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1. 发明授权

US06180720B2 Polyolefin mixture containing poly(1-butene) 有权
标题翻译：含聚（1-丁烯）的聚烯烃混合物
公开(公告)号：US06180720B2
公开(公告)日：2001-01-30
申请号：US09230682
申请日：1999-01-28
申请人： Gianni Collina , Anteo Pelliconi
发明人： Gianni Collina , Anteo Pelliconi
IPC分类号： C08F800
CPC分类号： C08L23/10 , C08L23/16 , C08L23/20 , C08L53/00 , C08L2207/02 , C08L2666/04
摘要： Thermoplastic and elastomeric polyolefin mixture including from 3 to 25% by weight of crystalline or partially crystalline isotactic poly(1-butene), and from 75 to 97% by weight of a heterophasic polyolefin composition; the latter containing a crystalline propylene polymer and an elastomeric copolymer of ethylene with propylene and/or an &agr;-olefin.
摘要翻译：包括3至25重量％的结晶或部分结晶的全同立构聚（1-丁烯）和75至97重量％的多相聚烯烃组合物的热塑性和弹性体聚烯烃混合物; 后者含有结晶丙烯聚合物和乙烯与丙烯和/或α-烯烃的弹性体共聚物。

2. 发明授权

US06908967B2 High transparency and high flexibility elastoplastic polyolefin compositions 失效
标题翻译：高透明度和高弹性弹性聚烯烃组合物
公开(公告)号：US06908967B2
公开(公告)日：2005-06-21
申请号：US10305072
申请日：2002-11-27
申请人： Gianni Collina , Anteo Pelliconi , Enea Garagnani
发明人： Gianni Collina , Anteo Pelliconi , Enea Garagnani
IPC分类号： C08F297/08 , C08L23/10 , C08L23/14 , C08L23/16 , C08L53/00 , C08L23/04
CPC分类号： C08L23/10 , C08F297/08 , C08L53/00 , C08L2205/02 , C08L2666/04
摘要： Highly transparent and flexible elastoplastic polyolefin compositions which contain A) 10-20 parts by weight of a propylene homopolymer or copolymer with ethylene and/or one or more CH2═CHR α-olefins, the copolymer containing at least 95% by weight of propylene; B) 5-20 parts by weight of propylene copolymer fraction containing ethylene and insoluble in xylene at room temperature; and C) 60-80 parts by weight of a propylene copolymer fraction containing a comonomer selected from ethylene and mixtures of ethylene with one or more CH2═CHR α-olefin and soluble in xylene at room temperature, the fraction containing from 15 to 25% by weight of the comonomer, the percent by weight of the sum of the B and C components with respect to the total polyolefin composition being from 80% to 90%.
摘要翻译：高透明和柔性的弹性聚烯烃组合物，其含有A）10-20重量份的丙烯均聚物或与乙烯和/或一个或多个CH 2 -CHRα-烯烃的共聚物，该共聚物含有至少95重量％的丙烯; B）5-20重量份含乙烯的丙烯共聚物部分，在室温下不溶于二甲苯; 和C）60-80重量份的丙烯共聚物部分，其含有选自乙烯的共聚单体和乙烯与一种或多种CH 2 -CHRα-烯烃的混合物，并在室温下可溶于二甲苯，所述级分含有15至25重量％的共聚单体，相对于总聚烯烃组合物，B和C组分的总和的重量百分数为80％至90％。

3. 发明授权

US07534848B2 1-butene copolymers and process for preparing them 有权
标题翻译： 1-丁烯共聚物及其制备方法
公开(公告)号：US07534848B2
公开(公告)日：2009-05-19
申请号：US10536857
申请日：2003-11-14
申请人： Luigi Resconi , Anteo Pelliconi , Enea Garagnani
发明人： Luigi Resconi , Anteo Pelliconi , Enea Garagnani
IPC分类号： C08F4/602 , C08F4/6192 , C08F210/08 , B01J31/22
CPC分类号： C08F210/08 , C08F4/65912 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/15 , C08F2500/20
摘要： A process comprising contacting 1-butene and one or more alpha-olefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R1 and R3 are hydrocarbon groups; R2 and R4 are hydrogen atoms or hydrocarbon groups; T1 and T2, equal to or different from each other are a moiety of formula (II), (III) or (IV): wherein: R5, R6, R7, R8 and R9, equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an alkylmetallocene cation.
摘要翻译：一种方法，包括在聚合条件下，在催化剂体系存在下使1-丁烯和一种或多种α-烯烃接触，所述催化剂体系可通过使下列物质接触而获得：（A）式（I）的茂金属化合物，其中：M是过渡金属的原子; p是0至3的整数; X相同或不同，为氢原子，卤素原子或烃基; L是二价桥基; R1和R3是烃基; R2和R4是氢原子或烃基; T 1和T 2彼此相同或不同的是式（II），（III）或（IV）的部分：其中：R 5，R 6，R 7，R 8和R 9彼此相同或不同，为氢或烃基; 和（B）铝氧烷或能够形成烷基茂金属阳离子的化合物。

