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1. 发明申请

US20120010317A1 (METH)ACRYLATE POLYMERS AND THE USE THEREOF AS POLYMER-BOUND UV INITIATORS OR ADDITIVE TO UV-CURABLE RESINS 审中-公开
标题翻译：（METH）丙烯酸酯聚合物及其作为聚合物紫外线引发剂或添加到紫外线固化树脂中的用途
公开(公告)号：US20120010317A1
公开(公告)日：2012-01-12
申请号：US13203993
申请日：2010-02-25
申请人： Gerold Schmitt , Reinhold Martin , Patrik Hartmann , Wolfgang Klesse , Joachim Knebel
发明人： Gerold Schmitt , Reinhold Martin , Patrik Hartmann , Wolfgang Klesse , Joachim Knebel
IPC分类号： C09D11/10 , C08F2/38 , C08F216/36
CPC分类号： C08F220/18 , C08F2/50 , C08F220/14 , C08F220/30
摘要： The invention relates to a (meth)acrylate polymer obtainable by polymerizing a mixture comprising a) 0.1% to 99.9% by weight of at least one (meth)acrylate of the general formula I in which the radicals R1-R6 and also m take on the definition indicated in the description; and b) 99.9% to 0.1% by weight of one or a plurality of ethylenically unsaturated monomers which are different from a) and which are copolymerizable with a), the components a) and b) together making up 100% by weight of the polymerizable constituents of the mixture, the MW of the polymer being situated in the range from greater than or equal to 1000 g/mol to less than or equal to 50 000 g/mol. The resulting polymers are preparable preferably by the route of suspension polymerization or bead polymerization and, preferably in solution in reactive diluent, serve as polymer-bonded photoinitiators or as an additive to UV-curable resins for a very wide variety of fields of application, particularly for printing inks.
摘要翻译：本发明涉及一种（甲基）丙烯酸酯聚合物，其可通过聚合包含a）0.1重量％至99.9重量％的至少一种通式I的（甲基）丙烯酸酯，其中基团R 1 -R 6和m取代描述中指出的定义; 和b）99.9重量％至0.1重量％的不同于a）的一种或多种烯属不饱和单体，并且它们可与a）共聚，组分a）和b）组合在一起构成100重量％的可聚合混合物的组分，聚合物的MW位于大于或等于1000g / mol至小于或等于50 000g / mol的范围内。所得聚合物优选通过悬浮聚合或珠粒聚合途径制备，优选在反应性稀释剂的溶液中，用作聚合物键合的光引发剂或作为UV可固化树脂的添加剂，用于各种各样的应用领域，特别是用于印刷油墨。

2. 发明授权

US07144954B2 Highly transparent plastic for optical materials 失效
标题翻译：用于光学材料的高透明塑料
公开(公告)号：US07144954B2
公开(公告)日：2006-12-05
申请号：US10529478
申请日：2003-09-13
申请人： Bardo Schmitt , Wolfgang Klesse , Volker Kerscher , Patrik Hartmann
发明人： Bardo Schmitt , Wolfgang Klesse , Volker Kerscher , Patrik Hartmann
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08F18/08 , C08G8/30
CPC分类号： C08G18/8175 , C08F222/1006 , C08G18/3876 , C08G18/73
摘要： The present invention relates to mixtures containing A) compounds of the formula (I) and (II) where R1 is independently at each instance hydrogen or a methyl radical, R2 is independently at each instance a linear or branched, aliphatic or cycloaliphatic radical or a substituted or unsubstituted aromatic or heteroaromatic radical and m and n are each independently an integer of not less than 0 subject to the proviso that m+n>0, and B) at least one ethylenically unsaturated monomer (A) which is different from the compounds of the formula (I) and (II). The present invention further relates to processes for polymerizing these mixtures, the highly transparent polymers thus obtainable and to their use.
摘要翻译：本发明涉及含有A）式（I）和（II）化合物的混合物，其中R 1各自独立地为氢或甲基，R 2，在每种情况下独立地为直链或支链的脂族或脂环族基团或取代或未取代的芳族或杂芳族基团，m和n各自独立地为不小于0的整数，条件是m + n> 0，B ）与式（I）和（II）的化合物不同的至少一种烯属不饱和单体（A）。本发明还涉及使这些混合物聚合的方法，由此获得的高度透明的聚合物及其用途。

