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1. 发明授权

US4072585A Valve metal electrode with valve metal oxide semi-conductive coating having a chlorine discharge catalyst in said coating 失效
标题翻译：具有阀金属氧化物半导电涂层的阀金属电极，在所述涂层中具有氯排放催化剂
公开(公告)号：US4072585A
公开(公告)日：1978-02-07
申请号：US729688
申请日：1976-10-05
申请人： Giuseppe Bianchi , Vittorio DE Nora , Patrizio Gallone , Antonio Nidola
发明人： Giuseppe Bianchi , Vittorio DE Nora , Patrizio Gallone , Antonio Nidola
IPC分类号： C25B1/46 , C25B11/04 , C25B11/06 , C25B11/08 , C25B11/10
CPC分类号： C25B1/46 , C25B11/0484
摘要： Describes chlorine resistant metal electrodes, preferably of valve metals such as titanium and tantalum, having coatings of mixed metal oxides, preferably valve metal oxides, which have been doped to provide semi-conducting surfaces on the electrodes, which coatings also have the capacity to catalyze chlorine discharge from the electrodes and to resist corrosive conditions in a chlorine cell.
摘要翻译：描述耐氯金属电极，优选阀门金属如钛和钽，具有混合金属氧化物（优选阀金属氧化物）的涂层，这些金属氧化物已被掺杂以在电极上提供半导体表面，该涂层还具有催化能力氯气从电极排出并抵抗氯气池中的腐蚀性条件。

2. 发明授权

US4318795A Valve metal electrode with valve metal oxide semi-conductor face and methods of carrying out electrolysis reactions 失效
标题翻译：带阀门金属氧化物半导体表面的阀门金属电极和进行电解反应的方法
公开(公告)号：US4318795A
公开(公告)日：1982-03-09
申请号：US871407
申请日：1978-01-23
申请人： Giuseppe Bianchi , Vittorio de Nora , Patrizio Gallone , Antonio Nidola
发明人： Giuseppe Bianchi , Vittorio de Nora , Patrizio Gallone , Antonio Nidola
IPC分类号： C25B1/46 , C25B11/04 , C25B11/08 , C25B11/10
CPC分类号： C25B1/46 , C25B11/04 , C25B11/0478 , C25B11/0484
摘要： Describes chlorine resistant metal electrodes, preferably of valve metals such as titanium and tantalum, having coatings of mixed metal oxides, preferably valve metal oxides and platinum group metal oxides, which have been doped to provide semi-conducting surfaces on the electrodes, which coatings also have the capacity to catalyze chlorine discharge from the electrodes and to resist corrosive conditions in a chlorine cell and methods of electrolysis.
摘要翻译：描述耐氯金属电极，优选阀门金属如钛和钽，具有混合金属氧化物（优选阀金属氧化物和铂族金属氧化物）的涂层，这些金属氧化物已被掺杂以在电极上提供半导电表面，该涂层也具有催化从电极排出氯气并抵抗氯电池中的腐蚀条件和电解方法的能力。

3. 发明授权

US4003817A Valve metal electrode with valve metal oxide semi-conductive coating having a chlorine discharge in said coating 失效
标题翻译：具有阀金属氧化物半导电涂层的阀金属电极，在所述涂层中具有氯气排放
公开(公告)号：US4003817A
公开(公告)日：1977-01-18
申请号：US508232
申请日：1974-09-23
申请人： Giuseppe Bianchi , Vittorio DE Nora , Patrizio Gallone , Antonio Nidola
发明人： Giuseppe Bianchi , Vittorio DE Nora , Patrizio Gallone , Antonio Nidola
IPC分类号： C25B1/46 , C25B11/04 , C25B11/06 , C25B11/08 , C25B11/10
CPC分类号： C25B1/46 , C25B11/04 , C25B11/0478 , C25B11/0484
摘要： Describes chlorine resistant metal electrodes, preferably of valve metals such as titanium and tantalum, having coatings of mixed metal oxides, preferably valve metal oxides, which have been doped to provide semi-conducting surfaces on the electrodes, which coatings also have the capacity to catalyze chlorine discharge from the electrodes and to resist corrosive conditions in a chlorine cell.
摘要翻译：描述耐氯金属电极，优选阀门金属如钛和钽，具有混合金属氧化物（优选阀金属氧化物）的涂层，这些金属氧化物已被掺杂以在电极上提供半导体表面，该涂层还具有催化能力氯气从电极排出并抵抗氯气池中的腐蚀性条件。