4. 发明申请

US20080004409A1 Butene-1 (Co)Polymers Having Low Isotacticity 有权
标题翻译：具有低全同立构规整度的丁烯-1（Co）聚合物
公开(公告)号：US20080004409A1
公开(公告)日：2008-01-03
申请号：US11665630
申请日：2005-10-12
申请人： Dino Bacci , Friederike Morhard , Fabrizio Piemontesi , Maria Tonti , Gianni Vitale , Giampiero Morini , Anteo Pelliconi
发明人： Dino Bacci , Friederike Morhard , Fabrizio Piemontesi , Maria Tonti , Gianni Vitale , Giampiero Morini , Anteo Pelliconi
IPC分类号： C08L23/18 , C08F10/08 , C08F4/42
CPC分类号： C08F10/08 , C08F110/08 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/15 , C08F210/14 , C08F210/16 , C08F210/06
摘要： Butene-1 (co)polymers characterized by the following properties: content of butene-1 units in the form of isotactic pentads (mmmm) from 25 to 55%; intrinsic viscosity [η] measured in tetraline at 135° C. from 1 to 3 dL/g; content of xylene insoluble fraction at 0° C. from 3 to 60%; and a ratio ES2/ES1>1, where ES1 is the boiling diethyl ether soluble fraction determined on the polymer as such and ES2 is the boiling diethyl ether soluble fraction determined after milling the polymer. The butene-1 (co)polymers show a good balance between processability and elastomeric behavior.
摘要翻译：丁烯-1（共）聚合物，其特征在于以下性质：全同立构五单元形式的丁烯-1单元的含量（mmmm）为25至55％; 在135℃的四氢化萘中测量的特性粘度η为1至3dL / g; 0℃下二甲苯不溶级分含量为3〜60％; 和ES ES 2 / ES 1比1，其中ES 1是在聚合物上测定的沸腾二乙醚可溶级分，ES为ES 沸点二乙醚可溶级分是在研磨聚合物之后测定的。丁烯-1（共）聚合物在加工性和弹性体性能之间显示出良好的平衡。

5. 发明授权

US07294674B2 Soft polyolefin compositions with improved flow 有权
标题翻译：具有改善流动性的软聚烯烃组合物
公开(公告)号：US07294674B2
公开(公告)日：2007-11-13
申请号：US10507250
申请日：2003-03-05
申请人： Anteo Pelliconi , Antonella Angelini
发明人： Anteo Pelliconi , Antonella Angelini
IPC分类号： C08L23/04 , C08L23/10 , C08L23/16
CPC分类号： C08L23/16 , C08L23/142 , C08L2205/02 , C08L2308/00 , C08L2666/06
摘要： A polyolefin composition suitable for preparing films and sheets, comprising: (A) from 15 to 40% by weight of a crystalline copolymer of propylene with at least one alpha-olefin of formula H2C═CHR1, where R1 is H or a C2-8 linear or branched alkyl, containing at least 90% by weight of propylene, having solubility in xylene at room temperature lower than 15% by weight; (B) from 60 to 85% by weight of an elastomeric fraction comprising: (1) a copolymer of propylene with ethylene, optionally containing 0.5 to 5% by weight of a diene, containing from 20 to 35% by weight ethylene, and having solubility in xylene at room temperature greater than 45% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 1.0 to 3.0 dl/g; and (2) a copolymer of ethylene with at least one alpha-olefin of formula H2C═CHR2, where R2 is a C2-8 linear or branched alkyl, optionally containing 0.5 to 5% by weight of a diene, containing 15% to 40% by weight alpha-olefin, and having solubility in xylene at room temperature greater than 35% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 1.0 to 3.0 dl/g; the (1)/(2) weight ratio ranging from 1:5 to 5:1. The polyolefin composition of the invention, preferably prepared by sequential polymerization in at least three stages, has a flexural modulus lower than 130 MPa, Shore D hardness lower than 40, and MFR≧1.5 g/10 min.
摘要翻译：一种适于制备薄膜和片材的聚烯烃组合物，其包含：（A）15至40重量％的丙烯与至少一种式H 2 C-CHR的α-烯烃的结晶共聚物，其中R 1是H或含有至少90重量％的丙烯的C 2〜2-8直链或支链烷基，其具有溶解度在二甲苯中室温低于15重量％; （B）60至85重量％的弹性体级分，其包含：（1）丙烯与乙烯的共聚物，任选含有0.5至5重量％的二烯，其含有20至35重量％的乙烯，并且具有在室温下在二甲苯中的溶解度大于45重量％，二甲苯可溶部分的特性粘度为1.0-3.0dl / g; 和（2）乙烯与至少一种式H 2 C-CHR 2的α-烯烃的共聚物，其中R 2是 C 2-8直链或支链烷基，任选地含有0.5至5重量％的二烯，含有15重量％至40重量％的α-烯烃，并且在室温下在二甲苯中的溶解度大于 35重量％，二甲苯可溶成分的特性粘度为1.0〜3.0dl / g; （1）/（2）重量比为1:5至5:1。本发明的聚烯烃组合物，优选通过至少三个阶段的顺序聚合制备，其挠曲模量低于130MPa，肖氏D硬度低于40，MFR> = 1.5g / 10min。