3. 发明申请

US20050261421A1 Highly transparent plastic for optical materials 失效
标题翻译：用于光学材料的高透明塑料
公开(公告)号：US20050261421A1
公开(公告)日：2005-11-24
申请号：US10529478
申请日：2003-09-13
申请人： Bardo Schmitt , Wolfgang Klesse , Volker Kerscher , Patrik Hartmann
发明人： Bardo Schmitt , Wolfgang Klesse , Volker Kerscher , Patrik Hartmann
IPC分类号： C08F222/10 , C08G18/38 , C08G18/73 , C08G18/81 , C08K3/00
CPC分类号： C08G18/8175 , C08F222/1006 , C08G18/3876 , C08G18/73
摘要： The present invention relates to mixtures containing A) compounds of the formula (I) and (II) where R1 is independently at each instance hydrogen or a methyl radical, R2 is independently at each instance a linear or branched, aliphatic or cycloaliphatic radical or a substituted or unsubstituted aromatic or heteroaromatic radical and m and n are each independently an integer of not less than 0 subject to the proviso that m+n>0, and B) at least one ethylenically unsaturated monomer (A) which is different from the compounds of the formula (I) and (II). The present invention further relates to processes for polymerizing these mixtures, the highly transparent polymers thus obtainable and to their use.
摘要翻译：本发明涉及含有A）式（I）和（II）化合物的混合物，其中R 1各自独立地为氢或甲基，R 2，在每种情况下独立地为直链或支链的脂族或脂环族基团或取代或未取代的芳族或杂芳族基团，m和n各自独立地为不小于0的整数，条件是m + n> 0，B ）与式（I）和（II）的化合物不同的至少一种烯属不饱和单体（A）。本发明还涉及使这些混合物聚合的方法，由此获得的高度透明的聚合物及其用途。

4. 发明申请

US20080139771A1 Thio(Meth)Acrylates, Mixtures For Producing Transparent Plastics, Transparent Plastics And Method For Their Production And Use 审中-公开
标题翻译：硫代（甲基）丙烯酸酯，透明塑料混合物，透明塑料及其生产和使用方法
公开(公告)号：US20080139771A1
公开(公告)日：2008-06-12
申请号：US11813216
申请日：2005-12-03
申请人： Bardo Schmitt , Joachim Knebel , Patrik Hartmann
发明人： Bardo Schmitt , Joachim Knebel , Patrik Hartmann
IPC分类号： C08F28/04
CPC分类号： C07C327/22 , C08F222/1006 , C08F222/24 , C08K5/38 , C08L33/04 , C08L33/14 , C08L41/00 , G02B1/04 , C08L2666/04
摘要： The present invention relates to thio(meth)acrylates, obtainable via reaction of compounds of the formula (I) and (II) where each R1, independently of the others, is hydrogen or a methyl radical, each R2, independently of the others is a linear or branched, aliphatic or cycloaliphatic radical, or a substituted or unsubstituted aromatic or heteroaromatic radical, and each of m and n, independently of the others, is whole number greater than or equal to 0, where m+n>0, with thiol compounds which encompass at least two thiol groups.
摘要翻译：本发明涉及通过式（I）和（II）化合物的反应获得的硫代（甲基）丙烯酸酯，其中每个R 1独立地是氢或甲基，每个R 2独立地为直链或支链的脂族或脂环族基团，或取代或未取代的芳族或杂芳族基团，m和n各自独立地为全部大于或等于0，其中m + n> 0，其中硫醇化合物包含至少两个硫醇基团。

