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    • 4. 发明授权
    • Low solvent content type-resin composition, coating composition
containing such resin composition and process for coating such coating
composition
    • 低溶剂含量型树脂组合物,含有这种树脂组合物的涂料组合物和涂覆这种涂料组合物的方法
    • US6040009A
    • 2000-03-21
    • US491736
    • 1995-06-19
    • Yoshiaki MarutaniTakashi TomitaTadamitsu NakahamaHiroyuki UemuraKazuhi KogaMika Ohsawa
    • Yoshiaki MarutaniTakashi TomitaTadamitsu NakahamaHiroyuki UemuraKazuhi KogaMika Ohsawa
    • B05D7/00C09D167/04C09B167/00C09B167/04
    • B05D7/532C09D167/04
    • The present invention is to provide a low solvent content type-coating composition by which the resultant coatings with good scuff resistance or water resistance as well as good chipping resistance are produced, while the content of an organic solvent to be used can be much reduced. The low solvent content type-coating composition comprises a polyester oligomer having a hydroxyl group in an amount of 2.0 to 10.0 moles/Kg-resin, a number average molecular weight (Mn) of 300 to 1500, a weight average molecular weight (Mw) of 300 to 3000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1 to 2.0, an amount of a modifying lactone being 31 to 85%, and an aliphatic hydrocarbon group of C4-22 which is not derived from lactones. The present invention is also to provide a process for coating a low solvent content type-coating composition on, for example, a base coating composition by a wet-on-wet coating. The base coating composition comprises a vinyl oligomer having a hydroxyl group and/or a blocked hydroxyl group, a melamine resin containing 50 to 100% of an imino type or methylol type mononucleus melamine and a weak acidic curing catalyst.
    • 本发明提供一种低溶剂含量型涂料组合物,通过该组合物可以产生具有良好耐擦伤性或耐水性的所得涂层以及良好的抗碎裂性,同时可以大大降低所用有机溶剂的含量。 低溶剂含量型涂料组合物包含羟基数为2.0〜10.0摩尔/ Kg-树脂的聚酯低聚物,数均分子量(Mn)为300〜1500,重均分子量(Mw) 的比例为300〜3000,重均分子量/数均分子量(Mw / Mn)为1〜2.0,改性内酯的量为31〜85%,C4- 22,它不是从内酯衍生的。 本发明还提供了通过湿式湿式涂布在例如底涂层组合物上涂布低溶剂含量型涂料组合物的方法。 基础涂料组合物包含具有羟基和/或封端羟基的乙烯基低聚物,含有50-100%亚氨基型或羟甲基型单核三聚氰胺的三聚氰胺树脂和弱酸性固化催化剂。
    • 9. 发明授权
    • Coating method
    • US5104682A
    • 1992-04-14
    • US390408
    • 1989-08-07
    • Tadamitsu NakahamaYoshio TanimotoTakakazu Yamane
    • Tadamitsu NakahamaYoshio TanimotoTakakazu Yamane
    • B05B13/02B05D1/00B05D3/02
    • B05D1/002B05B13/0221B05D3/0272B05B13/0452
    • A highly reflective surface coating on a substrate is formed by a coating method in a coating line. A paint is sprayed on the substrate in a viscosity of 18 seconds or lower when measured by means of Ford Cup #4 at 20.degree. C. in a film thickness thicker than a thickness at which the paint sags, the paint containing a solvent or solvents, having a boiling point as high as 110.degree. C. or lower in an amount of 50% by weight or higher.After completion of the spraying, a coat of the paint is dried by a drying step including sequential setting and baking steps. The substrate is held in an ambient temperature during the setting step which is lower than the ambient temperature during the baking step, and the rotation of the substrate in the drying step being carried out about its horizontal axis at a speed which is high enough to rotate the substrate from a vertical position to a horizontal position before the paint coated thereon substantially sags due to gravity yet which is low enough so as to cause no sagging as a result of centrifugal force, thereby allowing the coat formed thereon to achieve a substantially sagless state.This coating method prevents the paint from swelling on an edge portion of the substrate forming a mass, whereby a coat surface is provided with a high degree of flatness.
    • 10. 发明授权
    • Coating method
    • 涂布方法
    • US5009931A
    • 1991-04-23
    • US390546
    • 1989-08-08
    • Takakazu YamaneYoshio TanimotoTadamitsu Nakahama
    • Takakazu YamaneYoshio TanimotoTadamitsu Nakahama
    • B05B13/02B05D1/00B05D3/02
    • B05D1/002B05B13/0221B05D3/0272B05B13/0452
    • A highly reflective surface coating is formed by spraying a paint on a substrate as a vehicle body in a thickness thicker than a thickness at which the paint sags and rotating the substrate about its horizontal axis at a speed between a lower limit and an upper limit in order to cause no sagging until the paint sprayed is cured to a sagless state.Before the paint is sprayed in that thickness, an edge portion of the substrate is lowered than other portions thereof, thus preventing a mass of the paint from swelling on a top coat at its edge portion and providing a good appearance on the surface coating.The lowering of the edge portion thereof is effected by lowering the substrate itself without any coat or by spraying the edge portion in a film thickness thinner than the other portion thereof.The coat sprayed with a paint containing a volatilizable solvent may be dried through sequential setting and baking steps, while a powder paint sprayed may be baked without setting. The paint containing such a solvent may cause sagging in both the setting and baking steps or only in the setting step. The sagging is prevented by rotating the substrate during the time when the paint is sagging.
    • 高反射性表面涂层是通过将涂料喷涂在作为车体的基材上而形成的,所述涂料厚度比所述涂料凹陷的厚度厚,并且以基板的水平轴线的下限和上限之间的速度旋转基板 直到喷涂的油漆固化到无凹陷状态为止,才能产生下垂。 在涂料以该厚度喷涂之前,基材的边缘部分比其它部分下降,从而防止涂料在其边缘部分的顶涂层上膨胀,并在表面涂层上提供良好的外观。 其边缘部分的降低是通过降低基板本身而不用任何涂层或通过以比其它部分薄的薄膜厚度喷涂边缘部分来实现的。 用含有挥发性溶剂的涂料喷涂的涂层可以通过连续设置和烘烤步骤进行干燥,而喷涂的粉末涂料可以在不固化的情况下烘烤。 含有这种溶剂的涂料可能在设定和烘烤步骤中或仅在凝固步骤中下垂。 通过在油漆下垂时旋转基板来防止下垂。