6. 发明授权

US07288598B2 Polyolefin masterbatch for preparing impact-resistant polyolefin articles 有权
标题翻译：用于制备耐冲击聚烯烃制品的聚烯烃母料
公开(公告)号：US07288598B2
公开(公告)日：2007-10-30
申请号：US10506950
申请日：2003-03-06
申请人： Anteo Pelliconi , Enea Garagnani , Yutaka Yokoyama , Junichiro Washiyama , Hiroshi Takenouchi , Takeshi Nakajima
发明人： Anteo Pelliconi , Enea Garagnani , Yutaka Yokoyama , Junichiro Washiyama , Hiroshi Takenouchi , Takeshi Nakajima
IPC分类号： C08F10/02
CPC分类号： C08L23/08 , C08L23/10 , C08L23/12 , C08L2666/06
摘要： A masterbatch composition comprising (1) 10-50 wt % of a crystalline propylene homopolymer and (2) 50-90 wt % of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt %, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 d/Lg, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.
摘要翻译：一种母料组合物，其包含（1）10-50重量％的结晶丙烯均聚物和（2）50-90重量％的共混物，由（a）乙烯和一种或多种C 4 -C 10α-烯烃的共聚物），含有10-40个C 4 -C 10α-烯烃，和（b）丙烯和乙烯的无定形共聚物。共聚物（b）的乙烯含量为20〜70重量％，二甲苯可溶部分的特性粘度值为2.2〜3.5d / Lg，该值等于其特性粘度值的0.8〜1.2倍共聚物（a）的二甲苯可溶部分。共聚物（a）/（b）的重量比为3/1〜1/3。包含所述母料组合物的聚烯烃组合物适于制造汽车部件。

7. 发明申请

US20060155071A1 Butene-1 copolymers and process for their preparation 有权
标题翻译：丁烯-1共聚物及其制备方法
公开(公告)号：US20060155071A1
公开(公告)日：2006-07-13
申请号：US10532686
申请日：2003-11-03
申请人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
发明人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
IPC分类号： C08L23/00
CPC分类号： C08L23/04 , C08F10/00 , C08F210/08 , C08L23/14 , C08L23/22 , C08L2666/06 , C08F4/651 , C08F4/6543 , C08F4/6465 , C08F210/06 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F210/16 , C08F2/001
摘要： The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios r1·r2≦; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
摘要翻译：本发明涉及含有高达40摩尔％乙烯和/或丙烯的丁烯-1共聚物，其特征在于以下性质：d）反应性比r1r2的产物= e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。

8. 发明授权

US06599986B2 Propylene polymer compositions having improved impact strength and excellent optical properties 有权
标题翻译：丙烯聚合物组合物具有改善的冲击强度和优异的光学性能
公开(公告)号：US06599986B2
公开(公告)日：2003-07-29
申请号：US10031584
申请日：2002-01-18
申请人： Anteo Pelliconi , Päivi Helena Huovinen , Maria Di Diego
发明人： Anteo Pelliconi , Päivi Helena Huovinen , Maria Di Diego
IPC分类号： C08L2300
CPC分类号： C08F297/083 , C08L23/10 , C08L2205/02 , C08L2205/025 , C08L2308/00 , Y10T428/1352 , Y10T428/1397 , C08L2666/04
摘要： Propylene polymer compositions comprising (percent by weight): A) from 70 to 90% of a random copolymer of propylene with ethylene, containing from 1 to 6% of ethylene, having a content of fraction insoluble in xylene at room temperature (about 23° C.) of not less than 93%; B) from 10% to 30% of a copolymer of propylene with ethylene, containing from 8 to 18% of ethylene; wherein the ratio (B)/C2B of the percent by weight of (B), with respect to the total weight of (A) and (B), to the percent by weight of ethylene in (B), with respect to the total weight of (B), represented in the above formula by C2B, is 2.5 or lower.
摘要翻译：包含（重量％）的丙烯聚合物组合物：A）70-90％丙烯与乙烯的无规共聚物，其含有1-6％的乙烯，其含量在室温下不溶于二甲苯（约23℃） C.）不低于93％; B）10％至30％的丙烯与乙烯的共聚物，含有8至18％的乙烯; 其中（B）的重量百分比（B）相对于（A）和（B）的总重量相对于（B）中乙烯的重量百分比的比例（B）/ C2B，相对于通过C2B表示的上述式中的（B）的重量为2.5以下。