5. 发明申请

US20050154161A1 Method for producing highly transparent plastics for optical materials 审中-公开
标题翻译：用于制造光学材料的高透明塑料的方法
公开(公告)号：US20050154161A1
公开(公告)日：2005-07-14
申请号：US10509328
申请日：2003-06-13
申请人： Bardo Schmitt , Joachim Knebel , Patrik Hartmann
发明人： Bardo Schmitt , Joachim Knebel , Patrik Hartmann
IPC分类号： G02B1/04 , C07C327/22 , C08F22/10 , C08F220/38 , C08F2/00
CPC分类号： C08F22/105
摘要： The present invention relates to a process for preparing a highly transparent plastic obtainable by free-radical copolymerization of a mixture containing compounds of the formula (I) and (II) where R1 is independently at each instance hydrogen or a methyl radical, R2 is independently at each instance a linear or branched, aliphatic or cycloaliphatic radical or a substituted or unsubstituted aromatic or heteroaromatic radical and m and n are each independently an integer of not less than 0 subject to the proviso that m+n>0, which is characterized in that it is obtainable from a mixture which contains more than 10 mol %, based on the total amount of the compounds of the formula (I) and (II), of compounds of the formula (II) where m+n=2. The present invention also relates to the mixture of the compounds (I) and (II), to processes for preparing the mixture and to particular uses for the highly transparent plastics.
摘要翻译：本发明涉及制备通过含有式（I）和（II）化合物的混合物的自由基共聚获得的高透明塑料的方法，其中R 1各自独立地为氢或甲基，R 2在每种情况下独立地为直链或支链的脂族或脂环族基团或取代或未取代的芳族或杂芳族基团，m和n各自独立地为不小于 0，条件是m + n> 0，其特征在于，其可以从基于式（I）和（II）的化合物的总量的含量大于10摩尔％的混合物获得，其中m + n = 2的式（II）化合物。本发明还涉及化合物（I）和（II）的混合物，用于制备混合物的方法和用于高透明塑料的具体用途。

6. 发明授权

US07445728B2 Mixtures for producing transparent plastics, transparent plastics and method for producing the same and the use thereof 失效
标题翻译：用于生产透明塑料的混合物，透明塑料及其制备方法及其用途
公开(公告)号：US07445728B2
公开(公告)日：2008-11-04
申请号：US11547238
申请日：2005-01-19
申请人： Bardo Schmitt , Patrik Hartmann
发明人： Bardo Schmitt , Patrik Hartmann
IPC分类号： C09K3/00
CPC分类号： C08F228/00
摘要： The invention relates to mixtures for producing transparent plastic, which mixtures comprise: a) compounds of formulae (I) and (II), wherein R1 independently represents hydrogen or a methyl group, R2 independently represents a linear or branched, aliphatic or cycloaliphatic group or a substituted or unsubstituted aromatic or heteroaromatic group and m and n independently represent an integer ≧0, with m+n>0, b) a prepolymer produced from polymethacrylate and alkyldithiols or polythiols, preferably HS—R3—SH (III), wherein R3 is the same or different from R2 and may have the definition of R2, and c) aromatic vinyl compounds.
摘要翻译：本发明涉及用于生产透明塑料的混合物，其混合物包括：a）式（I）和（II）的化合物，其中R 1独立地表示氢或甲基，R 2 独立地表示直链或支链的脂族或脂环族基团或取代或未取代的芳族或杂芳族基团，m和n独立地表示整数> = 0，其中m + n> 0，b）由聚甲基丙烯酸酯和烷基二硫醇或多硫醇，优选HS-R 3 -SH（III），其中R 3和R 2相同或不同，并且可以具有R 2的定义，和c）芳族乙烯基化合物。

