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1. 发明授权

US07858222B2 Separator-electrode unit for lithium-ion batteries, method for the production and use thereof in lithium batteries 有权
标题翻译：锂离子电池用隔膜电极单元，锂电池的制造方法及其制造方法
公开(公告)号：US07858222B2
公开(公告)日：2010-12-28
申请号：US12846951
申请日：2010-07-30
申请人： Volker Hennige , Christian Hying , Gerhard Hoerpel , Sven Augustin
发明人： Volker Hennige , Christian Hying , Gerhard Hoerpel , Sven Augustin
IPC分类号： H01M2/26
CPC分类号： H01M10/0525 , H01M2/1646 , H01M2/1673 , H01M2/1686 , H01M4/0402 , H01M4/0471 , H01M4/13 , H01M10/052 , H01M10/0562 , H01M10/4235
摘要： The present invention relates to separator-electrode units for lithium batteries and also to a process for their production.The separator-electrode units comprise a porous electrode which is useful as a positive electrode (cathode) or negative electrode (anode) in a lithium battery and a separator layer applied to this electrode and are characterized in that the separator-electrode units comprise a purely inorganic separator layer which comprises at least two fractions of metal oxide particles which differ from each other in their average particle size and/or in the metal. More particularly, the separator layer comprises metal oxide particles having an average particle size (Dg) which is greater than the average pore size (d) of the pores of the porous positive electrode that are bonded together by metal oxide particles having a particle size (Dk) which is smaller than the pores of the porous electrode.The separator-electrode unit of the invention has the advantage that it is simple to manufacture as one component and, since the step of laminating the separator onto the electrode can be omitted, that it can comprise a large variation of materials. In addition, a separator-electrode unit according to the invention possesses excellent mechanical stability and a very low separator thickness, which is why it can even be used in lithium high energy batteries.
摘要翻译：本发明涉及锂电池用隔膜电极单元及其制造方法。分离电极单元包括可用作锂电池中的正电极（阴极）或负电极（阳极）的多孔电极和施加到该电极上的隔离层，其特征在于，隔膜 - 电极单元包括纯的无机分离器层，其包含在其平均粒度和/或金属中彼此不同的金属氧化物颗粒的至少两个级分。更具体地说，隔板层包括平均粒径（Dg）大于多孔正极的孔的平均孔径（d）的金属氧化物颗粒，该平均孔径（d）由具有颗粒尺寸的金属氧化物颗粒 Dk），其小于多孔电极的孔。本发明的隔膜 - 电极单元的优点在于，作为一个部件制造简单，并且由于可以省略将隔膜层压到电极上的步骤，所以可以包括大的材料变化。此外，根据本发明的隔膜 - 电极单元具有优异的机械稳定性和非常低的隔板厚度，这就是为什么甚至可以用于锂高能电池中的原因。

2. 发明授权

US08163441B2 Inorganic separator-electrode-unit for lithium-ion batteries, method for the production thereof and use thereof in lithium batteries 有权
标题翻译：锂离子电池用无机分离器电极单元及其制造方法及其在锂电池中的应用
公开(公告)号：US08163441B2
公开(公告)日：2012-04-24
申请号：US12559519
申请日：2009-09-15
申请人： Gerhard Hoerpel , Volker Hennige , Christian Hying , Sven Augustin
发明人： Gerhard Hoerpel , Volker Hennige , Christian Hying , Sven Augustin
IPC分类号： H01M4/50 , H01M2/16 , H01M10/50 , B05D5/12
CPC分类号： H01M10/052 , H01M2/1646 , H01M2/166 , H01M4/0404 , H01M4/131 , H01M4/1391 , H01M4/621 , H01M2004/027 , H01M2004/028 , Y10T29/49114
摘要： Separator-electrode assemblies (SEAs) comprise a porous electrode useful as a positive or negative electrode, in a lithium battery and a separator layer applied to this electrode, the separator layer being an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size and/or in the metal, and the electrode having active mass particles are bonded together and to the current collector by inorganic adhesive; and a process for their production.
摘要翻译：分离器 - 电极组件（SEA）包括可用作正电极或负电极的多孔电极，在锂电池中并且施加到该电极上的隔板层，隔离层是包含不同金属氧化物颗粒的至少两个部分的无机隔离层彼此之间的平均粒度和/或金属中，并且具有活性质量粒子的电极通过无机粘合剂结合在一起，并与集电体接合; 及其生产过程。

