性剂化合物：（RIO）3 Si-R 4 -S-SiR 33，式1（R 13 O）3 Si-R 9 -N（SiR 10 R 11 R 12式2 iii）按照公式3至6：（R 1 O）x（R 2）y Si-R 4 -S-SiR 33，式3（R 13 O）P（R 14）q Si-R 9 -N（SiR 10 R 11 R 12）2式4，式5，

8. 发明申请

US20050090383A1 Metal complex compositions and their use as catalysts to produce polydienes 审中-公开
标题翻译：金属络合物组合物及其作为制备聚二烯的催化剂的用途
公开(公告)号：US20050090383A1
公开(公告)日：2005-04-28
申请号：US10489370
申请日：2002-10-07
申请人： Sven Thiele , Victor Monroy , Hartmut Stoye , David Wilson
发明人： Sven Thiele , Victor Monroy , Hartmut Stoye , David Wilson
IPC分类号： C08F36/00 , B01J31/00 , C08F4/02 , C08F4/54 , C08F4/60 , C08F4/605 , C08F36/04
CPC分类号： C08F36/04 , C08F4/545
摘要： This invention relates to metal complex compositions, their preparation and their use as catalysts to produce polymers of conjugate dienes through polymerization of conjugated diene monomers. The used metal complex compositions are transition metal compounds in combination with an activator compound, optionally with a transition metal halide compound and optionally a catalyst modifier and optionally an inorganic or organic support material. The metal complexes comprises metals of group 3 to 10 of the Periodic System of the Elements in combination with activators, and optionally transition metal halide compounds of groups 3 to 10 of the Periodic Table of the Elements including lanthanide metals and actinide metals and optionally, catalyst modifiers, especially Lewis acids and optionally an inorganic or organic support material. More in particular the invention relates metal complex compositions, their preparation and their use as catalysts to produce homopolymers of conjugated dienes, preferably, but not limited to, through polymerization of 1,3-butadiene or isoprene.
摘要翻译：本发明涉及金属络合物组合物及其制备及其作为通过共轭二烯单体聚合生成共轭二烯聚合物的催化剂的用途。所使用的金属络合物组合物是与活化剂化合物，任选地与过渡金属卤化物化合物和任选的催化剂改性剂和任选的无机或有机载体材料组合的过渡金属化合物。金属络合物包括与活化剂组合的元素周期系统3至10族的金属，以及任选的元素周期表第3至10族的过渡金属卤化物化合物，包括镧系金属和锕系金属以及任选的催化剂改性剂，尤其是路易斯酸和任选的无机或有机载体材料。更具体地，本发明涉及金属络合物组合物及其制备及其用作催化剂以制备共轭二烯的均聚物，优选但不限于通过1,3-丁二烯或异戊二烯的聚合。

9. 发明授权

US09822195B2 Process for producing diene polymers 有权
公开(公告)号：US09822195B2
公开(公告)日：2017-11-21
申请号：US14376723
申请日：2012-02-29
申请人： Thomas D. Ruehmer , Sven Thiele , Anke Schmudde , Dieter Bellgardt
发明人： Thomas D. Ruehmer , Sven Thiele , Anke Schmudde , Dieter Bellgardt
IPC分类号： C08F36/06 , C08L9/00 , B60C1/00 , C08C19/44 , C08K3/04 , C08L9/06 , C08L15/00
CPC分类号： C08F36/06 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08K3/04 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L15/00
摘要： The invention describes a process for producing a diene polymer, the process comprising the following steps in this order: i) polymerizing one or more diene monomers in the presence of a catalyst composition to give a reaction mixture; ii) adding to the reaction mixture one or more alkoxysilane compounds; iii) adding S2Cl2, SCl2, SOCl2, S2Br2, SOBr2 or a mixture thereof to the reaction mixture; and iv) optionally adding a protic agent to the reaction mixture so as to deactivate the catalyst. The invention further includes polymers that are obtainable according to this process, as well as products including the polymer.

10. 发明授权

US08952100B2 Process to remove silanol from the preparation of a modified polymer 有权
标题翻译：从改性聚合物的制备中除去硅烷醇的方法
公开(公告)号：US08952100B2
公开(公告)日：2015-02-10
申请号：US13128512
申请日：2009-11-11
申请人： Sven Thiele , Jochen Boehm , Norbert Jantsch , Christiane Berndt
发明人： Sven Thiele , Jochen Boehm , Norbert Jantsch , Christiane Berndt
IPC分类号： C08F2/06 , C08F8/42 , C08F136/04 , C08C2/02 , C08C19/44
CPC分类号： C08C2/02 , C08C19/44
摘要： The invention provides a method for a preparation of a polymer selected from the following: (a) modified interpolymer comprising, in polymerized form, a conjugated diene and an aromatic alpha-olefin, or (b) a modified polymer comprising, in polymerized form, a conjugated diene; and wherein said method comprising at least the following steps: polymerizing monomers comprising at least one conjugated diene monomer in at least one polymerization reactor, in the presence of at least one solvent, to form the polymer, optionally coupling a fraction of the polymer chains using at least one coupling agent, modifying the polymer with at least one modifying agent, in at least one reactor, in the presence of the at least one solvent, to form a modified polymer solution; optionally, contacting the modified polymer solution with at least one proton donating compound; contacting the modified polymer solution with water; removing the at least one solvent; contacting the removed solvent with at least one material that will react with, and/or adsorb, silanol to form a purified solvent, recirculating the purified solvent back to the at least one polymerization reactor or to a storage container.
摘要翻译：本发明提供了一种选自以下的聚合物的制备方法：（a）以聚合形式包含共轭二烯和芳族α-烯烃的改性互聚物，或（b）以聚合形式包含的改性聚合物，共轭二烯并且其中所述方法至少包括以下步骤：在至少一种聚合反应器中，在至少一种溶剂的存在下聚合包含至少一种共轭二烯单体的单体以形成聚合物，任选地使用至少一种偶联剂，在至少一种反应器中，在至少一种溶剂的存在下，用至少一种改性剂改性聚合物，以形成改性的聚合物溶液; 任选地，使改性聚合物溶液与至少一种质子供体化合物接触; 使改性聚合物溶液与水接触; 去除所述至少一种溶剂; 使所除去的溶剂与至少一种将与硅烷醇反应和/或吸附硅烷醇的材料形成纯化的溶剂，将纯化的溶剂再循环回至少一个聚合反应器或储存容器。

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