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1. 发明授权

US06500952B1 Processes for preparing aminophenylsulfonylureas, and intermediates therefor 有权
标题翻译：制备氨基苯磺酰脲的方法及其中间体
公开(公告)号：US06500952B1
公开(公告)日：2002-12-31
申请号：US09664201
申请日：2000-09-18
申请人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
发明人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
IPC分类号： C07D23942
CPC分类号： C07D521/00 , A01N47/36 , H01R33/06 , Y02A40/143
摘要： The invention relates to the preparation of compounds (I) in which A=H or acyl and R1, R21, R3, R, n, X, Y and Z are as defined in claim 1 by halogenation and rearrangement of compounds (II) (optionally salt) to give compounds (III) a) ammonolysis of (III) to (IV), reduction of the nitro group and reaction with carbamate (salts) (VI) of the formula Ar—OCO—N(M)—Het, where Ar=phenyl, M=H or cation and Het=heterocycle from formula (I), to give compounds (I) (A=H), or b) ammonolysis of (III) to (IV), reaction with carbamate (salt) (VI) and reduction of resulting compounds (VII) at the NO2 group to give compounds (I) (A=H), or c) reaction of (III) with cyanates and amines (VIII) of the formula HNR3—Het and reduction of the resulting compound (VII) at the NO2 group to give compounds (I) (A=H) and optional acylation if A is to be other than H. Compounds of the formulae (I) (A=H), (III), (IV), (V), (VI) (M=cation) and (VII) are novel.
摘要翻译：本发明涉及化合物（Ⅰ）的制备，其中A = H或酰基，R 1，R 21，R 3，R 4，n，X，Y和Z如权利要求1中所定义，通过卤化和重排化合物任选的盐），得到化合物（III）a）（III）至（IV）的氨解，硝基的还原和与式Ar-OCO-N（M）-Het的氨基甲酸酯（盐）（VI）的反应，其中Ar =苯基，M = H或阳离子和Het =来自式（I）的杂环，得到（III）至（IV）化合物（I）（A = H），orb）氨解，与氨基甲酸酯（VI）和还原所得化合物（VII）在NO 2基团上得到化合物（I）（A = H），orc）（III）与式HNR3-Het的氰酸酯和胺（VIII）的反应，还原所得到的化合物（Ⅶ）在NO2基团上得到化合物（I）（A = H），任选的酰化如果A不为H.式（I）（A = H），（III）（IV），（V），（VI）（M =阳离子）和（VII）是新颖的。

2. 发明授权

US06790955B2 Processes for the preparation of aminophenylsulfonyl-ureas and intermediate products for the processes 有权
标题翻译：用于制备氨基苯磺酰脲和中间产物的方法
公开(公告)号：US06790955B2
公开(公告)日：2004-09-14
申请号：US10288052
申请日：2002-11-05
申请人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
发明人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
IPC分类号： C07D27300
CPC分类号： C07D521/00 , A01N47/36 , H01R33/06 , Y02A40/143
摘要： The invention relates to the preparation of compounds (I) in which A═H or acyl and R1, R2, R3, R, n, X, Y and Z are as defined in claim 1 by halogenation and rearrangement of compounds (II) (optionally salt) to give compounds (III) a) ammonolysis of (III) to (IV), reduction of the nitro group and reaction with carbamate (salts) (VI) of the formula Ar—OCO—N(M)-Het, where Ar=phenyl, M═H or cation and Het=heterocycle from formula (I), to give compounds (I) (A═H), or b) ammonolysis of (III) to (IV), reaction with carbamate (salt) (VI) and reduction of resulting compounds (VII) at the NO2 group to give compounds (I) (A═H), or c) reaction of (III) with cyanates and amines (VII) of the formula HNR3-Het and reduction of the resulting compound (VII) at the NO2 group to give compounds (I) (A═H) and optional acylation if A is to be other than H. Compounds of the formulae (I) (A═H), (III), (IV), (V), (VI) (M=cation) and (VII) are novel.
摘要翻译：本发明涉及其中A = H或酰基和R 1，R 2，R 3，R 3，n，X，Y和Z如权利要求1中所定义的化合物（I）的制备，化合物（II）（任选盐）的卤化和重排以得到化合物（III）a）（III）至（IV）的氨解，还原硝基并与式Ar-的氨基甲酸酯（盐）（Ⅵ）其中Ar =苯基，M = H或阳离子和Het =来自式（I）的杂环，得到化合物（I）（A = H），orb）氨解（III）至（III） IV），与氨基甲酸酯（盐）（VI）的反应和NO 2基团上得到的化合物（VII）的还原，得到化合物（I）（A = H），orc）（III）与氰酸酯和胺的反应（VII）的式（HNR 3）-Het，并且在NO 2基上还原所得化合物（Ⅶ），得到化合物（I）（A = H），并且如果A不为H，则为任意的酰化。式 I）（A = H），（III），（IV），（V），（VI）（M =阳离子）和（VII）