3. 发明授权

US08105733B2 Inorganic separator-electrode-unit for lithium-ion batteries, method for the production thereof and use thereof in lithium batteries 有权
标题翻译：锂离子电池用无机分离器电极单元及其制造方法及其在锂电池中的应用
公开(公告)号：US08105733B2
公开(公告)日：2012-01-31
申请号：US12559521
申请日：2009-09-15
申请人： Gerhard Hoerpel , Volker Hennige , Christian Hying , Sven Augustin
发明人： Gerhard Hoerpel , Volker Hennige , Christian Hying , Sven Augustin
IPC分类号： H01M4/50 , H01M2/16 , H01M10/50 , B05D5/12
CPC分类号： H01M10/052 , H01M2/1646 , H01M2/166 , H01M4/0404 , H01M4/131 , H01M4/1391 , H01M4/621 , H01M2004/027 , H01M2004/028 , Y10T29/49114
摘要： A process for producing a separator-electrode assemblies (SEAs) which comprises a porous electrode useful as a positive or negative electrode in a lithium battery and a separator layer applied to this electrode wherein the separator layer being an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size and/or in the metal, and the electrode having active mass particles that are bonded together and to a current collector by an inorganic adhesive; and the separator-electrode assembly comprises no organic polymer binder. The process comprising form the porous electrode by applying a suspension comprising active mass particles suspended in a sol or a dispersion of nanoscale active mass particles in a solvent and solidifying the suspension.
摘要翻译：一种用于制造分离器 - 电极组件（SEA）的方法，其包括用作锂电池中的正极或负极的多孔电极和施加到该电极的隔板层，其中隔板层是包含至少两个部分的无机隔离层的平均粒径和/或金属中彼此不同的金属氧化物颗粒，以及通过无机粘合剂结合在一起的活性质量粒子的电极和集电体; 并且分离器 - 电极组件不包括有机聚合物粘合剂。该方法包括通过将包含悬浮在溶胶中的活性物质颗粒或纳米级活性物质颗粒的分散体的悬浮液施加到溶剂中并固化该悬浮液来形成多孔电极。

4. 发明申请

US20160064712A1 USE OF A CERAMIC SEPARATOR IN LITHIUM-ION BATTERIES COMPRISING AN ELECTROLYTE COMPRISING IONIC LIQUIDS 审中-公开
标题翻译：在含有包含离子液体的电解质的锂离子电池中使用陶瓷分离器
公开(公告)号：US20160064712A1
公开(公告)日：2016-03-03
申请号：US14935841
申请日：2015-11-09
申请人： Gerhard HOERPEL , Volker Hennige , Christian Hying , Sven Augustin , Carsten Jost
发明人： Gerhard HOERPEL , Volker Hennige , Christian Hying , Sven Augustin , Carsten Jost
IPC分类号： H01M2/16 , H01M2/14 , H01M10/052 , H01M10/0566 , H01M10/0525
CPC分类号： H01M2/162 , H01M2/14 , H01M2/145 , H01M2/1626 , H01M2/1646 , H01M2/1666 , H01M8/0293 , H01M10/052 , H01M10/0525 , H01M10/0566 , H01M2300/0025 , H01M2300/0094 , Y02E60/122 , Y02E60/50 , Y02P70/54
摘要： The invention relates to a separator filled with an electrolyte composition, the separator having a ceramic surface and the electrolyte composition comprising an ionic liquid. The filling with the electrolyte composition can be effected for example by utilizing the separator in a battery, for example a lithium-ion battery, which has been filled with an appropriate electrolyte composition.
摘要翻译：本发明涉及一种填充有电解质组合物的隔膜，隔膜具有陶瓷表面，电解质组合物包含离子液体。电解质组合物的填充可以例如通过在已经填充有适当的电解质组合物的电池（例如锂离子电池）中利用隔膜来实现。

