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    • 1. 发明授权
    • Superabsorbent polymer with slow absorption times
    • 超吸收性聚合物吸收时间慢
    • US07285614B2
    • 2007-10-23
    • US10660982
    • 2003-09-12
    • Gerd JonasKlaus PfluegerRüdiger Gerlach
    • Gerd JonasKlaus PfluegerRüdiger Gerlach
    • C08F20/06
    • A61L15/60
    • The invention relates to hydrophilic superabsorbent polymer comprising a) from about 55 to about 99.9 wt. % of polymerizable unsaturated acid group containing monomers; b) from about 0.001 to about 5.0 wt. % of internal crosslinking agent; c) from about 0.001 to about 5.0 wt. % of surface crosslinking agent applied to the particle surface; and d) wherein the composition has a degree of neutralization of more than about 20%, and from about 20 mole % to about 75 mole % of the unsaturated acid group containing monomers are neutralized with a first neutralizing agent, and from about 5 mole % to about 40 mole % of the unsaturated acid group containing monomers are neutralized with a second neutralizing agent; at a temperature of about 75° C. or less. Such hydrophilic superabsorbent polymers have an Absorption Time of about 5+10 a2 minutes or greater, where a is the mean particle size of the superabsorbent material in millimeters, a capacity of about 15 g/g or greater, a Drop Penetration Value of about 2 seconds or less, and a floatability of 50% or less.
    • 本发明涉及亲水性超吸收性聚合物,其包含a)约55至约99.9重量% %的含可聚合不饱和酸基团的单体; b)约0.001至约5.0wt。 %的内部交联剂; c)约0.001至约5.0wt。 施加到颗粒表面的表面交联剂的%; 和d)其中所述组合物的中和度大于约20%,并且约20摩尔%至约75摩尔%的所述不饱和酸基团的单体用第一中和剂中和,约5摩尔% 至约40摩尔%的含不饱和酸基团的单体用第二中和剂中和; 在约75℃或更低的温度下。 这样的亲水性超吸收性聚合物的吸收时间为约5 + 10分钟或更大,其中a为超吸收材料的平均粒度,单位为毫米,容量为约15g / g或更大 ,下降穿透值约2秒以下,浮选性为50%以下。