3. 发明授权

US07057043B2 Processes for preparing aminophenylsulfonylureas, and intermediates therefor 失效
公开(公告)号：US07057043B2
公开(公告)日：2006-06-06
申请号：US10936180
申请日：2004-09-08
申请人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
发明人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
IPC分类号： C07D239/02
CPC分类号： C07D521/00 , A01N47/36 , H01R33/06 , Y02A40/143
摘要： The invention relates to the preparation of compounds (I) in which A=H or acyl and R1, R2, R3, R, n, X, Y and Z are as defined in claim 1 by halogenation and rearrangement of compounds (II) (optionally salt) to give compounds (III) R*═OH, R**═NR1R2 (II) R*═NR1R2, R**═Cl (III) R*═NR1R2, R**═NH2 (IV) a) ammonolysis of (III) to (IV), reduction of the nitro group and reaction with carbamate (salts) (VI) of the formula Ar—OCO—N(M)-Het, where Ar=phenyl, M=H or cation and Het=heterocycle from formula (I), to give compounds (I) (A=H), or b) ammonolysis of (III) to (IV), reaction with carbamate (salt) (VI) and reduction of resulting compounds (VII) at the NO2 group to give compounds (I) (A=H), or c) reaction of (III) with cyanates and amines (V) of the formula HNR3−Het and reduction of the resulting compound (VII) at the NO2 group to give compounds (I) (A=H) and optional acylation if A is to be other than H. Compounds of the formulae (I) (A=H), (III), (IV), (V), (VI) (M=cation) and (VII) are novel.