5. 发明授权

US07811700B2 Separator-electrode unit for lithium-ion batteries, method for the production and use thereof in lithium batteries 有权
标题翻译：锂离子电池用隔膜电极单元，锂电池的制造方法及其制造方法
公开(公告)号：US07811700B2
公开(公告)日：2010-10-12
申请号：US10524665
申请日：2003-07-04
申请人： Volker Hennige , Christian Hying , Gerhard Hoerpel , Sven Augustin
发明人： Volker Hennige , Christian Hying , Gerhard Hoerpel , Sven Augustin
IPC分类号： H01M2/26
CPC分类号： H01M10/0525 , H01M2/1646 , H01M2/1673 , H01M2/1686 , H01M4/0402 , H01M4/0471 , H01M4/13 , H01M10/052 , H01M10/0562 , H01M10/4235
摘要： The separator-electrode units comprise a porous electrode which is useful as a positive electrode (cathode) or negative electrode (anode) in a lithium battery and a separator layer applied to this electrode and are characterized in that the separator-electrode units comprise a purely inorganic separator layer which comprises at least two fractions of metal oxide particles which differ from each other in their average particle size and/or in the metal. More particularly, the separator layer comprises metal oxide particles having an average particle size (Dg) which is greater than the average pore size (d) of the pores of the porous positive electrode that are bonded together by metal oxide particles having a particle size (Dk) which is smaller than the pores of the porous electrode.
摘要翻译：分离电极单元包括可用作锂电池中的正电极（阴极）或负电极（阳极）的多孔电极和施加到该电极上的隔板层，其特征在于，隔板电极单元包括纯无机分离器层，其包含在其平均粒度和/或金属中彼此不同的金属氧化物颗粒的至少两个级分。更具体地说，隔板层包括平均粒径（Dg）大于多孔正极的孔的平均孔径（d）的金属氧化物颗粒，该平均孔径（d）由具有颗粒尺寸的金属氧化物颗粒 Dk），其小于多孔电极的孔。

6. 发明申请

US20070139860A1 Capacitor comprising a ceramic separating layer 失效
标题翻译：电容器包括陶瓷分离层
公开(公告)号：US20070139860A1
公开(公告)日：2007-06-21
申请号：US10575734
申请日：2004-08-19
申请人： Gerhard Hoerpel , Volker Hennige , Christian Hying , Sven Augustin
发明人： Gerhard Hoerpel , Volker Hennige , Christian Hying , Sven Augustin
IPC分类号： H01G4/06
CPC分类号： H01M2/162 , H01G9/02 , H01G9/155 , H01G11/04 , H01M2/145 , H01M2/1606 , Y02E60/13 , Y02T10/7022
摘要： An electrochemical capacitor including a separating layer on a support. The separating layer represents a porous inorganic, electrically non-conducting coating which is provided with particles of compounds of the elements Al, Si, and/or Zr, the particles being bonded to each other and to the support by an inorganic adhesive. The support can represent a porous electrode or a porous and planar substrate that is provided with polymer fibers.
摘要翻译：一种电化学电容器，其包括支撑体上的分离层。分离层表示多孔无机，不导电的涂层，其具有元素Al，Si和/或Zr的化合物颗粒，颗粒彼此结合并通过无机粘合剂粘合到载体上。支持体可以表示多孔电极或设置有聚合物纤维的多孔和平面基底。

7. 发明授权

US07525788B2 Capacitor comprising a ceramic separating layer 失效
标题翻译：电容器包括陶瓷分离层
公开(公告)号：US07525788B2
公开(公告)日：2009-04-28
申请号：US10575734
申请日：2004-08-19
申请人： Gerhard Hoerpel , Volker Hennige , Chistian Hying , Sven Augustin
发明人： Gerhard Hoerpel , Volker Hennige , Chistian Hying , Sven Augustin
IPC分类号： H01G9/00
CPC分类号： H01M2/162 , H01G9/02 , H01G9/155 , H01G11/04 , H01M2/145 , H01M2/1606 , Y02E60/13 , Y02T10/7022
摘要： An electrochemical capacitor including a separating layer on a support. The separating layer represents a porous inorganic, electrically non-conducting coating which is provided with particles of compounds of the elements Al, Si, and/or Zr, the particles being bonded to each other and to the support by an inorganic adhesive. The support can represent a porous electrode or a porous and planar substrate that is provided with polymer fibers.
摘要翻译：一种电化学电容器，包括支撑体上的分离层。分离层表示多孔无机，不导电的涂层，其具有元素Al，Si和/或Zr的化合物颗粒，颗粒彼此结合并通过无机粘合剂粘合到载体上。支持体可以表示多孔电极或设置有聚合物纤维的多孔和平面基底。

8. 发明授权

US09214659B2 Use of a ceramic separator in lithium ion batteries, comprising an electrolyte containing ionic fluids 有权
标题翻译：在锂离子电池中使用陶瓷隔膜，其包含含离子流体的电解质
公开(公告)号：US09214659B2
公开(公告)日：2015-12-15
申请号：US11578664
申请日：2005-02-24
申请人： Gerhard Hörpel , Volker Hennige , Christian Hying , Sven Augustin , Carsten Jost
发明人： Gerhard Hörpel , Volker Hennige , Christian Hying , Sven Augustin , Carsten Jost
IPC分类号： H01M2/16 , B05D3/00 , H01M2/14 , H01M8/02 , H01M10/0525 , H01M10/0566
CPC分类号： H01M2/162 , H01M2/14 , H01M2/145 , H01M2/1626 , H01M2/1646 , H01M2/1666 , H01M8/0293 , H01M10/052 , H01M10/0525 , H01M10/0566 , H01M2300/0025 , H01M2300/0094 , Y02E60/122 , Y02E60/50 , Y02P70/54
摘要： The invention relates to a separator filled with an electrolyte composition. The separator has a ceramic surface and the electrolyte composition comprises an ionic fluid. Filling with the electrolyte composition can take place, for example, by inserting the separator into a battery, e.g. into a lithium ion battery, which is filled with a corresponding electrolyte composition.
摘要翻译：本发明涉及填充有电解质组合物的隔膜。隔膜具有陶瓷表面，电解质组合物包含离子流体。填充电解质组合物可以例如通过将分离器插入电池中进行，例如，进入锂离子电池，其中填充有相应的电解质组合物。