4. 发明授权

US4070504A Method of producing a valve metal electrode with valve metal oxide semi-conductor face and methods of manufacture and use 失效
标题翻译：用金属氧化物半导体面制造阀门金属电极的方法及其制造和使用方法
公开(公告)号：US4070504A
公开(公告)日：1978-01-24
申请号：US635879
申请日：1975-11-28
申请人： Giuseppe Bianchi , Vittorio DE Nora , Patrizio Gallone , Antonio Nidola
发明人： Giuseppe Bianchi , Vittorio DE Nora , Patrizio Gallone , Antonio Nidola
IPC分类号： C25B1/46 , C25B11/04 , C25B11/10
CPC分类号： C25B11/04 , C25B1/46 , C25B11/0484
摘要： Describes chlorine resistant metal electrodes, preferably of valve metals such as titanium and tantalum, having coatings of mixed metal oxides, preferably valve metal oxides and platinum group metal oxides, which have been doped to provide semi-conducting surfaces on the electrodes, which coatings also have the capacity to catalyze chlorine discharge from the electrodes and to resist corrosive conditions in a chlorine cell and methods of their manufacture and use.
摘要翻译：描述耐氯金属电极，优选阀门金属如钛和钽，具有混合金属氧化物（优选阀金属氧化物和铂族金属氧化物）的涂层，这些金属氧化物已被掺杂以在电极上提供半导电表面，该涂层也具有催化从电极排出氯并抵抗氯气池中的腐蚀性的能力及其制造和使用方法的能力。

5. 发明授权

US3948751A Valve metal electrode with valve metal oxide semi-conductive face 失效
标题翻译：阀门金属电极带阀门金属氧化物半导电面
公开(公告)号：US3948751A
公开(公告)日：1976-04-06
申请号：US771665
申请日：1968-10-29
申请人： Giuseppe Bianchi , Vittorio De Nora , Patrizio Gallone , Antonio Nidola
发明人： Giuseppe Bianchi , Vittorio De Nora , Patrizio Gallone , Antonio Nidola
IPC分类号： C25B1/46 , C25B11/04 , C25B11/10
CPC分类号： C25B1/46 , C25B11/04 , C25B11/0484
摘要： Describes chlorine resistant metal electrodes, preferably of valve metals such as titanium and tantalum, having coatings of mixed metal oxides, preferably valve metal oxides, which have been doped to provide semi-conducting surfaces on the electrodes, which coatings also have the capacity to catalyze chlorine discharge from the electrodes and to resist corrosive conditions in a chlorine cell.

6. 发明授权

US4272354A Electrodes for electrolytic processes 失效
标题翻译：电解电极
公开(公告)号：US4272354A
公开(公告)日：1981-06-09
申请号：US97346
申请日：1979-11-26
申请人： Vittorio de Nora , Antonio Nidola , Placido M. Spaziante , Giuseppe Bianchi
发明人： Vittorio de Nora , Antonio Nidola , Placido M. Spaziante , Giuseppe Bianchi
IPC分类号： C25B1/34 , A61B1/227 , A61B1/233 , C25B1/46 , C25B9/10 , C25B11/04 , C25B11/06 , C25B11/10 , G01H9/00
CPC分类号： C25B11/0478 , C25B11/0484
摘要： Electrodes for electrolytic processes comprise an electrically-conductive and corrosion-resistant substrate, having a coating thereon which contains a solid solution of tin dioxide and bismuth trioxide, preferably in a ratio of 9:1 to 4:1 by weight of the respective metals. This solid solution may form the active coating or an intermediate layer covered with other electrocatalytic materials or may be included in a multi-component coating having selective properties for halogen evolution and oxygen inhibition.
摘要翻译：用于电解处理的电极包括导电和耐腐蚀的基底，其上具有包含二氧化锡和三氧化铋的固溶体的涂层，优选以相应金属的重量比为9:1至4:1。该固溶体可以形成活性涂层或用其它电催化材料覆盖的中间层，或者可以包含在具有卤素析出和氧抑制的选择性质的多组分涂层中。

7. 发明授权

US4267025A Electrodes for electrolytic processes, especially perchlorate production 失效
标题翻译：用于电解过程的电极，特别是高氯酸盐生产
公开(公告)号：US4267025A
公开(公告)日：1981-05-12
申请号：US97360
申请日：1979-11-26
申请人： Vittorio de Nora , Antonio Nidola , Placido M. Spaziante , Giuseppe Bianchi
发明人： Vittorio de Nora , Antonio Nidola , Placido M. Spaziante , Giuseppe Bianchi
IPC分类号： C25B1/28 , C25B11/04 , C25B11/08 , C25B1/26
CPC分类号： C25B1/28 , C25B11/0484
摘要： An electrode especially for the production of chlorates and perchlorates comprising an electrically-conductive corrosion-resistant substrate having an electrocatalytic coating which is preferably a mixture of 40 to 85 parts by weight of platinum, 0 to 20 parts by weight of palladium and 15 to 40 parts by weight (as tin metal) of tin dioxide.
摘要翻译：一种特别用于生产氯酸盐和高氯酸盐的电极，包括具有电催化涂层的导电耐腐蚀基底，其优选为40至85重量份的铂，0至20重量份的钯和15至40的混合物重量份（作为锡金属）二氧化锡。