7. 发明申请

US20070161766A1 Mixtures for producing transparent plastics, transparent plastics, method for producing the same and the use thereof 失效
标题翻译：用于生产透明塑料的混合物，透明塑料，其制备方法及其用途
公开(公告)号：US20070161766A1
公开(公告)日：2007-07-12
申请号：US10587257
申请日：2005-01-19
申请人： Bardo Schmitt , Patrik Hartmann
发明人： Bardo Schmitt , Patrik Hartmann
IPC分类号： C08F28/02
CPC分类号： C08F228/00
摘要： The present invention relates to mixtures for preparing transparent plastics, encompassing a) a prepolymer prepared from compounds of the formula (I) and (II) where each R1, independently of the others, is hydrogen or a methyl radical, each R2, independently of the others, is a linear or branched, aliphatic or cycloaliphatic radical, or a substituted or unsubstituted aromatic or heteroaromatic radical, and each of m and n, independently of the other, is a whole number greater than or equal to 0, where m+n>0, and from compounds of the formula (III), or from alkyl dithiols or from polythiols, preferably HS—R3—SH (III) where R3, identical with or different from R2, can be as defined for R2, and b) at least one monomer (A) capable of free-radical polymerization and having at least 2 methacrylate groups, and c) aromatic vinyl compounds, such as styrene, and d) if appropriate, a monomer capable of free-radical polymerization and having at least two terminal olefinic groups whose reactivity differs, and/or e) if appropriate, at least one monomer (B) from the group of the methacrylates, preferably 2-hydroxyethyl methacrylate.
摘要翻译：本发明涉及用于制备透明塑料的混合物，其包括a）由式（I）和（II）的化合物制备的预聚物，其中每个R 1独立地为氢或甲基，每个R 2独立地为直链或支链的脂族或脂环族基团，或取代或未取代的芳族或杂芳族基团，m和n各自独立地为另外，是大于或等于0的整数，其中m + n> 0，和式（III）的化合物，或烷基二硫醇或多硫醇，优选HS-R 3 -SH（III）其中R 3与R 2相同或不同，R 2可以如对R 2所定义，b）在至少一种能够自由基聚合并具有至少2个甲基丙烯酸酯基团的单体（A），和c）芳族乙烯基化合物如苯乙烯，以及d）如果合适，可以进行自由基聚合的单体 nd具有至少两个其反应性不同的末端烯属基团和/或e）如果合适的话，至少一种来自甲基丙烯酸酯基团的单体（B），优选甲基丙烯酸2-羟乙酯。

8. 发明申请

US20060052564A1 Mixture for the production of transparent plastic materials, transparent plastic materials, and method for the production and use thereof 失效
标题翻译：用于生产透明塑料材料，透明塑料材料的混合物及其生产和使用方法
公开(公告)号：US20060052564A1
公开(公告)日：2006-03-09
申请号：US10532823
申请日：2004-07-10
申请人： Bardo Schmitt , Patrik Hartmann
发明人： Bardo Schmitt , Patrik Hartmann
IPC分类号： C08F118/02
CPC分类号： G02B1/04 , C08F222/1006 , C08L81/00 , C08L33/14
摘要： The present invention relates to mixtures for preparing transparent plastics, encompassing a) compounds of the formula (I) and (II) where each R1, independently of the others, is hydrogen or a methyl radical, each R2, independently of the others, is a linear or branched, aliphatic or cycloaliphatic radical, or a substituted or unsubstituted aromatic or heteroaromatic radical, and each of m and n, independently of the other, is a whole number greater than or equal to 0, where m+n>0, and b) at least one monomer (A) capable of free-radical polymerization with a molar mass of at least 150 g/mol, which contains at least two terminal olefinic groups, where at least two of the olefinic groups of the monomer (A) have, in the α- and/or β-position with respect to the olefinic group, atoms which differ in nature and/or number, in the radical which connects the at least two olefinic groups.
摘要翻译：本发明涉及用于制备透明塑料的混合物