4. 发明申请

US20050033047A1 Processes for preparing aminophenylsulfonylureas, and intermediates therefor 失效
标题翻译：制备氨基苯磺酰脲的方法及其中间体
公开(公告)号：US20050033047A1
公开(公告)日：2005-02-10
申请号：US10936180
申请日：2004-09-08
申请人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
发明人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
IPC分类号： C07D251/16 , A01N47/36 , A01P13/00 , A01P21/00 , C07C309/89 , C07C311/39 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D251/42 , C07D251/44 , C07D251/46 , C07D521/00 , F21S4/00 , F21V31/00 , H01R33/06 , A01N43/54 , A01N43/90 , C07D239/02
CPC分类号： C07D521/00 , A01N47/36 , H01R33/06 , Y02A40/143
摘要： The invention relates to the preparation of compounds (I) in which A=H or acyl and R1, R2, R3, R, n, X, Y and Z are as defined in claim 1 by halogenation and rearrangement of compounds (II) (optionally salt) to give compounds (III) R*═OH, R**═NR1R2 (II) R*═NR1R2, R**═Cl (III) R*═NR1R2, R**═NH2 (IV) a) ammonolysis of (III) to (IV), reduction of the nitro group and reaction with carbamate (salts) (VI) of the formula Ar—OCO—N(M)-Het, where Ar=phenyl, M=H or cation and Het=heterocycle from formula (I), to give compounds (I) (A=H), or b) ammonolysis of (III) to (IV), reaction with carbamate (salt) (VI) and reduction of resulting compounds (VII) at the NO2 group to give compounds (I) (A=H), or c) reaction of (III) with cyanates and amines (V) of the formula HNR3−Het and reduction of the resulting compound (VII) at the NO2 group to give compounds (I) (A=H) and optional acylation if A is to be other than H. Compounds of the formulae (I) (A=H), (III), (IV), (V), (VI) (M=cation) and (VII) are novel.
摘要翻译：本发明涉及其中A = H或酰基和R 1，R 2，R 3，R 3，n，X，Y和Z如权利要求1中所定义的化合物（I）的制备，化合物（II）（任选盐）的卤化和重排，得到化合物（III）R * = OH，R ** = NR 1 R 2（II）R * = NR 1 R 2， R ** = Cl（III）R * = NR 1 R 2，R ** = NH 2（IV）a）（III）至（IV）的氨解，硝基还原和与氨基甲酸酯反应其中Ar =苯基，M = H或阳离子和Het =来自式（I）的杂环的式Ar-OCO-N（M）-Het的化合物（I）（A = H），或b）（III）至（IV）的氨解，与氨基甲酸酯（盐）（VI）的反应和所得化合物（VII）在NO 2基团上的还原，得到化合物（I）（A = H），或c）（III）与式HNR <3-> Het的氰酸酯和胺（V）的反应，并且在NO 2基团上还原所得化合物（VII），得到化合物（I）（A = H），任选的酰化如果A 式（I）（A = H），（III），（IV），（V），（VI）（M = on）和（VII）是新颖的。

5. 发明授权

US06498253B1 Acylated aminophenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators 有权
标题翻译：酰化氨基苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06498253B1
公开(公告)日：2002-12-24
申请号：US09257669
申请日：1999-02-25
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D23969
CPC分类号： C07D521/00 , A01N47/36 , C07C311/16 , C07C311/39 , C07C311/46 , C07C311/47 , C07D239/42 , C07D239/46 , C07D239/47 , C07D251/16 , C07D251/42 , C07D251/46 , C07D251/52 , C07D405/12 , C07D409/12
摘要： Compounds of the formula (I) and salts thereof in which W1, W2, R, n, R1, R2, R4, X, Y and Z are as defined in claim 1 and R3 is an acyl radical, are suitable as herbicides and plant growth regulators. The herbicides can be prepared by the process variants from claim 5, the novel intermediate products (II), (IV), (VI) and (VIII)* of claims 9 and 10 being employed.
摘要翻译： W1，W2，R，n，R1，R2，R4，X，Y和Z如权利要求1所定义的式（I）化合物及其盐，其中R 3为酰基，适用作除草剂和植物生长监管者。除草剂可以通过权利要求5的方法变体制备，使用权利要求9和10的新型中间产物（II），（IV），（VI）和（VIII）*。

6. 发明授权

US6017852A Method of controlling undesired plant growth in rice 失效
标题翻译：控制水稻不希望的植物生长的方法
公开(公告)号：US6017852A
公开(公告)日：2000-01-25
申请号：US77139
申请日：1998-05-21
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer
IPC分类号： C07D251/46 , A01N47/36 , C07D239/52 , C07D521/00 , A01N43/54 , A01N43/66
CPC分类号： C07D521/00 , A01N47/36
摘要： The invention relates to a method of controlling harmful plants in rice crops, which comprises applying one or more compounds of the formula (I) or salts thereof whereR.sup.1 is an acyl radical from the group CO--R.sup.2, CS--R.sup.2, CO--OR.sup.3, CS--OR.sup.3, CO--SR.sup.4, CS--SR.sup.4, CO--NR.sup.5 R.sup.6 and CS--NR.sup.5 R.sup.6, and R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 and also X, Y and Z are as defined in the formula (I) of claim 1,to the area under cultivation, which contains the harmful plants and rice plants or their seeds, in an effective amount of from 0.0001 to 0.5 kg of a.i./ha.The compounds (I) are known per se. The invention also provides novel salts of the compounds (I).
摘要翻译： PCT No.PCT / EP96 / 04798 Sec。 371日期1998年5月21日 102（e）日期1998年5月21日PCT提交1996年11月4日PCT公布。出版物WO97 / 18711 日期：1997年5月29日本发明涉及一种控制水稻作物中有害植物的方法，其包括应用一种或多种式（I）化合物或其盐，其中R 1为酰基，从CO-R 2，CS-R 2 ，CO-OR3，CS-OR3，CO-SR4，CS-SR4，CO-NR5R6和CS-NR5R6以及R2，R3，R4，R5和R6，X，Y和Z如式），其含有有害植物和水稻植物或其种子的耕作区域的有效量为0.0001至0.5kg的ai / ha。化合物（I）本身是已知的。本发明还提供了化合物（I）的新型盐。