8. 发明授权

US4056449A Electrowinning method 失效
标题翻译：电熨斗方法
公开(公告)号：US4056449A
公开(公告)日：1977-11-01
申请号：US616044
申请日：1975-09-23
申请人： Vittorio de Nora , Antonio Nidola , Giuseppe Bianchi
发明人： Vittorio de Nora , Antonio Nidola , Giuseppe Bianchi
IPC分类号： C25C1/00 , C25C1/06 , C25C1/08 , C25C1/10 , C25C7/00 , C25C7/06 , C25B1/04 , C25C1/12 , C25C1/16
CPC分类号： C25C1/00 , C25C7/06
摘要： In the method of electrowinning metals from acid aqueous solutions of the metals, the improvement comprising maintaining the anode surface at a temperature not greater than 40.degree. C to avoid deposits of manganese cobalt and iron dioxides and to improve anode life.

9. 发明授权

US4288302A Method for electrowinning metal 失效
标题翻译：电解冶金方法
公开(公告)号：US4288302A
公开(公告)日：1981-09-08
申请号：US763889
申请日：1977-01-31
申请人： Vittorio de Nora , Giuseppe Bianchi , Antonio Nidola
发明人： Vittorio de Nora , Giuseppe Bianchi , Antonio Nidola
IPC分类号： C25B11/08 , C25B11/04 , C25B11/10 , C25C7/02 , C25B1/02 , C25C1/00
CPC分类号： C25B11/0431 , C25C7/02
摘要： Novel dimensionally stable electrodes constituted by a film forming metallic material alloyed with at least one member of the group consisting of metal belonging to Groups VIB, VIIB, VIII, IIB, IB, IVA, lanthanum and lanthanide series of the Periodic Table, such as chromium, manganese, rhenium, iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, silver, gold, zinc, cadmium, silicon, germanium, tin, lead and lanthanum having an electroconductive and corrosion resistant surface preactivated on the surface thereof, preparation of said electrodes, use of said electrodes as anodes for electrolysis in aqueous and organic solutions or in fused salts as well as for cathodic protection and electrolysis methods using said electrodes.
摘要翻译：由与元素周期表中VIB族，VIIB族，VIII族，IIB族，IB族，IVA族，镧和镧系元素组成的组中的至少一种的至少一种成分合金成膜金属材料构成的新颖的尺寸稳定的电极，例如铬，具有导电和耐腐蚀表面预活化的锰，铼，铁，钌，锇，钴，铑，铱，镍，钯，铂，铜，银，金，锌，镉，硅，锗，锡，铅和镧在其表面上制备所述电极，使用所述电极作为阳极用于电解有机溶液或熔融盐，以及使用所述电极的阴极保护和电解方法。

10. 发明授权

US4037032A Electric storage battery with valve metal electrodes 失效
标题翻译：蓄电池带阀门金属电极
公开(公告)号：US4037032A
公开(公告)日：1977-07-19
申请号：US683544
申请日：1976-05-05
申请人： Antonio Nidola , Vittorio DE Nora , Placido M. Spaziante
发明人： Antonio Nidola , Vittorio DE Nora , Placido M. Spaziante
IPC分类号： H01M2/02 , H01M4/66 , H01M4/86 , H01M4/92 , H01M10/36 , H01M12/08 , H01M6/16
CPC分类号： H01M4/664 , H01M10/365 , H01M2/02 , H01M4/66 , H01M4/661
摘要： Electric storage batteries with titanium or other film forming metal anodes and cathodes are provided. The anodes are coated with mixed oxide coatings of a film forming metal oxide containing a platinum group metal oxide catalyst, which coatings may contain oxides of other metals to alter the breakdown voltage and increase the oxygen overpotential of the cathodes while preserving a low bromine and chlorine overpotential. The cathodes may be uncoated titanium or other film forming metals or film forming metals with a silver coating thereon. Bipolar film forming metal cathodes and anodes are provided carrying a mixed oxide coating on the cathodic face and either no coating or a silver coating on the anodic face. The invention is applicable to all types of electric storage batteries, either primary or secondary, and multiple batteries may be connected in series or in parallel to provide the desired amperage and voltage characteristics.
摘要翻译：提供具有钛或其它成膜金属阳极和阴极的蓄电池。阳极用含有铂族金属氧化物催化剂的成膜金属氧化物的混合氧化物涂层涂覆，该涂层可以含有其它金属的氧化物，以改变击穿电压并增加阴极的氧超电势，同时保持低溴和氯超电位阴极可以是未涂覆的钛或其它成膜金属或其上具有银涂层的成膜金属。提供双极成膜金属阴极和阳极，其在阴极表面上带有混合氧化物涂层，并且在阳极表面上没有涂层或银涂层。本发明适用于所有类型的主要或次要的蓄电池，并且多个电池可以串联或并联连接以提供所需的电流和电压特性。

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