9. 发明授权

US06395831B1 Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility 有权
标题翻译：结晶丙烯共聚物组合物具有改进的密封性和光学性质以及降低的溶解性
公开(公告)号：US06395831B1
公开(公告)日：2002-05-28
申请号：US09509658
申请日：2000-03-30
申请人： Anteo Pelliconi , Paolo Ferrari
发明人： Anteo Pelliconi , Paolo Ferrari
IPC分类号： C08L2300
CPC分类号： C08L23/14 , C08F8/50 , C08F210/06 , C08F2800/20 , C08F2810/10 , C08L23/142 , C08L2023/42 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08L2666/06 , C08F2/001 , C08F4/6492 , C08F210/16 , C08F2500/12 , C08F210/08 , C08F4/6543
摘要： A crystalline propylene copolymer composition having MFR L values from 2 to 15 g/10 min. and comprising (percent by weight): A) 20-80% of one or more propylene copolymers; B) 20-80% of one or more propylene copolymers with different comonomer(s) content than in A); the said MFR L values (MFR L (2)) being obtained by subjecting to degradation a precursor composition comprising the same components A) and B) in the above said proportions, but having MFR L values (MFR L (1)) from 0.3 to 5 g/10 min., with a ratio MFR L (2) to MFR L (1) of from 2 to 20.
摘要翻译： MFR L值为2〜15g / 10min的结晶丙烯共聚物组合物。并且包含（重量％）：A）20-80％的一种或多种丙烯共聚物; B）具有不同共聚单体含量的一种或多种丙烯共聚物的20-80％比A）; 通过使上述比例含有相同组分A）和B）的前体组合物降解而得到的所述MFR L值（MFR L（2）），但MFR L值（MFR L（1））为0.3 至5g / 10min，MFR L（2）与MFR L（1）的比率为2至20。

10. 发明授权

US5541260A Polypropylene compositions having good transparency and improved impact resistance 失效
标题翻译：具有良好的透明性和耐冲击性的聚丙烯组合物
公开(公告)号：US5541260A
公开(公告)日：1996-07-30
申请号：US399959
申请日：1995-03-06
申请人： Anteo Pelliconi , Antonio Ciarrocchi , Paola Massari
发明人： Anteo Pelliconi , Antonio Ciarrocchi , Paola Massari
IPC分类号： C08L23/08 , C08F297/08 , C08L23/00 , C08L23/10 , C08L23/16 , C08L23/14
CPC分类号： C08F297/08 , C08L23/10 , C08L23/0815 , C08L2308/00
摘要： Disclosed is a polymer composition containing:(A) from 70 to 98 parts by weight of a crystalline propylene homopolymer, or a crystalline random copolymer of propylene with ethylene and/or C.sub.4 -C.sub.10 .alpha.-olefins, containing from 0.5 to 10% by weight of ethylene and/or .alpha.-olefins [fraction (A)]; and(B) from 2 to 30 parts by weight of elastomeric copolymer of ethylene with one or more C.sub.4 -C.sub.10 .alpha.-olefins, containing from 60 to 85% by weight of ethylene, and partially soluble in xylene at 25.degree. C. [fraction (B)];wherein the composition has an intrinsic viscosity value in tetrahydronaphthalene at 135.degree. C. of the fraction soluble in xylene at 25.degree. C. ranging from 0.8 to 1.1 dl/g.
摘要翻译：公开了一种聚合物组合物，其包含：（A）70至98重量份的结晶丙烯均聚物，或丙烯与乙烯和/或C 4 -C 10α-烯烃的结晶无规共聚物，其含有0.5至10重量％的乙烯和/或α-烯烃[级分（A）]; 和（B）2-30重量份的乙烯与一种或多种C 4 -C 10α-烯烃的弹性体共聚物，其含有60至85重量％的乙烯，并且部分可溶于25℃的二甲苯中。（B）]; 其中所述组合物在135℃下在四氢萘中在25℃下可溶于二甲苯的级分的特性粘度值为0.8-1.1dl / g。

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