7. 发明授权

US5854179A Sulfur-substituted phenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators 失效
标题翻译：硫取代的苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US5854179A
公开(公告)日：1998-12-29
申请号：US552670
申请日：1995-11-03
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D239/42 , A01N47/36 , C07D239/46 , C07D239/47 , C07D521/00 , C07D403/12 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36
摘要： Sulfur-substituted phenylsulfonylureas; processes for their preparation and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof ##STR1## in which R*, R.sup.1, R.sup.2, R.sup.3, X, Y, Z, W, n and m are defined as in claim 1, and specifically R* is a formyl equivalent of the formula CHO, --CH.dbd.NR or CH(X.sup.1 R')(X.sup.2 R"), are suitable as herbicides and plant growth regulators. They are prepared analogously to known methods, in some cases using novel intermediate products of the formula (XVII) ##STR2## in which U*.dbd.NH.sub.2, Cl or (substituted) amino.
摘要翻译：硫取代苯磺酰脲; 其制备方法及其作为除草剂和植物生长调节剂的用途式（I）化合物及其盐其中R *，R 1，R 2，R 3，X，Y，Z，W，n和 m定义为权利要求1，特别地，R *为式CHO，-CH = NR或CH（X1R'）（X2R“）的甲酰当量，适用作除草剂和植物生长调节剂。它们是类似于已知方法制备的，在某些情况下，使用其中U * = NH 2，Cl或（取代的）氨基的式（XVII）的新型中间产物。

8. 发明授权

US08901036B2 Combinations of phenylsulfonylurea herbicides and safeners 有权
标题翻译：苯磺酰脲除草剂和安全剂的组合
公开(公告)号：US08901036B2
公开(公告)日：2014-12-02
申请号：US11365159
申请日：2006-03-01
申请人： Lothar Willms , Hermann Bieringer , Erwin Hacker , Gerhard Schnabel , Klaus Lorenz
发明人： Lothar Willms , Hermann Bieringer , Erwin Hacker , Gerhard Schnabel , Klaus Lorenz
IPC分类号： A01N25/32 , A01N43/26 , A01N43/56 , A01N43/00 , A01N43/42 , A01N43/66 , A01N47/36
CPC分类号： A01N47/36 , A01N43/80 , A01N43/653 , A01N43/56 , A01N43/42 , A01N25/32 , A01N2300/00
摘要： The invention relates to combinations of sulfonylurea herbicides (A) and their salts in which R2 is H, OH, aliphatic hydrocarbon radical or hydrocarbon-oxy radical, and R1 is an acyl radical, and the other symbols are as defined in claim 1, and safeners of type (B1) and (B2) in which the symbols are as defined in claim 1.
摘要翻译：本发明涉及磺酰脲类除草剂（A）及其盐，其中R2为H，OH，脂族烃基或烃氧基，R1为酰基，其它符号如权利要求1所定义，类型（B1）和（B2）的安全剂，其中符号如权利要求1所定义。