9. 发明授权

US07438830B2 Mixtures for producing transparent plastics, transparent plastics, method for producing the same and the use thereof 失效
标题翻译：用于生产透明塑料的混合物，透明塑料，其制备方法及其用途
公开(公告)号：US07438830B2
公开(公告)日：2008-10-21
申请号：US10587257
申请日：2005-01-19
申请人： Bardo Schmitt , Patrik Hartmann
发明人： Bardo Schmitt , Patrik Hartmann
IPC分类号： C09K3/00
CPC分类号： C08F228/00
摘要： The present invention relates to mixtures for preparing transparent plastics, encompassing a) a prepolymer prepared from compounds of the formula (I) and (II) where each R1, independently of the others, is hydrogen or a methyl radical, each R2, independently of the others, is a linear or branched, aliphatic or cycloaliphatic radical, or a substituted or unsubstituted aromatic or heteroaromatic radical, and each of m and n, independently of the other, is a whole number greater than or equal to 0, where m+n>0, and from compounds of the formula (III), or from alkyl dithiols or from polythiols, preferably HS—R3—SH (III) where R3, identical with or different from R2, can be as defined for R2, and b) at least one monomer (A) capable of free-radical polymerization and having at least 2 methacrylate groups, and c) aromatic vinyl compounds, such as styrene, and d) if appropriate, a monomer capable of free-radical polymerization and having at least two terminal olefinic groups whose reactivity differs, and/or if appropriate, at least one monomer (B) from the group of the methacrylates, preferably 2-hydroxyetyl methacrylate.
摘要翻译：本发明涉及用于制备透明塑料的混合物，其包括a）由式（I）和（II）的化合物制备的预聚物，其中每个R 1独立地为氢或甲基，每个R 2独立地为直链或支链的脂族或脂环族基团，或取代或未取代的芳族或杂芳族基团，m和n各自独立地为另外，是大于或等于0的整数，其中m + n> 0，和式（III）化合物或烷基二硫醇或多硫醇，优选<？在线公式描述=“In “公式”end =“lead”？> HS-R 3 -SH（III）<？in-line-formula description =“In-line Formulas”end =“tail”？> where R 2与R 2相同或不同，可以与R 2所定义，b）至少一种单体（A）能够进行自由基聚合并具有至少2个甲基丙烯酸酯基团，和c）芳族乙烯基化合物，例如苯乙烯，以及d）如果合适，可以进行自由基聚合并且具有至少两个反应性不同的末端烯烃基团的单体和/或如果合适的话至少一种单体（B）来自甲基丙烯酸酯的组，优选甲基丙烯酸2-羟基乙酯。

10. 发明申请

US20070135560A1 Mixtures for producing transparent plastics, transparent plastics and method for their production and use 失效
标题翻译：用于生产透明塑料，透明塑料的混合物及其生产和使用方法
公开(公告)号：US20070135560A1
公开(公告)日：2007-06-14
申请号：US10588210
申请日：2005-01-19
申请人： Bardo Schmitt , Patrik Hartmann
发明人： Bardo Schmitt , Patrik Hartmann
IPC分类号： C09D5/02
CPC分类号： C08F228/00
摘要： The invention relates to mixtures for producing transparent plastics, comprising a) a prepolymer, produced from the compounds of formulae (1) and (II), wherein R1 independently represents hydrogen or a methyl group, R2 independently represents a linear or branched, aliphatic or cycloaliphatic group or a substituted or unsubstituted aromatic or heteroaromatic group and m and n independently represent an integer greater or equal 0, with m+1>0, and compounds of formula (III), alkyldithiols or polythiols, preferably HS—R3—SH (III), wherein R3 is equal or different from R2 and can have the meaning indicated in R2, and b) at least one radically polymerizable monomer (A) having at least two methacrylate groups and c) aromatic vinyl compounds, such as styrene and d) optionally a radically polymerizable monomer having at least two terminal olefinic groups that have different reactivity, and/or e) optionally at least one monomer (B) from the group of methacrylates, preferably 2-hydroxyethylmethacrylate.
摘要翻译：本发明涉及用于生产透明塑料的混合物，其包含a）由式（1）和（II）化合物制备的预聚物，其中R 1独立地表示氢或甲基， SUP> 2独立地表示直链或支链的脂族或脂环族基团或取代或未取代的芳香族或杂芳族基团，m和n独立地表示大于或等于0且m + 1> 0的整数，以及式（III），烷基二硫醇或多硫醇，优选HS-R 3 -SH（III），其中R 3等于或不同于R 2 O 并且可以具有R 2中所示的含义，和b）至少一种具有至少两个甲基丙烯酸酯基团的可自由基聚合的单体（A）和c）芳族乙烯基化合物如苯乙烯和d）任选地具有至少两个具有不同反应性的末端烯基的自由基聚合单体和/或e）任选的至少一种单体（ B）甲基丙烯酸酯，优选甲基丙烯酸2-羟基乙酯。

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