9. 发明授权

US07829242B2 Inorganic separator-electrode-unit for lithium-ion batteries, method for the production thereof and use thereof in lithium batteries 有权
标题翻译：锂离子电池用无机分离器电极单元及其制造方法及其在锂电池中的应用
公开(公告)号：US07829242B2
公开(公告)日：2010-11-09
申请号：US11577542
申请日：2004-10-21
申请人： Gerhard Hörpel , Volker Hennige , Christian Hying , Sven Augustin
发明人： Gerhard Hörpel , Volker Hennige , Christian Hying , Sven Augustin
IPC分类号： H01M4/50 , H01M2/16 , H01M10/50 , B05D5/12
CPC分类号： H01M10/052 , H01M2/1646 , H01M2/166 , H01M4/0404 , H01M4/131 , H01M4/1391 , H01M4/621 , H01M2004/027 , H01M2004/028 , Y10T29/49114
摘要： Separator-electrode assemblies (SEAs) comprising a porous electrode useful as a positive or negative electrode in a lithium battery and a separator layer applied to this electrode, the separator layer being an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size and/or in the metal, and the electrode having active mass particles that are bonded together and to a current collector by an inorganic adhesive; and a process for their production.
摘要翻译：包含用作锂电池中的正极或负极的多孔电极和施加到该电极的隔离层的分离器电极组件（SEA），隔离层是包含至少两个不同于彼此平均粒度和/或金属，并且具有结合在一起的活性质量颗粒的电极和通过无机粘合剂的集电体; 及其生产过程。

10. 发明申请

US20080032197A1 Inorganic Separator-Electrode-Unit for Lithium-Ion Batteries, Method for the Production Thereof and Use Thereof in Lithium Batteries 有权
标题翻译：锂离子电池无机分离器 - 电极单元及其生产方法及其在锂电池中的应用
公开(公告)号：US20080032197A1
公开(公告)日：2008-02-07
申请号：US11577542
申请日：2004-10-21
申请人： Gerhard Horpel , Volker Hennige , Christian Hying , Sven Augustin
发明人： Gerhard Horpel , Volker Hennige , Christian Hying , Sven Augustin
IPC分类号： H01M4/48 , H01M4/08 , H01M4/36
CPC分类号： H01M10/052 , H01M2/1646 , H01M2/166 , H01M4/0404 , H01M4/131 , H01M4/1391 , H01M4/621 , H01M2004/027 , H01M2004/028 , Y10T29/49114
摘要： The present invention concerns separator-electrode assemblies for lithium batteries and also a process for their production. The separator-electrode assemblies (SEAs) comprise a porous electrode useful as an electrode, ie. Positive (cathode) or negative (anode) electrode, in a lithium battery and a separator layer applied to this electrode. The separator electrode assembly (SEA) is characterized in that it has an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size and/or in the metal, and an electrode whose active mass particles are bonded together and to the current collector by inorganic adhesive. The separator-electrode assembly of the invention has the advantage that it is simple to manufacture as one component and that distinctly higher temperatures can be employed in production than in the production of conventional separator-electrode assemblies, since the electrode does not contain heat-sensitive organic materials.
摘要翻译：本发明涉及用于锂电池的分离器 - 电极组件，以及它们的生产方法。分离器电极组件（SEA）包括可用作电极的多孔电极，即，在正极（阴极）或负极（阳极）电极中的锂电池和分隔层施加到该电极上。分离器电极组件（SEA）的特征在于其具有包含在平均粒径和/或金属中彼此不同的金属氧化物颗粒的至少两个部分的无机隔离层和活性质量颗粒为通过无机粘合剂结合在一起并与集电体接合。本发明的分离器 - 电极组件的优点在于，作为一个部件制造简单，并且在生产中可以使用明显更高的温度，而不是生产常规的隔离器 - 电极组件，因为电极不含有热敏感有机材料。

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