9. 发明授权

US5747421A Formylaminophenylsulfonylureas, preparation processes and use as herbicides and plant growth regulators 失效
标题翻译：甲酰氨基苯基磺酰脲，制备方法和用作除草剂和植物生长调节剂
公开(公告)号：US5747421A
公开(公告)日：1998-05-05
申请号：US453978
申请日：1995-05-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D251/16 , A01N47/36 , C07D239/42 , C07D251/46 , C07D251/50 , C07D405/12 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36
摘要： Formylaminophenylsulfonylureas; processes for their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) ##STR1## in which R.sup.1 is H, a substituted or unsubstituted hydrocarbon radical or an unsubstituted or substituted heterocyclic radical, R.sup.2 is H, (C.sub.1 -C.sub.6)-alkyl or (C.sub.1 -C.sub.6)-alkoxy, R.sup.3 is halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy, (C.sub.1 -C.sub.6)-haloalkyl, (C.sub.1 -C.sub.6)-haloalkoxy, NO.sub.2, CN, NH.sub.2, (C.sub.1 -C.sub.4) -mono- or dialkylamino, each independently of other radicals R.sup.3 if n is 2 or 3, n is 0, 1, 2 or 3, W is an oxygen atom or a sulfur atom, X and Y independently of one another are halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy or (C.sub.1 -C.sub.6)-alkylthio, each of the three last-mentioned radicals being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C.sub.1 -C.sub.4)-alkoxy and (C.sub.1 -C.sub.4)-alkylthio, or are (C.sub.3 -C.sub.6)-cycloalkyl, (C.sub.2 -C.sub.6)-alkenyl, (C.sub.2 -C.sub.6)-alkynyl, (C.sub.2 -C.sub.6)-alkenyloxy, (C.sub.2 -C.sub.6)-alkynyloxy, mono- or di�(C.sub.1 -C.sub.4 -alkyl)!amino, and Z is CH or N, are suitable as herbicides and plant growth regulators. The compounds (I) can be prepared by processes analogous to known processes whereby some novel intermediates of formula (II) are used.
摘要翻译：甲酰氨基苯基磺酰脲其制备方法及其作为除草剂和植物生长调节剂的用途式（I）取代烃基或未取代或取代的杂环基的化合物，R2是H，（C1-C6） - 烷基或（C1-C6） - 烷氧基，R 3为卤素，（C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基，（C 1 -C 6） - 卤代烷基，（C 1 -C 6） - 卤代烷氧基，NO 2，CN，NH 2，（C 1 -C 4）单或二烷基氨基，如果n为2或3，各自独立地为其它基团，n为0,1,2或3，W为氧原子或硫原子，X和Y彼此独立地为卤素，（C1 （C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基或（C 1 -C 6） - 烷硫基，三个最后提到的基团中的每一个是未取代的或被一个或多个选自卤素，（C1- 或（C 1 -C 6） - 烷硫基，或者是（C 3 -C 6） - 环烷基，（C 2 -C 6） - 烯基，（C 2 -C 6） - 炔基，（C 2 -C 6） - 炔基氧基，（C 2 -C 6） C6） - 炔氧基，单或二[（C1-C4烷基）]氨基，Z为CH或N，适合作为除草剂和植物生长调节剂。化合物（I）可以通过类似于已知方法的方法制备，由此使用一些新的式（II）中间体。

10. 发明授权

US5723409A Intermediates for the preparation of phenylsulfonylurea herbicides and plant growth regulators 失效
公开(公告)号：US5723409A
公开(公告)日：1998-03-03
申请号：US430343
申请日：1995-04-28
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N47/36 , C07C311/47 , C07C311/65 , C07C335/28 , C07D521/00 , C07D239/64 , A01N43/54 , C07D401/12
CPC分类号： C07D521/00 , A01N47/36 , C07C311/47 , C07C311/65 , C07C335/28
摘要： The compounds of the formula (I) ##STR1## in which R.sup.1 -R.sup.4, W, X, Y and Z are as defined in claim 1 are suitable for controlling harmful plants in crops. Their preparation may employ the intermediates of the formulae II and III: ##STR2##

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